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1. 发明授权

US4778857A Uncured rubber compositions containing aromatic furazan oxides 失效
标题翻译：含有芳族呋喃氧化物的未固化橡胶组合物
公开(公告)号：US4778857A
公开(公告)日：1988-10-18
申请号：US54971
申请日：1987-05-28
申请人： Daniel F. Graves , Walter R. Hausch
发明人： Daniel F. Graves , Walter R. Hausch
IPC分类号： C08K5/35 , C08C19/08
CPC分类号： C08K5/35 , Y10S260/43
摘要： Uncured rubber compositions containing fused aromatic furazan oxides exhibit improved processability and reduced viscosity. Useful furazan oxides have both carbons of the furazan ring as part of a fused aromatic ring and include benzofurazan oxide and its methyl and methoxy analogs. Improvements in processability, green strength and liquification of NR can be achieved through use of these furazan oxides in uncured rubber compositions.
摘要翻译：含有稠合芳族呋喃氧化物的未固化的橡胶组合物显示出改善的加工性能和降低的粘度。有用的呋咱氧化物具有作为稠合芳环的一部分的呋咱环的两个碳，并且包括苯并呋咱氧化物及其甲基和甲氧基类似物。通过在未固化的橡胶组合物中使用这些呋咱氧化物可以改善NR的加工性，生坯强度和液化。

2. 发明授权

US08344049B2 Modified asphalt binders and asphalt paving compositions 失效
标题翻译：改性沥青结合料和沥青铺路料
公开(公告)号：US08344049B2
公开(公告)日：2013-01-01
申请号：US12881791
申请日：2010-09-14
申请人： William L. Hergenrother , Peter W. Boerner , Christine Rademacher , Daniel F. Graves , Timothy P. Reece , Herbert L. Wissel
发明人： William L. Hergenrother , Peter W. Boerner , Christine Rademacher , Daniel F. Graves , Timothy P. Reece , Herbert L. Wissel
IPC分类号： C08L95/00
CPC分类号： C08L95/00 , C08L25/10 , C08L53/02 , C08L2666/74 , C08L53/00 , C08L2666/24 , C08L2666/04
摘要： A modified asphalt binder composition prepared by combining asphalt binder, phosphorus pentasulfide, and less than 2.5 parts by weight unsaturated polymer, per 100 parts by weight asphalt binder, to thereby produce a modified asphalt binder composition characterized by an elongation recovery at 25° C., as determined according to AASHTO T301, of greater than 75%.
摘要翻译：通过将沥青粘合剂，五硫化二磷和小于2.5重量份的不饱和聚合物相对于100重量份的沥青粘合剂混合制备的改性沥青粘合剂组合物，由此制备改性沥青粘合剂组合物，其特征在于在25℃下的伸长率恢复，根据AASHTO T301确定，大于75％。

3. 发明授权

US08124677B2 Modified asphalt binders and asphalt paving compositions 有权
标题翻译：改性沥青结合料和沥青铺路料
公开(公告)号：US08124677B2
公开(公告)日：2012-02-28
申请号：US12881768
申请日：2010-09-14
申请人： William L. Hergenrother , Peter W. Boerner , Daniel F. Graves , Christine Rademacher , Timothy P. Reece , Herbert L. Wissel
发明人： William L. Hergenrother , Peter W. Boerner , Daniel F. Graves , Christine Rademacher , Timothy P. Reece , Herbert L. Wissel
IPC分类号： C08L95/00
CPC分类号： C08L95/00 , C08L53/02 , C08L53/00
摘要： A modified asphalt binder composition prepared by combining asphalt binder, phosphorus pentasulfide, and less than 2.5 parts by weight unsaturated polymer, per 100 parts by weight asphalt binder, to thereby produce a modified asphalt binder composition characterized by an elongation recovery at 25° C., as determined according to AASHTO T301, of greater than 75%, where the phosphorus pentasulfide includes a blend of P4S10 and P4S9.
摘要翻译：通过将沥青粘合剂，五硫化二磷和小于2.5重量份的不饱和聚合物相对于100重量份的沥青粘合剂混合制备的改性沥青粘合剂组合物，由此制备改性沥青粘合剂组合物，其特征在于在25℃下的伸长率恢复，如根据AASHTO T301测定的大于75％，其中五硫化二磷包括P4S10和P4S9的共混物。

4. 发明授权

US07642302B2 Modified asphalt binders and asphalt paving compositions 失效
公开(公告)号：US07642302B2
公开(公告)日：2010-01-05
申请号：US11820716
申请日：2007-06-20
申请人： William L. Hergenrother , Peter W. Boerner , Daniel F. Graves , Christine Rademacher , Timothy P. Reece , Herbert L. Wissel
发明人： William L. Hergenrother , Peter W. Boerner , Daniel F. Graves , Christine Rademacher , Timothy P. Reece , Herbert L. Wissel
IPC分类号： C08K3/30 , C08K3/32 , C08L95/00
CPC分类号： C08L95/00 , C08L53/02 , C08L53/00
摘要： A process for preparing a modified asphalt binder composition, the process comprising mixing asphalt, an unsaturated polymer, and phosphorus pentasulfide to form a modified asphalt composition.

