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1. 发明授权

US06245727B1 Discontinuous process for conducting a heterogeneously catalyzed reaction and installation for heterogeneously catalyzed manufacture of products 失效
标题翻译：用于进行非均相催化反应和非均匀催化产物制造的不连续方法
公开(公告)号：US06245727B1
公开(公告)日：2001-06-12
申请号：US08259362
申请日：1994-06-14
申请人： Bernhard Gutsche , Lutz Jeromin , Eberhard Peukert , Levent Yueksel , Kurt Adrian , Heinz Bollweg
发明人： Bernhard Gutsche , Lutz Jeromin , Eberhard Peukert , Levent Yueksel , Kurt Adrian , Heinz Bollweg
IPC分类号： C07C4330
CPC分类号： B01J19/1881 , B01D3/009 , B01J8/025 , B01J8/0285 , B01J2208/00256 , B01J2208/00283 , B01J2208/00557 , B01J2208/00663 , B01J2219/00006 , C07C67/08 , Y02P20/127 , Y02P20/582 , C07C69/26
摘要： The invention relates firstly to a discontinuous process for conducting a heterogeneously catalyzed reaction taking place at elevated temperature, in which heat-sensitive products are formed, a heat transfer unit (4) different from the reactor (1) being used for heating and a fixed-bed catalyst (3) being used as the catalyst and the reaction mixture being continuously circulated in succession through the catalyst (3) and then through the heat transfer unit (4). The problem to be solved in this process is to avoid losses of catalyst and product and to shorten the batch time and, optionally, the reaction time in accordance with German patent applications P 38 13 612.0 and P 38 26 320.3. The invention also relates to a plant for the discontinuous heterogeneously catalyzed production of heat-sensitive products at elevated temperature comprising a reactor (1), characterized by a heat transfer unit (4) arranged outside and connected to the reactor (1), a catalyst container (3) containing a fixed-bed catalyst preceding the heat transfer unit and a pump (2) for continuously circulating the reaction mixture in succession through the catalyst (3) and then through the heat transfer unit (4).
摘要翻译：本发明首先涉及一种用于进行非均相催化反应的不连续过程，该反应发生在形成热敏产物的高温下，不同于用于加热的反应器（1）的传热单元（4）和固定用作催化剂的催化剂（3），反应混合物连续循环通过催化剂（3），然后通过传热单元（4）循环。在该过程中要解决的问题是避免催化剂和产物的损失，并缩短批料时间，以及根据德国专利申请P 38 13 612.0和P 38 26 3203的任选的反应时间。本发明还涉及用于在升高的温度下不连续地非均相催化生产热敏产物的设备，包括反应器（1），其特征在于布置在反应器（1）外部并连接到反应器（1）的传热单元（4），催化剂容器（3）在传热单元之前的固定床催化剂和用于使反应混合物连续循环通过催化剂（3）然后通过传热单元（4）的泵（2）。

2. 发明授权

US4976892A Process for the continuous transesterification of fatty acid lower alkyl esters 失效
标题翻译：脂肪酸低级烷基酯连续酯交换的方法
公开(公告)号：US4976892A
公开(公告)日：1990-12-11
申请号：US323517
申请日：1989-03-14
申请人： Lutz Jeromin , Eberhard Peukert , Bernhard Gutsche , Gerhard Wollmann , Bernard Schleper
发明人： Lutz Jeromin , Eberhard Peukert , Bernhard Gutsche , Gerhard Wollmann , Bernard Schleper
IPC分类号： C07C67/02 , B01J23/04 , B01J31/02 , C07B61/00 , C07C69/30
CPC分类号： C11C3/02
摘要： A process for the continuous transesterification of C.sub.6 -C.sub.22 fatty acid lower alkyl esters, particularly methyl esters, with polyhydric C.sub.2 -C.sub.5 alcohols, particularly glycerol, in a reaction column comprising a rectifying and reaction section, alkaline catalysts and polyhydric alcohol are introduced into the upper part of the reaction column and boiling fatty acid methyl ester is introduced into the middle part of the reaction column. The product collected in the sump of the column is removed, heated and returned to the lower part of the reaction column. Product is removed from the sump. Lower alkanols passing from the reaction column section to the rectifying section are rectified. The reaction column is operated in boiling equilibrium in its lower part and predominantly in an absorption/desorption equilibrium in its upper part.
摘要翻译：在包含精馏和反应部分的反应塔，碱性催化剂和多元醇中，将C6-C22脂肪酸低级烷基酯，特别是甲基酯与多元醇C 2 -C 5醇，特别是甘油连续酯交换的方法被引入将反应塔上部和沸腾脂肪酸甲酯引入反应塔的中间部分。将收集在柱的集水槽中的产物除去，加热并返回到反应塔的下部。产品从集水槽中取出。将从反应塔部分流出的低级链烷醇精馏。反应塔在其下部以沸腾平衡运行，主要在上部的吸收/解吸平衡。

