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1. 发明授权

US4613673A Catalysts preparation thereof and preparation of N-substituted acrylamides therewith 失效
标题翻译：催化剂的制备和N-取代的丙烯酰胺的制备
公开(公告)号：US4613673A
公开(公告)日：1986-09-23
申请号：US535017
申请日：1983-09-23
申请人： Edward E. McEntire , Kathy B. Sellstrom
发明人： Edward E. McEntire , Kathy B. Sellstrom
IPC分类号： C07F3/06 , C07F7/22
CPC分类号： C07F3/06 , C07F7/2284
摘要： This invention is directed to novel catalysts characterized as compounds of tin or zinc containing a direct metal-nitrogen bond. The novel catalysts are derived from a primary or secondary amine such as an alkyl amine, a heterocyclic amine, an aromatic amine, etc. The amine is reacted with a tin compound such as a tin chloride, a tin bromide, a tin oxide, or a tin alkoxide. Alternatively, the amine may be reacted with a zinc halide, a zinc alkoxide or an organozinc compound.In another aspect of the present invention, the novel catalysts are used to catalyze the reaction of an acrylate or methacrylate ester with an amine in order to prepare N-substituted acrylamides or methacrylamides in good yield and with high selectivity.
摘要翻译：本发明涉及以含有直接金属 - 氮键的锡或锌化合物为特征的新型催化剂。新型催化剂衍生自伯胺或仲胺如烷基胺，杂环胺，芳族胺等。胺与锡化合物如氯化锡，溴化锡，氧化锡或一种锡醇盐。或者，胺可以与卤化锌，烷氧基锌或有机锌化合物反应。在本发明的另一方面，新型催化剂用于催化丙烯酸酯或甲基丙烯酸酯与胺的反应，以便以高产率和高选择性制备N-取代的丙烯酰胺或甲基丙烯酰胺。

2. 发明授权

US4675441A Preparation of N-substituted acrylamides 失效
标题翻译： N-取代的丙烯酰胺的制备
公开(公告)号：US4675441A
公开(公告)日：1987-06-23
申请号：US836938
申请日：1986-03-06
申请人： Edward E. McEntire , Kathy B. Sellstrom
发明人： Edward E. McEntire , Kathy B. Sellstrom
IPC分类号： C07F3/06 , C07F7/22 , C07C102/06
CPC分类号： C07F3/06 , C07F7/2284
摘要： This invention is directed to novel catalysts characterized as compounds of tin or zinc containing a direct metal-nitrogen bond. The novel catalysts are derived from a primary or secondary amine such as an alkyl amine, a heterocyclic amine, an aromatic amine, etc. The amine is reacted with a tin compound such as a tin chloride, a tin bromide, a tin oxide, or a tin alkoxide. Alternatively, the amine may be reacted with a zinc halide, a zinc alkoxide or an organozinc compound.In another aspect of the present invention, the novel catalysts are used to catalyze the reaction of an acrylate or methacrylate ester with an amine in order to prepare N-substituted acrylamides or methacrylamides in good yield and with high selectivity.
摘要翻译：本发明涉及以含有直接金属 - 氮键的锡或锌化合物为特征的新型催化剂。新型催化剂衍生自伯胺或仲胺如烷基胺，杂环胺，芳族胺等。胺与锡化合物如氯化锡，溴化锡，氧化锡或一种锡醇盐。或者，胺可以与卤化锌，烷氧基锌或有机锌化合物反应。在本发明的另一方面，新型催化剂用于催化丙烯酸酯或甲基丙烯酸酯与胺的反应，以便以高产率和高选择性制备N-取代的丙烯酰胺或甲基丙烯酰胺。

