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    • 2. 发明授权
    • Manufacturing method of single crystal and apparatus of manufacturing
the same
    • 单晶的制造方法及其制造方法
    • US5980630A
    • 1999-11-09
    • US81665
    • 1998-05-20
    • Eiichi IinoKiyotaka TakanoMasanori KimuraHirotoshi Yamagishi
    • Eiichi IinoKiyotaka TakanoMasanori KimuraHirotoshi Yamagishi
    • C30B15/00C30B15/20C30B15/30C30B29/06C30B30/04C30B35/00
    • C30B15/305Y10S117/917Y10T117/1068
    • In a single crystal manufacturing method by a horizontal magnetic field applied CZ method wherein coils are disposed interposing a crucible coaxially with each other, the coils constituting superconductive electromagnets of a magnetic field application apparatus and the silicon crystal is pulled from melt in the crucible while applying a horizontal magnetic field to the melt; an elavation apparatus capable of finely adjusting relative positions of the superconductive electromagnets and the crcucible in a vertical direction is disposed. The descent of a central portion Cm in a depth direction of the melt is canceled by elevating the crucible with the elevating apparatus, the descent being accompanied with proceeding of process of pulling the single crystal, thereby a coil central axis Cc of the superconductive electromagnets always passes through the central portion Cm or below this portion. Compared with the conventional HMCZ method, an uniformity of an intensity distribution of the magnetic field applied to the melt is increased so that a suppression effect on the melt convection all over the crucible is enhanced.
    • 在通过水平磁场施加的CZ方法的单晶制造方法中,其中线圈彼此同轴地布置坩埚,构成磁场施加装置的超导电磁体的线圈和硅晶体在施加时从坩埚中的熔体拉出 熔体的水平磁场; 设置能够精细地调整超导电磁体和坩埚在垂直方向上的相对位置的冲压装置。 通过用升降装置升高坩埚来消除熔体深度方向上的中心部分Cm的下降,伴随着牵引单晶的过程的下降,超导电磁体的线圈中心轴Cc总是 通过中心部分Cm或者低于该部分。 与传统的HMCZ方法相比,施加到熔体的磁场的强度分布的均匀性增加,从而增强了对整个坩埚的熔体对流的抑制效果。
    • 7. 发明授权
    • Silicon single crystal with no crystal defect in peripheral part of
wafer and process for producing the same
    • 晶圆周边部分没有晶体缺陷的硅单晶及其制造方法
    • US6120749A
    • 2000-09-19
    • US101941
    • 1998-07-17
    • Kiyotaka TakanoMakoto IidaEiichi IinoMasanori KimuraHirotoshi Yamagishi
    • Kiyotaka TakanoMakoto IidaEiichi IinoMasanori KimuraHirotoshi Yamagishi
    • C30B15/22C30B15/00C30B29/06H01L21/02H01L21/208C31B33/00
    • C30B29/06C30B15/00Y10S257/913
    • A silicon single-crystal wafer having a diameter of 6 inches or larger and improved in the dielectric breakdown strength of oxide film especially in a peripheral part thereof is provided to thereby heighten the yield of device chips produced per wafer. This wafer has no crystal defects with regard to the dielectric breakdown strength of oxide film in its peripheral region which extends from the circumference and accounts for up to 50% of the total area, in particular which extends from the circumference to a circle 30 mm apart from the circumference. A process for producing a silicon single crystal for easily producing, by the Czochralski method, a silicon single-crystal wafer improved in the dielectric breakdown strength of oxide film especially in a peripheral part thereof without considerably lowering the production efficiency is provided. In this process, the silicon single crystal which is being grown by the Czochralski method is pulled at a rate which is 80 to 60% of the critical pull rate inherent in the pulling apparatus.
