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1. 发明授权

US06337305B1 Substituted 2-benz(o)ylpyridines, their preparation and their use as herbicides 失效
标题翻译：取代的2-苯并（o）吡啶，其制备及其作为除草剂的用途
公开(公告)号：US06337305B1
公开(公告)日：2002-01-08
申请号：US09381033
申请日：1999-09-15
申请人： Peter Schäfer , Gerhard Hamprecht , Markus Menges , Olaf Menke , Michael Rack , Cyrill Zagar , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Peter Schäfer , Gerhard Hamprecht , Markus Menges , Olaf Menke , Michael Rack , Cyrill Zagar , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： C07D21330
CPC分类号： C07D213/61 , A01N43/40
摘要： Substituted 2-benz(o)ylpyridines I and salts thereof where n=0, 1; X=CO, CH2, CH(C1-C4-alkyl), CH—OH, CH—CN, CH-halogen, C(halogen)2, CH—CONH2, CH—CO—O(C1-C4-alkyl), CH—O(C1-C4-alkyl), C(CN)(C1-C4-alkyl); R1=halogen, C1-C4-haloalkyl, C1-C4-alkylthio, C1-C4-alkylsulfinyl, C1-C4-alkylsulfonyl; R2=H, halogen; R3=H, NO2, OH, halogen, C1-C4-alkoxy; R4=H, NO2, OH, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy; R5=H, NO2, CN, halogen, C1-C8-alkyl, C3-C8-alkenyl, C3-C8-alkynyl, C3-C8-cycloalkyl, C1-C8-haloalkyl, C2-C8-haloalkenyl, C2-C8-haloalkinyl, C1-C4-alkoxy-C1-C4-alkyl, C2-C4-alkenyloxy-C1-C4-alkyl, C2-C4-alkynyloxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylsulfinyl-C1-C4-alkyl, C1-C4-alkylsulfonyl-C1-C4-alkyl, cyano-C1-C8-alkyl, cyano-C2-C8-alkenyl, cyano-C3-C8-alkynyl, unsubstituted or substituted OH, SH, SO—H, —SO2—H, COOH or NH—COOH, —SO2Cl, —N(R9,R10), —NH—SO2—(C1-C8-alkyl), —N[—SO2—(C1-C8-alkyl)]2, —N(C1-C8-alkyl)[—SO2—(C1-C8-alkyl)], —SO2—N(R9,R10), —O—CO—NH—R9, unsubstituted or substituted CHO, —O—CHO or —NH—CHO, —NH—CO—NH—R9, —O—CS—NH2, —O—CS—N(C1-C8-alkyl)2, —CO—N(R9,R10), —CS—N(R9,R10), —CO—NH—SO2—(C1-C4-alkyl).
摘要翻译：取代的2-苯并（o）吡啶I和其中n = 0,1; X = CO，CH 2，CH（C 1 -C 4 - 烷基），CH-OH，CH-CN，CH-卤素，C（卤素） CH-CONH 2，CH-CO-O（C 1 -C 4 - 烷基），CH-O（C 1 -C 4 - 烷基），C（CN）（C 1 -C 4 - 烷基）; R 1 =卤素，C 1 -C 4卤代烷基， C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基，C 1 -C 4烷基磺酰基; R 2 = H，卤素; R 3 = H，NO 2，OH，卤素，C 1 -C 4 - 烷氧基; R 4 = H，NO 2，OH，卤素， C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基; R 5 = H，NO 2，CN，卤素，C 1 -C 8烷基，C 3 -C 8 - 烯基，C 3 -C 8炔基，C 3 -C 8 - 环烷基，C 1 -C 8 - 卤代烷基，C 2 -C 8 - 卤代烯基，C 2 -C 8 - 卤代炔基，C 1 -C 4 - 烷氧基-C 1 -C 4烷基，C 2 -C 4 - 烯氧基-C 1 -C 4烷基，C 2 -C 4 - C 1 -C 4烷基，C 1 -C 4烷硫基-C 1 -C 4烷基，C 1 -C 4烷基亚磺酰基-C 1 -C 4烷基，C 1 -C 4烷基磺酰基-C 1 -C 4 - 烷基，氰基-C 1 -C 8烷基，氰基-C 2 -C 8 - 烯基，氰基-C 3 -C 8 - 炔基，未取代或取代的OH，SH，SO-H，-SO 2 -H，COOH或NH-COOH，-SO 2 Cl，-N（R 9，R 10） NH-SO 2 - （C 1 -C 8 - 烷基），-N [-SO 2 - （C 1 -C 8 - 烷基）] 2，-N（C 1 -C 8 - 烷基） -SO 2 -N（R 9，R 10），-O-CO-NH-R 9，未取代的取代的CHO，-O-CHO或-NH-CHO，-NH-CO-NH-R9，-O-CS-NH2，-O-CS-N（C1-

