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1. 发明授权

US4822917A Process for the hydroformylation of an olefin 失效
标题翻译：烯烃加氢甲酰化的方法
公开(公告)号：US4822917A
公开(公告)日：1989-04-18
申请号：US133807
申请日：1987-12-16
申请人： Chihiro Miyazawa , Hiroshi Mikami , Akio Tsuboi , Katsuhide Hamano
发明人： Chihiro Miyazawa , Hiroshi Mikami , Akio Tsuboi , Katsuhide Hamano
IPC分类号： C07C45/50
CPC分类号： B01J31/4046 , B01J31/1875 , B01J31/4053 , C07C45/50 , B01J2231/321 , B01J2531/822 , Y02P20/584
摘要： A process for the hydroformylation of an olefin, which comprises hydroformylating an olefinic compound by reacting it with carbon monoxide and hydrogen in a hydroformylation reaction zone in the presence of a catalyst solution containing rhodium and an oxide of an organic trivalent phosphorus compound to form an aldehyde having a carbon number larger by one than that of the olefinic compound; adding an organic trivalent phosphorus compound to the reaction mixture, followed by distillation to separate a distillate containing the aldehyde from a high-boiling residue containing rhodium; oxidizing the high-boiling residue at the same time as or subsequent to the distillation to convert the organic trivalent phosphorus compound to its oxide; and recycling the oxidized residue to the hydroformylation reaction zone as a recycling catalyst solution, wherein the hydroformylation reaction is conducted under a condition such that the proportion of an alcohol content supplied as contained in the recycling catalyst solution is maintained at a level of not higher than 14% by weight based on the total amount of the olefinic compound and the catalyst solution supplied to the hydroformylation reaction zone.

2. 发明授权

US5105018A Process for hydroformylation of an olefin 失效
标题翻译：烯烃氢化方法
公开(公告)号：US5105018A
公开(公告)日：1992-04-14
申请号：US596383
申请日：1990-10-12
申请人： Chihiro Miyazawa , Hiroshi Mikami
发明人： Chihiro Miyazawa , Hiroshi Mikami
IPC分类号： B01J31/22 , B01J31/24 , C07B61/00 , C07C45/50 , C07C47/02
CPC分类号： C07C45/50
摘要： A process for hydroformylation of an olefin, which comprises reacting an olefin with carbon monoxide and hydrogen in the presence of a rhodium catalyst having a trivalent organic phosphorus compound as a ligand, wherein the hydroformylation reaction is conducted by two stage reactor systems i.e., a first stage reactor system comprising a reactor or reactors having a mixing characteristic of the liquid phase being substantially of complete mixing type, and a second stage reactor system being a reaction system of a catalyst solution circulating type and comprising a reactor or reactors having a mixing characteristic of piston flow type wherein when the mixing characteristic of the liquid phase is represented by a diffusion model, a non-dimensional number U (hereafter referred to as a "flow mixing parameter") defined by the formula (I):U.tbd.uL/2E (I)wherein u is an average flow velocity (cm/sec), L is the length (cm) of the reaction layer, and E is an average diffusion coefficient (cm.sup.2 /sec), is at least 0.4, a gaseous product or gas-liquid mixture discharged from the first stage reactor system, is separated into a stream containing the unreacted olefin and other stream, and a part or whole of the stream containing the unreacted olefin is supplied to the second stage reactor system.

3. 发明授权

US08299273B2 Biphenyltetracarboxylic acid dianhydride and process for producing the same, and polyimide formed from the same and process for producing the same 有权
标题翻译：联苯四羧酸二酐及其制造方法，以及由其制造的聚酰亚胺及其制造方法
公开(公告)号：US08299273B2
公开(公告)日：2012-10-30
申请号：US12855597
申请日：2010-08-12
申请人： Hiroshi Mikami , Makoto Nitta , Naoki Noguchi
发明人： Hiroshi Mikami , Makoto Nitta , Naoki Noguchi
IPC分类号： C07D307/89
CPC分类号： C08G73/1007 , C07D307/89 , C08G73/10
摘要： To provide a process for producing BPDA whereby high productivity is attained while high purity is maintained.A process for producing biphenyltetracarboxylic acid dianhydride, which comprises heating biphenyltetracarboxylic acid to produce biphenyltetracarboxylic acid dianhydride, characterized in that the heating is carried out at a pressure of from 1×102 Pa to 1.1×105 Pa to a maximum temperature in a range of from 210° C. to 250° C. in such a manner that the temperature rising rate is higher than 50° C./hr for a period of at least ¼ of the time for the temperature rise from 60° C. to 210° C., and the temperature is maintained to be from 150° C. to 250° C. for from 0.5 to 10 hours.
摘要翻译：提供一种生产BPDA的方法，从而在保持高纯度的同时获得高生产率。制备联苯四羧酸二酐的方法，其包括加热联苯四羧酸以制备联苯四羧酸二酐，其特征在于，在1×102Pa至1.1×10 5 Pa的压力下进行加热至最高温度范围为 210℃至250℃，温度升高速率高于50℃/小时，至少为温度从60℃升至210℃的时间的1/4 并且将温度保持在150℃至250℃下0.5至10小时。

