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1. 发明授权

US5688607A Platinum group silicide modified aluminide coated metal superalloy body 失效
标题翻译：铂族硅化物改性铝化物涂层金属超合金体
公开(公告)号：US5688607A
公开(公告)日：1997-11-18
申请号：US500655
申请日：1995-07-12
申请人： Bernard R. Rose , Patrick R. Lavery
发明人： Bernard R. Rose , Patrick R. Lavery
IPC分类号： C23C10/02 , C23C10/58 , C23C10/60 , B32B15/00
CPC分类号： C23C10/58 , C23C10/02 , C23C10/60 , Y02T50/67 , Y10T428/1266 , Y10T428/12861 , Y10T428/12875
摘要： Coated nickel, cobalt or nickel-cobalt superalloy bodies having increased resistance to oxidation, corrosion and thermal fatigue at high temperature are produced by applying a thin layer of a platinum-group metal, siliciding and heating to an elevated temperature to diffuse and integrate the silicided platinum-group metal into the surface of the superalloy body. Then the superalloy body is exposed to a diffusion powder composition containing sources of aluminum or aluminum/chromium metals and heated in a hydrogen or inert gas atmosphere to an elevated temperature to codeposit and diffuse aluminum or aluminum and chromium into the silicided platinum-group metal-treated surface layer. Finally, the superalloy body is heated to its solvus temperature to form a ductile protective surface layer having an outer zone comprising a platinum-group metal aluminide, ductilized by the solutioning therein of beta chromium, and an inner stabilizing zone of silicided platinum group metal comprising from 3% to 20% by weight of silicon.
摘要翻译：在高温下具有增加的抗氧化，腐蚀和热疲劳性能的镀镍，钴或镍钴超合金体是通过将铂族金属薄层，硅化和加热施加到升高的温度来产生的，以将硅化物铂族金属进入超合金体的表面。然后将超合金体暴露于含有铝或铝/铬金属源的扩散粉末组合物，并在氢气或惰性气体气氛中加热至高温，以将铝或铝和铬分解成硅化物铂族金属 - 处理过的表层。最后，将超合金体加热至其固溶温度以形成具有外部区域的韧性保护性表面层，该外部区域包含通过其中溶解β铬的管道的铂族金属铝化物，以及硅化物铂族金属的内侧稳定区域，从3重量％至20重量％的硅。

2. 发明授权

US5492726A Platinum group silicide modified aluminide coating process and products 失效
标题翻译：铂族硅化物改性铝化物涂层工艺及产品
公开(公告)号：US5492726A
公开(公告)日：1996-02-20
申请号：US382874
申请日：1995-02-03
申请人： Bernard R. Rose , Patrick R. Lavery
发明人： Bernard R. Rose , Patrick R. Lavery
IPC分类号： C23C10/02 , C23C10/58 , C23C10/60 , C23C16/00
CPC分类号： C23C10/58 , C23C10/02 , C23C10/60 , Y02T50/67 , Y10T428/1266 , Y10T428/12861 , Y10T428/12875
摘要： Process for producing novel coated nickel and/or cobalt superalloy bodies having increased resistance to oxidation, corrosion and thermal fatigue at high temperatures. The process comprises applying a thin layer of a platinum-group metal, siliciding and heating to an elevated temperature to diffuse and integrate the silicided platinum-group metal into the surface of the superalloy body. Then the superalloy body is exposed to a diffusion powder composition containing sources of aluminum or aluminum/chromium metals and heated in a hydrogen or inert gas atmosphere to an elevated temperature to codeposit and diffuse aluminum or aluminum and chromium into the silicided platinum-group metal-treated surface. Finally, the superalloy body is heated to its solvus temperature to form a ductile surface having an outer zone comprising a platinum-group metal aluminide, optionally ductilized by the solutioning therein of beta chromium. An inner stabilizing zone of silicon-rich phases is formed during said diffusion processes.
摘要翻译：用于生产在高温下具有增加的耐氧化，腐蚀和热疲劳性能的新型涂覆的镍和/或钴超级合金体的方法。该方法包括将铂族金属的薄层，硅化和加热至高温以将硅化铂族金属扩散并整合到超级合金体的表面中。然后将超合金体暴露于含有铝或铝/铬金属源的扩散粉末组合物，并在氢气或惰性气体气氛中加热至高温，以将铝或铝和铬分解成硅化物铂族金属 - 处理过的表面。最后，将超合金体加热至其固溶温度以形成具有包含铂族金属铝化物的外部区域的韧性表面，该外部区域可选地通过其中溶解β型铬而导电。在所述扩散过程中形成富硅相的内部稳定区。