2. 发明授权

US06197973B1 Substituted 3-phenylpyrazoles 失效
标题翻译：取代的3-苯基吡唑
公开(公告)号：US06197973B1
公开(公告)日：2001-03-06
申请号：US09230838
申请日：1999-02-01
申请人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schäfer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schäfer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： C07D23114
CPC分类号： A01N43/56 , A01N47/06 , A01N47/12 , C07D231/16 , C07D231/22
摘要： 3-phenylpyrazoles of formula I wherein R1 is cyano, alkyl or haloalkyl; R2 is cyano or is optionally halogenated alkyl, alkoxy, alkylthio, alkylsulfinyl or alkylsulfonyl; R3 is hydrogen, cyano, halogen, alkyl or haloalkyl; R4 is hydrogen or halogen; R5 is cyano, halogen, or is optionally halogenated alkyl or alkoxy; R6, R7 independently of one another are optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl or phenyl, optionally substituted alkylcarbonyl, alkoxycarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl or optionally halogenated alkylsulfonyl; X is a chemical bond, —C≡C—, —CH2—CH(R8)— or —CH═C(R8)—, wherein R8 is hydrogen, cyano, nitro, halogen, alkyl or haloalkyl; Y is oxygen or sulfur; their preparation and their use for controlling undesirable vegetation.
摘要翻译：式I的3-苯基吡唑，其中R1是氰基，烷基或卤代烷基; R2是氰基或任选被卤代烷基，烷氧基，烷硫基，烷基亚磺酰基或烷基磺酰基; R3是氢，氰基，卤素，烷基或卤代烷基; R4是氢或卤素; R5是氰基，卤素或任选卤代烷基或烷氧基; R 6，R 7彼此独立地是任选取代的烷基，烯基，炔基，环烷基，杂环基或苯基，任选取代的烷基羰基，烷氧基羰基，氨基羰基，烷基氨基羰基，二烷基氨基羰基或任选卤代烷基磺酰基; X是化学键，-C = C-，-CH 2 -CH（R 8） - 或-CH = C（R 8） - ，其中R 8是氢，氰基，硝基，卤素，烷基或卤代烷基; Y是氧或硫 ;他们的准备和用于控制不良植被的用途。

3. 发明授权

US06232470B1 Substituted pyrazol-3-ylbenzazoles, their use as herbicides or desiccants/defoliants, and their preparation 失效
标题翻译：取代的吡唑-3-基苯并唑，其用作除草剂或干燥剂/脱叶剂，及其制备
公开(公告)号：US06232470B1
公开(公告)日：2001-05-15
申请号：US09331065
申请日：1999-06-16
申请人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schäfer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schäfer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： C07D41704
CPC分类号： C07D413/04 , A01N43/74 , C07D417/04
摘要： Substituted Pyrazol-3-ylbenzazoles I salts thereof, and their use as herbicides or for the desiccation/defoliation of plants.
摘要翻译：取代的吡唑-3-基苯并唑它们作为除草剂或作为植物干燥/脱叶的用途。

4. 发明授权

US06448205B1 Substituted 2-phenylpyridine as herbicide 失效
标题翻译：取代的2-苯基吡啶作为除草剂
公开(公告)号：US06448205B1
公开(公告)日：2002-09-10
申请号：US09242463
申请日：1999-02-17
申请人： Peter Schäfer , Michael Rack , Gerhard Hamprecht , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz , Markus Menges , Cyrill Zagar , Olaf Menke
发明人： Peter Schäfer , Michael Rack , Gerhard Hamprecht , Helmut Walter , Karl-Otto Westphalen , Ulf Misslitz , Markus Menges , Cyrill Zagar , Olaf Menke
IPC分类号： A01N4340
CPC分类号： C07D405/10 , A01N43/40 , C07D213/71 , C07D405/12 , C07D409/10 , C07D411/10
摘要： Substituted 2-phenylpyridines of formula I where R1 to R5 are described herein, their use as herbicides and for the desiccation and/or defoliation of plants.
摘要翻译：式I中的取代的2-苯基吡啶，其中R 1至R 5在本文中描述，其用作除草剂和用于植物的干燥和/或脱叶的用途。