3. 发明授权

US5654453A Process for the production of .alpha.-branched aliphatic monocarboxylic acids 失效
标题翻译：制备α-支链脂肪族单羧酸的方法
公开(公告)号：US5654453A
公开(公告)日：1997-08-05
申请号：US500905
申请日：1995-08-29
申请人： Gerhard Mueller , Bernhard Gutsche , Karl-Heinz Schmid , Frank Bongardt , Lutz Jeromin , Eberhard Peukert , Hermann Frankenbach
发明人： Gerhard Mueller , Bernhard Gutsche , Karl-Heinz Schmid , Frank Bongardt , Lutz Jeromin , Eberhard Peukert , Hermann Frankenbach
IPC分类号： C07C51/295 , C07C51/41 , C07C53/126 , C07C51/16
CPC分类号： C07C51/295 , C07C51/41 , Y02P20/582
摘要： A process is disclosed for preparing .alpha.-branched aliphatic monocarboxylic acids with 12 to 48 carbon atoms. In a first step of the process (a), .alpha.-branched aliphatic monohydric alcohols (Guerbet alcohols) are converted in the presence of caustic alkali into the alkali salts of the corresponding .alpha.-branched aliphatic monocarboxylic acids. In a second step of the process (b), the .alpha.-branched aliphatic monocarboxylic acids are released from the alkali salts by soap splitting in the presence of an inert diluting agent.
摘要翻译： PCT No.PCT / EP94 / 00155 Sec。 371日期1995年8月29日 102（e）日期1995年8月29日PCT 1994年1月21日PCT PCT。公开号WO94 / 17026 日期1994年8月4日公开了制备具有12至48个碳原子的α-支链脂肪族单羧酸的方法。在方法（a）的第一步中，将α-支链脂族一元醇（格伯特醇）在苛性碱存在下转化成相应的α-支链脂肪族单羧酸的碱金属盐。在方法（b）的第二步中，通过在惰性稀释剂存在下，通过皂裂解将α-支链脂肪族单羧酸从碱金属盐中释放出来。

4. 发明授权

US4647678A Process for the epoxidation of olefinically unsaturated hydrocarbon compounds with peracetic acid 失效
标题翻译：用过乙酸环氧化烯属不饱和烃化合物的方法
公开(公告)号：US4647678A
公开(公告)日：1987-03-03
申请号：US813444
申请日：1985-12-26
申请人： Klemens Eckwert , Lutz Jeromin , Alfred Meffert , Eberhard Peukert , Bernhard Gutsche
发明人： Klemens Eckwert , Lutz Jeromin , Alfred Meffert , Eberhard Peukert , Bernhard Gutsche
IPC分类号： C07D301/16 , C07D301/14 , C07D303/04 , C07D303/14 , C07D303/42
CPC分类号： C07D303/42 , C07D301/14 , C07D303/04 , C07D303/14 , B01J2219/0004
摘要： The epoxidation of terminally and/or internally olefinically unsaturated hydrocarbon compounds which are liquid at 50.degree. to 100.degree. C. and at atmospheric pressure (oil phase), in which the oil phase is treated with an acid phase containing acetic acid, hydrogen peroxide and peracetic acid in aqueous solution, after which the aqueous acid phase is separated from the oil phase, the peracetic acid in the aqueous acid phase is regenerated and the regenerated aqueous acid phase is returned to the epoxidation reactor. Epoxidation is carried out using an aqueous acid phase containing at most about 10% by weight of peracetic acid, and the peracetic acid content in the aqueous acid phase is reduced by at most about 50%, based on the peracetic acid content of the aqueous acid phase used, after a single passage through the epoxidation stage. After separation from the oil phase, the aqueous acid phase preferably is cooled before regeneration.
摘要翻译：末端和/或内部烯属不饱和烃化合物的环氧化，其在50℃至100℃和大气压（油相）下为液体，其中油相用含有乙酸，过氧化氢和过乙酸在水溶液中，然后从油相中分离含水酸相，酸性水相中的过乙酸再生，再生的含水酸相返回到环氧化反应器。使用含有至多约10重量％过乙酸的含水酸相进行环氧化，基于酸水溶液的过乙酸含量，酸性水相中的过乙酸含量减少至多约50％在单次通过环氧化阶段后使用。从油相分离后，酸性水相优选在再生前冷却。

