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    • 3. 发明授权
    • Blowing agent combination comprising azodicarbonamide, zinc oxide and a
benzenethiol sulphonic acid derivative
    • 包含偶氮二甲酰胺,氧化锌和苯硫醇磺酸衍生物的发泡剂组合
    • US4263165A
    • 1981-04-21
    • US147588
    • 1980-05-07
    • Ernst RoosWerner JeblickHelmut Hurnik
    • Ernst RoosWerner JeblickHelmut Hurnik
    • C09K3/00C08J9/06C08J9/10
    • C08J9/103Y10S264/05
    • A blowing agent combination comprising azodicarbonamide, zinc oxide and a benzenethiol sulphonic acid derivative having the general formula (I) ##STR1## wherein R is a hydrogen atom, a C.sub.1 -C.sub.4 alkyl radical and/or a chlorine atom,X is a number from 1 to 5, andR' is a C.sub.1 -C.sub.4 alkyl radical, a C.sub.5 -C.sub.6 cycloalkyl radical or a C.sub.7 -C.sub.8 arylalkyl radical each of these radicals being optionally substituted by from 1 to 3 C.sub.1 -C.sub.4 alkyl radicals, from 1 to 5 chlorine atoms and/or a carboxylic acid C.sub.1 -C.sub.4 alkyl ester radical, or a radical having one of the general formulae (11a), (11b), (11c) or (11d). ##STR2## in which y is a number from 0 to 3,R" is a C.sub.1 -C.sub.6 alkylene radical or a xylylene radical which is optionally substituted by from 1 to 4 methyl radicals and/or from 1-4 chlorine atoms and R and X are as defined above;may be used as blowing agents.
    • 包含偶氮二酰胺,氧化锌和具有通式(I)的苯硫醇磺酸衍生物的发泡剂组合,其中R是氢原子,C1-C4烷基和/或氯原子,X是一个 1至5,并且R'是C 1 -C 4烷基,C 5 -C 6环烷基或C 7 -C 8芳基烷基,这些基团各自任选被1至3个C 1 -C 4烷基取代,1至5个 氯原子和/或羧酸C1-C4烷基酯基,或具有通式(11a),(11b),(11c)或(11d)之一的基团。 其中y是0至3的数,R“是任选被1至4个甲基和/或1-4个氯取代的C 1 -C 6亚烷基或亚二甲苯基 原子和R和X如上所定义; 可用作发泡剂。
    • 4. 发明授权
    • Mixtures of azodicarbonamide and .alpha.-amidosulphones and their
production and use as a blowing agent
    • 偶氮二甲酰胺和α-氨基砜的混合物及其生产和用作发泡剂
    • US4280004A
    • 1981-07-21
    • US189736
    • 1980-09-22
    • Werner JeblickErnst RoosTheo KempermannManfred Abele
    • Werner JeblickErnst RoosTheo KempermannManfred Abele
    • C08J9/06C07C67/00C07C313/00C07C317/28C07C325/00C07C335/08C08J9/10
    • C08J9/102Y10S264/05Y10S521/91
    • A mixture of azodicarbonamide and an .alpha.-amidosulphone corresponding to the general formula: ##STR1## in which R represents hydrogen, a C.sub.1 -C.sub.4 -alkyl residue and/or halogen,x represents numbers from 0 to 5,y represents numbers from 1 to 3, corresponding to the valency of R.sub.1,R.sup.1 represents an aromatic carboxylic acid residue or sulphonic acid residue with 6 carbon atoms, which is optionally substituted once or several times by halogen, C.sub.1 -C.sub.4 alkyl residues, C.sub.1 -C.sub.4 alkoxy residues, nitro and/or cyano, or represents an aliphatic carboxylic acid residue or a sulphonic acid residue with 1-4 carbon atoms, a carbonic acid residue, a thiocarbonic acid residue or a phosphoric acid residue which, corresponding to the numerical value of y, contains 0-2 phenoxy residues or C.sub.1 -C.sub.4 alkoxy residues optionally substituted with C.sub.1 -C.sub.4 alkyl or halogen,R.sup.2 represents R.sup.1, or hydrogen, a C.sub.1 -C.sub.4 alkyl residue, a C.sub.5 -C.sub.7 cycloalkyl residue, a phenyl residue, which is optionally substituted once or several times by C.sub.1 -C.sub.4 -alkyl or halogen, a phenyl alkyl residue whose phenyl group is optionally substituted once or several times by C.sub.1 -C.sub.4 -alkyl or halogen and whose alkyl group has 1-3 carbon atoms or R.sub.1 and R.sub.2 together with the nitrogen atom form a cyclic lactam ring which has 4-6 carbon atoms, can be used as a blowing agent for rubber.
