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1. 发明申请

US20090023604A1 Scavenger supports and the use thereof in a process for the extraction of metals 有权
标题翻译：清除剂支持及其在金属萃取过程中的应用
公开(公告)号：US20090023604A1
公开(公告)日：2009-01-22
申请号：US11597837
申请日：2005-06-13
申请人： David Alan Pears , Kevin Edward Treacher , Mohammed Nisar
发明人： David Alan Pears , Kevin Edward Treacher , Mohammed Nisar
IPC分类号： C40B50/08 , C08F26/02 , C08F26/06
CPC分类号： C22B3/24 , B01J20/02 , B01J20/26 , B01J20/265 , B01J20/267 , B01J20/32 , B01J20/3204 , B01J20/3208 , B01J20/3242 , B01J20/3244 , B01J20/3251 , B01J20/3253 , B01J20/3255 , B01J45/00 , C22B11/048 , Y02P10/214 , Y02P10/234 , Y02W30/54
摘要： There is provided a process for removing metal from solution wherein a solution comprising a metal is contacted with a scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution, characterised in that the scavenger support comprises a functionalised support comprising pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof attached to a support wherein a number of the pendant groups are reacted with an amine. Scavenger supports comprising a functionalised support comprising pendant 1,3-ketoester or 1,3-ketoamide groups of formula 1: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group, wherein a number of the pendant groups are reacted with an amine are also provided. Preferred scavenger supports include scavenger supports comprising pendant 3-iminoesters, 3-iminoamides, 2,3-enaminoesters or 2,3-enaminoamides pendant groups of Formula (3) or (4): wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group; R4 is a substituent group; and R5 is hydrogen or a substituent group, or R4 and R5 may optionally be linked in such a way so as to form an optionally substituted heterocyclic ring, or tautomers or salts thereof.
摘要翻译：提供了一种从溶液中除去金属的方法，其中包含金属的溶液与清除剂载体接触，由此清除剂载体与溶液中的至少一些金属结合，从而减少溶液中的金属的量，其特征在于，清除剂载体包括官能化载体，其包含选自1,3-酮酯或1,3-酮酰胺或其混合物的侧基，其连接到载体上，其中许多侧基与胺反应。清除剂载体包含官能化载体，其包括1,3-酮酯或式1的1,3-酮酰胺基团：其中R 1是任选取代的烃基，全卤代烃基或杂环基; X是O或NR 2，其中O或NR 2的游离价可任意地通过连接基键合到支持物上; 并且还提供了其中多个侧基与胺反应的氢，任选取代的烃基或杂环基。优选的清除剂载体包括清除剂载体，其包含3-氨基亚氨酸侧体，3-亚氨基酰胺，2,3-烯氨基酯或2,3-烯氨基酰胺侧基的式（3）或（4）的侧链：其中R1是任选取代的烃基，全卤代烃基或杂环基 X是O或NR 2，其中O或NR 2的游离价可任意地通过连接基键合到支持物上; R2是氢，任选取代的烃基或杂环基; R4是取代基; 并且R 5是氢或取代基，或者R 4和R 5可以任选地以这样的方式连接，以便形成任选取代的杂环，或其互变异构体或其盐。

2. 发明申请

US20090221419A1 Microencapsulated Catalyst-Ligand System 审中-公开
标题翻译：微胶囊化催化剂配体体系
公开(公告)号：US20090221419A1
公开(公告)日：2009-09-03
申请号：US12224214
申请日：2007-02-20
申请人： David Alan Pears , Kevin Edward Treacher , Mohammed Nisar
发明人： David Alan Pears , Kevin Edward Treacher , Mohammed Nisar
IPC分类号： B01J31/06
CPC分类号： B01J31/06 , B01J13/16 , B01J31/2208 , B01J37/0219
摘要： A microencapsulated catalyst-ligand system is provided comprising a catalyst and a ligand microencapsulated within a permeable polymer microcapsule shell, wherein the ligand is a polymeric ligand. Processes for the preparation of said microencapsulated catalyst-ligand system are also provided.
摘要翻译：提供了一种微胶囊化的催化剂 - 配体体系，其包括催化剂和微囊化在可渗透聚合物微胶囊壳内的配体，其中配体是聚合配体。还提供了用于制备所述微囊化催化剂 - 配体体系的方法。

