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1. 发明申请

US20100034961A1 PHOTOSTABILIZED TIME TEMPERATURE INDICATOR 审中-公开
标题翻译：光照时间温度指示器
公开(公告)号：US20100034961A1
公开(公告)日：2010-02-11
申请号：US12522559
申请日：2007-12-28
申请人： Elena Tenetov , Husein Salman , Julien Assous , Leonhard Feiler , Thomas Raimann
发明人： Elena Tenetov , Husein Salman , Julien Assous , Leonhard Feiler , Thomas Raimann
IPC分类号： B05D3/10 , C07D209/96
CPC分类号： C09K9/02 , C09K2211/1029 , C09K2211/1088 , G01N31/229
摘要： The present invention relates to time-temperature indicator (TTI) systems comprising spiropyran indicator of formula (I) wherein R1 is hydrogen, —C1-C6 alkoxy, halogen, —C1-C6 alkyl or —NO2, R2 is hydrogen or —C1-C6 alkoxy; R3 is NO2 halogen; R4 is hydrogen, —C1-C6 alkoxy or halogen; R5 is hydrogen, halogen, —C1-C6 alkoxy, —COOH, —COO—C1-C6alkyl, —CF3 or phenyl; R11 hydrogen or R11 and R5 form together a phenyl ring; Y is phenyl, naphthyl, anthracen-9-yl, 9H-fluoren-9-yl or a residue Formula (A) wherein R6 is hydrogen, halogen, —C1-C6 alkoxy, —NO2, —CF3, —O—CF3, —CN, —COO—C1-C6alkyl, phenyl or biphenyl, 9H-fluoren-9-yl; R7 is hydrogen, halogen, —CN,—C1-C6 alkoxy or R7 and R6 form together a phenyl ring; R8 is hydrogen, halogen, —CN, or —C1-C6 alkoxy; R9 is hydrogen or halogen or CN. R10 is hydrogen or halogen or CN. Ra is —(CH2)n- with n=1-6 or —CH2—CH═CH—. With the proviso that Formula (B) and Formula (C) are excluded.
摘要翻译：本发明涉及包含式（I）的螺吡喃指示剂的时间 - 温度指示剂（TTI）系统，其中R 1是氢，-C 1 -C 6烷氧基，卤素，-C 1 -C 6烷基或-NO 2，R 2是氢或-C1- C6烷氧基 R3是NO2卤素; R4是氢，-C 1 -C 6烷氧基或卤素; R 5是氢，卤素，-C 1 -C 6烷氧基，-COOH，-COO-C 1 -C 6烷基，-CF 3或苯基; R11氢或R11和R5一起形成苯环; Y是苯基，萘基，蒽-9-基，9H-芴-9-基或其中R 6是氢，卤素，-C 1 -C 6烷氧基，-NO 2，-CF 3，-O-CF 3， -CN，-COO-C 1 -C 6烷基，苯基或联苯基，9H-芴-9-基; R7是氢，卤素，-CN，-C1-C6烷氧基或R7和R6一起形成苯环; R8是氢，卤素，-CN或-C1-C6烷氧基; R9是氢或卤素或CN。 R 10是氢或卤素或CN。 R a为 - （CH 2）n - ，其中n = 1-6或-CH 2 -CH-CH-。条件是排除式（B）和式（C）。

