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1. 发明申请

US20120095221A1 PROCESS FOR PREPARING A CYCLIC TERTIARY AMINE 有权
标题翻译：制备循环胺的方法
公开(公告)号：US20120095221A1
公开(公告)日：2012-04-19
申请号：US13273784
申请日：2011-10-14
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meißner
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meißner
IPC分类号： C07D295/03
CPC分类号： C07D295/03 , C07D295/023
摘要： A process for preparing a cyclic tertiary amine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, and the radical R2 is a linear or branched C2-C16-alkyl, C5-C7-cycloalkyl or C7-C20-aralkyl, in which (i) an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) and aminoethylethanolamine of the formula IIa where R1 is as defined above or hydrogen (H), in which case R1═R2 in the amine I, is reacted with a primary or secondary alcohol R2OH (III) at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst in a reactor.
摘要翻译：其中A是C 4 - 亚烷基，C 5 - 亚烷基或 - （CH 2）2 -B-（CH 2）2 - 基团，其中B是氧（O））的式I的环状叔胺的方法，或N-R 1基团，并且R 1是C 1 -C 5 - 烷基，芳基或C 5 -C 7 - 环烷基，并且基团R 2是直链或支链C 2 -C 16 - 烷基，C 5 -C 7 - 环烷基或C 7 -C 20 - 芳烷基，其中（i）由式IIa的其中R1如上所定义的氢原子（H）的1,4-氨基丁醇，1,5-氨基戊醇，氨基二甘醇（ADG）和氨基乙基乙醇胺组成的组中的氨基醇II，其中在胺I中的情况R1 = R2在初级醇或仲醇R 2 OH（III）中，在含有铜的非均相催化剂的存在下，在液相中在150-270℃的温度下反应反应堆。

2. 发明授权

US09000218B2 Process for preparing secondary amines in the liquid phase 有权
标题翻译：在液相中制备仲胺的方法
公开(公告)号：US09000218B2
公开(公告)日：2015-04-07
申请号：US13737158
申请日：2013-01-09
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
IPC分类号： C07C209/00 , C07C209/16 , C07C209/86
CPC分类号： C07C209/16 , C07C209/86 , C07C2601/14 , C07C2603/74 , C07C211/35 , C07C211/08
摘要： The present application relates to a process for preparing secondary amines by aminating excess primary or secondary alcohols with primary amines in the liquid phase in the presence of copper-comprising catalysts.
摘要翻译：本申请涉及通过在含铜催化剂存在下在液相中胺化过量的伯胺伯胺或仲醇来制备仲胺的方法。

3. 发明申请

US20120245389A1 PROCESS FOR HYDROGENATING NITRILES 审中-公开
标题翻译：加氢处理方法
公开(公告)号：US20120245389A1
公开(公告)日：2012-09-27
申请号：US13427308
申请日：2012-03-22
申请人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Martin Ernst , Thomas Heidemann , Johann-Peter Melder , Lucia Königsmann , Milind Joshi , Oliver Bey , Bernd Stein
发明人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Martin Ernst , Thomas Heidemann , Johann-Peter Melder , Lucia Königsmann , Milind Joshi , Oliver Bey , Bernd Stein
IPC分类号： C07C209/48
CPC分类号： C07C209/48 , C07C2601/14 , C07C211/36 , C07C211/09
摘要： The present invention relates to a process for hydrogenating organic nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the shaped body catalyst is arranged in a fixed bed, wherein the shaped body in the shape of spheres or rods has in each case a diameter 3 mm or less, in the shape of tablets a height of 4 mm or less, and in the case of all other geometries in each case has an equivalent diameter L=1/a′ of 0.70 mm or less, where a′ is the external surface area per unit volume (mms2/mmp3), where: a ′ = A p V p , where Ap is the external surface area of the catalyst particle (mms2) and Vp is the volume of the catalyst particle (mmp3). The present invention further relates to a process for preparing downstream products of isophoronediamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines prepared according to the invention.
摘要翻译：本发明涉及一种在反应器中催化剂存在下通过氢气氢化有机腈的方法，其中成形体催化剂布置在固定床中，其中球体或棒状的成形体具有每个壳体的直径为3mm以下，片状形状为4mm以下，在各种情况下，所有其他几何形状的等效直径L = 1 / a'为0.70mm以下，其中 a'是每单位体积的外表面积（mms2 / mmp3），其中：a'= A p V p，其中Ap是催化剂颗粒的外表面积（mms2），Vp是催化剂颗粒的体积 mmp3）。本发明还涉及由根据本发明制备的胺制备异佛尔酮二胺（IPDA）或N，N-二甲基氨基丙胺（DMAPA）的下游产物的方法。

