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1. 发明申请

US20050006279A1 Method for the valorization of heavy charges by bubbling-bed deasphalting and hydrocracking 审中-公开
标题翻译：通过鼓泡床脱沥青和加氢裂化来提高重质荷重的方法
公开(公告)号：US20050006279A1
公开(公告)日：2005-01-13
申请号：US10831365
申请日：2004-04-26
申请人： Christophe Gueret , Stephane Kressmann , Jan Verstraete
发明人： Christophe Gueret , Stephane Kressmann , Jan Verstraete
IPC分类号： C10G1/00 , C10G55/06 , C10G67/04 , C10G69/04
CPC分类号： C10G69/04 , C10G2300/107
摘要： The invention relates to a method for treating a hydrocarbons charge comprising the following stages, in which: a) the charge is brought into contact with a solvent in order to obtain a deasphalted effluent having a content of asphaltenes below 3000 ppm by weight, b) the deasphalted effluent is cracked in the presence of hydrogen and a hydrocracking catalyst, in a bubbling-bed reactor, so as to convert at least 50 wt. % of the fraction of the deasphalted effluent boiling above 500° C. to compounds having a boiling point below 500° C., c) the effluent from stage b) is fractionated to recover gasolines, kerosene, gas oils and a first residue, and d) at least a portion of this first residue is cracked so as to obtain an effluent comprising gasolines, kerosene, gas oils and a second residue.
摘要翻译：本发明涉及一种用于处理含有以下阶段的烃装料的方法，其中：a）使电荷与溶剂接触，以获得沥青质含量低于3000重量ppm的脱沥青流出物，b）在氢气和加氢裂化催化剂的存在下，在鼓泡床反应器中将脱沥青的流出物裂化，以便将至少50wt。沸点高于500℃的脱沥青流出物的百分比达到沸点低于500℃的化合物，c）将来自阶段b）的流出物分馏以回收汽油，煤油，瓦斯油和第一残渣，以及 d）该第一残留物的至少一部分被裂化，以获得包含汽油，煤油，瓦斯油和第二残余物的流出物。

2. 发明授权

US5770154A Device for testing and for analyzing a petrochemical process 失效
标题翻译：用于测试和分析石化工艺的设备
公开(公告)号：US5770154A
公开(公告)日：1998-06-23
申请号：US578223
申请日：1995-12-26
申请人： Pierre Bigeard , Stephane Kressmann , Christophe Gueret , Pierre Galtier , Julia Magne-Drisch
发明人： Pierre Bigeard , Stephane Kressmann , Christophe Gueret , Pierre Galtier , Julia Magne-Drisch
IPC分类号： B01J8/02 , G01N31/10 , G01N35/00
CPC分类号： B01J8/0285 , G01N31/10 , B01J2208/00415 , B01J2219/00135
摘要： A device for testing the development of processes or chemical reactions in the presence of solid catalysts comprising a reactor of cylindrical shape, of inside diameter D and of length L, such that 50
摘要翻译：在固体催化剂存在下测试方法或化学反应的发展的装置，其包括内径为D且长度为L的圆柱形反应器，使得50

3. 发明申请

US20060118463A1 Integrated SDA and ebullated-bed process 有权
标题翻译：综合SDA和沸腾床过程
公开(公告)号：US20060118463A1
公开(公告)日：2006-06-08
申请号：US11005062
申请日：2004-12-06
申请人： James Colyar , Stephane Kressmann , Christophe Gueret
发明人： James Colyar , Stephane Kressmann , Christophe Gueret
IPC分类号： C10G67/04
CPC分类号： C10G67/00 , C10G67/0463 , C10G67/049 , C10G69/02 , C10G2400/02 , C10G2400/04
摘要： This invention relates to a novel integrated method for economically processing vacuum residue from heavy crude oils. This is accomplished by utilizing a solvent deasphalter (SDA) in the first step of the process with a C3/C4/C5 solvent such that the DAO product can thereafter be processed in a classic fixed-bed hydrotreater or hydrocracker. The SDA feed also includes recycled stripper bottoms containing unconverted residue/asphaltenes from a downstream steam stripper unit. The asphaltenes from the SDA are sent to an ebullated-bed reactor for conversion of the residue and asphaltenes. Residue conversion in the range of 60-80% is achieved and asphaltene conversion is in the range of 50-70%. The overall residue conversion, with the DAO product considered non-residue, is in the range of 80 W %-90 W % and significantly higher than could be achieved without utilizing the present invention.
摘要翻译：本发明涉及一种用于从重质原油经济处理减压渣油的新型综合方法。这是通过在第一步骤中利用溶剂脱沥青（SDA）与C 3 N 3 C 4 C 5 C 5溶剂使得DAO产品此后可以在经典的固定床加氢处理器或加氢裂化器中加工。 SDA进料还包括来自下游蒸汽汽提塔单元的含有未转化的残余物/沥青质的再循环汽提塔底物。来自SDA的沥青质被送入沸腾床反应器以转化残渣和沥青质。实现了60-80％范围内的残渣转化率，沥青质转化率在50-70％的范围内。考虑到非残留物的DAO产物的总残留物转化率在80W％-90W％的范围内，并且显着高于在不利用本发明的情况下可以实现的。

