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1. 发明授权

US10501695B2 Process for the intense conversion of residues, maximizing the gas oil yield 有权
公开(公告)号：US10501695B2
公开(公告)日：2019-12-10
申请号：US14974313
申请日：2015-12-18
申请人： AXENS
发明人： Frederic Morel , Jacinthe Frecon
IPC分类号： C10G65/12 , C10G67/04 , C10G65/10 , C10G67/00
CPC分类号： C10G67/049 , C10G65/10 , C10G65/12 , C10G67/00
摘要： The invention concerns a process for the intense conversion of a heavy hydrocarbon feed, comprising the following steps: a) a first step for ebullated bed hydroconversion; b) a step for separating at least a portion of the hydroconverted liquid effluent obtained from step a); c) a step for hydrocracking at least a portion of the vacuum gas oil fraction obtained from step b); d) a step for fractionating at least a portion of the effluent obtained from step c); e) a step for recycling at least a portion of the unconverted vacuum gas oil fraction obtained from step d) to said first hydroconversion step a).

2. 发明申请

US20170145320A1 RESIDUE SLURRY BED HYDROCRACKING METHOD AND DEVICE 审中-公开
公开(公告)号：US20170145320A1
公开(公告)日：2017-05-25
申请号：US15319808
申请日：2015-06-18
申请人： CATECH TECHNOLOGY CO., LTD.
发明人： Suan LI , Qingyu DENG , Gang XIE
IPC分类号： C10G47/26 , C10G47/02
CPC分类号： C10G47/26 , C10G47/02 , C10G65/10 , C10G65/12 , C10G2300/80
摘要： A residue slurry bed hydrocracking method and device is used in the deep processing of crude oil. The processes of “slurry bed+fixed bed” reactor are applied. Raw materials, additives, catalysts and hydrogen are mixed, heated and pressurized before they are introduced into the slurry reactor, where thermal cracking and catalytic reactions occur under high hydrogen partial pressure. The coke, catalysts and additives in the reaction process are separated at the bottom of the heated high pressure separator (HHPS). Then they are transferred in a conventional fixed bed reactor to do further hydrocracking and hydrorefining, to product light oil products. The new Mo-Fe based catalyst developed in the invention can improve the activity of the main reactions, inhibit the reaction of coke production, and reduce system pressure from 20 Mpa to 17 Mpa, which can reduce device costs. Conversion rates can reach 90-95%, with the yield of light oil reaching 80-83%.

3. 发明申请

US20170029724A1 INTEGRATED EBULLATED-BED HYDROPROCESSING, FIXED BED HYDROPROCESSING AND COKING PROCESS FOR WHOLE CRUDE OIL CONVERSION INTO HYDROTREATED DISTILLATES AND PETROLEUM GREEN COKE 有权
标题翻译：集成的EBULLED-BED HYDROPROCESSING，固定床加氢和凝结过程，用于全部原油转化为加氢馏分和石油绿焦
公开(公告)号：US20170029724A1
公开(公告)日：2017-02-02
申请号：US15220840
申请日：2016-07-27
申请人： Saudi Arabian Oil Company
发明人： Omer Refa KOSEOGLU
IPC分类号： C10G69/06 , C10B55/00
CPC分类号： C10G69/06 , C10B55/00 , C10G9/005 , C10G65/10 , C10G69/00 , C10G69/14 , C10G2300/202 , C10G2300/4081
摘要： A system and process for upgrading a whole crude oil feed in an integrated ebullated-bed and hydrotreater is provided in which the whole crude oil is flashed into a flashed straight run distillates fraction and an atmospheric residue fraction. The atmospheric residue fraction is hydroprocessed in an ebullated-bed reaction zone, while the flashed straight run distillates fraction and the products fraction produced from the ebullated-bed reaction zone are hydrotreated in a fixed-bed reaction zone. The unconverted residue fraction from the ebullated-bed reaction zone is processed in a coker unit to produce high quality petroleum green coke.
摘要翻译：提供了一种用于升级整体沸腾床和加氢处理器中的整个原油进料的系统和方法，其中将全部原油闪蒸成闪蒸的直馏馏分和常压残渣馏分。常压残渣馏分在沸腾床反应区中加氢处理，而闪蒸的直馏馏分，将从沸腾床反应区产生的产物馏分在固定床反应区加氢处理。来自沸腾床反应区的未转化的残余物部分在焦化器单元中加工以产生高质量的石油焦炭。