5. 发明授权

US06387849B1 Herbicidal hydroximic acid derivatives 失效
标题翻译：除草剂的含氢阿魏酸衍生物
公开(公告)号：US06387849B1
公开(公告)日：2002-05-14
申请号：US09381474
申请日：1999-09-21
申请人： Olaf Menke , Gerhard Hamprecht , Markus Menges , Robert Reinhard , Peter Schäfer , Cyrill Zagar , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Olaf Menke , Gerhard Hamprecht , Markus Menges , Robert Reinhard , Peter Schäfer , Cyrill Zagar , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： C07D23954
CPC分类号： C07D239/54 , A01N43/54 , C07C251/48 , C07C265/12 , C07D239/56
摘要： Novel hydroximic acid derivatives I and salts thereof, where X=O, S; Y=O, S; R1=H, C1-C4-alkyl, NH2, C1-C4-alkylamino or di(C1-C4-alkyl)amino; R2=C1-C3-haloalkyl; R3=H, halogen, C1-C4-alkyl; R4=H, halogen; R5=CN, halogen; R6=C1-C6-alkyl, C2-C6-alkenyl, C3-C6-alkynyl or phenyl-C1-C6-alkyl, where the phenyl ring of this group may be unsubstituted or may carry 1-3 substituents; R7=a C1-C6-alkyl, C2-C6-alkenyl, C3-C6-alkynyl or phenyl-C1-C6-alkyl, where these 4 groups may be unsubstituted or may carry 1 to 2 substituents; Use: As herbicides; for the desiccation/defoliation of plants.
摘要翻译：其中X = O，S; Y = O，S; R1 = H，C1-C4-烷基，NH2，C1-C4-烷基氨基或二（C1-C4-烷基）氨基的新型氢亚甲酸衍生物I和盐; R2 = C1-C3-卤代烷基; R3 = H，卤素，C1-C4-烷基; R4 = H，卤素; R5 = CN，卤素; R6 = C1-C6-烷基，C2-C6-烯基，C3-C6-炔基或苯基-C 1 -C 6烷基，其中该基团的苯环可以是未取代的或可以带有1-3个取代基; R 7 = C 1 -C 6 - 烷基，C 2 -C 6 - 烯基，C 3 -C 6炔基或苯基-C 1 C 1-6 - 烷基，其中这4个基团可以是未取代的或可以携带1至2个取代基;用途：作为除草剂; 用于植物的干燥/脱叶。

6. 发明授权

US06451734B1 Substituted 3-benzylpyrazoles and their use as herbicides 失效
标题翻译：取代的3-苄基吡唑及其作为除草剂的用途
公开(公告)号：US06451734B1
公开(公告)日：2002-09-17
申请号：US09297529
申请日：1999-05-03
申请人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schäfer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter , Robert Reinhard , Robert Brian Jones
发明人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schäfer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter , Robert Reinhard , Robert Brian Jones
IPC分类号： A01N4356
CPC分类号： C07D401/10 , C07D231/20 , C07D401/12 , C07D403/10 , C07D403/12 , C07D405/12
摘要： The present invention relates to novel substituted 3-benzylpyrazoles of the formula I
摘要翻译：本发明涉及下式的新的取代的3-苄基吡唑