4. 发明授权

US08636896B2 Method for the valorization of heavy charges by bubbling-bed deasphalting and hydrocracking 有权
标题翻译：通过鼓泡床脱沥青和加氢裂化来提高重质荷重的方法
公开(公告)号：US08636896B2
公开(公告)日：2014-01-28
申请号：US12900987
申请日：2010-10-08
申请人： Christophe Gueret , Stéphane Kressmann , Jan Verstraete
发明人： Christophe Gueret , Stéphane Kressmann , Jan Verstraete
IPC分类号： C10G47/02 , C10G69/04 , C10G69/06
CPC分类号： C10G69/04 , C10G2300/107
摘要： The invention relates to a method for treating a hydrocarbons charge comprising the following stages, in which: a) the charge is brought into contact with a solvent in order to obtain a deasphalted effluent having a content of asphaltenes below 3000 ppm by weight, b) the deasphalted effluent is cracked in the presence of hydrogen and a hydrocracking catalyst, in a bubbling-bed reactor, so as to convert at least 50 wt. % of the fraction of the deasphalted effluent boiling above 500° C. to compounds having a boiling point below 500° C., c) the effluent from stage b) is fractionated to recover gasolines, kerosene, gas oils and a first residue, and d) at least a portion of this first residue is cracked so as to obtain an effluent comprising gasolines, kerosene, gas oils and a second residue.
摘要翻译：本发明涉及一种用于处理含有以下阶段的烃装料的方法，其中：a）使电荷与溶剂接触，以获得沥青质含量低于3000重量ppm的脱沥青流出物，b）在氢气和加氢裂化催化剂的存在下，在鼓泡床反应器中将脱沥青的流出物裂化，以便将至少50wt。沸点高于500℃的脱沥青流出物的百分比达到沸点低于500℃的化合物，c）将来自阶段b）的流出物分馏以回收汽油，煤油，瓦斯油和第一残渣，以及 d）该第一残留物的至少一部分被裂化，以获得包含汽油，煤油，瓦斯油和第二残余物的流出物。

5. 发明授权

US08318006B2 “Once through” process for hydrocracking hydrocarbon-containing feeds with high nitrogen contents 有权
标题翻译：一次通过加氢裂化高氮含量的含烃饲料
公开(公告)号：US08318006B2
公开(公告)日：2012-11-27
申请号：US10270075
申请日：2002-10-15
申请人： Eric Benazzi , Pierre Marion , Christophe Gueret
发明人： Eric Benazzi , Pierre Marion , Christophe Gueret
IPC分类号： C10G45/04 , C10G47/02
CPC分类号： C10G65/12 , C10G2300/107 , C10G2300/1077 , C10G2300/202 , C10G2300/4081 , C10G2300/703 , C10G2400/04 , C10G2400/06
摘要： The present invention concerns an improved once-through process for hydrocracking hydrocarbon-containing feeds with high nitrogen contents, with partial elimination of ammonia, for example by a hot flash located between the hydrorefining zone and the hydrocracking zone. Said hot flash drum functions at a pressure close to that of the hydrorefining reactor and at a temperature in the range from 150° C. to the hydrorefining reactor outlet temperature.
摘要翻译：本发明涉及一种改进的直接加工方法，用于将具有高氮含量的含烃进料加氢裂化，例如通过位于加氢精制区和加氢裂化区之间的热闪蒸部分排除氨。所述热闪鼓的压力接近于加氢精制反应器的压力，并且在150℃至加氢精制反应器出口温度的温度下起作用。