2. 发明申请

US20110059545A1 TIME-TEMPERATURE INDICATOR BASED ON OLIGOMERIC SPIROAROMATICS 审中-公开
标题翻译：基于低压螺旋桨的时间温度指示器
公开(公告)号：US20110059545A1
公开(公告)日：2011-03-10
申请号：US12523110
申请日：2008-01-14
申请人： Husein Salman , Elena Tenetov , Leonhard Feiler , Thomas Raimann
发明人： Husein Salman , Elena Tenetov , Leonhard Feiler , Thomas Raimann
IPC分类号： G01N21/00 , C07D209/96
CPC分类号： C09K9/02 , C09K2211/1029 , C09K2211/1088 , G01D7/005 , G01N31/229
摘要： The present invention relates to a time temperature indicator for indicating a temperature change over time comprising one dimeric or trimeric spiropyran indicator of the formula I or II wherein R1-R4 independently of one another is hydrogen, —C1C6 alkoxy, halogen, CF3, —C1C6 alkyl or —NO2, R5 is hydrogen, halogen, —C1-C6 alkoxy, —COOH, —COO—C1-C6 alkyl, —CF3 or phenyl; R11 is hydrogen or R11 and R5 form together a phenyl ring; Ra is —C1-C6 alkyl Rb is —C1-C6 alkyl, or together with Ra form a 5-6 membered ring L is a divalent linker; L′ is a trivalent linker.
摘要翻译：本发明涉及用于指示随时间的温度变化的时间温度指示剂，包括一种式I或II的二聚或三聚螺吡喃指示剂，其中R 1 -R 4彼此独立地是氢，-C 1 -C 6烷氧基，卤素，CF 3，-C 1 C 6 烷基或-NO 2，R 5是氢，卤素，-C 1 -C 6烷氧基，-COOH，-COO-C 1 -C 6烷基，-CF 3或苯基; R 11是氢或R 11和R 5一起形成苯环; R a为-C 1 -C 6烷基，R b为-C 1 -C 6烷基，或与R a一起形成5-6元环L为二价连接基; L'是三价接头。

3. 发明申请

US20110287549A1 TIME TEMPERATURE INDICATOR BASED ON THIOALKYL AND THIOARYL SUBSTITUTED SPIROAROMATICS 审中-公开
标题翻译：基于THIOALKYL和THIOARYL替代螺旋体的时间温度指示
公开(公告)号：US20110287549A1
公开(公告)日：2011-11-24
申请号：US13146230
申请日：2010-02-09
申请人： Husein Salman , Elena Tenetov
发明人： Husein Salman , Elena Tenetov
IPC分类号： G01N21/78 , B05D3/02 , G01D21/00 , C07D491/107
CPC分类号： C09K9/02 , C09K2211/1007 , C09K2211/1029 , C09K2211/1088 , Y10T436/141111
摘要： The present invention relates to photochromic spiropyrans as active ingredients of Time-Temperature Indicators (TTIs), and to new spiropyrans per se. More particularly, the invention provides TTIs on the base of photochromic spiropyrans comprising alkylsulfanyl/arylsulfanyl substituents in the phenyl ring of the benzopyrane moiety.
摘要翻译：本发明涉及作为时间 - 温度指示剂（TTI）的活性成分的光致变色螺吡喃，以及新的螺吡喃本身。更具体地，本发明提供了在苯并吡喃部分的苯环中包含烷基硫烷基/芳基硫烷基取代基的光致变色螺吡喃基的TTI。