5. 发明授权

US5189207A Process for the production of solid or paste-form products 失效
标题翻译：生产固体或塑料制品的方法
公开(公告)号：US5189207A
公开(公告)日：1993-02-23
申请号：US282073
申请日：1988-12-07
申请人： Gerhard Blasey , Christoph Breucker , Bernhard Gutsche , Lutz Jeromin , Guenter Panthel , Eberhard Peukert , Wolfgang Schmidt
发明人： Gerhard Blasey , Christoph Breucker , Bernhard Gutsche , Lutz Jeromin , Guenter Panthel , Eberhard Peukert , Wolfgang Schmidt
IPC分类号： B01J19/26 , C07B61/00 , C07C27/00 , C07C27/02 , C07C51/09 , C07C51/41 , C07C53/126 , C07C67/00 , C07C303/32 , C07C309/08 , C07C309/17 , C07C309/30 , C11D11/00
CPC分类号： B01J19/26 , C11D11/0082 , C11D11/0094 , C11D11/04 , B01J2219/00121 , B01J2219/00159 , B01J2219/00164 , B01J2219/00184
摘要： A process for the production of solid or paste-form products by fast reactions is carried out stoichiometrically wherein a gaseous medium is introduced into each of the reactants to be reacted with one another, the reactant streams formed are combined and are subsequently forced through a spray unit in a weight ratio of gaseous medium to product stream of from 0.04 to 0.3 (kg/kg) and at a rate of 0.1 to 15 m/second, as calculated from the gas-free reactant streams and based on the free cross-section of the spray unit. The products obtained are free from readily volatile constituents.
摘要翻译：通过快速反应生产固体或糊状产品的方法以化学计量方式进行，其中将气体介质引入每个反应物中以使其彼此反应，将形成的反应物流合并并随后强制通过喷雾单位为气体介质与产物流的重量比为0.04至0.3（kg / kg），速率为0.1至15m / s，由无气体反应物流计算，并且基于自由横截面的喷雾装置。所得产品不含挥发性成分。

6. 发明授权

US5008046A Process for the continuous esterification of fatty acids 失效
标题翻译：脂肪酸连续酯化的方法
公开(公告)号：US5008046A
公开(公告)日：1991-04-16
申请号：US326592
申请日：1989-03-21
申请人： Norbert Bremus , Bernhard Gutsche , Lutz Jeromin , Eberhard Peukert , Bernard Schleper
发明人： Norbert Bremus , Bernhard Gutsche , Lutz Jeromin , Eberhard Peukert , Bernard Schleper
IPC分类号： C07B61/00 , B01J27/02 , B01J31/02 , C07C67/08 , C07C69/02 , C07C69/24 , C07C69/28 , C11C3/00
CPC分类号： C07C67/08
摘要： The invention is a process for the continuous liquid-phase esterification of C.sub.2 -C.sub.24 fatty acids with alkanols in countercurrent contact and reaction in a reaction column, the catalysts and fatty acids are introduced at the top plate and the alkanols below the lowest plate, at a head pressure of the reaction column of 200 to 900 hPa. The process reduces dehydration of the alkanols.
摘要翻译：本发明是C2-C24脂肪酸与链烷醇在反应塔中逆流接触和反应中连续液相酯化的方法，将催化剂和脂肪酸引入顶板和最低板下方的链烷醇反应塔的压头压力为200〜900hPa。该方法减少了链烷醇的脱水。

