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1. 发明授权

US5359134A Process for preparing phenylterephthalic acid 失效
标题翻译：制备苯基对苯二甲酸的方法
公开(公告)号：US5359134A
公开(公告)日：1994-10-25
申请号：US930887
申请日：1992-08-14
申请人： Bruce L. Gustafson , Charles E. Sumner, Jr. , Michael Bellas , Gether Irick, Jr. , Dewey W. Fuller, Jr. , Ernest W. Arnold , Eric J. Fugate
发明人： Bruce L. Gustafson , Charles E. Sumner, Jr. , Michael Bellas , Gether Irick, Jr. , Dewey W. Fuller, Jr. , Ernest W. Arnold , Eric J. Fugate
IPC分类号： B01J27/128 , B01J29/08 , B01J31/04 , C07C51/265 , C07C51/43 , C07C63/26
CPC分类号： C07C51/265
摘要： Provided is a facile three step process for preparing 2-phenylterephthalic acid starting with p-xylene, followed by alkylation, dehydrogenation, and oxidation of the methyl groups corresponding to the origional p-xylene. The product, 2-phenylterephthalic acid, is useful as an intermediate in the synthesis of polyesters comprised of residues of 2-phenylterephthalic acid.
摘要翻译：提供了一种从对二甲苯开始制备2-苯基对苯二甲酸，然后进行对应于原始对二甲苯的甲基的烷基化，脱氢和氧化的简便的三步法。产物2-苯基对苯二甲酸可用作合成由2-苯基对苯二甲酸残基组成的聚酯的中间体。

2. 发明授权

US5334754A Process for preparing 2,5-diphenylterephthalic acid by oxidation 失效
标题翻译：通过氧化制备2,5-二苯基对苯二甲酸的方法
公开(公告)号：US5334754A
公开(公告)日：1994-08-02
申请号：US930890
申请日：1992-08-14
申请人： Charles E. Sumner, Jr. , Bruce L. Gustafson , Ernest W. Arnold, III , Eric J. Fugate , Dewey W. Fuller, Jr.
发明人： Charles E. Sumner, Jr. , Bruce L. Gustafson , Ernest W. Arnold, III , Eric J. Fugate , Dewey W. Fuller, Jr.
IPC分类号： B01J27/128 , B01J29/08 , B01J31/04 , C07C51/265 , C07C63/26 , C07C51/215 , C07C67/39
CPC分类号： C07C51/265 , Y02P20/582
摘要： Provided is a process for preparing 2,5-diphenylterephthalic acid, which is useful in preparing certain polyesters, especially liquid-crystalline polyesters. In this process, p-xylene is di-alkylated with cyclohexene to provide 2,5-dicyclo-hexyl-p-xylene, which is in turn dehydrogenated to provide 2,5-diphenylxylene. 2,5-Diphenylxylene is then oxidized to provide 2,5-diphenylterephthalic acid by utilization of a cobaltous/manganous/bromide oxidation system.
摘要翻译：提供了一种制备2,5-二苯基对苯二甲酸的方法，其可用于制备某些聚酯，特别是液晶聚酯。在此过程中，对二甲苯与环己烯二烷基化，得到2,5-二环己基对二甲苯，然后脱氢，得到2,5-二苯基二甲苯。然后将2,5-二苯基二甲苯氧化，通过利用钴 - 锌/二氧化锰/溴化物氧化体系提供2,5-二苯基对苯二甲酸。

3. 发明授权

US4804777A Process for the preparation of aryloxyacetic acid 失效
标题翻译：制备芳氧基乙酸的方法
公开(公告)号：US4804777A
公开(公告)日：1989-02-14
申请号：US106302
申请日：1987-10-09
申请人： Charles E. Sumner, Jr. , Eric J. Fugate
发明人： Charles E. Sumner, Jr. , Eric J. Fugate
IPC分类号： B01J23/50 , B01J23/68 , C07B61/00 , C07C51/235 , C07C51/255 , C07C59/70 , C07C51/16
CPC分类号： C07C51/255 , C07C51/235
摘要： Process for the preparation of an aryloxyacetic acid by oxidation of aryloxyethanol of the formula: ##STR1## wherein m represents 1 or 2,n represents the numeral which results from the difference between 6 and m and R either individually or independently of one another represents hydrogen, alkyl, cycloalky, aryl, aralkyl, alkoxy, cycloalkoxy, aryloxy, halogen, alkylcarbonyl, arylcarbonyl, carboxyl or nitro, or represents a benzene ring fused to the phenyl ring, in an aqueous alkaline reaction medium at a temperature in the range of 0.degree. C. to the boiling point of the reaction medium in the presence of a catalytic amount of a catalyst comprised of palladium, silver and optionally antimony, and carbon to form the corresponding alkali metal ester and contacting the alkali metal with a mineral acid.
摘要翻译：芳氧基乙酸通过氧化芳氧基乙醇制备下式的方法：其中m表示1或2，n表示由6和m之间的差异产生的数字，R和R独立地或彼此独立地表示氢烷基，环烷基，芳基，芳烷基，烷氧基，环烷氧基，芳氧基，卤素，烷基羰基，芳基羰基，羧基或硝基，或表示稠合于苯环的苯环，在碱性水溶液中，在催化量的由钯，银和任选的锑组成的催化剂存在下，在反应介质的沸点下进行反应，形成相应的碱金属酯并使碱金属与无机酸接触。

