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1. 发明申请

US20090057194A1 Process For Upgrading Heavy Oil Using A Reactor WIth A Novel Reactor Separation System. 有权
标题翻译：使用反应堆升级重油的方法，新型反应器分离系统。
公开(公告)号：US20090057194A1
公开(公告)日：2009-03-05
申请号：US12212231
申请日：2008-09-17
申请人： Darush Farshid , James Murphy , Bruce Reynolds
发明人： Darush Farshid , James Murphy , Bruce Reynolds
IPC分类号： C10G45/00
CPC分类号： C10G65/02 , C10G49/12 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/4081 , C10G2300/703
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil, hydrogen, and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is separated internally, within one of more of the reactors, to separate only the converted oil and hydrogen into a vapor product while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor as a liquid product. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons in the next reactor, once again creating a mixture of unconverted oil, hydrogen, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：申请人开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油，氢和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。将混合物在更多的反应器之一内部分离，仅将转化的油和氢分离成蒸气产物，同时允许未转化的油和浆料催化剂作为液体产物继续进入下一个连续的反应器。然后将未转化的油的一部分转化为下一个反应器中的低沸点烃，再次产生未转化的油，氢，转化的油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以替代地部分转化，留下浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。

2. 发明申请

US20070138056A1 Process for upgrading heavy oil using a reactor with a novel reactor separation system 有权
标题翻译：使用具有新型反应器分离系统的反应器升级重油的方法
公开(公告)号：US20070138056A1
公开(公告)日：2007-06-21
申请号：US11303427
申请日：2005-12-16
申请人： Darush Farshid , James Murphy , Bruce Reynolds
发明人： Darush Farshid , James Murphy , Bruce Reynolds
IPC分类号： C10G45/00 , C10G65/02 , C10G69/02
CPC分类号： C10G65/02 , C10G49/12 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/4081 , C10G2300/703
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil, hydrogen, and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is separated internally, within one of more of the reactors, to separate only the converted oil and hydrogen into a vapor product while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor as a liquid product. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons in the next reactor, once again creating a mixture of unconverted oil, hydrogen, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：申请人开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油，氢和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。将混合物在更多的反应器之一内部分离，仅将转化的油和氢分离成蒸气产物，同时允许未转化的油和浆料催化剂作为液体产物继续进入下一个连续的反应器。然后将未转化的油的一部分转化为下一个反应器中的低沸点烃，再次产生未转化的油，氢，转化的油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以替代地部分转化，留下浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。

3. 发明授权

US07901569B2 Process for upgrading heavy oil using a reactor with a novel reactor separation system 有权
标题翻译：使用具有新型反应器分离系统的反应器升级重油的方法
公开(公告)号：US07901569B2
公开(公告)日：2011-03-08
申请号：US12212231
申请日：2008-09-17
申请人： Darush Farshid , James Murphy , Bruce Reynolds
发明人： Darush Farshid , James Murphy , Bruce Reynolds
IPC分类号： C10G1/08
CPC分类号： C10G65/02 , C10G49/12 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/4081 , C10G2300/703
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil, hydrogen, and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is separated internally, within one of more of the reactors, to separate only the converted oil and hydrogen into a vapor product while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor as a liquid product. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons in the next reactor, once again creating a mixture of unconverted oil, hydrogen, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：申请人开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油，氢和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。将混合物在更多的反应器之一内部分离，仅将转化的油和氢分离成蒸气产物，同时允许未转化的油和浆料催化剂作为液体产物继续进入下一个连续的反应器。然后将未转化的油的一部分转化为下一个反应器中的低沸点烃，再次产生未转化的油，氢，转化的油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以替代地部分转化，留下浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。

4. 发明授权

US07431822B2 Process for upgrading heavy oil using a reactor with a novel reactor separation system 有权
标题翻译：使用具有新型反应器分离系统的反应器升级重油的方法
公开(公告)号：US07431822B2
公开(公告)日：2008-10-07
申请号：US11303427
申请日：2005-12-16
申请人： Darush Farshid , James Murphy , Bruce Reynolds
发明人： Darush Farshid , James Murphy , Bruce Reynolds
IPC分类号： C10B57/02 , C10G51/02
CPC分类号： C10G65/02 , C10G49/12 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/4081 , C10G2300/703
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil, hydrogen, and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is separated internally, within one of more of the reactors, to separate only the converted oil and hydrogen into a vapor product while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor as a liquid product. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons in the next reactor, once again creating a mixture of unconverted oil, hydrogen, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：申请人开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油，氢和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。将混合物在更多的反应器之一内部分离，仅将转化的油和氢分离成蒸气产物，同时允许未转化的油和浆料催化剂作为液体产物继续进入下一个连续的反应器。然后将未转化的油的一部分转化为下一个反应器中的低沸点烃，再次产生未转化的油，氢，转化的油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以替代地部分转化，留下浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。

