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    • 1. 发明申请
    • Process for reductively aminating ketones and aldehydes with aqueous amines and catalysts suitable therefor
    • 用含胺胺和合适的催化剂还原胺化酮和醛的方法
    • US20070078282A1
    • 2007-04-05
    • US11526337
    • 2006-09-25
    • Daniel SchrammDaniel DeckerKlaus ForstingerKlemens Flick
    • Daniel SchrammDaniel DeckerKlaus ForstingerKlemens Flick
    • C07C209/26
    • C07C209/26C07C211/27C07C211/29
    • A process for preparing amines of the general formula (I) R1R2CHNR3R4  (I) in which R1, R2, R3 and R4 are each independently hydrogen, straight-chain or branched, halogenated or halogen-free C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, by catalytic, hydrogenating amination of carbonyl compounds of the general formula (II) R1—C(═O)—R2  (II)with nitrogen compounds of the general formula (III) HNR3R4  (III)in the presence of bifunctional catalyst systems comprising a.) a hydrogenation-active catalyst component comprising one or more metals of transition group 8 of the Periodic Table and b.) one or more solid, acidic cocatalysts, wherein the hydrogenating amination is carried out in the presence of aqueous ammonia or aqueous amine of the formula (III) and at least one organic solvent miscible with ammonia or the aqueous amine of the formula (III).
    • 制备通式(I)的胺的方法<?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 2&lt; 2&gt; (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R R 1 -C(-O)-R 与通式(III)的氮化合物< 公式描述=“内联公式”end =“lead”?> HNR <3> 4(III)<?in-line-formula description =“In- 在包含a)包含一种或多种元素周期表第8族金属的氢化活性催化剂组分和b)一种或多种固体,酸性的双官能催化剂体系的存在下,式“末端=”尾“ 助催化剂,其中所述氢化胺化在式(III)的氨水或胺水溶液的存在下进行,和至少一种可与氨或式(III)的胺水溶液混合的至少一种有机溶剂。
    • 2. 发明授权
    • Process for reductively aminating ketones and aldehydes with aqueous amines and catalysts suitable therefor
    • 用含胺胺和合适的催化剂还原胺化酮和醛的方法
    • US07323599B2
    • 2008-01-29
    • US11526337
    • 2006-09-25
    • Daniel SchrammDaniel DeckerKlaus ForstingerKlemens Flick
    • Daniel SchrammDaniel DeckerKlaus ForstingerKlemens Flick
    • C07C209/00
    • C07C209/26C07C211/27C07C211/29
    • A process for preparing amines of the general formula (I) R1R2CHNR3R4  (I) in which R1, R2, R3 and R4 are each independently hydrogen, straight-chain or branched, halogenated or halogen-free C1-C12-alkyl, C3-C12-cycloalkyl, C6-C10-aryl or C7-C11-aralkyl, by catalytic, hydrogenating amination of carbonyl compounds of the general formula (II) R1—C(═O)—R2  (II) with nitrogen compounds of the general formula (III) HNR3R4  (III) in the presence of bifunctional catalyst systems comprising a.) a hydrogenation-active catalyst component comprising one or more metals of transition group 8 of the Periodic Table and b.) one or more solid, acidic cocatalysts, wherein the hydrogenating amination is carried out in the presence of aqueous ammonia or aqueous amine of the formula (III) and at least one organic solvent miscible with ammonia or the aqueous amine of the formula (III).
    • 制备通式(I)的胺的方法<?in-line-formula description =“In-line Formulas”end =“lead”?> R&lt; 2&lt; 2&gt; (I)<?in-line-formula description =“In-line Formulas”end =“tail”?>其中R R 1 -C(-O)-R 2 与式(III)的氮化合物相同的式(III)中,式(II)<?in-line-formula description =“In-line formula”end =“tail” 公式“end =”lead“?> HNR <3> 4(III)<?in-line-formula description =”In-line Formul 在包含a)包含一种或多种元素周期表第8族金属的氢化活性催化剂组分和b)一种或多种固体,酸性助催化剂的双官能催化剂体系存在下,ae“end =”tail“ 其中所述氢化胺化在式(III)的氨水或胺水溶液的存在下进行,和至少一种与氨或式(III)的胺水溶液混合的至少一种有机溶剂。
    • 8. 发明申请
    • RESINS FROM UNSATURATED POLYESTERS AND POLYSILAZANES AND DUROPLASTIC REACTION RESIN MOULDING MATERIALS PRODUCED THEREFROM
    • 来自不饱和聚酯和多晶硅的树脂和生产的酚醛树脂模塑材料
    • US20130338309A1
    • 2013-12-19
    • US13825929
    • 2011-09-13
    • Monika BauerSebastian SteffenDaniel DeckerFrank Richter
    • Monika BauerSebastian SteffenDaniel DeckerFrank Richter
    • C08G63/91C08K7/06
    • C08G63/918C08K7/06C08L67/06
    • The invention relates to an unsaturated polyester resin containing a polyester or a polyester mixture, produced from at least one unsaturated dicarboxylic acid and at least one diol; and at least one silazane which is accessible for copolymerization with a C═C double bond of the dicarboxylic acid. The invention also relates to an unsaturated polyester resin moulding material which can be obtained or is obtained by cross-linking an unsaturated polyester resin as defined above. Said moulding material can optionally contain reinforcing materials. Said unsaturated polyester resin can be produced using the following steps: (a) a polyester from at least one diol and at least one unsaturated dicarboxylic acid is provided; (b) at least one silazane which is accessible for copolymerization which a C═C double bond of the dicarboxylic acid is provided; (c) the components are mixed according to (a) and (b). The unsaturated polyester resin moulding material can be produced from the above-mentioned polyester resin by hardening thereof by means of a radical initiator.
    • 本发明涉及含有由至少一种不饱和二羧酸和至少一种二醇制成的聚酯或聚酯混合物的不饱和聚酯树脂; 和至少一个可与二羧酸的C = C双键共聚的硅氮烷。 本发明还涉及一种不饱和聚酯树脂成型材料,其可以通过交联如上所述的不饱和聚酯树脂获得或获得。 所述模制材料可任选地包含增强材料。 所述不饱和聚酯树脂可以使用以下步骤制备:(a)提供至少一种二醇和至少一种不饱和二羧酸的聚酯; (b)提供二羧酸的C = C双键的至少一种可用于共聚的硅氮烷; (c)根据(a)和(b)将组分混合。 不饱和聚酯树脂成型材料可以通过使用自由基引发剂进行硬化而由上述聚酯树脂制造。