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1. 发明授权

US06812265B1 Liquid composition polymerizable into organic glasses having good optical and physico-mechanical properties 有权
标题翻译：可聚合成具有良好光学和物理机械性能的有机玻璃的液体组合物
公开(公告)号：US06812265B1
公开(公告)日：2004-11-02
申请号：US09830841
申请日：2001-05-01
申请人： Fiorenzo Renzi , Andrea Bendandi , Roberto Forestieri , Nereo Nodari
发明人： Fiorenzo Renzi , Andrea Bendandi , Roberto Forestieri , Nereo Nodari
IPC分类号： C08F246
CPC分类号： C08F18/24 , C07C68/06 , C07C69/96 , G02B1/04 , C08L31/00
摘要： Liquid composition which can be polymerized into organic glasses, by means of radical polymerization with low shrinkage, comprising the product obtained from the trans-esterification of a diallycarbonate (A) with a mixture of one or more linear or branched aliphatic diols (B), containing from three to ten carbon atoms in the molecule, with a linear or branched aliphatic polyol (C), containing from four to twenty carbon atoms and from three to six hydroxyl groups in the molecule. The molar ratio A/(B+C) in the above polymerizable liquid composition ranges from 2/1 to 5/1 and the quantity of (C) in the mixture (B+C) is equal to or less than 25% by weight with respect to the total weight of this mixture.
摘要翻译：可以通过低收缩的自由基聚合将聚合成有机玻璃的液体组合物包含由二烯丙基碳酸酯（A）与一种或多种直链或支链脂族二醇（B）的混合物的酯交换获得的产物，在分子中含有3至10个碳原子的直链或支链脂族多元醇（C），其分子中含有4至20个碳原子和3至6个羟基。上述可聚合液体组合物中的摩尔比A /（B + C）为2/1〜5/1，混合物（C + C）的量（B + C）为25重量％相对于该混合物的总重量。

2. 发明授权

US06686401B1 Liquid composition polymerizable into organic glass having good optical and physico-mechanical properties 失效
标题翻译：可聚合成有机玻璃的液体组合物具有良好的光学和物理机械性能
公开(公告)号：US06686401B1
公开(公告)日：2004-02-03
申请号：US10069600
申请日：2002-05-16
申请人： Fiorenzo Renzi , Andrea Bendandi , Roberto Forestieri
发明人： Fiorenzo Renzi , Andrea Bendandi , Roberto Forestieri
IPC分类号： C08F246
CPC分类号： C08G63/64 , C07C69/96 , C08F218/00 , C08F218/16 , C08F218/18 , C08F290/061 , G02B1/041 , C08L31/00
摘要： Liquid composition polymerizable, by means of radicalic polymerization, into organic glass, comprising the product obtained from the transesterification of a mixture of diallyl carbonate (A) and a phthalic ester (B), with one or more polyols (C), linear or branced, containing from two to eight carbon atoms in the molecule.
摘要翻译：通过自由基聚合将液体组合物聚合成有机玻璃，其包含由二烯丙基碳酸酯（A）和邻苯二甲酸酯（B）的混合物酯交换得到的产物与一种或多种线性或分散的多元醇（C），在分子中含有2至8个碳原子。

3. 发明申请

US20130066034A1 POLYMERIZATION CATALYST FOR POLYTHIOURETHANES, POLYMERIZABLE LIQUID COMPOSITION AND PROCESS FOR THE PRODUCTION OF ORGANIC POLYTHIOURETHANE GLASS WITH A HIGH REFRACTIVE INDEX 审中-公开
标题翻译：聚异氰脲酸聚合催化剂，可聚合液体组合物和生产具有高折射率指数的有机聚四氟乙烯玻璃的方法
公开(公告)号：US20130066034A1
公开(公告)日：2013-03-14
申请号：US13699176
申请日：2011-05-20
申请人： Fiorenzo Renzi , Roberto Forestieri , Andrea Vecchione , Willem Bos
发明人： Fiorenzo Renzi , Roberto Forestieri , Andrea Vecchione , Willem Bos
IPC分类号： C08G18/28 , B29C39/38 , C08F4/00
CPC分类号： G02B1/041 , C08G18/089 , C08G18/18 , C08G18/3876 , C08G18/758 , C08G2125/00 , G02B1/04 , G02B1/043 , G11B7/2533 , C08L75/04 , C08L81/00
摘要： Polymerization catalysts for organic polythiourethane glass which do not contain organometallic compounds contain a mixture of a tertiary aliphatic amine and a disubstituted phosphoric acid in a molar ratio ranging from 1/1.3 to 1/20. Polymerizable liquid compositions containing three components (A), (B) and (C) are also provided, wherein component (A) contains at least one cycloaliphatic diisocyanate monomer wherein the weight percentage of free isocyanate groups in component (A) ranges from about 20% to about 50% by weight with respect to the total weight of component (A); component (B) contains at least one polythiol having a molecular weight ranging from 50 to 1,200 g/moles and a functionality ranging from 2 to 5, said components (A) and (B) being present in a weight ratio varying from 0.5:1 to 2:1; and component (C) being said polymerization catalyst. A process for the production of organic glass using the polymerizable liquid composition is further provided.
摘要翻译：不含有机金属化合物的有机聚硫氨酯玻璃的聚合催化剂含有1 / 1.3〜1/20摩尔比的叔脂族胺和二取代磷酸的混合物。还提供了含有三种组分（A），（B）和（C）的可聚合液体组合物，其中组分（A）含有至少一种脂环族二异氰酸酯单体，其中组分（A）中游离异氰酸酯基团的重量百分数为约20 相对于组分（A）的总重量为约50重量％至约50重量％组分（B）含有至少一种分子量为50至1,200g / mol且官能度为2至5的多硫醇，所述组分（A）和（B）以0.5:1的重量比存在至2：1; 和组分（C）是所述聚合催化剂。还提供了使用可聚合液体组合物生产有机玻璃的方法。

