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    • 4. 发明申请
    • MULTI-LAYERED LIGNOCELLULOSIC MOLDED BODIES WITH LOW FORMALDEHYDE EMISSIONS
    • 具有低甲醛排放的多层液晶成型体
    • US20110171473A1
    • 2011-07-14
    • US13119882
    • 2009-09-09
    • Daniel KäsmayrStephan WeinkötzChristian BeilMichael SchmidtMichael Finkenauer
    • Daniel KäsmayrStephan WeinkötzChristian BeilMichael SchmidtMichael Finkenauer
    • B32B27/18B32B37/02B32B37/10B32B27/42B32B27/40
    • B27N1/003B32B5/22B32B5/30B32B21/02B32B21/13B32B2260/025B32B2260/046B32B2264/065B32B2419/00B32B2479/00B32B2553/00B32B2605/00Y10T156/10Y10T428/31511Y10T428/31573Y10T428/31866
    • A multilayer lignocellulose-containing molding comprising A) a middle layer or a plurality of middle layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (a) and B) a covering layer or a plurality of covering layers comprising lignocellulose-containing particles which is/are obtainable by using a binder (b), the binder (a) being selected from the group consisting of (a1) formaldehyde resins and (a2) an organic isocyanate having at least two isocyanate groups; the binder (b) comprising the following components: an aqueous component (I) comprising (i) a polymer A which is composed of the following monomers: a) from 70 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 30% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) and, optionally, (ii) a low molecular weight crosslinker having at least two functional groups which are selected from the group consisting of hydroxyl, carboxyl and derivatives thereof, primary, secondary and tertiary amine, epoxy, aldehyde and, optionally, a component (II), as an aqueous dispersion, comprising one or more polymer(s) M which is composed of the following monomers: a) from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide and/or at least one hydroxyalkyl group (monomer(s) M1) and b) from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and, optionally, customary additives as component (III), and, where the binder (a) comprises a formaldehyde resin, the binder (b) comprising formaldehyde scavengers.
    • 一种含多层木素纤维素的成型体,其包含A)中间层或多层含有含木素纤维素的颗粒的中间层,其可通过使用粘合剂(a)获得,B)覆盖层或多层包含木质纤维素 - 所述粘合剂(a)选自(a1)甲醛树脂和(a2)具有至少两个异氰酸酯基的有机异氰酸酯的组合物, 粘合剂(b)包含以下组分:水性组分(I),其包含(i)聚合物A,其由以下单体组成:a)70至100重量%的至少一种烯键式不饱和单 - 和/ 或二羧酸(单体A1)和b)0至30重量%的至少一种其它不同于单体A1(单体A2)的烯属不饱和单体,和任选地,(ⅱ)低 分子量交联剂,其具有至少两个选自羟基,羧基及其衍生物的官能团,伯胺,仲胺和叔胺,环氧基,醛和任选的作为水分散体的组分(II),包括 一种或多种由以下单体组成的聚合物M:a)0至50重量%的至少一种烯属不饱和单体,其包含至少一个环氧化物和/或至少一个羟烷基(单体 )M1)和b)50至100重量%的l (单体M2)和任选的作为组分(III)的常规添加剂的另一种烯键式不饱和单体,并且当粘合剂(a)包含甲醛树脂时,粘合剂(b)包含 甲醛清除剂。
    • 5. 发明授权
    • Formaldehyde-free binders for producing wood products
    • 用于生产木制品的无甲醛粘合剂
    • US08466247B2
    • 2013-06-18
    • US12866987
    • 2009-02-11
    • Daniel KäsmayrSamira Nozari
    • Daniel KäsmayrSamira Nozari
    • C08L97/00C08L97/02
    • C08L97/02C08K5/04C08K5/16C08L1/00C08L33/00C09D133/00C08L2666/04
    • A lignocellulose-containing material, obtainable by treating lignocellulose particles A with a binder B, the binder B comprising the following components: An aqueous component (I) comprising (i) a polymer A which is composed of the following monomers: a) from 80 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 20% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) and ii) a low molecular weight crosslinking agent having at least two functional groups which are selected from the group consisting of hydroxyl, carboxylic acid and derivatives thereof, primary, secondary and tertiary amine, epoxy and a component (II) as an aqueous dispersion comprising one or more polymer(s) M which are composed of the following monomers: a) from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide group and/or hydroxyalkyl group (monomer(s) M1), and b) from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and optionally customary additives as component (III).