4. 发明申请

US20170009155A1 INTEGRATED HYDROCRACKING PROCESS 审中-公开
标题翻译：一体化水力过程
公开(公告)号：US20170009155A1
公开(公告)日：2017-01-12
申请号：US15121237
申请日：2014-12-23
申请人： Arno Johannes Maria OPRINS , SAUDI BASIC INDUSTRIES CORPORATION , SABIC GLOBAL TECHNOLOGIES B.V.
发明人： Arno Johannes Maria OPRINS
IPC分类号： C10G69/00
CPC分类号： C10G69/00 , C10G9/36 , C10G65/10 , C10G69/06 , C10G2300/1033 , C10G2400/20 , C10G2400/30
摘要： An integrated hydrocracking process for production of olefinic and aromatic petrochemicals from a hydrocarbon feedstock including crude oil. An object of the present invention is to provide an integrated hydrocracking process for the production of olefinic and aromatic petrochemicals from a hydrocarbon feedstock comprising crude oil in which the portion of the crude oil converted to LPG is increased significantly.
摘要翻译：一种用于从包括原油的烃原料生产烯烃和芳族石化产品的综合加氢裂化方法。本发明的目的是提供一种用于从包含原油的烃原料生产烯烃和芳族石化产品的综合加氢裂化方法，其中转化成LPG的原油部分显着增加。

5. 发明授权

US09487714B2 Hydrocracking process selective for improved distillate and improved lube yield and properties 有权
公开(公告)号：US09487714B2
公开(公告)日：2016-11-08
申请号：US14011061
申请日：2013-08-27
申请人： William J. Novak , Robert Allen Bradway , Stuart S. Shih , Timothy Lee Hilbert , Michel Daage
发明人： William J. Novak , Robert Allen Bradway , Stuart S. Shih , Timothy Lee Hilbert , Michel Daage
IPC分类号： C10G47/18 , C10G49/04 , C10G65/10 , C10G65/12
CPC分类号： C10G65/10 , C10G47/18 , C10G49/04 , C10G65/12 , C10G2300/1074 , C10G2300/202 , C10G2300/301 , C10G2300/302 , C10G2300/304 , C10G2300/307 , C10G2300/4018 , C10G2300/4025 , C10G2400/04 , C10G2400/08 , C10G2400/10
摘要： This invention relates to a process involving hydrocracking of a feedstream in which a converted fraction can exhibit relatively high distillate product yields and maintained or improved distillate fuel properties, while an unconverted fraction can exhibit improved properties particularly useful in the lubricant area. In this hydrocracking process, it can be advantageous for the yield of converted/unconverted product for gasoline fuel application to be reduced or minimized, relative to converted distillate fuel and unconverted lubricant. Catalysts and conditions can be chosen to assist in attaining, or to optimize, desirable product yields and/or properties.