4. 发明申请

US20110281742A1 METHOD FOR IDENTIFYING ELECTROPHILES AND NUCLEOPHILES IN A SAMPLE 审中-公开
标题翻译：在样品中鉴定电极和核酸的方法
公开(公告)号：US20110281742A1
公开(公告)日：2011-11-17
申请号：US13086486
申请日：2011-04-14
申请人： Yoav Eichen , Shay Tal , Yael Abraham , Husein Salman , Elana Borzin , Carmit Hertzog-Ronen
发明人： Yoav Eichen , Shay Tal , Yael Abraham , Husein Salman , Elana Borzin , Carmit Hertzog-Ronen
IPC分类号： C40B30/00 , C40B40/00
CPC分类号： G01N31/22 , G01N31/223 , G01N31/224 , G01N33/0036 , G01N33/0057 , G01N2021/6439 , G01N2021/773 , Y10T436/23
摘要： A method and device for identifying a molecule in a sample, the molecule comprising an electrophilic or nucleophilic moiety. The method comprises contacting the sample with a plurality of chemosensors, each of the chemosensors comprising a π-conjugated system and a moiety having a nucleophilic property or an electrophilic property; and measuring an electromagnetic property of each of the chemosensors in the sample; whereby the pattern of changes in the electromagnetic properties of the plurality of chemosensors after chemically reacting with the electrophile or nucleophile of the molecule identifies the molecule in said sample. The device comprises a substrate carrying a plurality of chemosensor molecules having at least one predetermined electromagnetic property, the at least one electromagnetic property being changeable by subjecting the chemosensor molecules to a sample containing at least one electrophile or nuclephile, wherein the pattern of change of the electromagnetic property of the plurality of chemosensor molecules allows the device to identify the electrophile or nuclephile in the sample.
摘要翻译：用于鉴定样品中分子的方法和装置，所述分子包含亲电子部分或亲核部分。该方法包括使样品与多个化学传感器接触，每个化学传感器包含共轭结构体系和具有亲核性质或亲电性质的部分; 并测量样品中每种化学传感器的电磁特性; 由此在与分子的亲电子试剂或亲核试剂发生化学反应之后，多种化学传感器的电磁特性的变化模式识别所述样品中的分子。该装置包括承载多个具有至少一个预定电磁特性的化学传感器分子的衬底，所述至少一个电磁特性可通过使化学传感器分子经受至少一种亲电子试剂或核仁的样品而变化，其中，多个化学传感器分子的电磁特性允许该装置鉴定样品中的亲电试剂或核仁。

5. 发明申请

US20100296545A1 TIME TEMPERATURE INDICATOR 有权
标题翻译：时间温度指示器
公开(公告)号：US20100296545A1
公开(公告)日：2010-11-25
申请号：US12522562
申请日：2007-12-28
申请人： Dietrich Haarer , Tali Gueta-Neyroud , Husein Salman
发明人： Dietrich Haarer , Tali Gueta-Neyroud , Husein Salman
IPC分类号： G01K3/04 , B32B37/14
CPC分类号： G01N31/229 , G01K3/04 , G01K11/12 , G01N21/78 , G01N31/22 , G01N2021/773 , Y10S252/962
摘要： The present invention is generally in the field of measuring and indicating techniques and relates to a time-temperature indicator and methods of manufacturing and use thereof. More specifically, the time-temperature indicator comprises a time temperature indicator comprising at least one metal layer or metal containing layer and in direct contact to the metal layer or to the metal containing layer at least one doped polymer layer, wherein the dopant is an acid, a base or a salt or a photolatent acid or a photolatent base which dopant is added to the polymer, and/or at least one polymer layer wherein a polymer is functionalized with acidic or latent acidic or basic or latent basic groups; or a time temperature indicator comprising at least one polymer layer containing metal particles and a photolatent acid or a photolatent base, or at least one polymer layer containing metal particles wherein the polymer is functionalized with latent acidic or latent basic groups.
摘要翻译：本发明通常在测量和指示技术领域中，并且涉及一种时间温度指示器及其制造和使用方法。更具体地，时间 - 温度指示器包括时间温度指示器，其包括至少一个金属层或金属含有层，并且与至少一个掺杂聚合物层直接接触金属层或含金属层，其中掺杂剂是酸，碱或盐或光潜酸或光潜碱，其中掺杂剂加入到聚合物中，和/或至少一个聚合物层，其中聚合物用酸性或潜酸性或碱性或潜碱性基团官能化; 或包含至少一个含有金属颗粒和光潜酸或光潜剂基质的聚合物层的时间温度指示剂，或包含金属颗粒的至少一个聚合物层，其中所述聚合物用潜在的酸性或潜在碱性基团官能化。

