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    • 1. 发明授权
    • Methods and apparatus for vapor processing of micro-device workpieces
    • 微器件工件蒸汽加工的方法和装置
    • US07118783B2
    • 2006-10-10
    • US10183250
    • 2002-06-26
    • Craig M. CarpenterRoss S. DandoDan GealyGaro J. DerderianAllen P. Mardian
    • Craig M. CarpenterRoss S. DandoDan GealyGaro J. DerderianAllen P. Mardian
    • C23C16/02
    • C23C16/4481
    • CVD, ALD, and other vapor processes used in processing semiconductor workpieces often require volatilizing a liquid or solid precursor. Certain embodiments of the invention provide improved and/or more consistent volatilization rates by moving a reaction vessel. In one exemplary embodiment, a reaction vessel is rotated about a rotation axis which is disposed at an angle with respect to vertical. This deposits a quantity of the reaction precursor on an interior surface of the vessel's sidewall which is exposed to the headspace as the vessel rotates. Other embodiments employ drivers adapted to move the reaction vessel in other manners, such as a pendulum arm to oscillate the vessel along an arcuate path or a mechanical linkage which moves the vessel along an elliptical path.
    • 用于处理半导体工件中的CVD,ALD和其它蒸气方法通常需要挥发液体或固体前体。 本发明的某些实施方案通过移动反应容器提供改进的和/或更一致的挥发速率。 在一个示例性实施例中,反应容器围绕相对于垂直方向以一定角度设置的旋转轴线旋转。 这将一定数量的反应前体沉积在容器侧壁的内表面上,该容器的侧壁在容器旋转时暴露于顶部空间。 其他实施例使用适于以其他方式移动反应容器的驱动器,例如摆臂,以沿着沿着椭圆形路径移动容器的弓形路径或机械连杆摆动容器。
    • 4. 发明授权
    • Apparatus and method for depositing materials onto microelectronic workpieces
    • 将材料沉积到微电子工件上的装置和方法
    • US07387685B2
    • 2008-06-17
    • US10933604
    • 2004-09-02
    • Craig M. CarpenterAllen P. MardianRoss S. DandoKimberly R. TschepenGaro J. Derderian
    • Craig M. CarpenterAllen P. MardianRoss S. DandoKimberly R. TschepenGaro J. Derderian
    • C23C16/455C23C16/00H01L21/3065
    • C23C16/45544C23C16/45565
    • Reactors for vapor deposition of materials onto a microelectronic workpiece, systems that include such reactors, and methods for depositing materials onto microelectronic workpieces. In one embodiment, a reactor for vapor deposition of a material comprises a reaction chamber and a gas distributor. The reaction chamber can include an inlet and an outlet. The gas distributor is positioned in the reaction chamber. The gas distributor has a compartment coupled to the inlet to receive a gas flow and a distributor plate including a first surface facing the compartment, a second surface facing the reaction chamber, and a plurality of passageways. The passageways extend through the distributor plate from the first surface to the second surface. Additionally, at least one of the passageways has at least a partially occluded flow path through the plate. For example, the occluded passageway can be canted at an oblique angle relative to the first surface of the distributor plate so that gas flowing through the canted passageway changes direction as it passes through the distributor plate.
    • 用于将材料气相沉积到微电子工件上的反应器,包括这种反应器的系统以及将材料沉积到微电子工件上的方法。 在一个实施方案中,用于气相沉积材料的反应器包括反应室和气体分配器。 反应室可以包括入口和出口。 气体分配器位于反应室中。 气体分配器具有联接到入口以接收气流的隔室和分布板,分配器板包括面向隔室的第一表面,面对反应室的第二表面和多个通道。 通道从第一表面延伸穿过分配器板到第二表面。 此外,至少一个通道具有穿过板的至少一部分闭塞的流动路径。 例如,封闭通道可以相对于分配器板的第一表面倾斜地倾斜,使得流过倾斜通道的气体在通过分配器板时改变方向。
    • 6. 发明授权
    • Apparatus for controlling gas pulsing in processes for depositing materials onto micro-device workpieces
    • 用于在将材料沉积到微器件工件上的过程中控制气体脉动的装置
    • US07481887B2
    • 2009-01-27
    • US11027809
    • 2004-12-29
    • Craig M. CarpenterRoss S. DandoAllen P. Mardian
    • Craig M. CarpenterRoss S. DandoAllen P. Mardian
    • H01L21/00C23C16/00C23C14/00
    • C23C16/45525C23C16/52
    • An apparatus for depositing materials onto a micro-device workpiece includes a gas source system configured to provide a first precursor, a second precursor, and a purge gas. The apparatus can also include a valve assembly coupled to the gas source system. The valve assembly is configured to control a flow of the first precursor, a flow the second precursor, and a flow of the purge gas. Another component of the apparatus is a reaction chamber including an inlet coupled to the valve assembly, a workpiece holder in the reaction chamber, and an outlet downstream from the workpiece holder. The apparatus also includes a monitoring system and a controller. The monitoring system comprises a radiation source that directs a selected radiation through the reaction chamber and a detector that senses a parameter of the radiation directed through the reaction chamber. The controller is operatively coupled to the monitoring system and the valve assembly. The controller contains computer operable instructions to terminate the flow of the first precursor, the flow of the second precursor and/or the flow of the purge gas based on the parameter sensed by the monitoring system in real-time during a deposition cycle of a workpiece.
