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    • 6. 发明授权
    • Process for the preparation of tapered copolymers via in situ dispersion
    • 通过原位分散制备锥形共聚物的方法
    • US5614579A
    • 1997-03-25
    • US352938
    • 1994-12-09
    • David M. RoggemanJames E. Hall
    • David M. RoggemanJames E. Hall
    • C08F297/04C08K3/02
    • C08F297/04
    • A process is provided for the preparation of tapered copolymers by the nonaqueous dispersion polymerization of a mixture of 30 to 70% by weight of a conjugated diolefin monomer, preferably butadiene, and 30 to 70% by weight of a vinyl substituted aromatic monomer, preferably styrene, in a liquid hydrocarbon dispersion medium with an anionic initiator catalyst system in the presence of a block copolymeric dispersing agent. At least one block of the dispersing agent is prepared prior to the dispersion polymerization reaction and at least one block of the dispersing agent is prepared in situ during the dispersion copolymerization. The block of the dispersing agent that is prepared in situ has the polymer structure of the tapered copolymer.
    • 提供了一种制备锥形共聚物的方法,该方法是通过非水分散聚合制备30至70重量%的共轭二烯烃单体,优选丁二烯和30至70重量%的乙烯基取代的芳族单体,优选苯乙烯 在具有阴离子引发剂催化剂体系的液体烃分散介质中,在嵌段共聚物分散剂存在下进行。 在分散聚合反应之前制备至少一个分散剂块,并且在分散共聚过程中原位制备至少一个分散剂块。 原位制备的分散剂块具有锥形共聚物的聚合物结构。
    • 9. 发明授权
    • Continuous method for preparing high cis-1,4 polybutadiene
    • 制备高顺式-1,4聚丁二烯的连续方法
    • US4501866A
    • 1985-02-26
    • US633814
    • 1984-07-23
    • David M. RoggemanShrikant R. MalaniJung W. Kang
    • David M. RoggemanShrikant R. MalaniJung W. Kang
    • C08F4/00C08F2/04C08F2/06C08F4/54C08F4/60C08F4/70C08F36/06C08F136/06C08F4/82
    • C08F136/06
    • A method for preparing high cis-1,4 polybutadiene by a continuous process which involves the continuous polymerization of 1,3-butadiene in solution under adiabatic conditions is provided. The method comprises the steps of: (I) feeding continuously to a single agitated polymerization reactor: (a) a monomer stream comprising 1,3-butadiene in a hydrocarbon solvent; (b) a preformed .pi. allyl catalyst stream formed by admixing a carboxylated metal oxy borate compound represented by the formulae (RCOOMO).sub.3 B or (ROCOOMO).sub.2 B-OR' wherein R and R' are alkyl radicals containing from 7 to 17 carbon atoms and M is nickel or cobalt, an organo aluminum compound, an alcohol, a small amount of 1,3-butadiene and a hydrocarbon solvent; and (c) a cocatalyst stream comprising a boron trifluoride complex with an alcohol; and (II) withdrawing continuously from said reactor high cis-1,4 polybutadiene at the same rate as said monomer, preformed catalyst and cocatalyst streams are fed to the reactor.In an additional embodiment of the invention, a method of preparing a preformed .pi. allyl catalyst having improved stability and solubility in hydrocarbon solvent is provided.High cis-1,4 polybutadiene polymers produced by the method of the invention have good green strength and tack and may be used as tire rubbers and impact modifiers for plastics.
    • 提供了一种通过连续方法制备高顺式-1,4聚丁二烯的方法,该方法涉及在绝热条件下在溶液中连续聚合1,3-丁二烯。 该方法包括以下步骤:(I)连续进料到单一搅拌聚合反应器中:(a)在烃溶剂中包含1,3-丁二烯的单体料流; (b)通过将由式(RCOOMO)3B或(ROCOOMO)2B-OR'表示的羧化金属硼酸硼酸盐化合物(RCOOMO)2B-OR'(其中R和R'是含有7至17个碳原子的烷基)和 M是镍或钴,有机铝化合物,醇,少量的1,3-丁二烯和烃溶剂; 和(c)包含三氟化硼配合物与醇的助催化剂流; 和(II)以与所述单体相同的速率从所述反应器高顺式-1,4-聚丁二烯中连续排出,将预制的催化剂和助催化剂物流进料到反应器中。 在本发明的另外的实施方案中,提供了一种制备具有改进的在烃溶剂中的稳定性和溶解度的预制的丙烯酸烯丙酯的方法。 通过本发明方法制备的高顺-1,4聚丁二烯聚合物具有良好的生坯强度和粘性,并可用作塑料的轮胎橡胶和抗冲击改性剂。