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    • 1. 发明授权
    • Acid based antifreeze composition
    • 酸性防冻剂组成
    • US07407599B2
    • 2008-08-05
    • US10755713
    • 2004-01-12
    • David E. TurcotteMichael DituroAlden W. OlsenArnold L. Coffey, Jr.Carl R. Stephens
    • David E. TurcotteMichael DituroAlden W. OlsenArnold L. Coffey, Jr.Carl R. Stephens
    • C09K5/00
    • C23F11/08C09K5/20
    • The present invention relates to a carboxylic acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic carboxylic organic acid, azoles, low levels of molybdates, a nitrite salt and/or nitrate salt and/or siloxane stabilized silicate, and combinations thereof, polyvinylpyrrolidone, provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的羧酸基防冻剂冷却剂制剂,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元羧酸有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐和/或硅氧烷稳定的硅酸盐的混合物及其组合,聚乙烯吡咯烷酮的组合​​提供了协同的保护作用 防止铝在水性液体中的气穴腐蚀降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 3. 发明授权
    • Monocarboxylic acid based antifreeze composition for diesel engines
    • 用于柴油机的单羧酸基防冻组合物
    • US06676847B2
    • 2004-01-13
    • US09851368
    • 2001-05-08
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • C09K750
    • C23F11/08C09K5/20
    • The present invention relates to a carboxylic acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic carboxylic organic acid, azoles, low levels of molybdates, a nitrite salt and/or nitrate salt and/or siloxane stabilized silicate, and combinations thereof, polyvinylpyrrolidone, provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的羧酸基防冻剂冷却剂制剂,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元羧酸有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐和/或硅氧烷稳定的硅酸盐的混合物及其组合,聚乙烯吡咯烷酮的组合​​提供了协同的保护作用 防止铝在水性液体中的气穴腐蚀降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 4. 发明授权
    • Monocarboxylic acid based antifreeze composition for diesel engines
    • 用于柴油机的单羧酸基防冻组合物
    • US06290870B1
    • 2001-09-18
    • US09513323
    • 2000-02-25
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • David E. TurcotteMichael A. DituroArnold L. Coffey, Jr.Alden W. OlsenCarl R. Stephens
    • C09K500
    • C09K5/20C23F11/08
    • The present invention relates to an acid based antifreeze coolant formulation for heavy duty applications such as for diesel engines which may be used for inhibition and prevention erosion and corrosion of aluminum and the corrosion of other metals exposed to an aqueous liquid in automotive coolant systems. The formulation further inhibits mineral scale. It may be packaged as an ethylene glycol based additive for use in new engines or in a concentrated inhibition package as an additive as for reinhibition of used coolant. The combination of a mixture of ethylene or propylene glycol, a monobasic aliphatic organic acid, azoles, low levels of molybdates, a combination of nitrite and/or nitrate salts, polyvinylpyrrolidone, a hydroxide salt, silicates and/or siloxane stabilized silicates with transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges.
    • 本发明涉及用于重型应用的酸性防冻剂冷却剂配方,例如用于柴油发动机,其可用于抑制和防止铝的侵蚀和腐蚀以及暴露于汽车冷却剂系统中的含水液体的其它金属的腐蚀。 该制剂进一步抑制矿物垢。 它可以作为用于新发动机的乙二醇基添加剂或作为添加剂的浓缩抑制包装被包装,用于重新抑制用过的冷却剂。 乙烯或丙二醇的混合物,一元脂族有机酸,唑类,低水平的钼酸盐,亚硝酸盐和/或硝酸盐的组合,聚乙烯吡咯烷酮,氢氧化物盐,硅酸盐和/或硅氧烷稳定化的硅酸盐与过渡金属的组合 化合物对水溶液中铝的气穴腐蚀提供协同的保护作用,降低腐蚀速率,并且在相对低的浓度和不同的pH范围内是有效的。
    • 8. 发明授权
    • Extended engine coolant lifetime through polymeric polycarboxylate secondary silicate stabilization
    • 通过聚合多羧酸酯二次硅酸盐稳定化延长发动机冷却剂寿命
    • US06203719B1
    • 2001-03-20
    • US08781848
    • 1997-01-10
    • David E. TurcotteFrances E. Lockwood
    • David E. TurcotteFrances E. Lockwood
    • C09K500
    • C23F11/08C09K5/10C09K5/20
    • The present invention provides corrosion inhibition formulations and compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids. The combination of a mixture of polymeric polycarboxylates, azoles, nitrate salts, phosphates, stabilized silicates and transition metal compounds provide a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids reducing the corrosion rate and is effective at relatively low concentrations and varying pH ranges. The addition of selected polymeric polycarboxylates not only significantly reduces glycol based coolant cavitation erosion-corrosion, heat rejecting aluminum corrosion, and hard water precipitates and scale, it has been discovered that polymeric polycarboxylates in combination with siloxane stabilized silicates enhance secondary silicate stabilization leading to improvement in aluminum corrosion protection and coolant life when utilized with selected amounts of the above-identified additives. The formulations are particularly suitable for automotive applications.
    • 本发明提供了用于抑制矿物垢和金属腐蚀的腐蚀抑制配方和组合物,特别是在含水液体存在下铝的气穴腐蚀。 聚合多羧酸盐,唑类,硝酸盐,磷酸盐,稳定的硅酸盐和过渡金属化合物的混合物的组合提供了抗水溶液中铝的气穴腐蚀的协同保护作用,降低了腐蚀速率,并且在相对低的浓度和变化的pH下是有效的 范围。 选择的聚合物多羧酸盐的添加不仅显着地减少了基于乙二醇的冷却剂空蚀腐蚀腐蚀,耐热铝腐蚀和硬水沉淀物和水垢,已经发现聚硅氧烷聚硅氧烷与硅氧烷稳定的硅酸盐结合增强了次级硅酸盐稳定性,从而改善了 当与所选量的上述添加剂一起使用时,防腐蚀和冷却剂寿命。 配方特别适用于汽车应用。