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    • 1. 发明授权
    • Oxide etch process with high selectivity to nitride suitable for use on surfaces of uneven topography
    • 氧化物蚀刻工艺,对氮化物具有高选择性,适用于不均匀地形的表面
    • US06194325B1
    • 2001-02-27
    • US08552030
    • 1995-12-04
    • Chan Lon YangJeffrey MarksNicolas BrightKenneth S. CollinsDavid GroechelPeter Keswick
    • Chan Lon YangJeffrey MarksNicolas BrightKenneth S. CollinsDavid GroechelPeter Keswick
    • H01L21302
    • H01J37/32871H01J37/321H01L21/31116
    • A plasma etch process is described for the etching of oxide with a high selectivity to nitride, including nitride formed on uneven surfaces of a substrate, e.g., on sidewalls of steps on an integrated circuit structure. The addition of one or more hydrogen-containing gases, preferably one or more hydrofluorocarbon gases, to one or more fluorine-substituted hydrocarbon etch gases and a scavenger for fluorine, in a plasma etch process for etching oxide in preference to nitride, results in a high selectivity to nitride which is preserved regardless of the topography of the nitride portions of the substrate surface. In a preferred embodiment, one or more oxygen-bearing gases are also added to reduce the overall rate of polymer deposition on the chamber surfaces and on the surfaces to be etched, which can otherwise reduce the etch rate and cause excessive polymer deposition on the chamber surfaces. The fluorine scavenger is preferably an electrically grounded silicon electrode associated with the plasma.
    • 描述了用于蚀刻具有对氮化物的高选择性的氧化物的等离子体蚀刻工艺,包括在衬底的不平坦表面上形成的氮化物,例如在集成电路结构上的台阶侧壁上。 在优先于氮化物蚀刻氧化物的等离子体蚀刻工艺中,向一种或多种氟取代烃蚀刻气体和氟清除剂中加入一种或多种含氢气体,优选一种或多种氢氟烃气体,导致 对氮化物的高选择性,与衬底表面的氮化物部分的形貌无关地被保留。 在一个优选的实施方案中,还加入一种或多种含氧气体以降低腔室表面和待蚀刻表面上的聚合物沉积的总体速率,否则可降低蚀刻速率并导致室上过量的聚合物沉积 表面。 氟清除剂优选为与等离子体相关联的电接地硅电极。
    • 5. 发明授权
    • High pressure high non-reactive diluent gas content high plasma ion density plasma oxide etch process
    • 高压高反应性稀释气体含量高等离子体离子密度等离子体氧化物蚀刻工艺
    • US06238588B1
    • 2001-05-29
    • US08733554
    • 1996-10-21
    • Kenneth CollinsDavid GroechelRaymond HungMichael RiceGerald YinJian DingChunshi Cui
    • Kenneth CollinsDavid GroechelRaymond HungMichael RiceGerald YinJian DingChunshi Cui
    • B44C122
    • H01L21/02063C23C16/517H01F2029/143H01J37/32082H01J37/321H01J37/32146H01J37/32165H01J37/32458H01J37/32467H01J37/32522H01J37/32688H01J37/32706H01J37/32871H01J2237/3343H01J2237/3345H01J2237/3346H01L21/31116H01L21/6831
    • The invention is embodied in a method of processing a semiconductor workpiece in a plasma reactor chamber, including supplying a polymer and etchant precursor gas containing at least carbon and fluorine into the chamber at a first flow rate sufficient of itself to maintain a gas pressure in the chamber in a low pressure range below about 20 mT, supplying a relatively non-reactive gas into the chamber at second flow rate sufficient about one half or more of the total gas flow rate into the chamber, in combination with the first flow rate of the precursor gas, to maintain the gas pressure in the chamber in a high pressure range above 20 mT, and applying plasma source power into the chamber to form a high ion density plasma having an ion density in excess of 1010 ions per cubic centimeter. In one application of the invention, the workpiece includes an oxygen-containing overlayer to be etched by the process and a non-oxygen-containing underlayer to be protected from etching, the precursor gas dissociating in the plasma into fluorine-containing etchant species which etch the oxygen-containing layer and carbon-containing polymer species which accumulate on the non-oxygen-containing underlayer. Alternatively, the high pressure range may be defined as a pressure at which the skin depth of the inductive field exceeds {fraction (1/10)} of the gap between the inductive antenna and the workpiece.
    • 本发明体现在一种在等离子体反应器室中处理半导体工件的方法,包括以足以自动维持气体压力的第一流量将至少含有碳和氟的聚合物和蚀刻剂前体气体供应到室中 在低于大约20mT的低压范围内,将第二流量的第二流量的相对非反应性气体供应到室内的总气体流速的约一半以上,并与第一流量 将气体压力保持在高于20mT的高压范围内,并将等离子体源功率施加到腔室中以形成离子密度超过每立方厘米1010离子的高离子密度等离子体。 在本发明的一个应用中,工件包括通过该方法蚀刻的含氧覆层和不受蚀刻保护的非含氧底层,前体气体在等离子体中解离成含氟蚀刻剂,其蚀刻 含氧层和积聚在非含氧底层上的含碳聚合物种类。 或者,高压范围可以被定义为感应场的趋肤深度超过感应天线和工件之间的间隙的{分数(1/10)}的压力。