    • PCT No.PCT / JP97 / 00090 Sec。 371日期:1998年7月17日 102(e)日期1998年7月17日PCT 1997年1月17日PCT PCT。 WO97 / 26393 PCT出版物 日期1997年7月24日提供直径为6英寸或更大并且提高了氧化膜的绝缘击穿强度的硅单晶晶片,特别是其周边部分,从而提高了每片晶片产生的器件芯片的产量。 该晶片在其周边区域中的氧化膜的介电击穿强度方面没有晶体缺陷,其从圆周延伸并占总面积的50%,特别是从圆周延伸到相隔30mm的圆 从圆周。 提供了一种用于通过切克劳斯斯克方法生产硅单晶的方法,其提供了特别在其周边部分提高氧化膜的介电击穿强度的硅单晶晶片,而不会显着降低生产效率。 在这个过程中,以切克劳斯基法生长的硅单晶以牵引装置固有的临界拉伸速率的80%至60%的速率被拉伸。
    • 8. 发明授权
    • Manufacturing method of single crystal
    • 单晶的制造方法
    • US5792255A
    • 1998-08-11
    • US655201
    • 1996-05-30
    • Eiichi IinoKiyotaka TakanoMasanori KimuraHirotoshi Yamagishi
    • Eiichi IinoKiyotaka TakanoMasanori KimuraHirotoshi Yamagishi
    • C30B15/00C30B15/20C30B15/30C30B29/06C30B30/04C30B15/22
    • C30B15/305Y10S117/917Y10T117/1068
    • In a single crystal manufacturing method by a horizontal magnetic field applied CZ method wherein coils are disposed interposing a crucible coaxially with each other, the coils constituting superconductive electromagnets of a magnetic field application apparatus and the silicon crystal is pulled from melt in the crucible while applying a horizontal magnetic field to the melt; an elavation apparatus capable of finely adjusting relative positions of the superconductive electromagnets and the crcucible in a vertical direction is disposed. The descent of a central portion Cm in a depth direction of the melt is canceled by elevating the crucible with the elevating apparatus, the descent being accompanied with proceeding of process of pulling the single crystal, thereby a coil central axis Cc of the superconductive electromagnets always passes through the central portion Cm or below this portion. Compared with the conventional HMCZ method, an uniformity of an intensity distribution of the magnetic field applied to the melt is increased so that a suppression effect on the melt convection all over the crucible is enhanced.
    • 在通过水平磁场施加的CZ方法的单晶制造方法中,其中线圈彼此同轴地布置坩埚,构成磁场施加装置的超导电磁体的线圈和硅晶体在施加时从坩埚中的熔体拉出 熔体的水平磁场; 设置能够精细地调整超导电磁体和坩埚在垂直方向上的相对位置的冲压装置。 通过用升降装置升高坩埚来消除熔体深度方向上的中心部分Cm的下降,伴随着牵引单晶的过程的下降,超导电磁体的线圈中心轴Cc总是 通过中心部分Cm或者低于该部分。 与传统的HMCZ方法相比,施加到熔体的磁场的强度分布的均匀性增加,从而增强了对整个坩埚的熔体对流的抑制效果。
    • 9. 发明授权
    • Crucible for pulling silicon single crystal
    • 坩埚用于拉硅单晶
    • US5720809A
    • 1998-02-24
    • US510436
    • 1995-08-02
    • Eiichi IinoKiyotaka TakanoIzumi FusegawaHirotoshi Yamagishi
    • Eiichi IinoKiyotaka TakanoIzumi FusegawaHirotoshi Yamagishi
    • C30B15/02C30B15/12C30B29/06
    • C30B15/02C30B15/12Y10S117/90Y10T117/1052
    • A double-wall crucible is disclosed which is constructed by coaxially disposing a cylindrical partition wall in an outer crucible for holding a molten mass of silicon as a raw material and operated by heating the outer crucible and meanwhile supplying the raw material silicon to the gap between the outer crucible and the cylindrical partition wall and introducing the consequently produced molten mass of silicon to the interior of the cylindrical partition wall through a passage below the level of the molten mass of silicon interconnecting the outer crucible and the inner side of the cylindrical partition wall and meanwhile pulling a single crystal bar from the molten mass of silicon in the cylindrical partition wall. In this double-wall crucible, at least the cylindrical partition wall is formed of quartz glass having a hydroxyl group (OH group) content of not more than 30 ppm. In the crucible of this invention, the produced silicon single crystal enjoys improved quality and the operation of pulling enjoys enhanced yield because the cylindrical partition wall is softened or deformed only sparingly by the intense heat emanating from the molten mass of silicon. Since the cylindrical partition wall does not readily soften or deform on exposure to the heat, the partition wall can be fixed in place with a simple construction and the whole apparatus for the operation of pulling enjoys simplicity of construction and low cost of production.
    • 公开了一种双壁坩埚,其通过在外坩埚中同轴设置圆筒形分隔壁而构成,用于将硅熔体作为原料保持,并通过加热外坩埚进行操作,同时将原料硅供应到 外坩埚和圆柱形分隔壁,并将由此产生的硅熔融物质通过下列通道引导到圆筒形分隔壁的内部,该通道位于将外坩埚与圆柱形分隔壁的内侧相互连接的熔融物质层的下方 同时从圆柱形分隔壁的硅熔融体中拉出单晶棒。 在该双壁坩埚中,至少圆筒形分隔壁由羟基(OH基)含量为30ppm以下的石英玻璃构成。 在本发明的坩埚中,所生产的硅单晶具有改进的质量,并且由于由熔融硅团发出的强烈热量,圆柱形分隔壁被轻微软化或变形,所以拉伸操作具有提高的产量。 由于圆柱形分隔壁在暴露于热量时不容易软化或变形,因此能够以简单的结构将分隔壁固定就位,并且用于拉动操作的整个装置具有简单的结构和低成本的生产。