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    • 1. 发明授权
    • Cyclohexenone derivatives and their use as herbicides
    • 环己烯酮衍生物及其作为除草剂的用途
    • US5034047A
    • 1991-07-23
    • US572357
    • 1990-08-24
    • Dieter KolassaJuergen KastThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • Dieter KolassaJuergen KastThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/06C07D271/10C07D333/22C07D413/04
    • C07D271/06A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/10C07D333/22C07D413/04
    • Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 : substituted or unsubstituted C.sub.1 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 : hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl or substituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 : hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A: a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m: 0 or 1;B: a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom; substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl; C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n: 1, 2 or 3;Y: not denoting hydrogen when m is O, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
    • 通式I的环己烯酮衍生物,其中取代基具有以下含义:R 1:取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,苯基,苄基或异丁基; R2:取代或未取代的C1-C6-烯基,C3-C6-烯基,C3-C6-炔基或苯基; R3:氢,C1-C6-烷基,C1-C10-烷基羰基,C1-C6-烷基磺酰基,C1-C4-三烷基甲硅烷基,C1-C4-二烷基膦酰基,C1-C4-二烷基硫代膦酰基,C3-C6-烯基,C3-C6- 烯基羰基,C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R4:氢,氰基,卤素,C1-C6-烷基或C1-C6-烷氧基羰基; A:取代或未取代的亚甲基可被氧或硫原子代替的C 1 -C 4 - 亚烷基链; m:0或1; B:含有至多2个氮原子和/或至多一个氧或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n:1,2或3; Y:当m为O时不表示氢,B为异唑-5-基,X为3-(C 3 -C 6环烷基),其环保可接受的盐,其制备方法及其作为除草剂的用途。
    • 2. 发明授权
    • Cyclohexenone derivatives
    • 环己烯酮衍生物
    • US5201935A
    • 1993-04-13
    • US934304
    • 1992-08-26
    • Dieter KolassaJuergen KasiThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • Dieter KolassaJuergen KasiThomas KuekenhoehnerNorbert MeyerKarl-Otto WestphalenBruno Wuerzer
    • A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/06C07D271/10C07D333/22C07D413/04
    • C07D271/06A01N43/10A01N43/14A01N43/50A01N43/74A01N43/80A01N43/82C07D261/04C07D261/08C07D271/10C07D333/22C07D413/04
    • Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl orsubstituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m 0 or 1;B a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom;substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl;C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n 1, 2 or 3;Y not denoting hydrogen when m is 0, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
    • 通式I的环己烯酮衍生物,其中取代基具有以下含义:R 1取代或未取代的C 1 -C 6 - 烷基,C 3 -C 6 - 烯基或C 3 -C 6 - 炔基,苯基,苄基或异丁基; R2取代或未取代的C1-C6-烷基,C3-C6-烯基,C3-C6-炔基或苯基; R3,C1-C6-烷基,C1-C10-烷基羰基,C1-C6-烷基磺酰基,C1-C4-三烷基甲硅烷基,C1-C4-二烷基膦酰基,C1-C4-二烷基硫代膦酰基,C3-C6-烯基,C3-C6-烯基羰基 ,C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R 4氢,氰基,卤素,C 1 -C 6 - 烷基或C 1 -C 6 - 烷氧基羰基; 取代或未取代的C1-C4亚烷基链,其中亚甲基可被氧或硫原子代替; m 0或1; B是含有至多2个氮原子和/或至多一个氧原子或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基,C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n 1,2或3; 当m为0时,Y不表示氢,B为异唑-5-基,X为3-(C 3 -C 6 - 环烷基)及其环境可接受的盐,其制备方法及其作为除草剂的用途。
    • 10. 发明授权
    • Carboxamides
    • US5201932A
    • 1993-04-13
    • US877365
    • 1992-05-04
    • Volker MaywaldWolfgang FreundGerhard HamprechtThomas KuekenhoehnerPeter PlathBruno WuerzerKarl-Otto Westphalen
    • Volker MaywaldWolfgang FreundGerhard HamprechtThomas KuekenhoehnerPeter PlathBruno WuerzerKarl-Otto Westphalen
    • A01N43/80C07D261/18C07D275/02C07D275/03
    • C07D275/03A01N43/80C07D261/18
    • Carboxamides Ia, Ib, Ic and Id ##STR1## (X=O, S; R.sup.1 =H, halogen, substituted or unsubstituted alkyl, substituted or unsubstituted benzyl, alkoxy, alkylthio, haloalkoxy, haloalkylthio, substituted or unsubstituted phenyl, substituted or unsubstituted phenoxy or phenylthio, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted alkynyl, substituted or unsubstituted cycloalkyl or cycloalkenyl; R.sup.1 '=cycloalkyl-substituted alkyl, substituted or unsubstituted alkenyl which may be epoxidized, substituted or unsubstituted cycloalkenyl; R.sup.2 =CHO, 4,5-dihydrooxazol-2-yl, COYR.sup.5, CONR.sup.6 R.sup.7 ; Y=O, S; R.sup.5 =H, substituted or unsubstituted alkyl, cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted cycloalkenyl, substituted or unsubstituted alkynyl, substituted or unsubstituted phenyl, a 5- or 6-membered heterocyclic radical containing up to 3 heteroatoms, benzotriazole, N-phthalimido, tetrahydrophthalimido, succinimido, maleiimido, 2,2-dimethyl-1,3-dioxolan-4-ylmethyl, 1,3-dioxolan-2-on-4-ylmethyl, and when Y.dbd.O: one equivalent of a cation from the group of the alkali or alkaline earth metals, Mn, Cu, Fe ammonium and substituted ammonium, a radical --N.dbd.CR.sup.8 R.sup.9 or --W--Z; R.sup.8, R.sup.9 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted haloalkyl, cycloalkyl, alkoxy, furanyl, substituted or unsubstituted phenyl; R.sup.8 +R.sup.9 =4-7-membered methylene chain; W=alkylene chain, ethoxyethylene chain, butylene, butynylene chain; Z=a molecular moiety bonded to W in the .omega.-position and is the same as that linked to W in the .alpha.-position of W; R.sup.6 .dbd.H, alkyl, cycloalkyl; R.sup.7 .dbd.H; alkyl; --C(O-alkyl).dbd.N--H or --(O--alkyl).dbd.N--alkyl; R.sup.6 +R.sup.7 =4-5-membered methylene chain; R.sup.3 .dbd.H, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl; R.sup.4 .dbd.H, OH, alkoxy, subsituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted alkenyl, substituted or unsubstituted alkynyl, di-(C.sub.1 -C.sub.4)-alkylamino, a substituted or unsubstituted 5- or 6-membered heterocyclic radical containing one or two heteroatoms, substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl; R.sub.3 +R.sub.4 =4-7-membered methylene chain which may be interrupted by O, S or N--CH.sub.3, or --(CH.sub.2).sub.3 --CO--)and their environmentally tolerated salts.The compounds Ia to Id are suitable as herbicides.