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1. 发明授权

US5597874A Coating compositions of an acrylic fluorocarbon polymer and a fluorinated polyisocyanate 失效
标题翻译：丙烯酸氟碳聚合物和氟化聚异氰酸酯的涂料组合物
公开(公告)号：US5597874A
公开(公告)日：1997-01-28
申请号：US543721
申请日：1995-10-16
申请人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
发明人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
IPC分类号： C08F8/30 , C08G18/62 , C08G18/80 , C09D133/14 , C09D175/08 , C08F8/18 , C08F14/18
CPC分类号： C08G18/8087 , C08F8/30 , C08G18/6279 , Y10T428/3154 , Y10T428/31544
摘要： A coating composition containing about 45-80% by weight of a binder and 20-55% by weight of an organic liquid; wherein the binder contains(A) about 40-90% by weight, based on the weight of the binder, of an acrylic polymer containing polymerized hydroxyl containing monomers of the following group of hydroxy alkyl acrylate or methacrylates having 1-4 carbon atoms in the alkyl group, and polymerized alkyl acrylates and methacrylates having 1-18 carbon atoms in the alkyl groups, or styrene or any mixtures of the above and 0.1-5.0% by weight, based on the weight of the acrylic polymer, of polymerized fluoroalkyl containing monomer represented by the formula ##STR1## where R is hydrogen or an alkyl group having 1-2 carbon atoms, n is an integer of 1-11 and R.sub.f is a fluoroalkyl containing group having at least 4 carbon atoms and(B) about 10-60% by weight, based on the weight of the binder, of a fluorinated organic polyisocyanate crosslinking agent.
摘要翻译：包含约45-80重量％的粘合剂和20-55重量％的有机液体的涂料组合物; 其中所述粘合剂含有（A）约40-90重量％，基于粘合剂的重量，含有聚合的羟基的丙烯酸类聚合物的丙烯酸类聚合物，所述聚合的含羟基的单体在下述基团中具有1-4个碳原子的丙烯酸羟烷基酯或甲基丙烯酸酯烷基和在烷基中具有1-18个碳原子的聚合的丙烯酸烷基酯和甲基丙烯酸烷基酯，或苯乙烯或上述的任何混合物和基于丙烯酸类聚合物的重量0.1-5.0重量％的聚合的含氟烷基的单体其中R为氢或具有1-2个碳原子的烷基，n为1-11的整数，Rf为含有至少4个碳原子的含氟烷基基团，（B）为约10- 60重量％，基于粘合剂的重量，含氟有机多异氰酸酯交联剂。

2. 发明授权

US5627238A Coating compositions of an acrylic polymer and a fluorinated polyisocyanate 失效
标题翻译：丙烯酸聚合物和氟化聚异氰酸酯的涂料组合物
公开(公告)号：US5627238A
公开(公告)日：1997-05-06
申请号：US543677
申请日：1995-10-16
申请人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
发明人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
IPC分类号： C08G18/62 , C08G18/77 , C08G18/80 , C09D175/04 , C08G18/70 , C08F20/10
CPC分类号： C08G18/6229 , C08G18/8087
摘要： A coating composition containing about 45-80% by weight of a binder and 20-55% by weight of an organic liquid; wherein the binder contains(A) about 40-90% by weight, based on the weight of the binder, of an acrylic polymer containing polymerized hydroxyl containing monomers of the following group of hydroxy alkyl acrylate or methacrylates having 1-4 carbon atoms in the alkyl group, and polymerized alkyl acrylates and methacrylates having 1-18 carbon atoms in the alkyl groups, or styrene or any mixtures of the above and(B) about 10-60% by weight, based on the weight of the binder, of a fluorinated organic polyisocyanate crosslinking agent.
摘要翻译：包含约45-80重量％的粘合剂和20-55重量％的有机液体的涂料组合物; 其中所述粘合剂含有（A）约40-90重量％，基于粘合剂的重量，含有聚合的羟基的丙烯酸类聚合物的丙烯酸类聚合物，所述聚合的含羟基的单体在下述基团中具有1-4个碳原子的丙烯酸羟烷基酯或甲基丙烯酸酯烷基和在烷基中具有1-18个碳原子的聚合的丙烯酸烷基酯和甲基丙烯酸烷基酯，或苯乙烯或上述和（B）的任何混合物，约10-60重量％，基于粘合剂的重量，氟化有机多异氰酸酯交联剂。