6. 发明授权

US07267758B2 Flexible method for producing oil bases and middle distillates with hydroisomerization-conversion followed by catalytic dewaxing 有权
标题翻译：生产油基和中间馏分的加氢异构化转化随后催化脱蜡的灵活方法
公开(公告)号：US07267758B2
公开(公告)日：2007-09-11
申请号：US10450397
申请日：2001-12-13
申请人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret
发明人： Eric Benazzi , Nathalie Marchal-George , Tivadar Cseri , Pierre Marion , Christophe Gueret
IPC分类号： C10G73/38 , C10G65/02
CPC分类号： B01J29/80 , B01J29/064 , B01J29/70 , B01J29/72 , C10G65/043 , C10G65/12
摘要： For producing very high quality base stock and for simultaneously producing high quality middle distillates, successive hydroisomerisation and catalytic dewaxmg steps are employed wherein the hydroisomerisation is carried out in the presence of a catalyst containing at least one noble metal deposited on an amorphous acidic support, the dispersion of the metal being 20%-100%. The support is preferably an amorphous silica-alumina. Catalytic dewaxing is carried out in the presence of a catalyst containing at least one hydrodehydrogenating element (group VIII) and at least one molecular sieve selected from ZBM-30, EU-2 and EU-11.
摘要翻译：为了生产非常高质量的基础油料并且同时生产高品质的中间馏分物，使用连续加氢异构化和催化脱蜡步骤，其中加氢异构化在含有沉积在无定形酸性载体上的至少一种贵金属的催化剂存在下进行，金属分散体为20％-100％。载体优选为无定形二氧化硅 - 氧化铝。催化脱蜡在含有至少一种脱氢元素（VIII族）和至少一种选自ZBM-30，EU-2和EU-11的分子筛的催化剂存在下进行。

7. 发明申请

US20070108102A1 Method for treating a hydrocarbon feedstock including resin removal 有权
标题翻译：用于处理包括树脂去除的烃原料的方法
公开(公告)号：US20070108102A1
公开(公告)日：2007-05-17
申请号：US10584048
申请日：2004-12-13
申请人： Christophe Gueret , Raphael Huyghe , Hugues Dulot , Patrick Euzen
发明人： Christophe Gueret , Raphael Huyghe , Hugues Dulot , Patrick Euzen
IPC分类号： C10G7/00 , B01D3/00
CPC分类号： C10G21/14 , C10G47/00 , C10G67/049 , C10G2300/107 , C10G2300/1077 , C10G2300/301 , C10G2300/44
摘要： The invention relates to a process, including removal of resins, for the treatment of a hydrocarbon charge, at least 80% of the compounds of which have a boiling point which is above or equal to 340° C., in which process: the charge is sent to a fractionation stage during which the recovery takes place of at least one heavy fraction and at least one light fraction, at least some of the heavy fraction is sent to an extraction stage during which resins contained in said heavy fraction are extracted, and a purified fraction is recovered, a mixture is made which comprises at least part of the purified fraction which was obtained in the extraction stage and at least one light fraction which was obtained in the fractionation stage, and the mixture thus obtained is sent to a cracking stage. Drawing to be published.
摘要翻译：本发明涉及一种方法，包括除去树脂，用于处理烃装料，其中至少80％的化合物具有高于或等于340℃的沸点，其中所述装料送入分馏阶段，在此阶段，回收发生至少一个重馏分和至少一个轻馏分，至少部分重馏分被送至萃取阶段，在此阶段萃取所述重馏分中所含的树脂，以及回收纯化的馏分，制备包含在萃取阶段获得的至少一部分纯化级分和在分馏阶段获得的至少一种轻馏分的混合物，将得到的混合物送入裂化阶段。绘图出版。

8. 发明申请

US20060289338A1 Process of mild hydrocracking including a dilution of the feedstock 有权
标题翻译：轻度加氢裂化的方法，包括原料稀释
公开(公告)号：US20060289338A1
公开(公告)日：2006-12-28
申请号：US11449867
申请日：2006-06-09
申请人： Christophe Gueret , Thierry Chapus , Damien Hudebine
发明人： Christophe Gueret , Thierry Chapus , Damien Hudebine
IPC分类号： C10G57/00 , B01J8/18
CPC分类号： C10G69/04 , C10G11/18 , C10G47/00
摘要： The invention relates to a process for FCC pretreatment by mild hydrocracking of a hydrocarbon feedstock that comprises a vacuum distillate fraction or a deasphalted oil or else a mixture of these two fractions, said primary feedstock, to produce gas oil and an effluent having an initial boiling point of more than 320° C., said effluent (FCC feedstock) then being subjected to a catalytic cracking, process in which at least 85% by weight of said primary feedstock ends above 375° C. and at least 95% by weight of said primary feedstock ends below 650° C., whereby the mild hydrocracking is performed under an absolute pressure of 2 to 12 MPa and at a temperature of between 300 and 500° C., characterized in that the hydrocarbon feedstock also comprises a lighter hydrocarbon fraction, a so-called secondary feedstock, of which at least 50% by weight ends below 375° C. and at least 80% ends above 200° C.
摘要翻译：本发明涉及通过烃原料的轻度加氢裂化来进行FCC预处理的方法，所述烃原料包括真空蒸馏馏分或脱沥青油，或者所述主要原料的这两个馏分的混合物，以产生瓦斯油和具有初始沸点的流出物所述流出物（FCC原料）然后进行催化裂化，其中至少85重量％的所述主要原料在375℃以上终止，并且至少95重量％所述主要原料终止于650℃以下，由此在2至12MPa的绝对压力和300至500℃的温度下进行轻度加氢裂化，其特征在于，烃原料还包含较轻的烃馏分，所谓的二次原料，其中至少50重量％终止于375℃以下且至少80％在200℃以上结束。

