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    • 5. 发明授权
    • Fluoroalkyl-functional organopolysiloxane-containing compositions
    • 含氟烷基官能的含有机聚硅氧烷的组合物
    • US5863509A
    • 1999-01-26
    • US94501
    • 1998-06-10
    • Burkhard StandkeRoland EdelmannAlbert-Johannes FringsRalf LavenMichael HornPeter JenknerHelmut MackJaroslaw Monkiewicz
    • Burkhard StandkeRoland EdelmannAlbert-Johannes FringsRalf LavenMichael HornPeter JenknerHelmut MackJaroslaw Monkiewicz
    • C09K3/00C03C17/30C03C25/40C04B41/49C08G77/22C08G77/24C08G77/26C08L83/08C09D5/00C09D183/08C09K3/18C14C9/00C23C30/00D06M15/657B05D7/00
    • C14C9/00C03C17/30C03C25/40C04B41/4961C08G77/22C08G77/24C08G77/26C09D183/08C09K3/18C23C30/00D06M15/657C23C2222/20D06M2101/06D06M2200/11D06M2200/12Y10T428/31663
    • An aqueous alcoholic fluoroalkyl functional group containing organopolysiloxane-composition, comprising:organopolysiloxanes of formula I:RO�Si(A)(CH.sub.3).sub.z (OR).sub.1-z O!.sub.a �Si(B)(R.sup.2).sub.y (OR).sub.1-y O!.sub.b �Si(C)(CH.sub.3)O!.sub.c �Si(D)(OR)O!.sub.d R.multidot.(HX) (I)wherein A is an aminoalkyl radical derived from the compound of formula II:H.sub.2 N(CH.sub.2).sub.f (NH).sub.g (CH.sub.2).sub.h Si(OR).sub.3-z (CH.sub.3).sub.z (II)wherein 0.ltoreq.f.ltoreq.6, 9=0 if f=0 and g=1 if f>0, 0.ltoreq.h.ltoreq.6 and 0.ltoreq.z.ltoreq.1, and B is a fluoroalkyl radical derived from the compound of formula III:R.sup.1 --Y--(CH.sub.2).sub.2 Si(R.sup.2).sub.y (OR).sub.3-y (III)wherein R.sup.1 is a mono-, oligo- or perfluorinated alkyl group having 1-9 C atoms or a mono-, oligo- or perfluorinated aryl group, Y is a CH.sub.2, O or S group, R.sub.2 is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group and 0.ltoreq.y.ltoreq.1, and C is an alkyl radical derived from the compound of formula IV:R.sup.3 --Si(CH.sub.3)(OR).sub.2 (IV)and D is also an alkyl radical derived from the compound of formula V:R.sup.3 --Si(OR).sub.3 (V)wherein R.sup.3 in the preceding formulae is in each case identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms, R in the preceding formulae is in each case identical or different, and is a linear, branched or cyclic alkyl group having 1-8 C atoms or an aryl group, and HX is an acid, in which X is an inorganic or organic acid radical, and 0.ltoreq.y.ltoreq.1, 0.ltoreq.z.ltoreq.1, a>0, b>0, c.gtoreq.0, d.gtoreq.0, e.gtoreq.0 and (a+b+c+d).gtoreq.2.
    • 含有有机聚硅氧烷组合物的含水醇氟代烷基官能团包括:式I的有机聚硅氧烷:RO [Si(A)(CH3)z(OR)1-zO] a [Si(B)(R2)y(OR) yO] b [Si(C)(CH3)O] c [Si(D)(OR)O] dRx(HX)(I)其中A是衍生自式II化合物的氨基烷基:H 2 N(CH 2)f (NH)g(CH 2)h Si(OR)3-z(CH 3)z(II)其中0 0,则g = R =(Y) - (CH 2)2 Si(R 2)y(OR)3-y (III)其中R1是具有1-9个C原子的单,低聚或全氟烷基或单,低聚或全氟化的芳基,Y是CH 2,O或S基团,R 2是直链,支链 或具有1-8个碳原子或芳基且0≤y≤1的环状烷基,C是衍生自式IV化合物的烷基:R3-Si(CH3)(OR)2( IV),D也是衍生自式V化合物的烷基:R3-Si(OR)3(V)其中前述通式中的R 3在每种情况下均为 或具有1-8个C原子的直链,支链或环状烷基,前述式中的R各自相同或不同,为具有1-8个C原子的直链,支链或环状烷基 或芳基,并且HX是酸,其中X是无机或有机酸基团,并且0≤y≤1,0≤z≤1,a> 0,b> 0 ,c> / = 0,d> / = 0,e> / = 0和(a + b + c + d)> / = 2。