7. 发明授权

US4698186A Process for the pre-esterification of free fatty acids in fats and oils 失效
标题翻译：脂肪和油中游离脂肪酸预酯化的方法
公开(公告)号：US4698186A
公开(公告)日：1987-10-06
申请号：US821109
申请日：1986-01-21
申请人： Lutz Jeromin , Eberhard Peukert , Gerhard Wollmann
发明人： Lutz Jeromin , Eberhard Peukert , Gerhard Wollmann
IPC分类号： C11B3/02 , C11C3/04 , C11C3/10
CPC分类号： C07C67/03 , C07C67/08 , C11B3/02
摘要： A process for reducing the free fatty acid content of fats and oils by esterifying the free fatty acids with a lower monoalcohol in the presence of an acidic cation exchange resin as a solid esterification catalyst.
摘要翻译：一种通过在酸性阳离子交换树脂作为固体酯化催化剂存在下，通过用较低一元醇酯化游离脂肪酸来降低脂肪和油的游离脂肪酸含量的方法。

8. 发明授权

US4584390A Continuous process for the catalytic epoxidation of olefinic double bonds with hydrogen peroxide and formic acid 失效
标题翻译：用过氧化氢和甲酸催化环氧化烯属双键的连续方法
公开(公告)号：US4584390A
公开(公告)日：1986-04-22
申请号：US615446
申请日：1984-05-30
申请人： Gerhard Dieckelmann , Klemens Eckwert , Lutz Jeromin , Eberhard Peukert , Udo Steinberner
发明人： Gerhard Dieckelmann , Klemens Eckwert , Lutz Jeromin , Eberhard Peukert , Udo Steinberner
IPC分类号： C07D301/14 , C07D301/16 , C07D303/00 , C07D303/04 , C07D303/14 , C07D303/42
CPC分类号： C07D303/42 , C07D301/14 , C07D301/16 , C07D303/04 , C07D303/14
摘要： In a multistage process for the continuous epoxidation of double bonds of terminal and non-terminal olefins containing more than 12 carbon atoms, unsaturated higher fatty acids and their lower alkanol and lower alkanediol esters and also unsaturated fatty alcohols containing from 8 to 18, preferably 18, carbon atoms and triglycerides of higher fatty acids including unsaturated fatty acids, preferably soyabean oil, using performic acid formed in situ from hydrogen peroxide and formic acid, the reactants, olefin and hydrogen peroxide/formic acid, are passed at ambient pressure in cross-counter flow through an at least three-stage reaction cascade. The olefinic phase is introduced into the first reaction stage, the hydrogen peroxide and the formic acid are introduced in separate streams into the penultimate reaction stage and the olefin phase and the hydrogen peroxide/formic acid phase (acid water phase) are separated from one another in a phase separator after each reaction stage. The olefinic phase passes successively through reaction stages I to n while the acid water, after reaction stage (n-1), passes through reaction stages (n-2) to 2 in counter flow to the olefin phase and then through stages n and 1, the reaction temperature being maintained in the range from 50.degree. to 80.degree. C. in the reactors and in the range from 15.degree. to 60.degree. C. in the phase separators.
摘要翻译：在用于连续环氧化含有12个以上碳原子的末端和非末端烯烃的双键的多级方法中，不饱和高级脂肪酸及其低级链烷醇和低级链烷二醇酯以及含有8-18个不饱和脂肪醇，优选18个，使用由过氧化氢和甲酸原位形成的甲酸，反应物，烯烃和过氧化氢/甲酸的高级脂肪酸的碳原子和甘油三酯，包括不饱和脂肪酸，优选大豆油，在环境压力下通过，逆流通过至少三级反应级联。将烯烃相引入第一反应阶段，将过氧化氢和甲酸分别引入倒数第二反应阶段，并将烯烃相和过氧化氢/甲酸相（酸水相）彼此分离在每个反应阶段之后的相分离器中。烯烃相依次通过反应段I至n，反应阶段（n-1）之后的酸性水通过反应阶段（n-2）反应到烯烃相，然后通过阶段n和1 ，反应器中的反应温度保持在50〜80℃，相分离器在15〜60℃的范围内。

