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    • 6. 发明授权
    • Method of doping and implanting using arsine, antimony, and phosphine
substitutes
    • 使用胂,锑和膦替代物的掺杂和注入方法
    • US4988640A
    • 1991-01-29
    • US433080
    • 1989-11-06
    • David A. BohlingGregory T. MuhrDavid A. Roberts
    • David A. BohlingGregory T. MuhrDavid A. Roberts
    • C23C16/30
    • C23C16/30Y10S148/041Y10S148/083Y10S438/961
    • The present invention addresses the use of at least partially fluorinated organometallic compounds in reactive deposition applications. More specifically, the present invention addresses the use of the fluoroorganometallic compounds M(CF.sub.3).sub.3, or any M(C.sub.n F.sub.(2n+1)).sub.3-y H.sub.y compound where (y.ltoreq.2), M(CH.sub.2 CF.sub.3).sub.3 or any fluoroalkyl organometallics of the general formula M(C.sub.n H.sub.[(2n+1)-x] F.sub.x).sub.3-y H.sub.y, where y.ltoreq.2; x has a value 1.ltoreq.x.ltoreq.2n+1; and M=As, P, or Sb, in processes requiring deposition of the corresponding element. These uses include a number of different processes; the organometallic vapor phase epitaxy of compound semiconductor materials such as GaAs, InP, AlGaAs, InSb, etc. doping of SiO.sub.2 or borosilicate based glasses to enhance the reflow properties of the glass; in-situ n-type doping of silicon epitaxial material; sourcing of arsenic or phosphorus for ion implantation; chemical beam epitaxy and diffusion doping into electronic materials such as silicon dioxide, silicon and polycrystalline silicon. These types of materials generally have high volatilities, low toxicities, labile metal-ligand bonds, and stable decomposition products.Specifically, the use of tris-trifluoromethyl arsenic (AS(CF.sub.3) .sub.3) as a substitute for arsine in the manufacture of silicon integrated circuits, Group III-V compound semiconductors, optoelectronics and other electronic devices has been identified.
    • 本发明涉及至少部分氟化的有机金属化合物在反应沉积应用中的用途。 更具体地说,本发明涉及氟代有机金属化合物M(CF 3)3或任何M(CnF(2n + 1))3-yHy化合物的用途,其中(y 2),M(CH 2 CF 3)3或任何 (CnH [(2n + 1)-x] Fx)3-yHy的氟代烷基有机金属化合物,其中y <= 2; x具有值1
    • 9. 发明授权
    • Amino replacements for arsine, antimony and phosphine
    • 氨基取代胂,锑和膦
    • US5124278A
    • 1992-06-23
    • US586845
    • 1990-09-21
    • David A. BohlingGregory T. MuhrSherri L. Bassner
    • David A. BohlingGregory T. MuhrSherri L. Bassner
    • C23C16/30C30B25/02
    • C30B25/02C23C16/301C30B29/40Y10S148/016Y10S148/041Y10S148/056Y10S148/065
    • The present invention addresses the use of metalorganic amines as metallic donor source compounds in reactive deposition applications. More specifically, the present invention addresses the use of the amino-substituted metallic donor source compounds M(NR.sub.2).sub.3-x H.sub.x, where R is organic, alkyl or fluoroalkyl, and x is less than or equal to 2, and M=As, Sb or P, in processes requiring deposition of the corresponding element. These uses include a number of different processes; the metalorganic vapor phase epitaxy of compound semiconductor material such as GaAs, InP, AlGaAs, etc.; doping of SiO.sub.2 or borosilicate based glasses to enhance the reflow properties of the glass; in-situ n-type doping of silicon epitaxial material; sourcing of arsenic or phosphorus for ion implantation; chemical beam epitaxy (or MOMBE); and diffusion doping into electronic materials such as silicon dioxide, silicon and polycrystalline silcon. These types of materials generally have high volatilities, low toxicities, labile metal-ligand bonds, and stable decomposition products.Specifically, the use of tris(dialkylamino) arsenic (As(NR.sub.2).sub.3) as a substitute for arsine in the manufacture of silicon integrated circuits, Group III-V compound semiconductors, optoelectronics and other electronic devices has been identified.
    • 本发明涉及金属有机胺作为反应沉积应用中金属供体源化合物的用途。 更具体地,本发明涉及氨基取代的金属供体源化合物M(NR2)3-xHx的用途,其中R是有机基团,烷基或氟代烷基,x小于或等于2,M = As, Sb或P,在需要沉积相应元素的工艺中。 这些用途包括许多不同的过程; 化合物半导体材料如GaAs,InP,AlGaAs等的金属有机气相外延; 掺杂SiO 2或硼硅酸盐基玻璃以增强玻璃的回流性能; 硅外延材料的原位n型掺杂; 采购砷或磷进行离子注入; 化学束外延(或MOMBE); 以及扩散掺杂到诸如二氧化硅,硅和多晶硅的电子材料中。 这些类型的材料通常具有高挥发性,低毒性,不稳定的金属 - 配体键和稳定的分解产物。 具体来说,已经确定了在制造硅集成电路,III-V族化合物半导体,光电子学和其他电子器件中使用三(二烷基氨基)砷(As(NR 2)3)作为胂的替代物。