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    • 9. 发明授权
    • Nitrogen-containing heterocyclic compounds
    • 含氮杂环化合物
    • US4752414A
    • 1988-06-21
    • US884349
    • 1986-07-11
    • Rudolf EidenschinkJoachim KrauseReinhard HittichEike PoetschBernhard ScheubleGeorg WeberLudwig Pohl
    • Rudolf EidenschinkJoachim KrauseReinhard HittichEike PoetschBernhard ScheubleGeorg WeberLudwig Pohl
    • C07D239/26C07D239/28C07D239/30C07D239/34C07D239/54C09K19/34C09K19/46G02F1/13C07D239/55C07D239/36C09K19/42
    • C07D239/26C07D239/34C09K19/3441
    • Nitrogen-containing heterocyclic compounds of the formula IR.sup.1 --A.sup.1 --Z.sup.1 --A.sup.2 --[Z.sup.2 --A.sup.3 ].sub.n --R.sup.2whereinR.sup.1 and R.sup.2 in each case independently of one another are an alkyl group with 1-15 C atoms, it also being possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms and/or --CO-- groups and/or --O--CO-- groups and/or --CO--O-- groups, and one of the radicals R.sup.1 and R.sup.2 is also H, F, Cl, Br or CN,A.sup.1 is a 1,4-cyclohexylene group, it also being possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms, a 1,4-bicyclo-(2,2,2)-octylene group or a 1,3-dithiane-2,5-diyl group,Z.sup.1 and Z.sup.2 in each case independently of one another are --CO--O--, --O--CO--, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --CH.sub.2 O-- or a single bond,A.sup.2 and A.sup.3 in each case independently of one another are a 1,4-phenylene group, pyrimidine-2,5-diyl group, 1,4-cyclohexylene group, it also being possible for one or two non-adjacent CH.sub.2 groups to be replaced by O atoms, 1,3-dithiane-2,5-diyl group or a 1,4-bicyclo(2,2,2)-octylene group andn is 0 or 1,with the provisos that(a) at least one of the groups A.sup.2 and A.sup.3 is a pyrimidine-2,5-diyl group,(b) at least one of the groups Z.sup.1 and Z.sup.2 is not a single bond if A.sup.2 is pyrimidine-2,5-diyl and R.sup.2 is alkyl or CN,(c) Z.sup.1 is not --CO--O-- if A.sup.3 is pyrimidine-2,5-diyl and A.sup.1 is 1,4-cyclohexylene,(d) n is not 0 if A.sup.1 is 1,4-cyclohexylene and Z.sup.1 is --CH.sub.2 CH.sub.2 --, and(e) Z.sup.1 is not --CH.sub.2 CH.sub.2 -- if R.sup.2 is CN, and(f) Z.sup.1 is --CH.sub.2 CH.sub.2 --, --OCH.sub.2 -- or --CH.sub.2 O--, if A.sup.1 is 1,4-cyclohexylene and --A.sup.2 --[Z.sup.2 --A.sup.3 ].sub.n -- is ##STR1## and acid addition salts thereof, can be used as components of liquid crystal phases.
    • 式Ⅰ的含氮杂环化合物R1-A1-Z1-A2- [Z2-A3] n-R2其中R1和R2各自独立地为具有1-15个C原子的烷基,它也是 一个或两个不相邻的CH2基团可以被O原子和/或-CO-基团和/或-O-CO-基团和/或-CO-O-基团取代,并且基团R1和R2之一 也是H,F,Cl,Br或CN,A1是1,4-亚环己基,也可以将一个或两个不相邻的CH 2基团替换为O原子,1,4-二环 - ( 2,2,2) - 亚辛基或1,3-二噻烷-2,5-二基,Z1和Z2各自独立地为-CO-O-,-O-CO-,-CH2CH2- ,-OCH 2 - , - CH 2 O-或单键,A2和A3各自独立地为1,4-亚苯基,嘧啶-2,5-二基,1,4-亚环己基, 一个或两个不相邻的CH 2基团被O原子替代,1,3-二噻烷-2,5-二基或1,4-二环(2,2,2) - 亚辛基是可能的,n是 0 或1,条件是(a)基团A2和A3中的至少一个是嘧啶-2,5-二基,(b)如果A 2是,则Z1和Z 2中的至少一个不是单键 嘧啶-2,5-二基和R2是烷基或CN,(c)如果A3是嘧啶-2,5-二基,并且A1是1,4-亚环己基,则Z1不是-CO-O-,(d)n不是 如果A 1为1,4-亚环己基且Z 1为-CH 2 CH 2,则为0,(e)如果R 2为CN,则(Z1)不为-CH2CH2-,(f)Z1为-CH2CH2-,-OCH2-或-CH2O- A1是1,4-亚环己基,-A2- [Z2-A3] n-是它们的酸加成盐,可以用作液晶相的成分。