3. 发明授权

US4492801A Production of N-substituted (meth)acrylamides from (meth)acrylates and amines over a metal alkoxide catalyst 失效
标题翻译：从（甲基）丙烯酸酯和胺在金属醇盐催化剂上制备N-取代的（甲基）丙烯酰胺
公开(公告)号：US4492801A
公开(公告)日：1985-01-08
申请号：US469860
申请日：1983-02-28
申请人： Edward E. McEntire , Kathy B. Sellstrom , Edward C. Y. Nieh , David R. Livingston
发明人： Edward E. McEntire , Kathy B. Sellstrom , Edward C. Y. Nieh , David R. Livingston
IPC分类号： C07B61/00 , B01J31/00 , C07C31/30 , C07C67/00 , C07C231/00 , C07C231/02 , C07C233/09 , C07C233/20 , C07C233/38 , C07C102/06 , C07C103/44
CPC分类号： C07C31/30
摘要： A one-step process for the preparation of N-substituted (meth)acrylamides from the reaction of a (meth)acrylate ester and an amine over a catalytic amount of a metal alkoxide catalyst is described. These catalysts, such as stannous dimethoxide, lead dimethoxide, zinc dimethoxide, copper dimethoxide and bismuth tributoxide give high selectivity to the N-substituted (meth)acrylamides and little selectivity of the Michael adduct propionate ester, which would predominate in the absence of these catalysts. Also, these catalysts are less costly than organo metal catalysts commonly used.
摘要翻译：描述了通过催化量的金属醇盐催化剂从（甲基）丙烯酸酯和胺的反应制备N-取代的（甲基）丙烯酰胺的一步法。这些催化剂，如二甲氧基亚锡，二甲氧基化铅，二甲氧基化锌，二甲氧基化铜和二氧化铋，对N-取代的（甲基）丙烯酰胺具有高选择性，并且在不存在这些催化剂的情况下主要是迈克尔加成丙酸酯的选择性很小。此外，这些催化剂比通常使用的有机金属催化剂成本低。

4. 发明授权

US4549017A Process for the production of N-substituted (meth)acrylamides from (meth)acrylates and amines over a metal oxide or alkoxide catalyst 失效
标题翻译：从（甲基）丙烯酸酯和胺在金属氧化物或醇盐催化剂上生产N-取代的（甲基）丙烯酰胺的方法
公开(公告)号：US4549017A
公开(公告)日：1985-10-22
申请号：US535010
申请日：1983-09-23
申请人： Edward E. McEntire , John F. Knifton , Edward C. Y. Nieh , Kathy B. Sellstrom
发明人： Edward E. McEntire , John F. Knifton , Edward C. Y. Nieh , Kathy B. Sellstrom
IPC分类号： C07C233/02 , C07D295/10 , C07C102/06
CPC分类号： C07C233/02
摘要： The invention is related to a catalytic method for the production of N-substituted (meth)acrylamides and is more particularly related to a catalytic method for the production of N-substituted (meth)acrylamides from (meth)acrylates and amines in the presence of an alkoxide of silicon, titanium or zirconium.
摘要翻译：本发明涉及一种用于制备N-取代的（甲基）丙烯酰胺的催化方法，更具体地涉及在（甲基）丙烯酸酯和胺的存在下由（甲基）丙烯酸酯和胺制备N-取代的（甲基）丙烯酰胺的催化方法。硅，钛或锆的醇盐。

5. 发明授权

US5286778A Latices and waterborne compositions for wood stains, sealers, and the like 失效
标题翻译：用于木材污渍，密封剂等的粘合剂和水性组合物
公开(公告)号：US5286778A
公开(公告)日：1994-02-15
申请号：US951619
申请日：1992-09-28
申请人： Roy E. Dean , Edward E. McEntire
发明人： Roy E. Dean , Edward E. McEntire
IPC分类号： C09D15/00 , C09D127/06 , C09D127/08 , C08L27/08 , B32B21/08
CPC分类号： C09D127/08 , C09D127/06 , C09D15/00 , Y10T428/31989
摘要： Latex copolymers of vinyl halide and vinylidene halide reacted in the presence of a polymeric surfactant are advantageously employed as binders in waterborne stains and other coating compositions. Monomers from which the latex is polymerized may additionally include acrylates, vinyl esters, and/or unsaturated epoxies.
摘要翻译：在聚合物表面活性剂存在下反应的乙烯基卤化物和亚乙烯基卤化物的乳胶共聚物有利地用作水性染料和其它涂料组合物中的粘合剂。胶乳聚合的单体可另外包括丙烯酸酯，乙烯基酯和/或不饱和环氧树脂。