    • 用于将材料沉积到微器件工件上的装置包括构造成提供第一前体,第二前体和吹扫气体的气体源系统。 该装置还可以包括联接到气源系统的阀组件。 阀组件被配置为控制第一前体的流动,第二前体的流动和净化气体的流动。 该装置的另一部件是反应室,其包括联接到阀组件的入口,反应室中的工件保持器和工件保持器下游的出口。 该装置还包括监视系统和控制器。 监测系统包括将选定的辐射引导通过反应室的辐射源和感测通过反应室引导的辐射的参数的检测器。 控制器可操作地耦合到监视系统和阀组件。 控制器包含计算机可操作的指令,以在工件的沉积循环期间实时地基于由监测系统感测的参数终止第一前体的流动,第二前体的流动和/或吹扫气体的流动 。
    • 7. 发明授权
    • Chemical vapor deposition methods
    • 化学气相沉积法
    • US06858264B2
    • 2005-02-22
    • US10132003
    • 2002-04-24
    • Ross S. DandoPhilip H. CampbellCraig M. CarpenterAllen P. Mardian
    • Ross S. DandoPhilip H. CampbellCraig M. CarpenterAllen P. Mardian
    • C23C16/44C23C16/56
    • C23C16/4405C23C16/4412
    • A chemical vapor deposition chamber has a vacuum exhaust line extending therefrom. Material is deposited over a first plurality of substrates within the deposition chamber under conditions effective to deposit effluent product over internal walls of the vacuum exhaust line. At least a portion of the vacuum exhaust line is isolated from the deposition chamber. While isolating, a cleaning fluid is flowed to the vacuum exhaust line effective to at least reduce thickness of the effluent product over the internal walls within the vacuum exhaust line from what it was prior to initiating said flowing. After said flowing, the portion of the vacuum exhaust line and the deposition chamber are provided in fluid communication with one another and material is deposited over a second plurality of substrates within the deposition chamber under conditions effective to deposit effluent product over internal walls of the vacuum exhaust line.
    • 化学气相沉积室具有从其延伸的真空排气管。 在有效地将流出物产物沉积在真空排气管的内壁上的条件下,材料沉积在沉积室内的第一组多个衬底上。 真空排气管线的至少一部分与沉积室隔离。 在分离时,清洁流体流到真空排气管线,有效地至少将真空排气管内的内壁上的流出物的厚度从起始流动之前的厚度减小到最小。 在所述流动之后,真空排气管线和沉积室的部分设置成彼此流体连通,并且在有效地将流出物产物沉积在真空内壁上的条件下,在沉积室内的第二多个基板上沉积材料 排气管路。
    • 10. 发明授权
    • Methods for controlling gas pulsing in processes for depositing materials onto micro-device workpieces
    • 用于在将材料沉积到微器件工件上的过程中控制气体脉动的方法
    • US06838114B2
    • 2005-01-04
    • US10155547
    • 2002-05-24
    • Craig M. CarpenterRoss S. DandoAllen P. Mardian
    • Craig M. CarpenterRoss S. DandoAllen P. Mardian
    • C23C16/44C23C16/455C23C16/52C23C16/00
    • C23C16/45525C23C16/52
    • Methods for depositing materials onto micro-device workpieces in a reaction chamber. One embodiment of such a method comprises providing a flow of a first precursor through the reaction chamber to deposit the first precursor onto the micro-device workpiece in the reaction chamber, and providing a flow of a purge gas through the reaction chamber to purge excess amounts of the first precursor. The method continues by monitoring a parameter correlated to a quantity of the first precursor and/or the purge gas in the reaction chamber as the first precursor and/or the purge gas flows through the reaction chamber. An additional aspect of this method is terminating the flow of the first precursor and/or the flow of the purge gas based on the monitored parameter of the quantity of the first precursor and/or the purge gas. The procedure of monitoring a parameter correlated to a quantity of the first precursor and/or the purge gas can comprise determining a concentration of the first precursor and/or the purge gas in the reaction chamber using a selected radiation.
    • 在反应室中将材料沉积到微器件工件上的方法。 这种方法的一个实施方案包括提供通过反应室的第一前体的流动,以将第一前体沉积在反应室中的微器件工件上,并且提供净化气体流过反应室以净化过量 的第一个前体。 当第一前体和/或吹扫气体流过反应室时,通过监测与反应室中的第一前体和/或吹扫气体的量相关的参数来继续该方法。 该方法的另一方面是基于所监测的第一前体和/或吹扫气体的量的参数来终止第一前体和/或吹扫气体的流动。 监测与第一前体和/或吹扫气体的量相关的参数的程序可以包括使用所选择的辐射确定反应室中的第一前体和/或吹扫气体的浓度。