3. 发明授权

US09234256B2 Scavenger supports and the use thereof in a process for the extraction of metals 有权
标题翻译：清除剂支持及其在金属萃取过程中的应用
公开(公告)号：US09234256B2
公开(公告)日：2016-01-12
申请号：US11597837
申请日：2005-06-13
申请人： David Alan Pears , Kevin Edward Treacher
发明人： David Alan Pears , Kevin Edward Treacher
IPC分类号： B01J20/02 , B01J20/10 , B01J20/26 , C22B3/24 , B01J20/32 , B01J45/00 , C22B3/00
CPC分类号： C22B3/24 , B01J20/02 , B01J20/26 , B01J20/265 , B01J20/267 , B01J20/32 , B01J20/3204 , B01J20/3208 , B01J20/3242 , B01J20/3244 , B01J20/3251 , B01J20/3253 , B01J20/3255 , B01J45/00 , C22B11/048 , Y02P10/214 , Y02P10/234 , Y02W30/54
摘要： There is provided a process for removing metal from solution wherein a solution comprising a metal is contacted with a scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution, characterized in that the scavenger support comprises a functionalized support comprising pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof attached to a support wherein a number of the pendant groups are reacted with an amine. Scavenger supports comprising a functionalized support comprising pendant 1,3-ketoester or 1,3-ketoamide groups of formula 1: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group, wherein a number of the pendant groups are reacted with an amine are also provided. Preferred scavenger supports include scavenger supports comprising pendant 3-iminoesters, 3-iminoamides, 2,3-enaminoesters or 2,3-enaminoamides pendant groups of Formula (3) or (4): wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group; R4 is a substituent group; and R5 is hydrogen or a substituent group, or R4 and R5 may optionally be linked in such a way so as to form an optionally substituted heterocyclic ring, or tautomers or salts thereof.
摘要翻译：提供了一种从溶液中除去金属的方法，其中包含金属的溶液与清除剂载体接触，由此清除剂载体与溶液中的至少一些金属结合，从而减少溶液中的金属的量，其特征在于，清除剂载体包括官能化载体，其包含选自1,3-酮酯或1,3-酮酰胺或其混合物的侧基，所述支链与支链反应，其中许多侧基与胺反应。清除剂载体包含官能化载体，其包括1,3-酮酯或式1的1,3-酮酰胺基团：其中R 1是任选取代的烃基，全卤代烃基或杂环基; X是O或NR 2，其中O或NR 2的游离价可任意地通过连接基键合到支持物上; 并且还提供了其中多个侧基与胺反应的氢，任选取代的烃基或杂环基。优选的清除剂载体包括清除剂载体，其包含3-氨基亚氨酸侧体，3-亚氨基酰胺，2,3-烯氨基酯或2,3-烯氨基酰胺侧基的式（3）或（4）的侧链：其中R1是任选取代的烃基，全卤代烃基或杂环基 X是O或NR 2，其中O或NR 2的游离价可任意地通过连接基键合到支持物上; R2是氢，任选取代的烃基或杂环基; R4是取代基; 并且R 5是氢或取代基，或者R 4和R 5可以任选地以这样的方式连接，以形成任选取代的杂环，或其互变异构体或其盐。

4. 发明申请

US20120211439A1 SCAVENGER SUPPORTS AND THE USE THEREOF IN A PROCESS FOR THE EXTRACTION OF METALS 失效
标题翻译： SCAVENGER支持及其在金属提取过程中的应用
公开(公告)号：US20120211439A1
公开(公告)日：2012-08-23
申请号：US13462288
申请日：2012-05-02
申请人： David Alan Pears , Kevin Edward Treacher
发明人： David Alan Pears , Kevin Edward Treacher
IPC分类号： B01D15/00
CPC分类号： C22B3/24 , B01J20/02 , B01J20/26 , B01J20/265 , B01J20/267 , B01J20/32 , B01J20/3204 , B01J20/3208 , B01J20/3242 , B01J20/3244 , B01J20/3251 , B01J20/3253 , B01J20/3255 , B01J45/00 , C22B11/048 , Y02P10/214 , Y02P10/234 , Y02W30/54
摘要： A scavenger support and a process for removing metal from solution by contacting the solution with the scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution. The scavenger support is a functionalised support having pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof having a structure according to formula 1, wherein a number of the pendant groups are reacted with an amine: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group.
摘要翻译：清除剂载体和通过使溶液与清除剂载体接触来从溶液中除去金属的方法，由此清除剂载体与溶液中的至少一些金属结合，从而减少溶液中金属的量。清除剂载体是具有选自1,3-酮酯或1,3-酮酰胺或其混合物的侧基的官能化载体，其具有根据式1的结构，其中多个侧基与胺反应：其中R1为任选取代的烃基，全卤代烃基或杂环基; X是O或NR 2，其中O或NR 2的游离价可任意地通过连接基键合到支持物上; 和R 2是氢，任选取代的烃基或杂环基。