3. 发明授权

US5629372A Acrylic fluorocarbon polymer containing coating 失效
标题翻译：含丙烯酸氟碳聚合物的涂层
公开(公告)号：US5629372A
公开(公告)日：1997-05-13
申请号：US543770
申请日：1995-10-16
申请人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
发明人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
IPC分类号： C08F220/24 , C08F220/38 , C08G18/62 , C09D133/14 , C09D175/04 , C08L27/12
CPC分类号： C08G18/6287 , C08G18/6279
摘要： A clear coating composition containing about 45-80% by weight of a binder and 20-55% by weight of an organic liquid; wherein the binder contains(A) about 40-90% by weight, based on the weight of the binder, of an acrylic polymer containing polymerized hydroxyl containing monomers of the following group of hydroxy alkyl acrylate or methacrylates having 1-4 carbon atoms in the alkyl group, and polymerized alkyl acrylates and methacrylates having 1-18 carbon atoms in the alkyl groups, or styrene or any mixtures of the above and 0.1-5.0% by weight, based on the weight of the acrylic polymer, of polymerized fluoroalkyl containing monomer represented by the formula ##STR1## where R is hydrogen or an alkyl group having 1-2 carbon atoms, n is an integer of 1-11 and R.sub.f is a fluoroalkyl containing group having at least 4 carbon atoms and (B) about 10-60% by weight, based on the weight of the binder, of an organic polyisocyanate crosslinking agent; and where a cured layer of the coating composition has a combination of a water advancing contact angle of at least 100.degree. and a hexadecane contact angle of at least 40.degree..A process for making the acrylic fluorocarbon polymer and articles coated with the composition also are part of this invention.
摘要翻译：含有约45-80重量％粘合剂和20-55重量％有机液体的透明涂料组合物; 其中所述粘合剂含有（A）约40-90重量％，基于粘合剂的重量，含有聚合的羟基的丙烯酸类聚合物的丙烯酸类聚合物，所述聚合的含羟基的单体在下述基团中具有1-4个碳原子的丙烯酸羟烷基酯或甲基丙烯酸酯烷基和在烷基中具有1-18个碳原子的聚合的丙烯酸烷基酯和甲基丙烯酸烷基酯，或苯乙烯或上述的任何混合物和基于丙烯酸类聚合物的重量0.1-5.0重量％的聚合的含氟烷基的单体其中R为氢或具有1-2个碳原子的烷基，n为1-11的整数，Rf为含有至少4个碳原子的含氟烷基基团，（B）为约10- 60重量％，基于粘合剂的重量;有机多异氰酸酯交联剂; 并且其中涂料组合物的固化层具有至少100°的进水接触角和至少40°的十六烷接触角的组合。制备丙烯酸氟碳聚合物和用该组合物涂覆的制品的方法也是本发明的一部分。