5. 发明授权

US06881795B2 CO2 terminated rubber for plastics 有权
标题翻译：用于塑料的二氧化碳终止橡胶
公开(公告)号：US06881795B2
公开(公告)日：2005-04-19
申请号：US09819336
申请日：2001-03-28
申请人： Daniel F. Graves , David J. Dougherty , Thomas A. Antkowiak
发明人： Daniel F. Graves , David J. Dougherty , Thomas A. Antkowiak
IPC分类号： C08C19/34 , C08C19/44 , C08F36/00 , C08F212/00 , C08F36/06 , C08F4/46 , C08F36/14
CPC分类号： C08C19/44
摘要： A process for the manufacture of a baleable lithium carboxylate polymer. The process includes polymerizing at least one conjudated diene in the presence of an organolithium initiator to a substantial completion. Thereafter, the polymerization process is terminated by the addition of carbon dioxide.
摘要翻译：一种生产可膨胀的羧酸锂聚合物的方法。该方法包括在有机锂引发剂的存在下聚合至少一种结构二烯基本完成。此后，通过加入二氧化碳来终止聚合过程。

6. 发明授权

US4524052A Borate chloride polymerization catalysts 失效
标题翻译：硼酸氯化物聚合催化剂
公开(公告)号：US4524052A
公开(公告)日：1985-06-18
申请号：US685582
申请日：1984-12-24
申请人： Daniel F. Graves
发明人： Daniel F. Graves
IPC分类号： C01B35/14 , C01B21/098 , C01B25/10 , C01B35/06 , C08G79/00 , C08G79/02 , C01B33/20
CPC分类号： C01B21/0986 , C01B21/098 , C01B35/06
摘要： New compositions of matter which are halogenated derivatives of borates are disclosed which are catalytically active in the polymerization of halogenated phosphazene trimers and other oligomers are disclosed.
摘要翻译：公开了作为硼酸盐的卤化衍生物的物质的新组合物，其在卤代磷腈三聚体的聚合中具有催化活性，并公开了其它低聚物。

7. 发明授权

US4179555A Oil-free elastomeric poly(aryloxyphosphazene) copolymers 失效
标题翻译：无油弹性聚（芳氧基磷腈）共聚物
公开(公告)号：US4179555A
公开(公告)日：1979-12-18
申请号：US919888
申请日：1978-06-28
申请人： Tai C. Cheng , John W. Fieldhouse , Arthur E. Oberster , Daniel F. Graves
发明人： Tai C. Cheng , John W. Fieldhouse , Arthur E. Oberster , Daniel F. Graves
IPC分类号： C08G79/00 , C08G79/02 , C08G79/04 , C08J9/10 , C08L85/00 , C08L85/02 , C09D185/00 , H01B3/30
CPC分类号： C08J9/10 , C08G79/025 , C08L85/02 , H01B3/30 , C08J2385/02 , Y10T428/294
摘要： Poly(aryloxyphosphazene) copolymers are prepared having randomly repeating units represented by the formula: ##STR1## wherein R and R.sup.1 may be the same or different and are selected from the group consisting of monovalent aryl radicals and substituted aryl radicals having the structure: ##STR2## wherein X is a substituent selected from the group consisting of alkyl, alkoxy, aryl, aryloxy, amino and halogen substituted on any sterically permissible position on the phenyl group; and wherein the amount of Cl present in the form of P--C1 bonds is from about 0.4 percent to about 10 percent by weight based upon the total weight of copolymer.The copolymers may contain minor proportions of randomly distributed units in addition to the repeating units described above, these additional units containing reactive sites enabling the properties of the copolymers to be modified by crosslinking and/or curing.The copolymers are elastomeric even in the absence of low molecular weight polyphosphazene oils. The copolymers are curable by a variety of curing agents such as sulfur and peroxides, and can also be cured by radiation and ultraviolet light. The copolymers may be utilized in various applications such as foams and coatings, and are particularly suited for use in wire coating formulations.
摘要翻译：制备具有由下式表示的无规重复单元的聚（芳氧基磷腈）共聚物：其中R和R 1可以相同或不同，并且选自具有以下结构的一价芳基和取代的芳基：其中X是选自烷基，烷氧基，芳基，芳氧基，氨基和在苯基上的任何空间上允许的位置上取代的卤素的取代基; 并且其中以P-C1键形式存在的Cl的量为基于共聚物总重量的约0.4重量％至约10重量％。除了上述重复单元之外，共聚物可以含有少量的随机分布的单元，这些含有能够通过交联和/或固化来改性共聚物性质的反应性位点的这些附加单元。即使在不存在低分子量聚磷腈油的情况下，共聚物也是弹性体。共聚物可通过各种固化剂如硫和过氧化物固化，并且还可以通过辐射和紫外光固化。共聚物可以用于各种应用中，例如泡沫和涂料，并且特别适用于丝线涂布配方。