7. 发明授权

US6057269A Benzylhydroxylamines and intermediates used to prepare them 失效
公开(公告)号：US6057269A
公开(公告)日：2000-05-02
申请号：US973780
申请日：1998-01-05
申请人： Ralf Klintz , Gerhard Hamprecht , Elisabeth Heistracher , Peter Schafer , Cyrill Zagar , Karl-Otto Westphalen , Helmut Walter , Ulf Misslitz , Olaf Menke , Markus Menges
发明人： Ralf Klintz , Gerhard Hamprecht , Elisabeth Heistracher , Peter Schafer , Cyrill Zagar , Karl-Otto Westphalen , Helmut Walter , Ulf Misslitz , Olaf Menke , Markus Menges
IPC分类号： A01N43/54 , A01N47/12 , A01N47/24 , A01N47/30 , A01N53/00 , C07C239/08 , C07C239/10 , C07C239/16 , C07C239/20 , C07C265/12 , C07C271/22 , C07C271/28 , C07C271/54 , C07C271/58 , C07C275/32 , C07C275/40 , C07D239/54 , C07D405/12
CPC分类号： C07D239/54 , A01N43/54 , A01N47/12 , A01N47/24 , A01N47/30 , A01N53/00 , C07C239/08 , C07C239/10 , C07C265/12 , C07C271/22 , C07C271/28 , C07C271/54 , C07C271/58 , C07C275/40
摘要： Benzylhydroxylamines I ##STR1## (X=--N(R.sup.7)--O--; Y=O, S; R.sup.1 =halogen, CN, NO.sub.2, CF.sub.3 ; R.sup.2 =H, halogen; R.sup.3 =H, NH.sub.2, CH.sub.3 ;R.sup.4 =H, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -alkylsulfinyl or C.sub.1 -C.sub.6 -alkylsulfonyl;R.sup.5 =H, halogen, C.sub.1 -C.sub.6 -alkyl;R.sup.6 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.6 -alkenyl;R.sup.7 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynylcarbonyl, C.sub.1 -C.sub.6 -alkoxycarbonyl, C.sub.2 -C.sub.8 -alkenyloxycarbonyl, C.sub.2 -C.sub.6 -alkynyloxycarbonyl, C.sub.1 -C.sub.6 -alkylthiocarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -alkylcarbamoyl, it being possible for the 14 last-mentioned radicals to have attached to them 1-3 substituents:NO.sub.2, CN, halogen, C.sub.3 -C.sub.8 -cycloalkyl, OH, C.sub.1 -C.sub.6 -alkoxy, C.sub.3 -C.sub.8 -cycloalkoxy, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylcarbonyloxy, C.sub.1 -C.sub.6 -alkylsulfinyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -alkylideneaminoxy, C.sub.1 -C.sub.6 -alkylcarbamoyl,unsubstituted or substituted phenyl, phenoxy or phenylsulfonyl,a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents,--CO--Z.sup.1 R.sup.9, --OCO--Z.sup.1 R.sup.9, --N(R.sup.9)R.sup.10 orR.sup.7 =unsubstituted or substituted cycloalkylcarbonyl, phenylcarbonyl, phenylsulfonyl, phenylcarbamoyl;R.sup.8 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, it being possible for each of the 5 last-mentioned radicals to have attached to it 1-3 substituents:NO.sub.2, CN, halogen, C.sub.3 -C.sub.8 -cycloalkyl, OH, C.sub.1 -C.sub.6 -alkoxy, C.sub.3 -C.sub.8 -cycloalkoxy, C.sub.3 -C.sub.6 -alkenyloxy, C.sub.3 -C.sub.6 -alkynyloxy, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.1 -C.sub.6 -alkylsulfinyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.6 -alkylideneaminoxy,unsubstituted or substituted phenyl- [sic], phenoxy-[sic] or phenylsulfonyl,a 3- to 7-membered heterocyclyl or heterocyclyloxy group having 1-3 hetero atoms, it being possible for this group to be saturated, unsaturated or aromatic and to have attached to it 1-3 substituents,--CO--Z.sup.2 R.sup.11, --OCO--Z.sup.2 R.sup.11, --N(R.sup.11)R.sup.12 ;Z.sup.1 a chemical bond, oxygen, sulfur or --N(R.sup.10)--;Z.sup.2 =a chemical bond, oxygen, sulfur or --N(R.sup.12)--;R.sup.9, R.sup.11 =H, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkyl, (C.sub.1 -C.sub.6 -alkoxy)carbonyl-C.sub.1 -C.sub.6 -alkyl, unsubstituted or substituted phenyl or phenyl-C.sub.1 -C.sub.6 -alkyl,orZ.sup.1 and R.sup.9 and/or Z.sup.2 and R.sup.11 together=a 3- to 7-membered heterocycle having 1-3 hetero atoms and bonded via nitrogen, it being possible for this heterocycle to be saturated, unsaturated or aromatic and, if desired, to have attached to it one to three substituents,R.sup.10, R.sup.12 =H, OH, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.1 -C.sub.6 -alkoxy)and the salts of I where R.sup.3, R.sup.7 and/or R.sup.8 =hydrogenare used as herbicides and for the desiccation/defoliation of plants.

