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    • 1. 发明授权
    • Dispersing agents for aqueous coatings compositions
    • 水性涂​​料组合物分散剂
    • US5910556A
    • 1999-06-08
    • US915184
    • 1997-08-20
    • Christian WamprechtOswald WilmesStephan KirchmeyerJan Mazanek
    • Christian WamprechtOswald WilmesStephan KirchmeyerJan Mazanek
    • B01F17/00B01F17/52C08G18/10C08G18/28C08G18/32C08G18/48C08G18/66C09D5/00C09D5/02C09D7/45C09D175/08
    • C09D7/02B01F17/005C08G18/10C08G18/283C08G18/284C08G18/2865C08G18/2875C09D5/027
    • The present invention relates to a process for the solvent-free production of polyisocyanate addition products, which are suitable as dispersing agents for incorporating solids into aqueous coating compositions, wherein the polyisocyanate addition products have a maximum content of 1% by weight of isocyanate groups and a content of 30 to 95% by weight of ethylene oxide units (molecular weight=44) present in the polyether chains of monofunctional alcohols B), and are prepared by reactingA) a polyisocyanate component having an average NCO functionality of 1.7 to 2.5 and an NCO content of 10 to 65% by weight with one or more of the following components:B) monohydric polyether alcohols having a number average molecular weight of 150 to 5000 and an ethylene oxide content of 40 to 99.5% by weight,C) monohydric alcohols having a number average molecular weight of 32 to 5000, which are different from the alcohols of component B),D) an amine component which contains at least one tertiary amine having a molecular weight of 88 to 250 and which contains one isocyanate-reactive group andE) compounds having a number average molecular weight of 32 to 5000 and at least two isocyanate-reactive groups,The present invention also relates to the polyisocyanate addition products obtained by this process and to their use as dispersing agents incorporating solids into aqueous and/or solvent-containing coating compositions.
    • 本发明涉及一种无溶剂生产多异氰酸酯加成产物的方法,其适合作为将固体掺入水性涂料组合物中的分散剂,其中多异氰酸酯加成产物的最大含量为异氰酸酯基团的1重量% 通过使A)具有1.7〜2.5的平均NCO官能度的多异氰酸酯成分和1.7〜2.5的多异氰酸酯成分与通式(I)所示的单体官能醇B)的聚醚链中存在的30〜95重量%的环氧乙烷单元(分子量= 44) NCO含量为一种或多种以下组分的10至65重量%:B)数均分子量为150至5000且环氧乙烷含量为40至99.5重量%的一元聚醚醇,C)一元 数均分子量为32〜5000的醇,其与组分B)的醇不同,D)含有至少一个叔胺的胺组分 其分子量为88〜250,含有一个异氰酸酯反应性基团,E)数均分子量为32〜5000的化合物和至少两种异氰酸酯反应性基团。本发明还涉及多异氰酸酯加成物 通过该方法获得并用作将固体掺入含水和/或含溶剂的涂料组合物中的分散剂。
    • 6. 发明申请
    • Aqueous coatings for food containers
    • 食品容器用水性涂料
    • US20060149019A1
    • 2006-07-06
    • US11301622
    • 2005-12-13
    • Christian WamprechtJan MazanekBeate BaumbachWolfram KuttnerDorota Greszta-Franz
    • Christian WamprechtJan MazanekBeate BaumbachWolfram KuttnerDorota Greszta-Franz
    • C08G18/00
    • C08G18/4263C08G18/792C08G18/8067C08G18/8074C08G2390/40C09D175/06
    • The present invention relates to aqueous coating compositions containing A) at least one polyisocyanate which contains an average of at least two NCO groups per molecule and in which at least 85% of the NCO groups are blocked with a blocking agent selected from ε-caprolactam and/or a hydroxycarboxylic acid, and B) at least one hydrophilic polyester polyol containing an average of at least two reactive hydroxyl groups per molecule, or a mixture of hydrophilic and non-hydrophilic polyester polyols, wherein component B) has an acid number of ≧15 mg KOH/g, a hydroxyl number of 20 to 300 mg KOH/g and a weight average molecular weight, Mw, of >1500 g/mol, wherein the equivalent ratio between the blocked isocyanate groups of component A) and the isocyanate-reactive groups of component B) is 0.5 to 5.0:1. The present invention also relates to a process for preparing these aqueous coating compositions, to coatings obtained from these aqueous coating compositions, particularly coatings for packaging and for the interior of cans.
    • 本发明涉及包含A)至少一种多异氰酸酯的水性涂料组合物,其每分子含有平均至少两个NCO基团,其中至少85%的NCO基团用封闭剂封闭,所述封闭剂选自ε-己内酰胺和 /或羟基羧酸,和B)至少一种含有每分子平均至少两个反应性羟基的亲水性聚酯多元醇,或亲水性和非亲水性聚酯多元醇的混合物,其中组分B)的酸值> = 15mg KOH / g,羟值为20-300mg KOH / g,重均分子量M w> 1500g / mol,其中封端异氰酸酯之间的当量比 组分A)和组分B)的异氰酸酯反应性基团为0.5至5.0:1。 本发明还涉及一种制备这些水性涂料组合物的方法,由这些水性涂料组合物获得的涂料,特别是用于包装的涂料和罐内部。