4. 发明授权

US5605956A Fluorinated polyisocyanates 失效
标题翻译：氟化多异氰酸酯
公开(公告)号：US5605956A
公开(公告)日：1997-02-25
申请号：US543773
申请日：1995-10-16
申请人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
发明人： Douglas R. Anton , Michael J. Darmon , William F. Graham , Richard R. Thomas
IPC分类号： C08L75/04 , C08G18/77 , C08G65/00 , C09D175/04 , C09D175/08 , C08J3/00 , C08G18/28 , C08K3/20 , C08L75/00
CPC分类号： C08G65/007
摘要： A fluorinated polyisocyanate which comprises an organic polyisocyanate reacted with a fluorinated monofunctional alcohol represented by the formula ##STR1## where R.sub.f is a fluoroalkyl containing group having at least 4 carbon atoms, X is a divalent radical, R.sup.3 is H or an alkyl group having 1-4 carbon atoms, n is 0-1 and m is 0-30, provided that when n is 0 then m must be equal to or greater than 1 and when m is 0, n is 1, wherein about 0.1-33 mole percent of active isocyanate groups are reacted with the fluorinated monofunctional alcohol; the fluorinated polyisocynate can be used with acrylic polymers, polyesters, alkyd resins, polyols and the like to form coating compositions, sealants, adhesives and the like.
摘要翻译：含有有机多异氰酸酯的氟化聚异氰酸酯与由式“IMAGE”表示的氟化单官能醇反应，其中Rf是具有至少4个碳原子的含氟代烷基基团，X是二价基团，R 3是H或具有1个 -4个碳原子，n为0-1，m为0-30，条件是当n为0时，m必须等于或大于1，当m为0时，n为1，其中约0.1-33摩尔％的活性异氰酸酯基团与氟化单官能醇反应; 氟化聚异氰酸酯可以与丙烯酸聚合物，聚酯，醇酸树脂，多元醇等一起使用，以形成涂料组合物，密封剂，粘合剂等。

5. 发明授权

US08124172B2 Process for making contained layers and devices made with same 有权
标题翻译：制作含有相同层数和装置的方法
公开(公告)号：US08124172B2
公开(公告)日：2012-02-28
申请号：US11401151
申请日：2006-04-10
申请人： Charles D. Lang , Stephen Sorich , Charles K. Taylor , Douglas R. Anton , Alberto Goenaga , Paul A. Sant
发明人： Charles D. Lang , Stephen Sorich , Charles K. Taylor , Douglas R. Anton , Alberto Goenaga , Paul A. Sant
IPC分类号： B05D5/06
CPC分类号： H01L51/0004 , H01L51/0003 , H01L51/0005 , H01L51/0011 , H01L51/0018 , H01L51/5012 , H01L51/56
摘要： There is provided a process for forming a contained second layer over a first layer, including the steps: forming the first layer having a first surface energy; treating the first layer with a reactive surface-active composition to form a treated first layer having a second surface energy which is lower than the first surface energy; exposing the treated first layer with radiation; and forming the second layer. There is also provided an organic electronic device made by the process.
摘要翻译：提供了一种用于在第一层上形成包含的第二层的方法，包括以下步骤：形成具有第一表面能的第一层; 用反应性表面活性组合物处理第一层以形成具有低于第一表面能的第二表面能的经处理的第一层; 用辐射暴露经处理的第一层; 并形成第二层。还提供了通过该方法制造的有机电子装置。

6. 发明授权

US5233058A Partially fluorinated compounds and polymers 失效
标题翻译：部分氟化的化合物和聚合物
公开(公告)号：US5233058A
公开(公告)日：1993-08-03
申请号：US780374
申请日：1991-10-21
申请人： Douglas R. Anton , William B. Farnham , Ming-Hong Hung , Ronald J. McKinney
发明人： Douglas R. Anton , William B. Farnham , Ming-Hong Hung , Ronald J. McKinney
IPC分类号： C07C43/313 , C07C51/08 , C07C55/32 , C07C69/63 , C07C211/09 , C07C211/15 , C07C255/10 , C07D305/10 , C07D317/16 , C07D317/28 , C07D317/30 , C07D317/42 , C08G63/682 , C08G73/10
CPC分类号： C08G73/1039 , C07C211/09 , C07C211/15 , C07C255/10 , C07C43/313 , C07C51/08 , C07C55/32 , C07C69/63 , C07D305/10 , C07D317/16 , C07D317/28 , C07D317/30 , C07D317/42 , C08G63/682
摘要： Partially fluorinated compounds of specified formulas that are useful as chemical intermediates and monomers are disclosed. Partially fluorinated polymers prepared from one of these compounds are also disclosed. Fluoro-2,2-dimethyldioxolanes and copolymers thereof are further disclosed.
摘要翻译：公开了可用作化学中间体和单体的具体化学式的部分氟化化合物。还公开了由这些化合物之一制备的部分氟化聚合物。进一步公开了氟-2,2-二甲基二氧戊环及其共聚物。