8. 发明授权

US6054413A 1-sulfonyl-3-phenylpyrazoles and their use as herbicides and for desiccating or defoliating plants 失效
标题翻译： 1-磺酰基-3-苯基吡唑及其作为除草剂的用途，用于干燥或脱叶植物
公开(公告)号：US6054413A
公开(公告)日：2000-04-25
申请号：US254923
申请日：1999-03-17
申请人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schafer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Cyrill Zagar , Gerhard Hamprecht , Markus Menges , Olaf Menke , Peter Schafer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： A01N43/56 , C07D231/12 , C07D231/18 , C07D231/24 , C07D401/12 , C07D403/12 , C07D405/12 , A01N43/84 , C07D231/14 , C07D413/12
CPC分类号： C07D231/18 , A01N43/56 , C07D231/24
摘要： The present invention relates to novel 1-sulfonyl-3-phenylpyrazoles of the formula I ##STR1## and agriculturally useful salts of I. Furthermore, the invention relates tothe use of the compounds I as herbicides and/or for the desiccation and/or defoliation of plants,herbidical compositions and compositions for the desiccation and/or defoliation of plants which comprise the compounds I as active ingredients,
摘要翻译： PCT No.PCT / EP97 / 04911 Sec。 371日期1999年3月17日 102（e）1999年3月17日PCT 1997年9月9日PCT公布。公开号WO98 / 12182 日期：1998年3月26日本发明涉及式I的新型1-磺酰基-3-苯基吡唑和I的农业上有用的盐。此外，本发明涉及化合物I作为除草剂和/或用于干燥和/ /或用于将化合物I作为活性成分的植物的干燥和/或脱叶的植物脱叶，草药组合物和组合物，

9. 发明授权

US6150303A Substituted 3-phenylisoxazolines 失效
公开(公告)号：US6150303A
公开(公告)日：2000-11-21
申请号：US463246
申请日：2000-01-21
申请人： Olaf Menke , Markus Menges , Gerhard Hamprecht , Robert Reinhard , Peter Schafer , Cyrill Zagar , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Olaf Menke , Markus Menges , Gerhard Hamprecht , Robert Reinhard , Peter Schafer , Cyrill Zagar , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： A01N43/80 , C07D261/04 , A01N43/72
CPC分类号： C07D261/04
摘要： Substituted 3-phenylisoxazolines I, and their salts and enol ethers, are described as herbicides ##STR1## where X.dbd.--O--, --S--, --N(R.sup.9)--;R.sup.1 .dbd.CN, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylsulfonyl;R.sup.2 .dbd.H or unsubstituted or substituted C.sub.1 -C.sub.6 -alkyl, (C.sub.1 -C.sub.6 -alkyl)carbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.2 -C.sub.6 -alkenyl, (C.sub.2 -C.sub.6 -alkenyl)carbonyl, C.sub.2 -C.sub.6 -alkynyl, (C.sub.2 -C.sub.6 -alkynyl)carbonyl;R.sup.3 .dbd.H, halogen;R.sup.4 .dbd.CN, halogen, C.sub.1 -C.sub.3 -haloalkyl;R.sup.5 .dbd.H, CN, halogen, C.sub.1 -C.sub.3 -haloalkyl;R.sup.6 .dbd.H, CN, halogen, C.sub.1 -C.sub.3 -haloalkyl or unsubstituted or substituted C.sub.1 -C.sub.6 -alkoxy;R.sup.7 .dbd.CN, halogen;R.sup.8 in position .alpha., R.sup.7 in this case being in position .beta., or in position .beta., R.sup.7 in this case being in position .alpha., is1) H, OH, SH, CN, NO.sub.2, halogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -haloalkyl, C.sub.1 -C.sub.6 -haloalkoxy, C.sub.1 -C.sub.6 -haloalkylthio, C.sub.1 -C.sub.6 -alkylthio-(C.sub.1 -C.sub.6 -alkyl)carbonyl, (C.sub.1 -C.sub.6 -alkyl)iminooxycarbonyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxyamino-C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkylamino-C.sub.1 -C.sub.6 -alkyl,2) unsubstituted or substituted C.sub.1 -C.sub.6 -alkoxy, C.sub.1 -C.sub.6 -alkylthio, C.sub.3 -C.sub.6 -cycloalkoxy, C.sub.3 -C.sub.6 -cycloalkylthio, C.sub.2 -C.sub.6 -alkenyloxy, C.sub.2 -C.sub.6 -alkenylthio, C.sub.2 -C.sub.6 -alkynyloxy, C.sub.2 -C.sub.6 -alkynylthio, (C.sub.1 -C.sub.6 -alkyl)carbonyloxy, (C.sub.1 -C.sub.6 -alkyl)carbonylthio, (C.sub.1 -C.sub.6 -alkoxy)carboxyloxy, (C.sub.2 -C.sub.6 -alkenyl)carbonyloxy, (C.sub.2 -C.sub.6 -alkenyl)carbonylthio, (C.sub.2 -C.sub.6 -alkynyl)carbonyloxy, (C.sub.2 -C.sub.6 -alkynyl)carbonylthio, C.sub.1 -C.sub.6 -alkylsulfonyloxy or C.sub.1 -C.sub.6 -alkylsulfonyl,3) 29 further radicals;R.sup.9 .dbd.H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl, C.sub.1 -C.sub.6 -alkoxy-C.sub.1 -C.sub.6 -alkyl, (C.sub.1 -C.sub.6 -alkoxy)carbonyl-C.sub.1 -C.sub.6 -alkyl, (C.sub.3 -C.sub.6 -alkenyloxy)carbonyl-C.sub.1 -C.sub.6 -alkyl, unsubstituted or substituted phenyl or phenyl-C.sub.1 -C.sub.6 -alkyl.