4. 发明授权

US08252061B2 Femoral stem for artificial hip joint and artificial hip joint including the same 有权
标题翻译：股骨柄用于人造髋关节和人造髋关节包括相同
公开(公告)号：US08252061B2
公开(公告)日：2012-08-28
申请号：US12084265
申请日：2006-10-26
申请人： Hiroshi Mikami , Sumihiko Maeno
发明人： Hiroshi Mikami , Sumihiko Maeno
IPC分类号： A61F2/32
CPC分类号： A61F2/30739 , A61F2/32 , A61F2/34 , A61F2/36 , A61F2/367 , A61F2/3676 , A61F2002/30332 , A61F2002/30354 , A61F2002/30462 , A61F2002/30469 , A61F2002/30471 , A61F2002/30474 , A61F2002/30492 , A61F2002/30507 , A61F2002/30538 , A61F2002/30578 , A61F2002/30599 , A61F2002/30604 , A61F2002/30626 , A61F2002/30784 , A61F2002/3625 , A61F2002/3627 , A61F2002/3631 , A61F2002/365 , A61F2002/3674 , A61F2220/0025 , A61F2220/0033 , A61F2220/0075 , A61F2220/0091 , A61F2250/0006 , A61F2250/0063
摘要： A femoral stem including a stem member having a distal part of the stem member which is inserted in a medullary cavity of a femur and fixed therein and a proximal part of the stem member which has a neck for fixing an artificial head and is positioned at a proximal end of the distal part. The distal part and the proximal part are integrated or separable. Also, a plate fixing portion is detachably attached at a top of the proximal part, and a greater trochanter plate is provided for depressing the greater trochanter. The greater trochanter is fixed to the plate fixing portion at a certain angle or is fixed to the plate fixing portion so as to adjust an angle of the trochanter plate.
摘要翻译：股骨柄，其包括杆部件，所述杆部件具有杆部件的远端部分，其插入在股骨的髓腔中并固定在其中，并且所述杆部件的近端部分具有用于固定人造头部的颈部并且位于远端部分的近端。远侧部分和近端部分是一体的或可分离的。此外，板固定部分可拆卸地附接在近端部分的顶部，并且设置有用于压下大转子的大转子板。大转子以一定的角度固定在板固定部上，或固定在板固定部上，调整转子板的角度。

5. 发明授权

US07842824B2 Biphenyltetracarboxylic acid dianhydride and process for producing the same, and polyimide formed from the same and process for producing the same 有权
标题翻译：联苯四羧酸二酐及其制造方法，以及由其制造的聚酰亚胺及其制造方法
公开(公告)号：US07842824B2
公开(公告)日：2010-11-30
申请号：US11570812
申请日：2005-06-28
申请人： Hiroshi Mikami , Makoto Nitta , Naoki Noguchi
发明人： Hiroshi Mikami , Makoto Nitta , Naoki Noguchi
IPC分类号： C07D307/89 , C08G69/32
CPC分类号： C08G73/1007 , C07D307/89 , C08G73/10
摘要： To provide a process for producing BPDA whereby high productivity is attained while high purity is maintained.A process for producing biphenyltetracarboxylic acid dianhydride, which comprises heating biphenyltetracarboxylic acid to produce biphenyltetracarboxylic acid dianhydride, characterized in that the heating is carried out at a pressure of from 1×102 Pa to 1.1×105 Pa to a maximum temperature in a range of from 210° C. to 250° C. in such a manner that the temperature rising rate is higher than 50° C./hr for a period of at least ¼ of the time for the temperature rise from 60° C. to 210° C., and the temperature is maintained to be from 150° C. to 250° C. for from 0.5 to 10 hours.
摘要翻译：提供一种生产BPDA的方法，从而在保持高纯度的同时获得高生产率。制备联苯四羧酸二酐的方法，其包括加热联苯四羧酸以制备联苯四羧酸二酐，其特征在于，在1×102Pa至1.1×10 5 Pa的压力下进行加热至最高温度范围为 210℃至250℃，温度升高速率高于50℃/小时，至少为温度从60℃升至210℃的时间的1/4 并且将温度保持在150℃至250℃下0.5至10小时。