5. 发明申请

US20070138057A1 Process for upgrading heavy oil using a highly active slurry catalyst composition 有权
标题翻译：使用高活性浆料催化剂组合物对重油进行改质的方法
公开(公告)号：US20070138057A1
公开(公告)日：2007-06-21
申请号：US11305377
申请日：2005-12-16
申请人： Darush Farshid , Bruce Reynolds
发明人： Darush Farshid , Bruce Reynolds
IPC分类号： C10G45/00
CPC分类号： C10G49/12 , C10G65/02
摘要： The instant invention is directed to a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen, while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：本发明涉及一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油和转化油在连续混合物中在整个反应器中循环，而不限制混合物。混合物在反应器之间部分分离以除去产物和氢气，同时允许未转化的油和浆料催化剂继续进入下一个顺序的反应器，其中一部分未转化的油转化为低沸点烃，一次再次产生未转化的油，转化油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以部分地转化，留下高度浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。

6. 发明授权

US07708877B2 Integrated heavy oil upgrading process and in-line hydrofinishing process 有权
标题翻译：综合重油改造工艺和在线加氢精加工工艺
公开(公告)号：US07708877B2
公开(公告)日：2010-05-04
申请号：US11410826
申请日：2006-04-24
申请人： Darush Farshid , Bruce Reynolds
发明人： Darush Farshid , Bruce Reynolds
IPC分类号： C10G45/04
CPC分类号： C10G65/02 , C10G47/14 , C10G47/26 , C10G65/04 , C10G65/10 , C10G65/12 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/302 , C10G2300/4018 , C10G2300/4081
摘要： A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil is subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.
摘要翻译：已经开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。混合物在反应器之间部分分离以除去仅转化的油，同时允许未转化的油和浆料催化剂继续进入下一个顺序的反应器，其中一部分未转化的油转化为低沸点烃，再次产生未转化油，转化油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以部分地转化，留下高度浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。完全转化的油随后被加氢处理，以便几乎完全除去诸如硫和氮的氢原子。

7. 发明申请

US20090011931A1 Highly Active Slurry Catalyst Composition 有权
标题翻译：高活性浆料催化剂组合物
公开(公告)号：US20090011931A1
公开(公告)日：2009-01-08
申请号：US12212483
申请日：2008-09-17
申请人： Kaidong Chen , Bruce Reynolds , Darush Farshid
发明人： Kaidong Chen , Bruce Reynolds , Darush Farshid
IPC分类号： B01J27/051 , B01J27/049
CPC分类号： B01J23/85 , B01J27/049 , B01J27/0515 , B01J37/03 , B01J37/20 , C10G49/04
摘要： The instant invention is directed to the preparation of a slurry catalyst composition. The slurry catalyst composition is prepared in a series of steps, involving mixing a Group VIB metal oxide and aqueous ammonia to form an aqueous mixture and sulfiding the mixture to form a slurry. The slurry is then promoted with a Group VIII metal. Subsequent steps involve mixing the slurry with a hydrocarbon oil, and combining the resulting mixture with hydrogen gas (under conditions which maintain the water in a liquid phase) to produce the active slurry catalyst.
摘要翻译：本发明涉及制备淤浆催化剂组合物。浆料催化剂组合物是以一系列步骤制备的，包括将VIB族金属氧化物与氨水混合以形成含水混合物并硫化混合物以形成浆料。然后用VIII族金属促进该浆料。随后的步骤包括将浆料与烃油混合，并将所得混合物与氢气（在将水保持在液相中的条件下）组合以产生活性淤浆催化剂。