10. 发明授权

US06175007B1 Substituted aromatic phoshonic acid derivatives 失效
标题翻译：取代芳香族磷酸衍生物
公开(公告)号：US06175007B1
公开(公告)日：2001-01-16
申请号：US09117665
申请日：1998-08-04
申请人： Cyrill Zagar , Elisabeth Heistracher , Olaf Menke , Gerhard Hamprecht , Markus Menges , Peter Sch{umlaut over (a)}fer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
发明人： Cyrill Zagar , Elisabeth Heistracher , Olaf Menke , Gerhard Hamprecht , Markus Menges , Peter Sch{umlaut over (a)}fer , Karl-Otto Westphalen , Ulf Misslitz , Helmut Walter
IPC分类号： C07D27300
CPC分类号： C07F9/6561 , A01N57/24 , A01N57/32 , C07F9/4015 , C07F9/4056 , C07F9/5537 , C07F9/65031 , C07F9/65038 , C07F9/6506 , C07F9/650905 , C07F9/6512 , C07F9/6539 , C07F9/65583 , C07F9/65586
摘要： Phosphonic acid compounds I wherein Eth is optionally substituted 1,2-ethynediyl, ethanediyl or ethene-1,2-diyl; Y1 is oxygen or sulfur; Y2 is oxygen, sulfur or —N(R6)—; Y3 is oxygen, sulfur or —N(R7)—; R1, R2, R6 and R7 are hydrogen or optionally substituted alkyl, alkenyl, alkynyl, cycloalkyl, phenyl or heterocyclyl, or R1 and R2, R1 and R6, R2 and R7 together are optionally substituted 1,2-ethanediyl, 1,3-propylene, tetramethylene, pentamethylene or ethyleneoxyethylene, or R1 and R2 together are optionally substituted 1,2-phenylene; R3 is cyano, halogen, alkyl, haloalkyl, alkoxy or haloalkoxy; R4 is hydrogen or halogen, and R5 is a heterocycle &PHgr;1 to &PHgr;22 as defined in the specification, their manufacture and intermediates therefore. The phosphonic acid compounds are effective against unwanted plants and act as desiccants and defoliants.
摘要翻译：膦酸化合物Ⅰ其中任选被取代的1,2-亚乙炔基，乙二基或乙烯-1,2-二基; Y1是氧或硫; Y2是氧，硫或-N（R6） - ; Y3是氧，硫或-N （R 7） - ; R 1，R 2，R 6和R 7是氢或取代的烷基，烯基，炔基，环烷基，苯基或杂环基，或R 1和R 2，R 1和R 6，R 2和R 7一起是任选取代的1,2-乙二基，，3-亚丙基，四亚甲基，五亚甲基或亚乙基氧乙烯，或者R 1和R 2一起是任选取代的1,2-亚苯基; R 3是氰基，卤素，烷基，卤代烷基，烷氧基或卤代烷氧基; R 4是氢或卤素，R 5是杂环＆ 1至＆lt; PHgr 22，因此其制造和中间体。膦酸化合物对有害植物有效，作为干燥剂和脱叶剂。

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