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    • 1. 发明授权
    • Integrated circuit polishing method
    • 集成电路抛光方法
    • US5314843A
    • 1994-05-24
    • US858670
    • 1992-03-27
    • Chris C. YuGurtej S. SandhuTrung T. Doan
    • Chris C. YuGurtej S. SandhuTrung T. Doan
    • H01L21/3105H01L21/302
    • H01L21/7684H01L21/3105H01L21/31053
    • A semiconductor wafer has a surface layer to be planarized in a chemical mechanical polishing (CMP) process. An area of the layer that is higher than another area is altered so that the removal rate is higher. For example, if the surface layer is TEOS oxide, the higher layer may be bombarded with boron and phosphorus to produce BPSG, which has a polishing rate 2-3 times that of the TEOS. Upon CMP planarization, the higher area erodes faster resulting in improved planarization. Alternatively, the lower area may be doped with nitrogen to produce a nitride which is more resistant to CMP, with the same result. Likewise areas, such as tungsten troughs, which tend to be dished by CMP, may be changed to WNx which is more resistant to the tungsten CMP than the adjacent tungsten, eliminating the dishing upon planarization.
    • 半导体晶片在化学机械抛光(CMP)工艺中具有待平坦化的表面层。 高于另一区域的层的区域被改变,使得去除率更高。 例如,如果表面层是TEOS氧化物,则可以用硼和磷轰击较高层以产生BPSG,其具有2-3倍于TEOS的抛光速率。 在CMP平坦化之后,较高区域的侵蚀速度更快,从而改善了平面化。 或者,下部区域可以掺杂氮气以产生更耐CMP的氮化物,具有相同的结果。 同样倾向于通过CMP抛光的钨槽的区域也可以改变为比相邻钨更耐钨钨的WNx,消除了平面化时的凹陷。
    • 3. 发明授权
    • Method of providing high flux of point of use activated reactive species for semiconductor processing
    • 提供高通量使用激活活性物质进行半导体加工的方法
    • US06793736B2
    • 2004-09-21
    • US10392940
    • 2003-03-20
    • Gurtej S. SandhuTrung T. Doan
    • Gurtej S. SandhuTrung T. Doan
    • B08B702
    • H01L21/67069
    • A method for providing a high flux of point of use activated reactive species for semiconductor processing wherein a workpiece is exposed to a gaseous atmosphere containing a transmission gas that is substantially nonattenuating to preselected wavelengths of electromagnetic radiation. A laminar flow of a gaseous constituent is also provided over a substantially planar surface of the workpiece wherein a beam of the electromagnetic radiation is directed into the gaseous atmosphere such that it converges in the laminar flow to provide maximum beam energy in close proximity to the surface of the workpiece, but spaced a finite distance therefrom. The gaseous constituent is dissociated by the beam producing an activated reactive species that reacts with the surface of the workpiece.
    • 一种用于提供用于半导体加工的高通量使用激活活性物质的方法,其中工件暴露于含有基本上不衰减到预选的电磁辐射波长的透射气体的气体气氛中。 气体成分的层流还设置在工件的基本上平坦的表面上,其中电磁辐射的束被引导到气态气氛中,使得其在层流中会聚以提供最接近表面的最大束能 的距离。 气体组分由光束解离,产生与工件表面反应的活化反应物质。
    • 4. 发明授权
    • Method of providing a silicon film having a roughened outer surface
    • 提供具有粗糙化外表面的硅膜的方法
    • US5320880A
    • 1994-06-14
    • US155585
    • 1993-11-18
    • Gurtej S. SandhuTrung T. Doan
    • Gurtej S. SandhuTrung T. Doan
    • C23C16/24C23C16/505H01L21/02H01L21/205B05D3/06B05D3/02C23C16/00
    • H01L28/84C23C16/24C23C16/505H01L21/02381H01L21/02532H01L21/0262
    • A method of providing a silicon film having a roughened outer surface atop a semiconductor wafer comprises: a) placing a semiconductor wafer into a plasma enhanced RF powered chemical vapor deposition reactor; and b) plasma enhanced chemical vapor depositing a layer of silicon over the wafer surface by providing quantities of a silicon source gas, a carrier gas, and TiCl.sub.4 to the reactor, the atomic ratio of the quantities of silicon source gas and TiCl.sub.4 being greater than or equal to 4 at the wafer surface; and by maintaining the reactor at a selected RF power, pressure and temperature; the RF power being supplied at a frequency of at least 5 MHz and preferably at least 10 MHz, the quantities of silicon source gas, RF power, temperature and pressure being effective to produce a predominately silicon film having an outer surface, the quantity of TiCl.sub.4 being effective to induce roughness into the outer silicon surface as compared to an outer silicon surface prepared under identical conditions but for introduction of TiCl.sub.4 but ineffective to produce a predominately titanium silicide film.