4. 发明申请

US20130178656A1 PROCESS FOR PREPARING SECONDARY AMINES IN THE LIQUID PHASE 有权
标题翻译：在液相中制备二级胺的方法
公开(公告)号：US20130178656A1
公开(公告)日：2013-07-11
申请号：US13737158
申请日：2013-01-09
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein
IPC分类号： C07C209/16
CPC分类号： C07C209/16 , C07C209/86 , C07C2601/14 , C07C2603/74 , C07C211/35 , C07C211/08
摘要： The present application relates to a process for preparing secondary amines by aminating excess primary or secondary alcohols with primary amines in the liquid phase in the presence of copper-comprising catalysts.
摘要翻译：本申请涉及通过在含铜催化剂存在下在液相中胺化过量的伯胺伯胺或仲醇来制备仲胺的方法。

5. 发明授权

US08637668B2 Process for preparing a cyclic tertiary methylamine 有权
标题翻译：制备环状叔甲胺的方法
公开(公告)号：US08637668B2
公开(公告)日：2014-01-28
申请号：US13158667
申请日：2011-06-13
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
IPC分类号： C07D295/03
CPC分类号： C07D295/03
摘要： Process for preparing a cyclic tertiary methylamine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, wherein an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) or aminoethylethanolamine of the formula IIa where R1 is as defined above or is hydrogen (H), in which case R1═CH3 in the amine I, is reacted with methanol in a reactor at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst.
摘要翻译：制备式I的环状叔甲胺的方法，其中A是C 4 - 亚烷基，C 5-亚烷基或 - （CH 2）2 -B-（CH 2）2 - 基，其中B是氧（O）或 R 1是C 1 -C 5 - 烷基，芳基或C 5 -C 7 - 环烷基，其中由1,4-氨基丁醇，1,5-氨基戊醇，氨基二甘醇（ADG）或氨基乙基乙醇胺组成的组中的氨基醇II 其中R 1如上定义或是氢（H），在这种情况下，胺I中的R 1 = CH 3在反应器中在150-270℃的温度下与甲醇反应，在在含铜的非均相催化剂存在下的液相。

6. 发明授权

US08445726B2 Process for preparing unsymmetric secondary tert-butylamines in the liquid phase 失效
标题翻译：在液相中制备不对称的仲叔丁胺的方法
公开(公告)号：US08445726B2
公开(公告)日：2013-05-21
申请号：US13080080
申请日：2011-04-05
申请人： Christof Wilhelm Wigbers , Christoph Mueller , Johann-Peter Melder , Bernd Stein , Harald Meissner , Gerd Haderlein , Norbert Gutfrucht
发明人： Christof Wilhelm Wigbers , Christoph Mueller , Johann-Peter Melder , Bernd Stein , Harald Meissner , Gerd Haderlein , Norbert Gutfrucht
IPC分类号： C07C209/26
CPC分类号： C07C209/26 , Y02P20/582 , C07C211/17 , C07C211/08
摘要： The present application relates to a process for preparing unsymmetric secondary tert-butylamines which, as well as the tert-butyl radical, also comprise an alkyl, cycloalkyl or benzyl radical. They are prepared by reacting corresponding aldehydes with tert-butylamine and hydrogen in the presence of hydrogenation catalysts (reductive amination) in the liquid phase.
摘要翻译：本申请涉及一种制备不对称仲叔丁胺的方法，其中叔丁基以及叔丁基也包括烷基，环烷基或苄基。它们通过在液相中的氢化催化剂（还原胺化）存在下，使相应的醛与叔丁胺和氢反应来制备。