7. 发明授权

US5637657A Surface coating compositions containing fluoroalkyl esters of unsaturated fatty acids 失效
标题翻译：含有不饱和脂肪酸的氟烷基酯的表面涂料组合物
公开(公告)号：US5637657A
公开(公告)日：1997-06-10
申请号：US529899
申请日：1995-09-18
申请人： Douglas R. Anton
发明人： Douglas R. Anton
IPC分类号： C07C311/04 , C09D167/00 , C09D167/08 , C09D175/04 , C08L75/04 , C08K5/101 , C08K5/435 , C08L67/08
CPC分类号： C09D167/08 , C07C311/04 , C09D167/00 , C09D175/04
摘要： Perfluoroalkenoate esters containing at least two double bonds and coasting compositions, having durable advancing and receding hexadecane contact angles, containing such esters with alkyd or urethane resins are provided.
摘要翻译：提供含有至少两个双键和惯性组合物的全氟链烯酸酯，具有耐久的前进和后退十六烷接触角，其中含有这些酯与醇酸树脂或聚氨酯树脂。

8. 发明授权

US5176757A 1,1,2,2,3,3-hexafluorocyclopentane and use thereof in compositions and processes for cleaning 失效
标题翻译： 1,1,2,2,3,3-六氟环戊烷及其在组合物和清洗方法中的应用
公开(公告)号：US5176757A
公开(公告)日：1993-01-05
申请号：US783648
申请日：1991-10-28
申请人： Douglas R. Anton
发明人： Douglas R. Anton
IPC分类号： C07C17/23 , C07C23/08 , C11D7/50 , C23G5/028 , H05K3/26
CPC分类号： C23G5/02803 , C07C17/23 , C07C23/08 , C11D7/5081 , H05K3/26
摘要： The compound 1,1,2,2,3,3-hexafluorocyclopentane and mixtures thereof with alcohols, ethers, esters, ketones, nitromethane, and halogenated hydrocarbons are disclosed; as is a process for cleaning a solid surface which comprises treating the surface with said compound or said mixtures. Binary mixtures of 1,1,2,2,3,3-hexafluorocyclopentane either with about 27 to 35 weight percent methanol, or with about 21 to 29 weight percent ethanol are disclosed as azeotrope or azeotrope-like compositions and are particularly suited for use where solvent recovery and reuse is practiced.
摘要翻译：公开了化合物1,1,2,2,3,3-六氟环戊烷及其与醇，醚，酯，酮，硝基甲烷和卤代烃的混合物; 以及清洁固体表面的方法，包括用所述化合物或所述混合物处理所述表面。公开了1,1,2,2,3,3-六氟环戊烷与约27-35重量％甲醇或约21-29重量％乙醇的二元混合物作为共沸物或类共沸组合物，特别适用于其中进行溶剂回收和再利用。