8. 发明申请

US20070138055A1 Process for upgrading heavy oil using a highly active slurry catalyst composition 有权
标题翻译：使用高活性浆料催化剂组合物对重油进行改质的方法
公开(公告)号：US20070138055A1
公开(公告)日：2007-06-21
申请号：US11303426
申请日：2005-12-16
申请人： Darush Farshid , Bruce Reynolds
发明人： Darush Farshid , Bruce Reynolds
IPC分类号： C10G65/02 , C10G45/00 , C10G69/02
CPC分类号： C10G65/00 , C10G65/10 , C10G65/18 , C10G2300/1022 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/1088 , C10G2300/4081 , C10G2300/703
摘要： Applicants have developed a new residuum full hydroconversion slurry reactor system that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen gas, while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor. A portion of the unconverted oil is then converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, products, hydrogen, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. Additional oil may be added at the interstage feed inlet, possibly in combination with slurry. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor.
摘要翻译：申请人开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。混合物在反应器之间部分分离以除去产物和氢气，同时允许未转化的油和浆料催化剂继续进入下一个连续的反应器。然后将未转化的油的一部分转化成低沸点烃，再次产生未转化的油，产物，氢气和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。可以在级间进料口加入额外的油，可能与浆料混合。油可以部分地转化，留下高度浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。

9. 发明申请

US20070138059A1 Integrated heavy oil upgrading process and in-line hydrofinishing process 有权
标题翻译：综合重油改造工艺和在线加氢精加工工艺
公开(公告)号：US20070138059A1
公开(公告)日：2007-06-21
申请号：US11410826
申请日：2006-04-24
申请人： Darush Farshid , Bruce Reynolds
发明人： Darush Farshid , Bruce Reynolds
IPC分类号： C10G45/00
CPC分类号： C10G65/02 , C10G47/14 , C10G47/26 , C10G65/04 , C10G65/10 , C10G65/12 , C10G2300/1022 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2300/302 , C10G2300/4018 , C10G2300/4081
摘要： A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil and converted oil to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the converted oil while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor where a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, converted oil, and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. Fully converted oil is subsequently hydrofinished for the nearly complete removal of hetoroatoms such as sulfur and nitrogen.
摘要翻译：已经开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油和转化的油在连续混合物中在整个反应器中循环，而不限制混合物。混合物在反应器之间部分分离以除去仅转化的油，同时允许未转化的油和浆料催化剂继续进入下一个顺序的反应器，其中一部分未转化的油转化为低沸点烃，再次产生未转化油，转化油和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以部分地转化，留下高度浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。完全转化的油随后被加氢处理，以便几乎完全除去诸如硫和氮的氢原子。

10. 发明申请

US20070138058A1 Integrated in-line pretreatment and heavy oil upgrading process 有权
标题翻译：综合在线预处理和重油升级过程
公开(公告)号：US20070138058A1
公开(公告)日：2007-06-21
申请号：US11305378
申请日：2005-12-16
申请人： Darush Farshid , Bruce Reynolds
发明人： Darush Farshid , Bruce Reynolds
IPC分类号： C10G45/00
CPC分类号： C10G47/26 , C10G47/14 , C10G65/10 , C10G65/12
摘要： A new residuum full hydroconversion slurry reactor system has been developed that allows the catalyst, unconverted oil, products and hydrogen to circulate in a continuous mixture throughout an entire reactor with no confinement of the mixture. The mixture is partially separated in between the reactors to remove only the products and hydrogen while permitting the unconverted oil and the slurry catalyst to continue on into the next sequential reactor. In the next reactor, a portion of the unconverted oil is converted to lower boiling point hydrocarbons, once again creating a mixture of unconverted oil, products, hydrogen and slurry catalyst. Further hydroprocessing may occur in additional reactors, fully converting the oil. The oil may alternately be partially converted, leaving a highly concentrated catalyst in unconverted oil which can be recycled directly to the first reactor. The slurry reactor system is, in this invention, preceded by an in-line pretreating step, such as hydrotreating or deasphalting. Following the slurry reactor system, fully converted oil may be subsequently hydrofinished for the removal of hetoroatoms such as sulfur and nitrogen.
摘要翻译：已经开发了一种新的残渣全加氢转化淤浆反应器系统，其允许催化剂，未转化的油，产物和氢气在连续混合物中在整个反应器中循环，而不限制混合物。混合物在反应器之间部分分离，以仅去除产物和氢气，同时允许未转化的油和浆料催化剂继续进入下一个顺序的反应器。在下一个反应器中，未转化的油的一部分转化为低沸点烃，再次产生未转化的油，产物，氢气和浆料催化剂的混合物。进一步的加氢处理可能发生在额外的反应器中，完全转化油。油可以部分地转化，留下高度浓缩的催化剂在未转化的油中，其可以直接再循环到第一反应器。在本发明中，浆料反应器系统之前是在线预处理步骤，例如加氢处理或脱沥青。在浆料反应器系统之后，随后可以将完全转化的油加氢处理以除去诸如硫和氮的氢原子。

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