4. 发明申请

US20060217506A1 Liquid composition polymerizable into organic glass having good optical and physico-mechanical characteristics 审中-公开
标题翻译：可聚合成有机玻璃的液体组合物具有良好的光学和物理机械特性
公开(公告)号：US20060217506A1
公开(公告)日：2006-09-28
申请号：US10552368
申请日：2004-04-06
申请人： Fiorenzo Renzi , Willem Bos , Simon Postmus , Roberto Forestieri
发明人： Fiorenzo Renzi , Willem Bos , Simon Postmus , Roberto Forestieri
IPC分类号： C08F4/28
CPC分类号： C08F218/00 , G02B1/041
摘要： A liquid composition is described, which can undergo radicalic polymerization into organic glass, comprising: 1) the product obtained from the transesterification of diallyl carbonate (A) with a blend of one or more linear or branched aliphatic diols (B), containing from three to ten carbon atoms in the molecule, with a linear or branched aliphatic polyol (C), containing from four to twenty carbon atoms and from three to six hydroxyl groups in the molecule, in an overall concentration ranging from 70 to 100% by weight with respect to the total weight of the mixture of components 1) and 2); 2) one or more comonomers of the acrylic, methacrylic, vinylic or allylic type and mixtures thereof, in an overall concentration ranging from 0 to 30% by weight with respect to the total weight of the mixture of components 1) and 2); 3) a polymerization initiator or a mixture of two or more polymerization initiators, stable at room temperature, belonging to the group of peroxides, in an overall concentration ranging from 0.03 to 0.1 moles per 1 kg of final composition
摘要翻译：描述了可以经历自由基聚合成有机玻璃的液体组合物，其包括：1）由二烯丙基碳酸酯（A）与一种或多种直链或支链脂族二醇（B）的共混物的酯交换获得的产物，其含有三与分子中含有4至20个碳原子和3至6个羟基的直链或支链脂族多元醇（C）的总碳浓度在70至100重量％之间，分子中具有10个碳原子，相对于组分1）和2）的混合物的总重量; 2）一种或多种丙烯酸，甲基丙烯酸，乙烯基或烯丙基类型的共聚单体及其混合物，其总浓度相对于组分1）和2）的混合物的总重量为0至30重量％。 3）聚合引发剂或两种或多种聚合引发剂的混合物，其在室温下稳定，属于过氧化物基团，总浓度范围为每1kg最终组合物为0.03至0.1摩尔