9. 发明授权

US5076956A Compositions of octafluorotrifluoromethylpentane and nonafluorotrifluoromethylpentane and use thereof for cleaning solid surfaces 失效
标题翻译：八氟三氟甲基戊烷和九氟三氟甲基戊烷的组合物及其用于清洁固体表面的用途
公开(公告)号：US5076956A
公开(公告)日：1991-12-31
申请号：US621335
申请日：1990-11-29
申请人： Douglas R. Anton
发明人： Douglas R. Anton
IPC分类号： C11D7/26 , C11D7/28 , C11D7/50
CPC分类号： C11D7/261 , C11D7/5018 , C11D7/5081 , C11D7/5086 , C11D7/5095 , C11D7/263 , C11D7/264 , C11D7/266 , C11D7/28
摘要： Mixtures of the two fluorocarbon compounds 1,1,2,2,3,5,5,5-nonafluoro-4-trifluoromethylpentane and 1,1,1,2,2,5,5,5-octafluoro-4-trifluoromethylpentane with alcohols, ethers, esters, ketones, nitrogen-containing organic compounds, and halogenated hydrocarbons are disclosed; as is a process for cleaning a solid surface which comprises treating the surface with said mixtures. Ternary mixtures of about 88 to 96 weight percent total of said two fluorocarbon compounds with methanol (including at least about 11 weight percent 1,1,1,2,2,3,5,5,5-nonafluoro-4-trifluoromethylpentane and at least about 13 weight percent 1,1,1,2,2,5,5,5-octafluoro-4-trifluoromethylpentane) and with ethanol (including at least about 28 weight percent 1,1,1,2,2,3,5,5,5-nonafluoro-4-triluoformethylpentane and at least about 16 weight percent 1,1,1,2,2,5,5,5-octafluoro-4-trifluoromethyl-pentane) are disclosed as quasiazeotrope compositions that are useful where recovery and reuse of solvents is practiced.
摘要翻译：两种碳氟化合物1,1,2,2,3,5,5,5-九氟-4-三氟甲基戊烷和1,1,1,2,2,5,5,5-八氟-4-三氟甲基戊烷的混合物与醇，醚，酯，酮，含氮有机化合物和卤代烃; 清洁固体表面的方法也是如此，其中包括用所述混合物处理表面。所述两种碳氟化合物与甲醇（包括至少约11重量％的1,1,1,2,2,3,5,5,5-九氟-4-三氟甲基戊烷）的总共约88至96重量％的三元混合物，至少约13重量％的1,1,1,2,2,5,5,5-八氟-4-三氟甲基戊烷）和乙醇（包括至少约28重量％的1,1,1,2,2,3， 5,5,5-九氟-4-三氟甲基戊烷和至少约16重量％的1,1,1,2,2,5,5,5-八氟-4-三氟甲基 - 戊烷）作为可用的升华酸组合物其中实施溶剂的回收和再利用。

10. 发明授权

US5286825A Partially fluorinated compounds and polymers 失效
标题翻译：部分氟化的化合物和聚合物
公开(公告)号：US5286825A
公开(公告)日：1994-02-15
申请号：US76063
申请日：1993-06-14
申请人： Douglas R. Anton , William B. Farnham , Ming-Hong Hung , Ronald J. McKinney , Paul R. Resnick
发明人： Douglas R. Anton , William B. Farnham , Ming-Hong Hung , Ronald J. McKinney , Paul R. Resnick
IPC分类号： C07C43/313 , C07C51/08 , C07C55/32 , C07C69/63 , C07C211/09 , C07C211/15 , C07C255/10 , C07D305/10 , C07D317/16 , C07D317/28 , C07D317/30 , C07D317/42 , C08G63/682 , C08G73/10 , C08F224/00
CPC分类号： C08G73/1039 , C07C211/09 , C07C211/15 , C07C255/10 , C07C43/313 , C07C51/08 , C07C55/32 , C07C69/63 , C07D305/10 , C07D317/16 , C07D317/28 , C07D317/30 , C07D317/42 , C08G63/682
摘要： Partially fluorinated compounds of specified formulas that are useful as chemical intermediates and monomers are disclosed. Partially fluorinated polymers prepared from one of these compounds are also disclosed. Fluoro-2,2-dimethyldioxolanes and copolymers thereof are further disclosed.
摘要翻译：公开了可用作化学中间体和单体的具体化学式的部分氟化化合物。还公开了由这些化合物之一制备的部分氟化聚合物。进一步公开了氟-2,2-二甲基二氧戊环及其共聚物。

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