    • 通过用粘合剂B处理木质纤维素颗粒A可获得的含木素纤维素的材料,粘合剂B包含以下组分:包含(i)由以下单体组成的聚合物A的水性组分(I):a)80 至100重量%的至少一种烯键式不饱和单 - 和/或二羧酸(单体A1)和b)0至20重量%的至少一种其它烯属不饱和单体,其不同于单体A1( 单体A2)和ii)具有至少两个官能团的低分子量交联剂,其选自羟基,羧酸及其衍生物,伯,仲和叔胺,环氧和组分(II )作为水分散体,其包含由以下单体组成的一种或多种聚合物M:a)0至50重量%的至少一种烯键式不饱和单体,其包含至少一个环氧基和/或氢 和(b)50-100%(重量)至少一种不同于单体M1(单体M2)的烯属不饱和单体和任选的常规添加剂作为组分(III) 。
    • 6. 发明申请
    • FORMALDEHYDE-FREE BINDERS FOR PRODUCING WOOD PRODUCTS
    • 用于生产木制品的无伐木粉饼
    • US20110009530A1
    • 2011-01-13
    • US12866987
    • 2009-02-11
    • Daniel KäsmayrSamira Nozari
    • Daniel KäsmayrSamira Nozari
    • C08L97/02B05D1/02B29C43/00
    • C08L97/02C08K5/04C08K5/16C08L1/00C08L33/00C09D133/00C08L2666/04
    • A lignocellulose-containing material, obtainable by treating lignocellulose particles A with a binder B, the binder B comprising the following components:An aqueous component (I) comprising(i) a polymer A which is composed of the following monomers: a) from 80 to 100% by weight of at least one ethylenically unsaturated mono- and/or dicarboxylic acid (monomer(s) A1) and b) from 0 to 20% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers A1 (monomer(s) A2) and optionally (ii) a low molecular weight crosslinking agent having at least two functional groups which are selected from the group consisting of hydroxyl, carboxylic acid and derivatives thereof, primary, secondary and tertiary amine, epoxy and a component (II) as an aqueous dispersion comprising one or more polymer(s) M which are composed of the following monomers: a) from 0 to 50% by weight of at least one ethylenically unsaturated monomer which comprises at least one epoxide group and/or at least one hydroxyalkyl group (monomer(s) M1), and b) from 50 to 100% by weight of at least one further ethylenically unsaturated monomer which differs from the monomers M1 (monomer(s) M2) and optionally customary additives as component (III).
    • 通过用粘合剂B处理木质纤维素颗粒A可获得的含木素纤维素的材料,粘合剂B包含以下组分:包含(i)由以下单体组成的聚合物A的水性组分(I):a)80 至100重量%的至少一种烯键式不饱和单 - 和/或二羧酸(单体A1)和b)0至20重量%的至少一种其它烯属不饱和单体,其不同于单体A1( 单体A2)和任选地(ii)具有至少两个选自羟基,羧酸及其衍生物的官能团的低分子量交联剂,伯,仲和叔胺,环氧树脂和组分 (II),其包含一种或多种由以下单体组成的聚合物M的水分散体:a)0至50重量%的至少一种烯属不饱和单体,其包含至少一个环氧树脂 p和/或至少一个羟烷基(单体M1),和b)50至100重量%的至少一种其它不同于单体M1(单体M2)的烯属不饱和单体和任选地 常规添加剂作为组分(III)。