6. 发明授权

US5118752A Vinyl polymer latex systems 失效
标题翻译：乙烯基聚合物乳胶体系
公开(公告)号：US5118752A
公开(公告)日：1992-06-02
申请号：US776104
申请日：1991-10-15
申请人： Wen-Hsuan Chang , Marvin L. Kaufman , Edward E. McEntire , James C. Su , Anbazhagan Natesh
发明人： Wen-Hsuan Chang , Marvin L. Kaufman , Edward E. McEntire , James C. Su , Anbazhagan Natesh
IPC分类号： C08F2/24 , C08F30/08 , C08F220/10 , C08F220/18 , C08F230/08 , C08F246/00 , C08G18/62 , C08G18/67 , C08L25/00 , C08L75/04 , C08L101/00 , C08L101/02 , C09D125/06 , C09D143/04 , C09D151/00 , C09D151/08
CPC分类号： C09D151/08 , C08F2/24 , C09D125/06 , C09D143/04 , C08L75/04
摘要： An aqueous polymer emulsion latex is claimed composed of particles comprising a vinyl polymer and a surfactant containing at least one hydrophobic moiety and at least one hydrophilic moiety and also carrying silicon moieties and amido functionalities. Also claimed are coating compositions containing the aqueous polymer emulsion latex, processes for preparing the aqueous polymer emulsion latex wherein ethylenically unsaturated monomers are polymerized in the presence of a surfactant containing a silicon moiety and amido functionality, and substrates carrying a coating composition containing the aqueous polymer emulsion latex.
摘要翻译：含水聚合物乳液胶乳由包含乙烯基聚合物和含有至少一个疏水部分和至少一个亲水部分并且还带有硅部分和酰胺官能团的表面活性剂的颗粒组成。还要求保护的是含有聚合物水乳液胶乳的涂料组合物，制备含水聚合物乳液胶乳的方法，其中烯属不饱和单体在含有硅部分和酰胺官能团的表面活性剂存在下聚合，以及承载含有含水聚合物乳液胶乳。

7. 发明授权

US4483997A Olefin epoxidation with inorganic metal phosphate enhanced catalyst 失效
标题翻译：烯烃环氧化与无机金属磷酸盐增强催化剂
公开(公告)号：US4483997A
公开(公告)日：1984-11-20
申请号：US462250
申请日：1983-01-31
申请人： Edward E. McEntire , Robert M. Gipson
发明人： Edward E. McEntire , Robert M. Gipson
IPC分类号： B01J23/24 , B01J27/188 , C07D301/19 , C07D303/04
CPC分类号： C07D301/19 , B01J23/24 , B01J27/188 , C07D303/04
摘要： A method for the preparation of an epoxide by reacting an olefin having 3 or more carbon atoms with a hydroperoxide in the presence of a catalyst. The catalyst includes molybdenum and/or tungsten and an inorganic metal phosphate and/or arsenate wherein at least the inorganic metal phosphate and/or arsenate is substantially insoluble in the olefin hydroperoxide reaction mixture. The metal portion of the inorganic metal phosphate and/or arsenate is one or more metals selected from the group consisting of the metals found in Groups I to III, VIIb and VIII, of the Periodic Table of Elements. Preferred metals include aluminum, iron, zinc and mixtures of these metals.
摘要翻译：一种通过在催化剂存在下使具有3个或更多个碳原子的烯烃与氢过氧化物反应来制备环氧化物的方法。催化剂包括钼和/或钨和无机金属磷酸盐和/或砷酸盐，其中至少无机金属磷酸盐和/或砷酸盐基本上不溶于烯烃氢过氧化物反应混合物。无机金属磷酸盐和/或砷酸盐的金属部分是选自元素周期表第I至III，VIIb和VIII族中的金属的一种或多种金属。优选的金属包括铝，铁，锌和这些金属的混合物。