5. 发明授权

US08652335B2 Scavenger supports and the use thereof in a process for the extraction of metals 失效
标题翻译：清除剂支持及其在金属萃取过程中的应用
公开(公告)号：US08652335B2
公开(公告)日：2014-02-18
申请号：US13462288
申请日：2012-05-02
申请人： David Alan Pears , Kevin Edward Treacher
发明人： David Alan Pears , Kevin Edward Treacher
IPC分类号： B01J20/10 , B01J20/26 , B01D15/38 , B01D15/00
CPC分类号： C22B3/24 , B01J20/02 , B01J20/26 , B01J20/265 , B01J20/267 , B01J20/32 , B01J20/3204 , B01J20/3208 , B01J20/3242 , B01J20/3244 , B01J20/3251 , B01J20/3253 , B01J20/3255 , B01J45/00 , C22B11/048 , Y02P10/214 , Y02P10/234 , Y02W30/54
摘要： A scavenger support and a process for removing metal from solution by contacting the solution with the scavenger support, whereby the scavenger support binds to at least some of the metal in solution thereby decreasing the amount of metal in solution. The scavenger support is a functionalised support having pendant groups selected from 1,3-ketoesters or 1,3-ketoamides or mixtures thereof having a structure according to formula 1, wherein a number of the pendant groups are reacted with an amine: wherein R1 is an optionally substituted hydrocarbyl, perhalogenated hydrocarbyl or heterocyclyl group; X is O or NR2, wherein the free valence of O or NR2 is bonded to a support optionally via a linker; and R2 is hydrogen, an optionally substituted hydrocarbyl, or heterocyclyl group.
摘要翻译：清除剂载体和通过使溶液与清除剂载体接触来从溶液中除去金属的方法，由此清除剂载体与溶液中的至少一些金属结合，从而减少溶液中金属的量。清除剂载体是具有选自1,3-酮酯或1,3-酮酰胺或其混合物的侧基的官能化载体，其具有根据式1的结构，其中多个侧基与胺反应：其中R1为任选取代的烃基，全卤代烃基或杂环基; X是O或NR 2，其中O或NR 2的游离价可任意地通过连接基键合到支持物上; 和R 2是氢，任选取代的烃基或杂环基。

6. 发明授权

US5792860A Substituted phthalocyanides with sulfonyl substituted with amino or carboxyl groups 失效
标题翻译：具有被氨基或羧基取代的磺酰基的取代的酞菁
公开(公告)号：US5792860A
公开(公告)日：1998-08-11
申请号：US700405
申请日：1996-09-25
申请人： Neil Bruce McKeown , Kevin Edward Treacher , Guy James Clarkson
发明人： Neil Bruce McKeown , Kevin Edward Treacher , Guy James Clarkson
IPC分类号： B41M5/26 , C07D487/22 , C09B47/067 , C09B47/08 , C09B47/18 , C09B67/22 , C09K19/34 , C09K19/38 , C09K19/40 , C09K19/60 , G02F1/13 , G11B7/248 , C07D478/22 , C09B47/00
CPC分类号： C07D487/22 , C09B47/0675 , C09B67/0035 , C09K19/3488 , C09K19/3861 , C09K19/40 , C09K19/406 , G11B7/248 , C09K2019/0429
摘要： Phthalocyanines of formula (I) are described, wherein M is a metal atom, metal compound or silicon or a compound of silicon or is 2H; R.sub.1 -R.sub.25 may be the same or different, provided that at least one of R.sub.1 -R.sub.25 has the Formula (II), wherein Y groups are independently H, C.sub.1-3 alkyl, halogen or CN; k=0 or 1; l=1-10; m=0 or 1; n=1-10; p=1-10; q=1-20; r=0 or 1; X may be H, Me, etc . . . Compounds of the above formulae are useful in a broad range of applications, including electrooptical devices, and for use in optical recording media. ##STR1##
摘要翻译： PCT No.PCT / GB95 / 00647 Sec。 371日期1996年9月25日 102（e）1996年9月25日PCT PCT 1995年3月23日PCT公布。第WO95 / 26381号公报日期：1995年10月5日描述了式（I）的酞菁，其中M是金属原子，金属化合物或硅或硅化合物或2H; R1-R25可以相同或不同，条件是R 1 -R 25中的至少一个具有式（II），其中Y基团独立地为H，C 1-3烷基，卤素或CN; k = 0或1; l = 1-10; m = 0或1; n = 1-10; p = 1-10; q = 1-20; r = 0或1; X可以是H，Me等。。。上述式的化合物可用于广泛的应用，包括电光装置，并用于光学记录介质。

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