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    • 2. 发明授权
    • Alkadiene/vinylaromatic copolymers containing side groups, and their use
    • 含有侧基的二烯/乙烯基芳族共聚物及其用途
    • US5290874A
    • 1994-03-01
    • US854386
    • 1992-03-19
    • Dietmar BenderKlaus BronstertHelmut Mach
    • Dietmar BenderKlaus BronstertHelmut Mach
    • C08G61/04C08C19/00C08C19/30C08C19/42C08F8/00C08G61/00C10M143/16C08F287/00C08F293/00
    • C10M143/16C08C19/00C08C19/30C08C19/42C08F8/00C10M2205/04C10M2205/06C10M2205/10Y10S525/94
    • The novel alkadiene/vinyl-aromatic copolymers which contain side groups and have a random, block-like or star-like structure and whose polymerized alkadiene comonomer units are partially or completely selectively hydrogenated, and which contain one or more side groups having one or more radicals capable of (4+2) cycloaddition (Diels-Alder reaction) with dienophiles are suitable as such as viscosity index (VI) improvers or can be used for the preparation of dispersant VI improvers. For this purpose, they are reacted with one or more dienophiles which are capable of a Diels-Alder (4+2) cycloaddition reaction and preferably contain strongly polar functional groups. The resulting selectively hydrogenated alkadiene/vinylaromatic copolymers having one or more side groups which constitute a (4+2) cycloadduct or a Diels-Alder adduct can be modified in their performance characteristics by further reaction with ammonia, an organic amine, an alkylene oxide, a polyalkylene oxide and/or a condensate of ammonia and/or an organic amine with an alkylene oxide.
    • 含有侧基且具有无规,嵌段状或星形结构且其聚合的链烯二
      烯共聚单体部分或全部被选择性氢化的新型链二烯/乙烯基 - 芳族共聚物,其含有一个或多个具有一个或多个 具有双亲性的(4 + 2)环加成(Diels-Alder反应)的基团是适合的,如粘度指数(VI)改进剂或可用于制备分散剂VI改进剂。 为此,它们与一种或多种能够进行狄尔斯 - 阿尔德(4 + 2)环加成反应并且优选含有极性极性官能团的亲二烯体反应。 可以通过与氨,有机胺,环氧烷烃等进一步反应,将具有构成(4 + 2)环加成物或狄尔斯 - 阿尔德加合物的一个或多个侧基的所得选择性氢化的二烯烃/乙烯基芳族共聚物的性能特性改性, 聚氧化烯和/或氨和/或有机胺与烯化氧的缩合物。
    • 10. 发明授权
    • Stilbene compounds use in anionic polymerization
    • 苯乙烯化合物在阴离子聚合中的应用
    • US5081251A
    • 1992-01-14
    • US404206
    • 1989-09-07
    • Dietmar BenderKlaus Bronstert
    • Dietmar BenderKlaus Bronstert
    • C07D215/04C07C1/32C07C13/48C07C15/52C07C15/58C07C15/60C07C41/18C07C43/215C07C211/48C07D213/16C07D215/12C07D215/14C08C19/44C08F4/42C08F4/46C08F297/02C09B57/00
    • C07C43/215C07C13/48C07C15/52C07C15/58C07C211/48C07D213/16C08C19/44C08F4/46C07C2102/10
    • Stilbene compounds of the general formula Ia, Ib or IcR.sup.1 R.sup.2 R.sup.3 Ar.sup.1 --CH.dbd.CH--Ar.sup.3 R.sup.4 R.sup.5 R.sup.6 (Ia)R.sup.1 R.sup.2 R.sup.3 Ar.sup.1 --CH.dbd.CH--Ar.sup.2 R.sup.4 R.sup.5 R.sup.6 --CH.dbd.CH--Ar.sup.3 R.sup.7 R.sup.8 R.sup.9 (Ib)R.sup.1 R.sup.2 R.sup.3 Ar.sup.1 --CH.dbd.CH--Ar.sup.2 (CH.sub.2).sub.n Ar.sup.3 --CH.dbd.CH--Ar.sup.4 R.sup.4 R.sup.5 R.sup.6 (Ic)where Ar.sup.1 to Ar.sup.4 are identical or different aromatic or quasi-aromatic radicals and n is from 0 to 20 and where either at least one of the radicals R.sup.1 to R.sup.6 or R.sup.9 is hydrocarbon-solubilizing alkyl, alkoxy, dialkylamino or diarylamino of 4 or more carbon atoms in the alkyl moiety or, if formula Ic contains no radicals R.sup.1 to R.sup.6, n is not less than 4, are prepared by metalating a toluene/xylene analog R.sup.1 R.sup.2 R.sup.3 ArCH.sub.3 or H.sub.3 CR.sup.4 R.sup.5 R.sup.6 ArCH.sub.3 with an appropriate aldehyde Ar-CHO or dialdehyde OHC-Ar-CHO to form correspondingly substituted metal mono- or dialcoholates which are hydrolyzed/solvolyzed and dehydrated or pyrolyzed, and are used for preparing bifunctional initiators for anionic polymerization.
    • 通式Ia,Ib或Ic的二苯乙烯化合物R1R2R3Ar1-CH = CH-Ar3R4R5R6(Ia)R1R2R3Ar1-CH = CH-Ar2R4R5R6-CH = CH-Ar3R7R8R9(Ib)R1R2R3Ar1-CH = CH-Ar2(CH2)nAr3-CH = CH-Ar 4 R 4 R 5 R 6(Ic)其中Ar 1至Ar 4是相同或不同的芳族或准芳族基,n为0至20,并且其中基团R 1至R 6或R 9中​​的至少一个为烃溶解性烷基,烷氧基, 如果式Ic不含R 1至R 6基团,n不小于4,则通过用合适的醛Ar-金属化甲苯/二甲苯类似物R1R2R3ArCH3或H3CR4R5R6ArCH3制备二烷基氨基或二芳基氨基, CHO或二醛OHC-Ar-CHO形成相应取代的水解/溶剂分解和脱水或热解的金属单或二醇化物,并用于制备用于阴离子聚合的双功能引发剂。