6. 发明授权

US07459570B2 High-purity biphenyltetracarboxylic dianhydride and process for producing the same 有权
公开(公告)号：US07459570B2
公开(公告)日：2008-12-02
申请号：US10753881
申请日：2004-01-09
申请人： Hiroshi Mikami , Takeshi Sano , Makoto Nitta
发明人： Hiroshi Mikami , Takeshi Sano , Makoto Nitta
IPC分类号： C07D307/00 , C07D493/04
CPC分类号： C07C63/331 , C07C51/42
摘要： There is provided biphenyltetracarboxylic dianhydride containing biphenyltetracarboxylic monoanhydride in an amount of not more than 0.4%. By using the biphenyltetracarboxylic dianhydride as a raw material, it is possible to produce polyimide or polyamic acid having an increased molecular weight.

7. 发明申请

US20060197503A1 Battery state monitoring device and its method, and dischargeable capacity detecting method 审中-公开
标题翻译：电池状态监测装置及其方法，以及放电容量检测方法
公开(公告)号：US20060197503A1
公开(公告)日：2006-09-07
申请号：US10550953
申请日：2004-03-23
申请人： Youichi Arai , Hiroshi Mikami
发明人： Youichi Arai , Hiroshi Mikami
IPC分类号： H02J7/00
CPC分类号： G01R31/389 , G01R31/3648 , G01R31/3842 , G01R31/392
摘要： A microcomputer 23 monitors a dischargeable capacity corresponding to a value by subtracting a capacity not to be discharged caused by an internal resistance of a battery from a charge capacity of the battery 13 based on outputs of a current sensor 15 and a voltage sensor 17.
摘要翻译：微型计算机23基于电流传感器15和电压传感器17的输出，从电池13的充电容量中减去由电池的内部电阻引起的不被放电的容量，从而监视对应于该值的放电容量。

8. 发明授权

US3981906A Process for preparing alkyl 4,4'-(ethylenedioxy)bis-benzoates 失效
标题翻译：制备烷基4,4（40-（亚乙二氧基）双苯甲酸酯的方法
公开(公告)号：US3981906A
公开(公告)日：1976-09-21
申请号：US575229
申请日：1975-05-07
申请人： Yohei Fukuoka , Toshio Kato , Norio Imai , Joji Nishikido , Masato Hamada , Hiroshi Mikami , Hirohumi Iwasaki , Toshihisa Koike
发明人： Yohei Fukuoka , Toshio Kato , Norio Imai , Joji Nishikido , Masato Hamada , Hiroshi Mikami , Hirohumi Iwasaki , Toshihisa Koike
IPC分类号： C07C69/92 , C07C69/76
CPC分类号： C07C69/76
摘要： Alkyl 4,4'-(ethylenedioxy)bis-benzoates having improved properties such as anti-oxidation and anti-coloration are prepared in high yield and selectivity by, at the first step, reacting an excess alkyl p-hydroxybenzoate with a recycling alkyl p-(2-chloro-ethoxy)benzoate with heating in the presence of an alkali carbonate and an inert organic solvent until almost said alkyl p-(2-chloroethoxy)benzoate is consumed to produce an alkyl 4,4'-(ethylenedioxy)bis-benzoate and at the second step adding ethylene dichloride to the reaction system and continuing the heating to produce an alkyl p-(2-chloroethoxy)benzoate which is recycled, and separating the alkyl 4,4'-(ethylenedioxy)bis-benzoate produced.
摘要翻译：通过在第一步骤中，通过使过量的对羟基苯甲酸烷基酯与再循环烷基p反应，以高产率和选择性制备具有改进性能如抗氧化和抗着色的4,4' - （亚乙二氧基）双苯甲酸烷基酯 - （2-氯 - 乙氧基）苯甲酸酯，在碱金属碳酸盐和惰性有机溶剂的存在下加热直到几乎所有的对 - （2-氯乙氧基）苯甲酸烷基酯被消耗以产生4,4' - （亚乙二氧基）双 - 苯甲酸酯，并且在第二步骤中将二氯乙烯加入到反应体系中并继续加热以产生被再循环的对 - （2-氯乙氧基）苯甲酸烷基酯，并分离生成的4,4' - （亚乙二氧基）双苯甲酸烷基酯。