8. 发明申请

US20110251347A1 STYRENE/BUTADIENE DIBLOCK COPOLYMER-CONTAINING BLENDS THAT ARE NOT AN AGGLOMERATION AND A PROCESS FOR PREPARATION 审中-公开
标题翻译：苯乙烯/丁二烯二嵌段共聚物混合物不是聚集体和制备方法
公开(公告)号：US20110251347A1
公开(公告)日：2011-10-13
申请号：US13057678
申请日：2009-08-05
申请人： Daniel F. Graves , Peter W. Boerner , John R. Schreffler , Christine M. Rademacher
发明人： Daniel F. Graves , Peter W. Boerner , John R. Schreffler , Christine M. Rademacher
IPC分类号： C08L53/02
CPC分类号： C08L53/02 , C08F297/04 , C08F297/044 , C08J3/005 , C08J2325/10 , C08J2353/02 , C08L2205/02 , C08L2205/025 , C08L2666/02 , C08L2666/24
摘要： A process for producing a styrene-butadiene diblock copolymer-containing blend that is not an agglomeration, that involves mixing a styrene-butadiene multiblock thermoplastic elastomer solution with a styrene-butadiene diblock copolymer solution. Blends comprising a styrene-butadiene diblock copolymer and a styrene-butadiene multiblock thermoplastic elastomer, which blends are not an agglomeration.
摘要翻译：一种制备不含聚苯乙烯 - 丁二烯二嵌段共聚物的共混物的方法，其中包括将苯乙烯 - 丁二烯多嵌段热塑性弹性体溶液与苯乙烯 - 丁二烯二嵌段共聚物溶液混合。包含苯乙烯 - 丁二烯二嵌段共聚物和苯乙烯 - 丁二烯多嵌段热塑性弹性体的共混物不是聚集体。

9. 发明申请

US20100113699A1 METHOD OF PREPARING RUBBER COMPRISING POLYMERIC COMPOSITIONS AND ISOPRENE COMPRISING INTERPOLYMERS 审中-公开
标题翻译：制备包含聚合物组合物的橡胶和包含嵌段共聚物的异丙酚的方法
公开(公告)号：US20100113699A1
公开(公告)日：2010-05-06
申请号：US12521616
申请日：2007-12-21
申请人： Mark N. Dedecker , James E. Hall , Daniel F. Graves
发明人： Mark N. Dedecker , James E. Hall , Daniel F. Graves
IPC分类号： C08L55/02 , C08L53/00 , C08L9/00
CPC分类号： C08F287/00
摘要： A process for preparing a rubber comprising polymeric composition, and the resulting compositions, and certain isoprene comprising interpolymers.
摘要翻译：一种制备包含聚合物组合物的橡胶的方法，以及所得组合物和包含互聚物的某些异戊二烯。

10. 发明申请

US20100076123A1 MODIFIED ASPHALT BINDERS AND ASPHALT PAVING COMPOSITIONS 有权
标题翻译：改性沥青混合料和沥青混合料
公开(公告)号：US20100076123A1
公开(公告)日：2010-03-25
申请号：US12628667
申请日：2009-12-01
申请人： William L. Hergenrother , Peter W. Boerner , Christine Rademacher , Daniel F. Graves , Timothy P. Reece , Herbert L. Wissel
发明人： William L. Hergenrother , Peter W. Boerner , Christine Rademacher , Daniel F. Graves , Timothy P. Reece , Herbert L. Wissel
IPC分类号： C08L95/00
CPC分类号： C08L95/00 , C08L25/10 , C08L53/02 , C08L2666/74 , C08L53/00 , C08L2666/24 , C08L2666/04
摘要： A method for forming a modified asphalt binder composition, the method comprising preparing a phosphorus pentasulfide-binder concentrate by introducing and mixing phosphorus pentasulfide and asphalt binder, where the phosphorus pentasulfide-binder concentrate includes greater than 0.5 parts by weight phosphorus pentasulfide per 100 parts by weight asphalt, preparing a polymer-binder concentrate by introducing and mixing polymer and asphalt binder, where the polymer-binder concentrate includes greater than 5 parts by weight polymer per 100 parts by weight asphalt, and introducing and mixing the phosphorus pentasulfide-binder concentrate with the polymer-binder concentrate to form a modified asphalt binder composition.
摘要翻译：一种形成改性沥青粘合剂组合物的方法，该方法包括通过引入和混合五硫化二磷和沥青粘合剂制备五硫化二磷 - 粘合剂浓缩物，其中五硫化二磷 - 粘合剂浓缩物包含大于0.5重量份的五硫化二磷每100份通过引入和混合聚合物和沥青粘合剂制备聚合物 - 粘合剂浓缩物，其中聚合物 - 粘合剂浓缩物包含每100重量份沥青大于5重量份的聚合物，并将五硫化二磷 - 粘合剂浓缩物与聚合物 - 粘合剂浓缩物以形成改性沥青粘合剂组合物。

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