9. 发明授权

US5110508A Process and apparatus for making a heat-sensitive material 失效
标题翻译：制造热敏材料的工艺和装置
公开(公告)号：US5110508A
公开(公告)日：1992-05-05
申请号：US340977
申请日：1989-04-20
申请人： Karl-Heinz Buettgen , Bernhard Gutsche , Friedrich Hommers , Wilhelm Johannisbauer , Eberhard Peukert , Reinhold Sedelies
发明人： Karl-Heinz Buettgen , Bernhard Gutsche , Friedrich Hommers , Wilhelm Johannisbauer , Eberhard Peukert , Reinhold Sedelies
IPC分类号： B01D1/22 , B01D3/00 , B01J14/00 , B01J19/00 , B01J19/18 , C07C67/08
CPC分类号： B01D3/009 , B01J14/00 , B01J19/0013 , B01J19/1881 , B01J2219/0009 , B01J2219/00101
摘要： The invention relates to a process, more especially a discontinuous process, for conducting a reaction taking place at elevated temperature in which heat-sensitive products are formed. To increase the volume-time yield, a heat transfer unit independent of the reactor is used for heating. The invention also relates to an apparatus for the production of heat-sensitive products at elevated temperatures. This apparatus comprises a reactor and a heating system. To increase the volume-time yield, the heating system comprises at least one heat transfer unit arranged outside and connected to the reactor.
摘要翻译：本发明涉及一种用于进行在其中形成热敏产物的升高的温度下进行的反应的方法，更特别是不连续的方法。为了增加体积 - 时间产率，独立于反应器的传热装置被用于加热。本发明还涉及一种用于在高温下生产热敏产品的装置。该装置包括反应器和加热系统。为了增加体积 - 时间产量，加热系统包括布置在外部并连接到反应器的至少一个传热单元。

10. 发明授权

US06683224B1 Process for the production of fatty alcohols 失效
标题翻译：生产脂肪醇的方法
公开(公告)号：US06683224B1
公开(公告)日：2004-01-27
申请号：US10304445
申请日：2002-11-26
申请人： Roland Hourticolon , Guenther Demmering , Hans-Peter Kubersky , Lothar Friesenhagen , Friedrich Hommers , Juergen Latzel , Eberhard Peukert , Hans-Guenther Richard , Udo Kreutzer
发明人： Roland Hourticolon , Guenther Demmering , Hans-Peter Kubersky , Lothar Friesenhagen , Friedrich Hommers , Juergen Latzel , Eberhard Peukert , Hans-Guenther Richard , Udo Kreutzer
IPC分类号： C07C29136
CPC分类号： C07C29/149 , C07C31/125 , C07C33/02
摘要： Naturally occurring fats, oils and fatty derivatives are continuously hydrogenated to fatty alcohols in a fixed-bed reactor in the presence of hydrogen in excess and hydrogenation catalysts under static pressures of 50 to 300 bar and at temperatures of 160 to 320° C. The liquid product is cooled and the excess hydrogen is returned to the reactor entrance by a gas circulation pump as a recycle gas after separation of the liquid product. The expense involved in cooling and reheating the recycle gas is eliminated without any reduction in the quality of the fatty alcohol produced providing the recycle gas is returned to the reactor entrance without reheating and the hydrogenation reaction is carried out under static pressures of at least 200 bar.
摘要翻译：天然存在的脂肪，油和脂肪衍生物在固定床反应器中在过量的氢气和氢化催化剂的存在下，在50至300巴的静态压力和160至320℃的温度下，连续氢化成脂肪醇。液体产物被冷却，并且在分离液体产物之后，过量的氢气作为循环气体由气体循环泵返回到反应器入口。除去循环气体的冷却和再加热所涉及的费用被消除，而不会降低所产生的脂肪醇的质量，提供循环气体将不再重新加热而返回到反应器入口，氢化反应在至少200巴的静压下进行。

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