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1. 发明授权

US4629718A Alkali promoted manganese oxide compositions containing silica and/or alkaline earth oxides 失效
标题翻译：碱促进含有二氧化硅和/或碱土氧化物的氧化锰组合物
公开(公告)号：US4629718A
公开(公告)日：1986-12-16
申请号：US683118
申请日：1984-12-18
申请人： C. Andrew Jones , John J. Leonard , John A. Sofranko , Howard P. Withers , E. William Breder, Jr. , Marvin F. L. Johnson , John A. Jaecker
发明人： C. Andrew Jones , John J. Leonard , John A. Sofranko , Howard P. Withers , E. William Breder, Jr. , Marvin F. L. Johnson , John A. Jaecker
IPC分类号： B01J23/08 , B01J23/14 , B01J23/18 , B01J23/34 , B01J27/18 , C07C2/84 , B01J21/08
CPC分类号： B01J23/14 , B01J23/08 , B01J23/18 , B01J23/34 , B01J27/18 , C07C2/84 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/34 , C07C2527/18
摘要： A class of mixed oxide catalysts comprising Mn-containing oxides, alkali metals or compounds thereof, and at least one member of the group consisting of oxides of Si, oxides of alkaline earth metals, and mixed oxides of Si and at least one alkaline earth metal. In the more preferred embodiments, the third component serves as a carrier for the Mn and alkali metal components. The composition preferably comprises a major amount of the carrier material and minor amounts of the other components. The compositions are useful for hydrocarbon coversion, methane conversion, and oxidative dehydrogenation processes characterized by formation of coproduct water.
摘要翻译：一类含有Mn的氧化物，碱金属或其化合物的混合氧化物催化剂，以及由Si的氧化物，碱土金属的氧化物以及Si和至少一种碱土金属的混合氧化物组成的组中的至少一种。在更优选的实施方案中，第三组分用作Mn和碱金属组分的载体。组合物优选包含主要量的载体材料和少量的其它组分。该组合物可用于烃转化，甲烷转化和以特征为副产物水形成的氧化脱氢方法。

2. 发明授权

US4544786A Methane conversion using a magnesia/silica support 失效
标题翻译：使用氧化镁/二氧化硅载体的甲烷转化
公开(公告)号：US4544786A
公开(公告)日：1985-10-01
申请号：US600925
申请日：1984-04-16
申请人： E. William Breder, Jr. , John A. Jaecker , Marvin F. L. Johnson
发明人： E. William Breder, Jr. , John A. Jaecker , Marvin F. L. Johnson
IPC分类号： C07C2/84 , C07C2/00
CPC分类号： C07C2/84 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/34 , Y10S585/943
摘要： An improved method for converting methane to higher hydrocarbon products by contacting a gas comprising methane with a contact agent at a selected temperature, the agent comprising a reducibile metal oxide, a support of at least two oxides, and an alkali metal.
摘要翻译：一种通过使包含甲烷的气体与选定温度下的接触剂接触而将甲烷转化为较高级烃产物的改进方法，所述试剂包含还原性金属氧化物，至少两种氧化物的载体和碱金属。

3. 发明授权

US4794100A Preparative process for supports 失效
标题翻译：支持的准备过程
公开(公告)号：US4794100A
公开(公告)日：1988-12-27
申请号：US737750
申请日：1985-05-28
申请人： E. William Breder, Jr.
发明人： E. William Breder, Jr.
IPC分类号： C07C2/84 , B01J21/14
CPC分类号： C07C2/84 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/34 , Y10S585/943
摘要： An improved process for the production of a contact agent comprising digesting a reducible oxide of at least one metal, the oxide of which forms a reduced metal oxide, and a support in the presence of a silicon component, drying the precipitate of the reducible oxide and calcining the precipitate to form the contact agent.
摘要翻译：一种用于生产接触剂的改进方法，其包括在硅组分存在下，消化至少一种金属的还原氧化物，其氧化物形成还原的金属氧化物和载体，干燥可还原氧化物的沉淀物，以及煅烧沉淀物形成接触剂。

4. 发明授权

US4544787A Preparative process for supports 失效
公开(公告)号：US4544787A
公开(公告)日：1985-10-01
申请号：US600926
申请日：1984-04-16
申请人： E. William Breder, Jr.
发明人： E. William Breder, Jr.
IPC分类号： C07C2/84 , C07C2/00
CPC分类号： C07C2/84 , C07C2521/08 , C07C2521/10 , C07C2523/02 , C07C2523/04 , C07C2523/08 , C07C2523/14 , C07C2523/18 , C07C2523/34 , Y10S585/943
摘要： An improved process for the production of a contact agent comprising digesting a reducible oxide of at least one metal, the oxide of which forms a reduced metal oxide, and a support in the presence of a silicon component, drying the precipitate of the reducible oxide and calcining the precipitate to form the contact agent.

5. 发明授权

US5210353A Aromatic transformation process 失效
标题翻译：芳香族转化过程
公开(公告)号：US5210353A
公开(公告)日：1993-05-11
申请号：US620529
申请日：1990-11-30
申请人： Carl A. Udovich , E. William Breder, Jr. , Ibrahim Ghanayem , Mark W. Meszaros , Thomas E. Nemo , Thomas G. Smith
发明人： Carl A. Udovich , E. William Breder, Jr. , Ibrahim Ghanayem , Mark W. Meszaros , Thomas E. Nemo , Thomas G. Smith
IPC分类号： C07C6/12
CPC分类号： C07C6/126
摘要： A process is provided for transaralkylating a class of starting compounds comprised of aryl-substituted lower alkanes and aryl-substituted fused alkylene ring compounds to produce derivatives of such compounds wherein benzyl substituents thereof have different alkyl substituents compared to the starting compounds. The process is carried out by admixing such a starting compound with a lower alkyl-substituted aromatic compound under liquid phase conditions in the presence of a catalytically effective amount of a Friedel-Crafts catalyst. The process makes possible new and economical routes for synthesizing desired lower alkyl-substituted benzyl group containing compounds, such as 2,2-di(lower alkyl-substituted) phenyl propanes and 1,3,3-trimethyl-1-(lower alkyl-substituted)-phenyl indans. Thus, there is provided a three-step process for making dixylylpropane from alpha methyl styrene and also a two-step process for making 1,3,3,6-tetramethyl-1-o-xylyl indan from alpha-4-dimethyl styrene. Provided also is a process for preparing 3,3',4,4'-dixylylmethane from a mixture of isomeric dixylylmethanes.
摘要翻译：提供了一种方法，用于将由芳基取代的低级烷烃和芳基取代的稠合亚烷基环化合物组成的一类起始化合物转烷基化以产生这样的化合物的衍生物，其中苄基取代基与起始化合物相比具有不同的烷基取代基。该方法通过在液相条件下在催化有效量的Friedel-Crafts催化剂的存在下将这种起始化合物与低级烷基取代的芳族化合物混合来进行。该方法可用于合成所需的低级烷基取代苄基化合物如2,2-二（低级烷基取代的）苯基丙烷和1,3,3-三甲基-1-（低级烷基取代的苄基）取代的） - 苯基茚二酮。因此，提供了由α-甲基苯乙烯制备二甲苯基丙烷的三步法，以及由α-4-二甲基苯乙烯制备1,3,3,6-四甲基-1-邻苯二甲酰基茚二酮的两步法。还提供了从异构二烷基甲烷的混合物制备3,3'，4,4'-二甲苯基甲烷的方法。

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