4. 发明授权

US4791224A Process for preparation of an oxyacetic acid/hydroxyethyl ether compound 失效
标题翻译：羟乙酸/羟乙基醚化合物的制备方法
公开(公告)号：US4791224A
公开(公告)日：1988-12-13
申请号：US178702
申请日：1988-04-07
申请人： Charles E. Sumner, Jr. , Eric J. Fugate
发明人： Charles E. Sumner, Jr. , Eric J. Fugate
IPC分类号： B01J23/644 , C07B61/00 , C07C51/235 , C07C51/255 , C07C59/70 , C07C51/16
CPC分类号： C07C51/235 , C07C51/255
摘要： Process for the preparation of an aryloxyacetic acid/hydroxyethyl ether by oxidation of aryloxyethanol of the formula: ##STR1## wherein R either individually or independently of one another represents hydrogen, alkyl, cycloalkyl, aryl, aralkyl, alkoxy, cycloalkoxy, aryloxy, halogen, alkylcarbonyl, arylcarbonyl, carboxyl or nitro, or represents a benzene ring fused to the phenyl ring, in an aqueous alkaline reaction medium at a temperature in the range of 0.degree. C. to the boiling point of the reaction medium in the presence of a catalytic amount of a catalyst comprised of palladium, bismuth, and carbon in the presence of a phenol corresponding to the structure: ##STR2## wherein R is as described above and p is 0, 1 or 2, to form the corresponding alkali metal ester/hydroxyethyl ether after catalyst removal the alkali metal ester is contacted with a mineral acid.
摘要翻译：通过芳氧基乙醇氧化制备芳氧基乙酸/羟乙基醚的方法，其结构式如下：其中R各自独立地或独立地表示氢，烷基，环烷基，芳基，芳烷基，烷氧基，环烷氧基，芳氧基，卤素，烷基羰基，芳基羰基，羧基或硝基，或表示与苯环稠合的苯环，在碱性水溶液中，在催化剂存在下，在0℃至反应介质的沸点温度范围内在由对应于以下结构的苯酚存在下由钯，铋和碳组成的催化剂的量：其中R如上所述，p为0,1或2，形成相应的碱金属酯/羟乙基催化剂除去后，乙醚与无机酸接触。

5. 发明授权

US4935559A Olefination of iodoaromatic compounds 失效
标题翻译：碘芳香化合物的烯化
公开(公告)号：US4935559A
公开(公告)日：1990-06-19
申请号：US303347
申请日：1989-01-30
申请人： Mark Rule , Eric J. Fugate
发明人： Mark Rule , Eric J. Fugate
IPC分类号： C07C2/86 , C07C17/16
CPC分类号： C07C2/861 , C07C17/16 , C07C2531/04
摘要： A method of preparing an aryl alkene compound comprising reacting an iodoaromatic compound an alkene and an alkanol in the presence of a palladium catalyst and the absence of a Bronsted base.
摘要翻译：一种制备芳基烯烃化合物的方法，包括在钯催化剂存在下和不存在Bronsted碱的情况下使碘芳香族化合物与烯烃和链烷醇反应。

6. 发明授权

US4925998A Process for dehydrohalogenating aromatic halides 失效
标题翻译：脱卤化氢芳香族卤化物的方法
公开(公告)号：US4925998A
公开(公告)日：1990-05-15
申请号：US290678
申请日：1988-12-27
申请人： Thomas J. Abraham, Jr. , Eric J. Fugate , Guy R. Steinmetz , Martin D. Dolfi
发明人： Thomas J. Abraham, Jr. , Eric J. Fugate , Guy R. Steinmetz , Martin D. Dolfi
IPC分类号： C07C1/26 , C07C17/23
CPC分类号： C07C17/23 , C07C1/26 , C07C2521/18 , C07C2523/44
摘要： Disclosed is a process for dehydrohalogenating an aromatic bromide or iodide by contacting the aromatic halide with hydrogen at elevated pressure in the presence of an alkyl halide-forming compound and a Group VIII metal catalyst. The presence of the alkyl halide-forming compound, such as an alkanol, diol, triol or derivative thereof, facilitates the dehydrohalogenation reaction and permits the recovery of the halogen ad alkyl halides from which the bromide and iodide values can be economically recovered.

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