6. 发明申请

US20160177203A1 PROCESS FOR THE INTENSE CONVERSION OF RESIDUES, MAXIMIZING THE GASOLINE YIELD 有权
标题翻译：积极改变残留物的过程，最大限度地提高汽油的使用寿命
公开(公告)号：US20160177203A1
公开(公告)日：2016-06-23
申请号：US14974968
申请日：2015-12-18
申请人： AXENS
发明人： Frederic MOREL , Jacinthe FECON
IPC分类号： C10G67/04
CPC分类号： C10G67/049 , C10G65/10 , C10G65/12 , C10G67/00
摘要： A process for the intense conversion of a heavy hydrocarbon feed, comprising a) ebullated bed hydroconversion of the feed; b) separating at least a portion of hydroconverted liquid effluent obtained from a); c)i) either hydrotreatment of at least a portion of the gas oil fraction and of the vacuum gas oil fraction obtained from b), ii) or hydrocracking at least a portion of gas oil fraction and vacuum gas oil fraction obtained from b); d) fractionation of at least a portion of the effluent obtained from c)i) or c)ii); e) recycling at least a portion of unconverted vacuum gas oil fraction obtained from the fractionation d) to said first hydroconversion a); f) hydrocracking at least a portion of gas oil fraction obtained from fractionation d); g) recycling all or a portion of effluent obtained from f) to the fractionation d).
摘要翻译：一种重质烃进料的强烈转化的方法，包括a）进料的沸腾床加氢转化; b）分离从a）获得的至少一部分加氢转化的液体流出物; c）i）对至少一部分粗柴油馏分和从b）获得的减压瓦斯油馏分进行加氢处理，ii）或加氢裂化从b）得到的瓦斯油馏分和减压瓦斯油馏分的至少一部分; d）从c）i）或c）ii）中获得的至少一部分流出物的分馏; e）将从分馏d）获得的至少一部分未转化的减压瓦斯油馏分循环到所述第一加氢转化a）; f）加氢裂化从分馏得到的至少一部分粗柴油馏分d）; g）将从f）获得的所有或部分流出物全部或部分再循环至分馏d）。

7. 发明授权

US09145523B2 Upgrading of hydrocarbons by hydrothermal process 有权
公开(公告)号：US09145523B2
公开(公告)日：2015-09-29
申请号：US14688007
申请日：2015-04-16
申请人： Saudi Arabian Oil Company
发明人： Ki-Hyouk Choi , Ashok K. Punetha , Mohammed R. Al-Dossary , Mohammad F. Aljishi
IPC分类号： C10G47/32 , C10G65/10
CPC分类号： C10G65/10 , C10G47/32 , C10G49/18 , C10G49/22 , C10G65/02 , C10G2300/42 , C10G2300/805
摘要： A hydrocarbon feedstock upgrading method is provided. The method includes supplying the hydrocarbon feedstock, water and a pre-heated hydrogen donating composition to a hydrothermal reactor where the mixed stream is maintained at a temperature and pressure greater than the critical temperatures and pressure of water in the absence of catalyst for a residence time sufficient to convert the mixed stream into a modified stream. The hydrogen donating composition is pre-heated and maintained at a temperature of greater than about 50° C. for a period of at least about 10 minutes. The modified stream includes upgraded hydrocarbons relative to the hydrocarbon feedstock. The modified stream is then separated into a gas stream and a liquid stream and the liquid stream is separated into a water stream and an upgraded hydrocarbon product stream.

8. 发明申请

US20150136645A1 METHOD FOR MAKING MIDDLE DISTILLATES AND A HEAVY VACUUM GAS OIL FCC FEEDSTOCK 有权
标题翻译：制备中间馏分和重油气体FCC原料的方法
公开(公告)号：US20150136645A1
公开(公告)日：2015-05-21
申请号：US14541874
申请日：2014-11-14
申请人： Subhasis Bhattacharya , Ujjal Kumar Mukherjee , Marvin I. Greene
发明人： Subhasis Bhattacharya , Ujjal Kumar Mukherjee , Marvin I. Greene
IPC分类号： C10G65/12 , C10G65/10
CPC分类号： C10G65/12 , C10G65/10 , C10G69/00
摘要： The present invention is directed to a refining process for producing hydroprocessed distillates and a heavy vacuum gas oil (HVGO). The process produces middle distillates that have reduced nitrogen and sulfur content, while simultaneously producing a 900° F.+ (482° C.+) HVGO stream useful as a fluidized catalytic cracking (FCC) unit feedstock.
摘要翻译：本发明涉及一种用于生产加氢馏出物和重质真空瓦斯油（HVGO）的精制方法。该方法产生具有降低的氮和硫含量的中间馏分，同时产生用作流化催化裂化（FCC）单元原料的900°F +（482℃+）HVGO流。