8. 发明授权

US4457371A Method for demulsification of bitumen emulsions 失效
标题翻译：沥青乳液的破乳方法
公开(公告)号：US4457371A
公开(公告)日：1984-07-03
申请号：US326455
申请日：1981-12-02
申请人： David R. McCoy , Edward E. McEntire , Robert M. Gipson
发明人： David R. McCoy , Edward E. McEntire , Robert M. Gipson
IPC分类号： B01D17/04 , E21B43/40 , E21B43/24
CPC分类号： E21B43/40 , B01D17/047
摘要： A process for recovering bitumen from oil-in-water (O/W) emulsions is disclosed wherein water soluble demulsifiers are used. These demulsifiers are polymers of specific quaternary ammonium monomers or co-polymers of these quaternary ammonium monomers wth other types of monomers wherein the greater portion of the co-polymer is comprised of the quaternary ammonium monomers. To resolve the bituminous petroleum emulsions, the process is carried out between 25.degree. and 160.degree. C. wherein the demulsifier of the invention is contacted with the bituminous emulsion.
摘要翻译：公开了一种从水包油（O / W）乳液中回收沥青的方法，其中使用水溶性破乳剂。这些破乳剂是特定季铵单体的聚合物或这些季铵单体与其它类型单体的共聚物，其中大部分共聚物由季铵单体组成。为了解决沥青石油乳液，该方法在25℃至160℃之间进行，其中本发明的破乳剂与沥青乳液接触。

9. 发明授权

US4359540A Method for making rim elastomers using a catalyst system which is a polymer containing tertiary amine moieties 失效
标题翻译：使用催化剂体系制备边缘弹性体的方法，所述催化剂体系是含有叔胺部分的聚合物
公开(公告)号：US4359540A
公开(公告)日：1982-11-16
申请号：US268220
申请日：1981-05-29
申请人： Edward E. McEntire , Richard J. G. Dominquez
发明人： Edward E. McEntire , Richard J. G. Dominquez
IPC分类号： C08F20/00 , C08F20/52 , C08G18/00 , C08G18/16 , C08G18/18 , C08G18/20 , C08G18/14
CPC分类号： C08G18/165 , C08G18/18 , C08G18/2081 , C08G2120/00
摘要： The invention is a method for making reaction injection molded polyurethane of improved properties. The method comprises injecting into a mold cavity a high molecular weight polyhydric polyether, a low molecular weight active hydrogen containing compound of at least two functionality, a polyisocyanate and a catalyst comprising polymers substantially without active hydrogens containing tertiary amine moieties. This catalyst results in improved paintability when using high solids paint. Reaction injection molded elastomers are useful as molded articles of commerce including, but not limited to, vehicle body parts.
摘要翻译：本发明是改进性能的反应注塑聚氨酯的制备方法。该方法包括向模腔注入高分子量多羟基聚醚，含有至少两种官能团的低分子量含活性氢化合物，多异氰酸酯和包含基本上不含有叔胺部分的活性氢的聚合物的催化剂。当使用高固含量涂料时，该催化剂可改善涂料的性能。反应注射成型的弹性体可用作商业模制品，包括但不限于车身部件。

10. 发明授权

US4265821A Substituted alkylene oxides from substituted alkylene carbonates 失效
标题翻译：取代的亚烷基碳酸酯取代的环氧烷烃
公开(公告)号：US4265821A
公开(公告)日：1981-05-05
申请号：US92126
申请日：1979-11-07
申请人： Edward E. McEntire , Robert M. Gipson
发明人： Edward E. McEntire , Robert M. Gipson
IPC分类号： C07D301/02
CPC分类号： C07D301/02
摘要： Alkyl substituted ethylene carbonates are converted to substituted ethylene oxides by heating the respective carbonates in the presence of a catalyst comprising alkali metal halides or lanthanum iodide. The alkyl substituted ethylene carbonates have the general formula ##STR1## where R is alkyl, aryl, substituted alkyl, substituted aryl, alkaryl or aralkyl.
摘要翻译：在包含碱金属卤化物或碘化镧的催化剂存在下，通过加热相应的碳酸酯将烷基取代的亚乙基碳酸酯转化成取代的环氧乙烷。烷基取代的碳酸亚乙酯具有通式：其中R是烷基，芳基，取代的烷基，取代的芳基，烷芳基或芳烷基。

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