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1. 发明授权

US08609187B1 Method of producing an oxide dispersion strengthened coating and micro-channels 有权
标题翻译：生产氧化物分散强化涂层和微通道的方法
公开(公告)号：US08609187B1
公开(公告)日：2013-12-17
申请号：US13337589
申请日：2011-12-27
申请人： Bruce S. Kang , Minking K. Chyu , Mary Anne Alvin , Brian M. Gleeson
发明人： Bruce S. Kang , Minking K. Chyu , Mary Anne Alvin , Brian M. Gleeson
IPC分类号： B05D3/00 , B05D1/12 , B05D1/02 , B05D7/00
CPC分类号： B05D3/00 , B22F5/10 , B22F2998/10 , B22F2999/00 , C22C1/1084 , C22C19/058 , C22C32/0026 , C22F1/10 , C23C24/04 , Y10T428/2982 , B22F1/02 , B22F2009/043
摘要： The disclosure provides a method for the production of composite particles utilizing a mechano chemical bonding process following by high energy ball milling on a powder mixture comprised of coating particles, first host particles, and second host particles. The composite particles formed have a grain size of less than one micron with grains generally characterized by a uniformly dispersed coating material and a mix of first material and second material intermetallics. The method disclosed is particularly useful for the fabrication of oxide dispersion strengthened coatings, for example using a powder mixture comprised of Y2O3, Cr, Ni, and Al. This particular powder mixture may be subjected to the MCB process for a period generally less than one hour following by high energy ball milling for a period as short as 2 hours. After application by cold spraying, the composite particles may be heat treated to generate an oxide-dispersion strengthened coating.
摘要翻译：本公开提供了一种利用机械化学键合方法生产复合颗粒的方法，随后通过高能球磨在由涂层颗粒，第一主体颗粒和第二主体颗粒组成的粉末混合物上。形成的复合颗粒具有小于1微米的晶粒尺寸，其晶粒通常以均匀分散的涂层材料和第一材料和第二材料金属间化合物的混合物为特征。所公开的方法对于制备氧化物分散强化涂层特别有用，例如使用由Y 2 O 3，Cr，Ni和Al组成的粉末混合物。这种特定的粉末混合物可以通过高能球磨几小时，经历一般小于1小时的时间段。在通过冷喷涂施用后，可以对复合颗粒进行热处理以产生氧化物分散强化涂层。

2. 发明授权

US08658311B2 High temperature rechargeable battery for greenhouse gas decomposition and oxygen generation 失效
标题翻译：用于温室气体分解和氧气生成的高温可充电电池
公开(公告)号：US08658311B2
公开(公告)日：2014-02-25
申请号：US13708541
申请日：2012-12-07
申请人： Bruce S. Kang , Huang Guo
发明人： Bruce S. Kang , Huang Guo
IPC分类号： H01M10/0525
CPC分类号： H01M8/06 , C25B1/02 , C25B9/00 , H01M4/38 , H01M4/48 , H01M4/9025 , H01M12/08 , Y02E60/128 , Y02P20/133
摘要： Instead of CCS technique, a possible approach to mitigate the greenhouse gas (GHG) emission is to decompose it into useful products. This invention shows a high temperature rechargeable battery system for decomposition of oxygen-containing gases (e.g CO2/H2O, NOx, SOx, in particular GHG), oxygen generation, and energy storage by using ODF/La2NiO4-based materials in Li/Ti/Mg—CO2 battery architecture. Different from ionic Lithium conducting electrolyte, the invention has a higher ionic oxygen conducting electrolyte to work efficiently at higher temperature without sacrificing safety. During battery discharge, GHG can be decomposed into syngas (CO+H2) or solid carbon, while renewable energy (e.g. solar/wind power) could be used to charge the battery and generate oxygen. The energy consumption for GHG decomposition is self-sustainable and the byproducts (i.e. carbon/syngas and oxygen) have good market values. The adoption of cost effective materials other than Lithium is significant for scaled-up applications and represents an entirely new approach.
摘要翻译：而不是CCS技术，减轻温室气体（GHG）排放的可能方法是将其分解为有用的产品。本发明示出了通过在Li / Ti / Al 2 O 3中使用基于ODF / La2NiO4的材料来分解含氧气体（例如CO 2 / H 2 O，NO x，SO x，特别是GHG），产生氧气和储能的高温可再充电电池系统。 Mg-CO2电池架构。与离子导电电解质不同，本发明具有较高的离子导电电解质，可在较高温度下有效地工作，而不会牺牲安全性。在电池放电期间，GHG可以分解为合成气（CO + H2）或固体碳，而可再生能源（例如太阳能/风力发电）可用于对电池充电并产生氧气。 GHG分解的能源消耗是可持续的，副产物（即碳/合成气和氧气）具有良好的市场价值。采用锂以外的成本效益材料对于扩大应用是重要的，并且是一种全新的方法。