9. 发明授权

US09028674B2 Conversion of asphaltenic pitch within an ebullated bed residuum hydrocracking process 有权
标题翻译：在沸腾床残渣加氢裂化过程中沥青沥青的转化
公开(公告)号：US09028674B2
公开(公告)日：2015-05-12
申请号：US13743936
申请日：2013-01-17
申请人： Lummus Technology Inc.
发明人： Ujjal K. Mukherjee , Mario C. Baldassari , Marvin I. Greene
IPC分类号： C10G65/10 , C10G47/26 , C10G1/08
CPC分类号： B01J8/18 , B01J19/245 , B01J2208/00796 , B01J2219/24 , C10G1/08 , C10G1/086 , C10G47/26 , C10G65/10 , C10G65/12 , C10G67/02 , C10G67/049 , C10G2300/701
摘要： A process for upgrading residuum hydrocarbons including: feeding pitch, hydrogen, and a partially spent catalyst recovered from a hydrocracking reactor to an ebullated bed pitch hydrocracking reactor; contacting the pitch, hydrogen, and the catalyst in the ebullated bed pitch hydrocracking reactor at reaction conditions of temperature and pressure sufficient to convert at least a portion of the pitch to distillate hydrocarbons; and separating the distillate hydrocarbons from the catalyst. In some embodiments, the process may include selecting the ebullated bed pitch hydrocracking reactor reaction conditions to be at or below the level where sediment formation would otherwise become excessive and prevent continuity of operations.
摘要翻译：一种用于升级残油烃的方法，包括：将沥青，氢气和从加氢裂化反应器回收的部分废催化剂进料到沸腾床沥青加氢裂化反应器; 在沸腾床沥青加氢裂化反应器中的沥青，氢气和催化剂在足以将至少一部分沥青转化成馏出物烃的温度和压力的反应条件下接触; 并将馏出物烃与催化剂分离。在一些实施方案中，该方法可以包括选择沸腾床沥青加氢裂化反应器反应条件处于或低于沉淀物形成否则将变得过大并防止操作连续性的水平。

10. 发明申请

US20150060331A1 METHOD FOR MULTI-STAGED HYDROPROCESSING USING QUENCH 审中-公开
标题翻译：使用Quench进行多阶段加氢处理的方法
公开(公告)号：US20150060331A1
公开(公告)日：2015-03-05
申请号：US14537284
申请日：2014-11-10
申请人： UOP LLC
发明人： Paul A. Sechrist , Robert L. Bunting , Nicholas W. Bridge , RIchard K. Hoehn
IPC分类号： C10G65/12 , C10G65/10 , C10G65/04
CPC分类号： C10G65/12 , C10G65/02 , C10G65/04 , C10G65/10 , C10G2300/4006
摘要： Methods for processing a hydrocarbonaceous feedstock flows are provided. In one embodiment, the method includes providing two or more hydroprocessing stages disposed in sequence, each hydroprocessing stage having a hydroprocessing reaction zone with a hydrogen requirement and each stage in fluid communication with the preceding stage. The hydrocarbonaceous feedstock flow may be separated into portions of fresh feed for each hydroprocessing stage, and the first portion of fresh feed to the first hydroprocessing stage is heated. The heated first portion of fresh feed may be supplied with hydrogen from the hydrogen source in an amount satisfying substantially all of the hydrogen requirements of the hydroprocessing stages to a first hydroprocessing zone. The unheated second portion of fresh feed is injected counter current to the process flow as quench at one or more locations in one or more of the reaction zones.
摘要翻译：提供了处理含烃原料流的方法。在一个实施方案中，该方法包括提供依次设置的两个或更多个加氢处理阶段，每个加氢处理阶段具有氢需求的加氢处理反应区，每个阶段与前一阶段流体连通。烃类原料流可以分离成每个加氢处理阶段的新鲜进料的一部分，并且加热到第一加氢处理阶段的新鲜进料的第一部分。新鲜进料的加热的第一部分可以从氢源中以基本上满足加氢处理阶段的所有氢气要求的量向第一加氢处理区供应氢气。新鲜进料的未加热的第二部分在一个或多个反应区中的一个或多个位置处的淬火被逆流地流入工艺流程。

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