    • 对应于以下通式的偶氮二甲酰胺和α-氨基砜的混合物:其中R表示氢,C1-C4烷基和/或卤素,其中x表示0至5的数,y表示1至 3,对应于R1的化合价,R1表示具有6个碳原子的芳族羧酸残基或磺酸残基,其任选被卤素,C 1 -C 4烷基残基,C 1 -C 4烷氧基残基,硝基和 /或氰基,或表示具有1-4个碳原子的脂族羧酸残基或磺酸残基,对应于y的数值的碳酸残基,硫代碳酸残基或磷酸残基含有0- 2个苯氧基残基或任选被C 1 -C 4烷基或卤素取代的C 1 -C 4烷氧基残基,R 2表示R 1或氢,C 1 -C 4烷基残基,C 5 -C 7环烷基残基,苯基残基,其任选被一次取代或 几次 通过C 1 -C 4烷基或卤素取代苯基烷基,其苯基任选被C 1 -C 4烷基或卤素取代一次或几次,并且其烷基具有1-3个碳原子,或者R 1和R 2与氮原子一起 形成具有4-6个碳原子的环状内酰胺环,可以用作橡胶的发泡剂。
    • 5. 发明授权
    • Pest-combating agents containing phosphorus-heterocyclic compounds
    • 含有磷杂环化合物的抗虫剂
    • US4678777A
    • 1987-07-07
    • US762979
    • 1985-08-06
    • Bernd-Wieland KrugerHellmut HoffmannErnst RoosWolfgang Behrenz
    • Bernd-Wieland KrugerHellmut HoffmannErnst RoosWolfgang Behrenz
    • A01N57/36C07F9/6571
    • C07F9/657181A01N57/36C07F9/657118C07F9/657127C07F9/657154
    • An arthropodicidal composition comprising an arthropodicidally effective amount of an arthropodicidally active compound and a synergistically effective amount of at least one compound of the formula ##STR1## in which A is amino, alkylamino, dialkylamino or N-alkyl-N-arylamino, or an optionally substituted alkyl, alkenyl, alkoxy, alkenyloxy, alkylthio, aralkyl, aralkoxy, phenyl, phenoxy or phenylthio radical,R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently is hydrogen, or an optionally halogen-substituted alkyl, alkenyl, alkoxyalkyl or alkylthioalkyl radical, or is halogen, nitro or dialkylaminoalkyl, or is optionally substituted phenyl or benzyl, or two of the radicals R.sup.1 to R.sup.8, together with the carbon atom or atoms to which they are bonded form an optionally substituted monocyclic or bicyclic ring andn and m each independently is 0 or 1.
    • 一种节肢动物杀伤组合物,其包含节肢动物节肢动物有效量的节肢动物杀虫活性化合物和协同有效量的至少一种下式的化合物,其中A是氨基,烷基氨基,二烷基氨基或N-烷基-N-芳基氨基,或任选地 取代的烷基,烯基,烷氧基,烯氧基,烷硫基,芳烷基,芳烷氧基,苯基,苯氧基或苯硫基,R1,R2,R3,R4,R5,R6,R7和R8各自独立地为氢或任选卤素取代的烷基, 烯基,烷氧基烷基或烷硫基烷基,或为卤素,硝基或二烷基氨基烷基,或任选取代的苯基或苄基,或两个基团R 1至R 8与它们所连接的碳原子或原子一起形成任选取代的单环或 双环,n和m各自独立地为0或1。