5. 发明申请

US20110251301A1 POLYMERIZABLE LIQUID COMPOSITION AND PROCESS FOR THE PRODUCTION OF ORGANIC GLASS STARTING FROM POLYMERIZABLE LIQUID COMPOSITIONS OF THE POLYURETHANE TYPE 有权
标题翻译：可聚合液体组合物和从聚氨酯类聚合物组合物开始生产有机玻璃的方法
公开(公告)号：US20110251301A1
公开(公告)日：2011-10-13
申请号：US13124570
申请日：2009-10-14
申请人： Willem Bos , Fiorenzo Renzi , Roberto Forestieri , Andrea Vecchione
发明人： Willem Bos , Fiorenzo Renzi , Roberto Forestieri , Andrea Vecchione
IPC分类号： C08L75/08 , B29C45/00 , C08K5/17 , G02C7/04 , C08G18/75 , C08K5/08
CPC分类号： C08G18/089 , C08G18/168 , C08G18/3206 , C08G18/75 , G02B1/041 , Y10T428/1036 , Y10T428/31551 , C08L75/04
摘要： Polymerizable liquid compositions of the polyurethane type, consisting of two components (A) and (B), wherein component (A) contains at least one cyclo-aliphatic diisocyanate monomer or a mixture of one cyclo-aliphatic diisocyanate monomer and a pre-polymer obtained by reaction, in the presence of an acid phosphate ester catalyst, between said cyclo-aliphatic diisocyanate monomer and one or more polyols having two or more hydroxy 1 groups per molecule and a molecular weight ranging from 50 to 2,000 g/mole; the second component (B) contains one or more polyols having a molecular weight ranging from 50 to 2,000 g/mole and a functionality between 2 and 5; in the absence of polyalkoxylated tertiary diamines and organometallic catalysts, said components (A) and (B) being present in a weight ratio which varies from 1:1 to 2:1 and the process for the production of organic glass starting from polymerizable liquid compositions of the polyurethane type.
摘要翻译：聚氨酯类型的可聚合液体组合物由两种组分（A）和（B）组成，其中组分（A）含有至少一种环脂族二异氰酸酯单体或一种环脂族二异氰酸酯单体和获得的预聚物的混合物在酸性磷酸酯催化剂的存在下，在所述环脂族二异氰酸酯单体和一种或多种每分子具有两个或多个羟基1的多元醇和分子量为50-2,000g / mol的反应中，第二组分（B）含有一种或多种分子量范围为50-2,000g / mol且官能度在2和5之间的多元醇; 在不存在聚烷氧基化二叔胺和有机金属催化剂的情况下，所述组分（A）和（B）以1:1至2:1的重量比存在，以及从可聚合液体组合物开始制备有机玻璃的方法的聚氨酯类型。

6. 发明授权

US08829147B2 Polymerizable liquid composition and process for the production of organic glass starting from polymerizable liquid compositions of the polyurethane type 有权
标题翻译：可聚合液体组合物和从聚氨酯类型的可聚合液体组合物开始生产有机玻璃的方法
公开(公告)号：US08829147B2
公开(公告)日：2014-09-09
申请号：US13124570
申请日：2009-10-14
申请人： Willem Bos , Fiorenzo Renzi , Roberto Forestieri , Andrea Vecchione
发明人： Willem Bos , Fiorenzo Renzi , Roberto Forestieri , Andrea Vecchione
IPC分类号： B29D22/00 , B32B3/02 , B32B27/00 , B32B27/40 , B64C1/10 , B64C1/14 , B64D7/00 , B64D17/02 , C08G18/00 , C08G18/08 , C08G18/10 , C08G18/22 , C08G18/28 , C08G18/30 , C08G18/70 , C08J5/00 , C08L75/00 , C09K19/00 , E06B3/00 , F16L9/00 , G02B6/00 , G02C7/02
CPC分类号： C08G18/089 , C08G18/168 , C08G18/3206 , C08G18/75 , G02B1/041 , Y10T428/1036 , Y10T428/31551 , C08L75/04
摘要： Polymerizable liquid compositions of the polyurethane type, consisting of two components (A) and (B), wherein component (A) contains at least one cyclo-aliphatic diisocyanate monomer or a mixture of one cyclo-aliphatic diisocyanate monomer and a pre-polymer obtained by reaction, in the presence of an acid phosphate ester catalyst, between said cyclo-aliphatic diisocyanate monomer and one or more polyols having two or more hydroxy 1 groups per molecule and a molecular weight ranging from 50 to 2,000 g/mole; the second component (B) contains one or more polyols having a molecular weight ranging from 50 to 2,000 g/mole and a functionality between 2 and 5; in the absence of polyalkoxylated tertiary diamines and organometallic catalysts, said components (A) and (B) being present in a weight ratio which varies from 1:1 to 2:1 and the process for the production of organic glass starting from polymerizable liquid compositions of the polyurethane type.
摘要翻译：聚氨酯类型的可聚合液体组合物由两种组分（A）和（B）组成，其中组分（A）含有至少一种环脂族二异氰酸酯单体或一种环脂族二异氰酸酯单体和获得的预聚物的混合物在酸性磷酸酯催化剂的存在下，在所述环脂族二异氰酸酯单体和一种或多种每分子具有两个或多个羟基1的多元醇和分子量为50-2,000g / mol的反应中，第二组分（B）含有一种或多种分子量范围为50-2,000g / mol且官能度在2和5之间的多元醇; 在不存在聚烷氧基化二叔胺和有机金属催化剂的情况下，所述组分（A）和（B）以1:1至2:1的重量比存在，以及从可聚合液体组合物开始制备有机玻璃的方法的聚氨酯类型。

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