    • 提供在半导体晶片顶部具有粗糙化的外表面的硅膜的方法包括:a)将半导体晶片放置在等离子体增强的RF功率化学气相沉积反应器中; 和b)通过向反应器提供大量的硅源气体,载气和TiCl 4,等离子体增强化学气相沉积在晶片表面上的硅层,硅源气体和TiCl 4的量的原子比大于 或在晶片表面等于4; 并通过将反应器维持在选定的RF功率,压力和温度; RF功率以至少5MHz,优选至少10MHz的频率提供,硅源气体的量,RF功率,温度和压力有效地产生主要具有外表面的硅膜,TiCl 4的量 与在相同条件下制备的但用于引入TiCl 4但不能产生主要的硅化钛膜的外硅表面相比,有效地将粗糙度引入外硅表面。
    • 5. 发明授权
    • Chemical vapor deposition technique for depositing titanium silicide on
semiconductor wafers
    • 用于在半导体晶片上沉积硅化钛的化学气相沉积技术
    • US5278100A
    • 1994-01-11
    • US789585
    • 1991-11-08
    • Trung T. DoanGurtej S. Sandhu
    • Trung T. DoanGurtej S. Sandhu
    • H01L21/205H01L21/28H01L21/285H01L21/768H01L21/441
    • H01L21/76855H01L21/285H01L21/28518H01L21/76843H01L21/76877Y10S148/147
    • A method of providing a conformal layer of TiSi.sub.x atop a semiconductor wafer within a chemical vapor deposition reactor includes the following steps: a) positioning a wafer within the reactor; b) injecting selected quantities of gaseous Ti(NR.sub.2).sub.4 precursor, gaseous silane and a carrier gas to within the reactor, where R is selected from the group consisting of H and a carbon containing radical, the quantities of Ti(NR.sub.2).sub.4 precursor and silane being provided in a volumetric ratio of Ti(NR.sub.2).sub.4 to silane of from 1:300 to 1:10, the quantity of carrier gas being from about 50 sccm to about 2000 sccm and comprising at least one noble gas; and c) maintaining the reactor at a selected pressure and a selected temperature which are effective for reacting the precursor and silane to deposit a film on the wafer, the film comprising a mixture of TiSi.sub.x and TiN, the selected temperature being from about 100.degree. C. to about 500.degree. C., and the selected pressure being from about 150 mTorr to about 100 Torr.
    • 在化学气相沉积反应器内提供半导体晶片顶部的TiSix共形层的方法包括以下步骤:a)将晶片定位在反应器内; b)将选定量的气态Ti(NR 2)4前体,气态硅烷和载气注入反应器内,其中R选自H和含碳基团,Ti(NR 2)4前体的量 硅烷以Ti(NR 2)4与硅烷的体积比为1:300至1:10,载气量为约50sccm至约2000sccm并包含至少一种惰性气体; 以及c)将所述反应器保持在选择的压力和所选择的温度下,所述选择的温度对于使所述前体和硅烷反应以在所述晶片上沉积膜是有效的,所述膜包含TiSix和TiN的混合物,所述选定温度为约100℃ 至约500℃,并且所选择的压力为约150mTorr至约100Torr。