9. 发明授权

US08641819B2 Cement composition and process for producing cement composition 有权
标题翻译：水泥组合物和水泥组合物生产工艺
公开(公告)号：US08641819B2
公开(公告)日：2014-02-04
申请号：US13701278
申请日：2011-05-24
申请人： Norihiko Sawabe , Hitoshi Tonokohchi , Takayasu Itoh , Hiroshi Mikami
发明人： Norihiko Sawabe , Hitoshi Tonokohchi , Takayasu Itoh , Hiroshi Mikami
IPC分类号： C04B14/00
CPC分类号： C04B22/066 , C04B2/02 , C04B7/147 , C04B7/246 , C04B18/06 , C04B18/067 , Y02P40/143 , Y02P40/145
摘要： A cement composition, and a process for producing a cement composition, wherein the cement composition has the Sr content of 0.065 mass % to 1.0 mass % and the MgO content of greater than 1.0 mass % to 3.0 mass %. The process for producing a cement composition comprises a step (A) of adjusting the basic raw material units of raw materials selected from the group consisting of limestone, silica stone, coal ash, clay, blast furnace slag, soil generated by construction work, sewage sludge, hydrocake and iron sources so that the cement composition has the Sr content of 0.065 mass % to 1.0 mass % and the MgO content of greater than 1.0 mass % to 3.0 mass %, blending the adjusted raw materials and burning to produce cement clinker, and a step (B) of mixing the cement clinker with gypsum and an admixture of limestone and blast furnace slag followed by grinding.
摘要翻译：水泥组合物和水泥组合物的制造方法，其中，所述水泥组合物的Sr含量为0.065质量％〜1.0质量％，MgO含量大于1.0质量％〜3.0质量％。水泥组合物的制造方法包括：调整从石灰石，硅石，煤灰，粘土，高炉矿渣，建筑工程产生的土壤，污水中选出的原料的基本原料单位的工序（A）污泥，水泥和铁源，使得水泥组合物的Sr含量为0.065质量％至1.0质量％，MgO含量大于1.0质量％至3.0质量％，将调整后的原料混合并燃烧以生产水泥熟料，以及将水泥熟料与石膏混合的石灰石和高炉矿渣的混合物的步骤（B），随后研磨。

10. 发明申请

US20130068140A1 CEMENT COMPOSITION AND PROCESS FOR PRODUCING CEMENT COMPOSITION 有权
标题翻译：水泥组合物和水泥组合物生产工艺
公开(公告)号：US20130068140A1
公开(公告)日：2013-03-21
申请号：US13701278
申请日：2011-05-24
申请人： Norihiko Sawabe , Hitoshi Tonokohchi , Takayasu Itoh , Hiroshi Mikami
发明人： Norihiko Sawabe , Hitoshi Tonokohchi , Takayasu Itoh , Hiroshi Mikami
IPC分类号： C04B22/06 , C04B2/02 , C04B18/06
CPC分类号： C04B22/066 , C04B2/02 , C04B7/147 , C04B7/246 , C04B18/06 , C04B18/067 , Y02P40/143 , Y02P40/145
摘要： A cement composition, and a process for producing a cement composition, wherein the cement composition has the Sr content of 0.065 mass % to 1.0 mass % and the MgO content of greater than 1.0 mass % to 3.0 mass %. The process for producing a cement composition comprises a step (A) of adjusting the basic raw material units of raw materials selected from the group consisting of limestone, silica stone, coal ash, clay, blast furnace slag, soil generated by construction work, sewage sludge, hydrocake and iron sources so that the cement composition has the Sr content of 0.065 mass % to 1.0 mass % and the MgO content of greater than 1.0 mass % to 3.0 mass %, blending the adjusted raw materials and burning to produce cement clinker, and a step (B) of mixing the cement clinker with gypsum and an admixture of limestone and blast furnace slag followed by grinding.
摘要翻译：水泥组合物和水泥组合物的制造方法，其中，所述水泥组合物的Sr含量为0.065质量％〜1.0质量％，MgO含量大于1.0质量％〜3.0质量％。水泥组合物的制造方法包括：调整从石灰石，硅石，煤灰，粘土，高炉矿渣，建筑工程产生的土壤，污水中选出的原料的基本原料单位的工序（A）污泥，水泥和铁源，使得水泥组合物的Sr含量为0.065质量％至1.0质量％，MgO含量大于1.0质量％至3.0质量％，将调整后的原料混合并燃烧以生产水泥熟料，以及将水泥熟料与石膏混合的石灰石和高炉矿渣的混合物的步骤（B），随后研磨。

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