9. 发明授权

US06814856B1 Method for improving a gas oil fraction cetane index 失效
$Method for improving a gas oil fraction cetane index$
标题翻译：提高瓦斯油馏分十六烷指数的方法
公开(公告)号：US06814856B1
公开(公告)日：2004-11-09
申请号：US09445573
申请日：2000-05-04
申请人： Marcel Aussillous , Alain Billion , Patrick Briot , Christophe Gueret , Slavik Kasztelan , Narhalie Marchal , Pierre Marion
发明人： Marcel Aussillous , Alain Billion , Patrick Briot , Christophe Gueret , Slavik Kasztelan , Narhalie Marchal , Pierre Marion
IPC分类号： C10G6512
CPC分类号： C10G65/12 , C10G2400/04
摘要： A process for transforming a gas oil cut from a conversion process or from an aromatic crude is described, the aim of the process being to improve the cetane number of said cut. The process comprises at least one hydrogenation step in which said gas oil cut is passed, in the presence of hydrogen, over a catalyst comprising an amorphous mineral support, at least one compound of a group VIB metal, at least one compound of a non noble group VIII metal and at least phosphorous or a compound of phosphorous, the process then comprising a hydrocracking step in which the hydrogenated feed is passed, in the presence of hydrogen, over a catalyst comprising an acidic support, at least one compound of a group VIB metal and at least one compound of a non noble group VIII metal.

10. 发明授权

US06733658B2 EU-1 zeolite catalyst and a process for the reduction of the pour point of feeds containing paraffins 失效
标题翻译： EU-1沸石催化剂和降低含有链烷烃的进料的倾点的方法
公开(公告)号：US06733658B2
公开(公告)日：2004-05-11
申请号：US09103528
申请日：1998-06-24
申请人： Eric Benazzi , Nathalie George-Marchal , Christophe Gueret , Patrick Briot , Alain Billon , Pierre Marion
发明人： Eric Benazzi , Nathalie George-Marchal , Christophe Gueret , Patrick Briot , Alain Billon , Pierre Marion
IPC分类号： C10G4716
CPC分类号： B01J29/7023 , B01J29/04 , B01J29/7446 , B01J29/7846 , B01J2229/16 , B01J2229/32 , B01J2229/37 , B01J2229/42 , C01B39/026 , C10G45/64 , C10G2300/1022 , C10G2300/1048 , C10G2300/1059 , C10G2300/1077 , C10G2300/301 , C10G2300/304 , C10G2300/4018
摘要： The invention concerns a process for improving the pour point of a feed comprising paraffins containing more than 10 carbon atoms, in which process the feed to be treated is brought into contact with a catalyst comprising an EU-1 zeolite and at least one hydro-dehydrogenating element, at a temperature which is in the range 170° C. to 500° C., a pressure in the range 1 to 250 bar and an hourly space velocity in the range 0.05 to 100 h−1, in the presence of hydrogen in a proportion of 50 to 2000 l/l of feed. The oils obtained have good pour points and high viscosity indices (VI). The process is also applicable to gas oils and other feeds requiring a reduction of pour point. The invention also concerns an EU-1 zeolite from which a portion of elements T (Al, Ga, Fe or B) have been removed and which has an Si/T atomic ratio of at least 10.
摘要翻译：本发明涉及一种改进含有多于10个碳原子的链烷烃的进料的倾点的方法，其中待处理的进料与包含EU-1沸石的催化剂和至少一种加氢脱氢的催化剂接触元素，温度范围为170℃至500℃，压力范围为1至250巴，小时空间速度为0.05至100小时-1，在存在氢气比例为50〜2000升/升饲料。所得油具有良好的倾点和高粘度指数（VI）。该方法也适用于需要降低倾点的瓦斯油和其他进料。本发明还涉及一部分元素T（Al，Ga，Fe或B）被去除并且其Si / T原子比至少为10的EU-1沸石。

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