6. 发明申请

US20110155043A1 TIME TEMPERATURE INDICATOR 有权
标题翻译：时间温度指示器
公开(公告)号：US20110155043A1
公开(公告)日：2011-06-30
申请号：US13001049
申请日：2009-06-15
申请人： Dietrich Haarer , Tal Gueta-Neyroud , Husein Salman
发明人： Dietrich Haarer , Tal Gueta-Neyroud , Husein Salman
IPC分类号： G01D21/00 , B32B37/00
CPC分类号： G01K3/04
摘要： The present invention is generally in the field of measuring and indicating techniques and relates to a time-temperature indicator and methods of manufacturing and use thereof. More specifically, the time-temperature indicator comprises at least one metal layer or metal containing layer, and in direct contact to the metal layer or to the metal containing layer at least one pad member affixed onto a pad carrier layer,wherein the pad member comprises a pad made of an absorbent material and a dopant medium, whereby the dopant medium comprises a liquid medium or a viscous medium or a viscoelastic medium which is doped with a dopant that destroys the metal/metal containing layers such as an acid, a base or a salt or a photolatent acid or a photolatent base.
摘要翻译：本发明通常在测量和指示技术领域中，并且涉及一种时间温度指示器及其制造和使用方法。更具体地，时间 - 温度指示器包括至少一个金属层或含金属层，并且与金属层或金属含有层直接接触固定到衬垫载体层上的至少一个衬垫构件，其中衬垫构件包括由吸收材料制成的垫和掺杂剂介质，由此掺杂剂介质包括液体介质或粘性介质或粘弹性介质，其掺杂有破坏含金属/金属的层的掺杂剂，例如酸，碱或盐或光潜酸或光潜碱。

7. 发明授权

US09011794B2 Time temperature indicator 有权
标题翻译：时间温度指示器
公开(公告)号：US09011794B2
公开(公告)日：2015-04-21
申请号：US12522562
申请日：2007-12-28
申请人： Dietrich Haarer , Tal Gueta-Neyroud , Husein Salman
发明人： Dietrich Haarer , Tal Gueta-Neyroud , Husein Salman
IPC分类号： G01N33/00 , G01K3/04
CPC分类号： G01N31/229 , G01K3/04 , G01K11/12 , G01N21/78 , G01N31/22 , G01N2021/773 , Y10S252/962
摘要： The present invention is generally in the field of measuring and indicating techniques and relates to a time-temperature indicator and methods of manufacturing and use thereof. More specifically, the time-temperature indicator comprises a time temperature indicator comprising at least one metal layer or metal containing layer and in direct contact to the metal layer or to the metal containing layer at least one doped polymer layer, wherein the dopant is an acid, a base or a salt or a photolatent acid or a photolatent base which dopant is added to the polymer, and/or at least one polymer layer wherein a polymer is functionalized with acidic or latent acidic or basic or latent basic groups; or a time temperature indicator comprising at least one polymer layer containing metal particles and a photolatent acid or a photolatent base, or at least one polymer layer containing metal particles wherein the polymer is functionalized with latent acidic or latent basic groups.
摘要翻译：本发明通常在测量和指示技术领域中，并且涉及一种时间温度指示器及其制造和使用方法。更具体地，时间 - 温度指示器包括时间温度指示器，其包括至少一个金属层或金属含有层，并且与至少一个掺杂聚合物层直接接触金属层或含金属层，其中掺杂剂是酸，碱或盐或光潜酸或光潜碱，其中掺杂剂加入到聚合物中，和/或至少一个聚合物层，其中聚合物用酸性或潜酸性或碱性或潜碱性基团官能化; 或包含至少一个含有金属颗粒和光潜酸或光潜剂基质的聚合物层的时间温度指示剂，或包含金属颗粒的至少一个聚合物层，其中所述聚合物用潜在的酸性或潜在碱性基团官能化。