7. 发明授权

US08933223B2 Process for preparing a cyclic tertiary amine 有权
标题翻译：制备环状叔胺的方法
公开(公告)号：US08933223B2
公开(公告)日：2015-01-13
申请号：US13273784
申请日：2011-10-14
申请人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
发明人： Christof Wilhelm Wigbers , Johann-Peter Melder , Bernd Stein , Harald Meiβner
IPC分类号： C07D295/02 , C07D295/00 , C07D295/03 , C07D295/023
CPC分类号： C07D295/03 , C07D295/023
摘要： A process for preparing a cyclic tertiary amine of the formula I where A is a C4-alkylene group, a C5-alkylene group or a —(CH2)2—B—(CH2)2— group, where B is oxygen (O) or an N—R1 radical and R1 is C1-C5-alkyl, aryl or C5-C7-cycloalkyl, and the radical R2 is a linear or branched C2-C16-alkyl, C5-C7-cycloalkyl or C7-C20-aralkyl, in which (i) an amino alcohol II from the group consisting of 1,4-aminobutanol, 1,5-aminopentanol, aminodiglycol (ADG) and aminoethylethanolamine of the formula IIa where R1 is as defined above or hydrogen (H), in which case R1=R2 in the amine I, is reacted with a primary or secondary alcohol R2OH (III) at a temperature in the range from 150 to 270° C. in the liquid phase in the presence of a copper-comprising heterogeneous catalyst in a reactor.
摘要翻译：其中A是C 4 - 亚烷基，C 5 - 亚烷基或 - （CH 2）2 -B-（CH 2）2 - 基团，其中B是氧（O））的式I的环状叔胺的方法，或N-R 1基团，并且R 1是C 1 -C 5 - 烷基，芳基或C 5 -C 7 - 环烷基，并且基团R 2是直链或支链C 2 -C 16 - 烷基，C 5 -C 7 - 环烷基或C 7 -C 20 - 芳烷基，其中（i）由式IIa的其中R1如上所定义的氢原子（H）的1,4-氨基丁醇，1,5-氨基戊醇，氨基二甘醇（ADG）和氨基乙基乙醇胺组成的组中的氨基醇II，其中在胺I中的情况R1 = R2在初级醇或仲醇R 2 OH（III）中在150-270℃的温度下在液相中在含铜的非均相催化剂存在下与反应堆。

8. 发明授权

US08450530B2 Process for preparing unsymmetric secondary tert-butylamines in the gas phase 失效
标题翻译：在气相中制备不对称二级叔丁胺的方法
公开(公告)号：US08450530B2
公开(公告)日：2013-05-28
申请号：US13080885
申请日：2011-04-06
申请人： Christoph Mueller , Christof Wilhelm Wigbers , Johann-Peter Melder , Gerd Haderlein , Norbert Gutfrucht
发明人： Christoph Mueller , Christof Wilhelm Wigbers , Johann-Peter Melder , Gerd Haderlein , Norbert Gutfrucht
IPC分类号： C07C209/16 , C07C209/26
CPC分类号： C07C209/26 , C07C211/08
摘要： The present invention relates to a process for preparing unsymmetric secondary tert-butylamines by continuous amination in the gas phase, wherein tert-butylamine is converted over hydrogenation catalysts in the presence of an alcohol or aldehyde and hydrogen.
摘要翻译：本发明涉及通过在气相中连续胺化来制备不对称仲叔丁胺的方法，其中叔丁胺在醇或醛和氢的存在下转化为氢化催化剂。

