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    • 6. 发明申请
    • Method for the production of chlorine
    • 生产氯的方法
    • US20060263290A1
    • 2006-11-23
    • US10567579
    • 2004-08-06
    • Christian WalsdorffMartin FieneMartin SesingOlga MetelkinaLothar SeidemannEckhard StroeferKlaus Harth
    • Christian WalsdorffMartin FieneMartin SesingOlga MetelkinaLothar SeidemannEckhard StroeferKlaus Harth
    • C01B7/00
    • C01B7/04Y02P20/228
    • The invention relates to a process for preparing chlorine by catalytic gas-phase oxidation of hydrogen chloride, which comprises the steps: a) providing a feed gas stream I comprising hydrogen chloride and a feed gas stream II comprising oxygen; b) in a first oxidation stage, feeding the feed gas stream I, the feed gas stream II, if desired a recycle stream la comprising hydrogen chloride and if desired an oxygen-containing recycle stream IIa into a first oxidation zone and bringing them into contact with a first oxidation catalyst so that a first partial amount of the hydrogen chloride is oxidized to chlorine and a gas stream III comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; c) in a second oxidation stage, feeding the gas stream III into a second oxidation zone and bringing it into contact with at least one further oxidation catalyst so that a second partial amount of the hydrogen chloride is oxidized to chlorine and a product gas stream IV comprising chlorine, unreacted oxygen, unreacted hydrogen chloride and water vapor is obtained; d) isolating chloride, if desired the recycle stream Ia and if desired the recycle stream IIa from the product gas stream IV, wherein the first oxidization catalyst in the first oxidation zone is present in a fluidized bed and the further oxidation catalyst or catalysts in the second oxidation zone is/are present in a fixed bed.
    • 本发明涉及通过氯化氢的催化气相氧化制备氯的方法,其包括以下步骤:a)提供包含氯化氢的进料气流I和包含氧的进料气流II; b)在第一氧化阶段,如果需要,将进料气流I,进料气流II进料到包含氯化氢的再循环流1a,并且如果需要,将含氧循环流IIa进入第一氧化区并使其接触 用第一氧化催化剂使得第一部分氯化氢被氧化成氯,得到包含氯,未反应的氧,未反应的氯化氢和水蒸气的气流III; c)在第二氧化阶段,将气流III进料到第二氧化区并使其与至少一种其它氧化催化剂接触,使得第二部分量的氯化氢被氧化成氯,产物气流IV 包括氯,未反应的氧,未反应的氯化氢和水蒸气; d)如果需要,根据需要从产物气流IV中分离氯化物,如果需要,再循环流Ia,如果需要,再循环流IIa,其中第一氧化区中的第一氧化催化剂存在于流化床中, 第二氧化区存在于固定床中。