3. 发明申请

US20130122381A1 HIGH TEMPERATURE RECHARGEABLE BATTERY FOR GREENHOUSE GAS DECOMPOSITION AND OXYGEN GENERATION 失效
公开(公告)号：US20130122381A1
公开(公告)日：2013-05-16
申请号：US13708541
申请日：2012-12-07
申请人： Bruce S. Kang , Huang Guo
发明人： Bruce S. Kang , Huang Guo
IPC分类号： H01M8/06 , C25B9/00 , C25B1/02
CPC分类号： H01M8/06 , C25B1/02 , C25B9/00 , H01M4/38 , H01M4/48 , H01M4/9025 , H01M12/08 , Y02E60/128 , Y02P20/133
摘要： This invention shows a high temperature rechargeable battery system for energy storage, oxygen generation, and decomposition of oxygen-containing gases (e.g. CO2/H2O, NOR, SOx, in particular greenhouse gas (GHG)) by using ODF/La2NiO4-based materials in Li/Ti/Mg-CO2 battery architecture. Different from ionic Lithium conducting electrolyte, the invention has a higher ionic oxygen conducting electrolyte to work efficiently at elevated temperature without sacrificing safety. During battery discharge, GHG can be decomposed into syngas (CO+H2) or solid carbon, while renewable energy (e.g. solar or wind power) can be used to charge the battery and generate oxygen. The energy consumption for GHG decomposition is self-sustainable and the byproducts (i.e. carbon/syngas and oxygen) have good market values. The adoption of cost effective materials other than Lithium is significant for scaled-up applications and represents an entirely new approach.With carbon capture and sequestration becoming a key element in worldwide efforts to control/minimize CO2 emission, it can be anticipated that large amount of CO2 will become available for use as feedstock for innovative conversions into synthetic fuels. This invention shows a high temperature rechargeable battery system for decomposition of oxygen containing gases (in particular greenhouse gas (GHG)), oxygen generation, and energy storage by using ODF/La2NiO4-based materials in a rechargeable Li/Ti/Mg-CO2 battery architecture. Different from traditional Lithium ion conducting electrolyte, the invention has a higher ionic oxygen conducting electrolyte, which can work efficiently at higher temperature without sacrificing safety. During battery discharge, GHG such as CO2/H2O, NOx and SOx can be decomposed into syngas (CO+H2) or solid carbon. Whereas, solar, wind or other renewable energy can be used to charge the battery and generate oxygen. The energy consumption for GHG decomposition is self-sustainable with the integrated system and the byproducts (i.e. solid carbon, syngas (CO+H2), O2) have good market values. The adoption of cost effective materials other than Lithium is significant for scaled-up applications and represents an entirely new approach.

4. 发明申请

US20120228150A1 CO2 DECOMPOSITION VIA OXYGEN DEFICIENT FERRITE ELECTRODES USING SOLID OXIDE ELECTROLYSER CELL 审中-公开
标题翻译：通过使用固体氧化物电解质电池的氧气缺乏的铁氧体电极的二氧化碳分解
公开(公告)号：US20120228150A1
公开(公告)日：2012-09-13
申请号：US13043335
申请日：2011-03-08
申请人： Bruce S. Kang , Huang Guo , Gulfam Iqbal
发明人： Bruce S. Kang , Huang Guo , Gulfam Iqbal
IPC分类号： C25B1/00
CPC分类号： C25B9/10 , C25B1/04 , C25B11/0452 , Y02E60/366
摘要： Oxygen Deficient Ferrites (ODF) electrodes integrated with Yttria Stabilized Zirconia (YSZ) electrolyte, electrochemically decompose carbon dioxide (CO2) into carbon (C)/carbon monoxide (CO) and oxygen (O2) in a continuous process. The ODF electrodes can be kept active by applying a small potential bias across the electrodes. CO2 and water (H2O) can also be electrolyzed simultaneously to produce syngas (H2+CO) and O2 continuously that can be fed back to the oxy-fuel combustion. With this approach, CO2 can be transformed into a valuable fuel source allowing CO2 neutral use of the hydrocarbon fuels.
摘要翻译：与氧化钇稳定氧化锆（YSZ）电解质结合的氧缺陷铁氧体（ODF）电极在连续过程中电化学分解为碳（C）/一氧化碳（CO）和氧（O 2）。通过在电极上施加小的电位偏置，ODF电极可以保持有效。 CO2和水（H 2 O）也可以同时电解，以产生可以反馈到氧 - 燃料燃烧的合成气（H2 + CO）和O2。通过这种方法，可以将二氧化碳转化为有价值的燃料源，从而使二氧化碳中和使用烃燃料。

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