8. 发明授权

US09518964B2 Method for identifying electrophiles and nucleophiles in a sample 有权
标题翻译：识别样品中亲电子和亲核试剂的方法
公开(公告)号：US09518964B2
公开(公告)日：2016-12-13
申请号：US13086486
申请日：2011-04-14
申请人： Yoav Eichen , Shay Tal , Yael Abraham , Husein Salman , Elana Borzin , Carmit Hertzog-Ronen
发明人： Yoav Eichen , Shay Tal , Yael Abraham , Husein Salman , Elana Borzin , Carmit Hertzog-Ronen
IPC分类号： C40B30/00 , C40B40/00 , G01N31/22 , G01N33/00 , G01N21/77 , G01N21/64
CPC分类号： G01N31/22 , G01N31/223 , G01N31/224 , G01N33/0036 , G01N33/0057 , G01N2021/6439 , G01N2021/773 , Y10T436/23
摘要： A method and device for identifying a molecule in a sample, the molecule comprising an electrophilic or nucleophilic moiety. The method comprises contacting the sample with a plurality of chemosensors, each of the chemosensors comprising a π-conjugated system and a moiety having a nucleophilic property or an electrophilic property; and measuring an electromagnetic property of each of the chemosensors in the sample; whereby the pattern of changes in the electromagnetic properties of the plurality of chemosensors after chemically reacting with the electrophile or nucleophile of the molecule identifies the molecule in said sample. The device comprises a substrate carrying a plurality of chemosensor molecules having at least one predetermined electromagnetic property, the at least one electromagnetic property being changeable by subjecting the chemosensor molecules to a sample containing at least one electrophile or nucleophile, wherein the pattern of change of the electromagnetic property of the plurality of chemosensor molecules allows the device to identify the electrophile or nucleophile in the sample.
摘要翻译：用于鉴定样品中分子的方法和装置，所述分子包含亲电子部分或亲核部分。该方法包括使样品与多种化学传感器接触，每种化学传感器包含π共轭体系和具有亲核性质或亲电性质的部分; 并测量样品中每种化学传感器的电磁特性; 由此在与分子的亲电子试剂或亲核试剂发生化学反应之后，多种化学传感器的电磁特性的变化模式识别所述样品中的分子。该装置包括承载多个具有至少一个预定电磁特性的化学传感器分子的基底，所述至少一个电磁特性可通过使化学传感器分子经受含有至少一种亲电子试剂或亲核试剂的样品而变化，其中，多个化学传感器分子的电磁特性允许该装置鉴定样品中的亲电试剂或亲核试剂。

9. 发明授权

US08968662B2 Time temperature indicator 有权
标题翻译：时间温度指示器
公开(公告)号：US08968662B2
公开(公告)日：2015-03-03
申请号：US13001049
申请日：2009-06-15
申请人： Dietrich Haarer , Tal Gueta-Neyroud , Husein Salman
发明人： Dietrich Haarer , Tal Gueta-Neyroud , Husein Salman
IPC分类号： G01D21/00 , G01K3/04
CPC分类号： G01K3/04
摘要： The present invention is generally in the field of measuring and indicating techniques and relates to a time-temperature indicator and methods of manufacturing and use thereof. More specifically, the time-temperature indicator comprises at least one metal layer or metal containing layer, and in direct contact to the metal layer or to the metal containing layer at least one pad member affixed onto a pad carrier layer,wherein the pad member comprises a pad made of an absorbent material and a dopant medium, whereby the dopant medium comprises a liquid medium or a viscous medium or a viscoelastic medium which is doped with a dopant that destroys the metal/metal containing layers such as an acid, a base or a salt or a photolatent acid or a photolatent base.
摘要翻译：本发明通常在测量和指示技术领域中，并且涉及一种时间温度指示器及其制造和使用方法。更具体地，时间 - 温度指示器包括至少一个金属层或含金属层，并且与金属层或金属含有层直接接触固定到衬垫载体层上的至少一个衬垫构件，其中衬垫构件包括由吸收材料制成的垫和掺杂剂介质，由此掺杂剂介质包括液体介质或粘性介质或粘弹性介质，其掺杂有破坏含金属/金属的层的掺杂剂，例如酸，碱或盐或光潜酸或光潜碱。

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