9. 发明申请

US20110313188A1 METHOD FOR IMPROVING THE CATALYTIC ACTIVITY OF MONOLITHIC CATALYSTS 审中-公开
标题翻译：改进单体催化剂催化活性的方法
公开(公告)号：US20110313188A1
公开(公告)日：2011-12-22
申请号：US13148595
申请日：2010-02-04
申请人： Christof Wilhelm Wigbers , Jochen Steiner , Martin Ernst , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder
发明人： Christof Wilhelm Wigbers , Jochen Steiner , Martin Ernst , Bram Willem Hoffer , Ekkehard Schwab , Johann-Peter Melder
IPC分类号： C07C209/48 , B01J21/02 , B01J21/10 , B01J21/16 , B01J21/06 , B01J23/83 , C07C253/30 , B01J21/08
CPC分类号： B01J23/78 , B01J23/83 , B01J27/1817 , B01J27/1853 , B01J35/04 , B01J37/0201 , B01J37/0205 , B01J37/0215 , B01J37/0234 , B01J2523/00 , C07C209/48 , C07C253/30 , C07C2601/14 , C07C211/09 , C07C211/11 , C07C211/12 , C07C211/36 , C07C255/24 , B01J2523/12 , B01J2523/31 , B01J2523/51 , B01J2523/72 , B01J2523/845 , B01J2523/11 , B01J2523/48 , B01J2523/847
摘要： The present invention relates to a catalyst comprising one or more elements selected from the group consisting of cobalt, nickel and copper, said catalyst being present in the form of a structured monolith, wherein said catalyst comprises one or more elements selected from the group of the alkali metals, alkaline earth metals and rare earth metals. The invention further relates to processes for preparing the inventive catalyst and to the use of the inventive catalyst in a process for hydrogenating organic substances, especially for hydrogenating nitriles.
摘要翻译：本发明涉及包含一种或多种选自钴，镍和铜的元素的催化剂，所述催化剂以结构化整料的形式存在，其中所述催化剂包括一种或多种选自以下的元素：碱金属，碱土金属和稀土金属。本发明还涉及用于制备本发明催化剂的方法和本发明催化剂在用于氢化有机物质，特别是用于氢化腈的方法中的用途。

10. 发明授权

US09139511B2 Process for hydrogenating nitriles 有权
标题翻译：腈水解工艺
公开(公告)号：US09139511B2
公开(公告)日：2015-09-22
申请号：US13427388
申请日：2012-03-22
申请人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Petr Kubanek , Thomas Heidemann , Johann-Peter Melder , Thomas Krug , Oliver Bey
发明人： Christof Wilhelm Wigbers , Christoph Müller , Wolfgang Mägerlein , Petr Kubanek , Thomas Heidemann , Johann-Peter Melder , Thomas Krug , Oliver Bey
IPC分类号： C07C209/00 , C07C209/48
CPC分类号： C07C209/48
摘要： The present invention relates to a process for hydrogenating nitriles by means of hydrogen in the presence of a catalyst in a reactor, where the catalyst is arranged in a fixed bed, wherein the cross-sectional loading in the reactor is in the range from 5 kg/(m2 s) to 50 kg/(m2 s). The present invention further relates to a process for preparing downstream products of isophoronediamine (IPDA) or N,N-dimethylaminopropylamine (DMAPA) from amines prepared according to the invention.
摘要翻译：本发明涉及在反应器中催化剂存在下通过氢气氢化腈的方法，其中催化剂布置在固定床中，其中反应器中的横截面负载在5kg /（m2·s）至50 kg /（m2·s）。本发明还涉及由根据本发明制备的胺制备异佛尔酮二胺（IPDA）或N，N-二甲基氨基丙胺（DMAPA）的下游产物的方法。

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