3. 发明授权

US5843588A Diffusion coating products 失效
标题翻译：扩散涂料产品
公开(公告)号：US5843588A
公开(公告)日：1998-12-01
申请号：US520282
申请日：1995-08-28
申请人： Bernard R. Rose , John K. Willis
发明人： Bernard R. Rose , John K. Willis
IPC分类号： C23C10/02 , C23C10/52 , B32B15/00 , B32B15/16
CPC分类号： C23C10/52 , C23C10/02 , Y02T50/67 , Y10T428/1275 , Y10T428/12875
摘要： Process for producing novel nickel superalloy bodies having increased resistance of to oxidation and corrosion at high temperatures. The process comprises applying a thin layer of a platinum-group metal and heating to an elevated temperature to diffuse or integrate the platinum-group metal into the surface of the metal superalloy. Then the superalloy body is packed into a container filled with a diffusion powder composition containing sources of aluminum and chromium metals and heated in a hydrogen gas atmosphere to an elevated temperature to codeposit and diffuse aluminum and chromium into the platinum-group metal-treated surface. Finally, the superalloy body is removed from the diffusion coating container and heated to the solvus temperature to form a ductile surface having an outer zone microstructure comprising a normally brittle PtAl.sub.2 which has been ductilized by the solutioning therein of beta chromium. This ductilized PtAl.sub.2 may or may not be in a beta phase nickel aluminide matrix depending on substrate composition.
摘要翻译：用于生产在高温下具有增加的耐氧化和腐蚀性的新型镍超合金体的方法。该方法包括施加铂族金属的薄层并加热到升高的温度以将铂族金属扩散或整合到金属超耐热合金的表面中。然后将超合金体填充到填充有含有铝和铬金属源的扩散粉末组合物的容器中，并在氢气气氛中升高到高温，以将铝和铬分解并扩散到铂族金属处理的表面中。最后，将超合金体从扩散涂层容器中取出并加热到固溶体温度，形成具有外部微结构的韧性表面，该外部微结构包含通过其中β溶液溶解而导致的通常脆性的PtAl2。根据底物组成，该经管的PtAl 2可以是或不是在β相的镍铝化物基质中。

4. 发明授权

US3978598A Apparatus for simulating an open fire 失效
标题翻译：用于模拟明火的装置
公开(公告)号：US3978598A
公开(公告)日：1976-09-07
申请号：US541605
申请日：1975-01-16
申请人： Bernard R. Rose , Daniel H. Meggs , Janos Beny
发明人： Bernard R. Rose , Daniel H. Meggs , Janos Beny
IPC分类号： F21S10/04 , F24C7/00 , G09F13/34 , G09F19/20 , G09F13/36
CPC分类号： F24C7/004 , F21S10/04 , G09F13/34 , G09F19/20
摘要： Apparatus for simulating an open fire having a lamp mounted on a base structure within a shell. The shell is simulative of a pile of burning logs or the like and is at least in part light transmitting. Light masks are included, one of which operates to project the image of a flame on a projection screen mounted at the rear of the apparatus base. Arrangements may also be included for varying the light pattern projected from the lamp, for simulating the heat of a fire and for simulating the burning noise of a fire.
摘要翻译：用于模拟明火的装置，其具有安装在壳体内的基座结构上的灯。壳体模拟一堆燃烧的原木等，至少部分透光。包括光掩模，其中之一用于在安装在设备底座后部的投影屏幕上投射火焰图像。也可以包括用于改变从灯投射的光图案，用于模拟火的热量和模拟火的燃烧噪声的布置。

5. 发明授权

US5482578A Diffusion coating process 失效
标题翻译：扩散涂层工艺
公开(公告)号：US5482578A
公开(公告)日：1996-01-09
申请号：US212274
申请日：1994-03-14
申请人： Bernard R. Rose , John K. Willis
发明人： Bernard R. Rose , John K. Willis
IPC分类号： C23C10/02 , C23C10/52 , C21D9/00 , C23C10/56
CPC分类号： C23C10/52 , C23C10/02 , Y02T50/67 , Y10T428/1275 , Y10T428/12875
摘要： Process for producing novel nickel superalloy bodies having increased resistance of to oxidation and corrosion at high temperatures. The process comprises applying a thin layer of a platinum-group metal and heating to an elevated temperature to diffuse or integrate the platinum-group metal into the surface of the metal superalloy. Then the superalloy body is packed into a container filled with a diffusion powder composition containing sources of aluminum and chromium metals and heated in a hydrogen gas atmosphere to an elevated temperature to codeposit and diffuse aluminum and chromium into the platinum-group metal-treated surface. Finally, the superalloy body is removed from the diffusion coating container and heated to the solvus temperature to form a ductile surface having an outer zone microstructure comprising a normally brittle PtAl.sub.2 which has been ductilized by the solutioning therein of beta chromium. This ductilized PtAl.sub.2 may or may not be in a beta phase nickel aluminide matrix depending on substrate composition.
摘要翻译：用于生产在高温下具有增加的耐氧化和腐蚀性的新型镍超合金体的方法。该方法包括施加铂族金属的薄层并加热到升高的温度以将铂族金属扩散或整合到金属超耐热合金的表面中。然后将超合金体填充到填充有含有铝和铬金属源的扩散粉末组合物的容器中，并在氢气气氛中升高到高温，以将铝和铬分解并扩散到铂族金属处理的表面中。最后，将超合金体从扩散涂层容器中取出并加热到固溶体温度，形成具有外部微结构的韧性表面，该外部微结构包含通过其中β溶液溶解而导致的通常脆性的PtAl2。根据底物组成，该经管的PtAl 2可以是或不是在β相的镍铝化物基质中。

6. 发明授权

US4293338A Diffusion coating composition of improved flowability 失效
标题翻译：扩散涂料组合物具有改善的流动性
公开(公告)号：US4293338A
公开(公告)日：1981-10-06
申请号：US60891
申请日：1979-07-26
申请人： Bernard R. Rose , John K. Willis
发明人： Bernard R. Rose , John K. Willis
IPC分类号： C23C10/56 , B22F9/00
CPC分类号： C23C10/56
摘要： Improved powder-type diffusion-coating compositions for use in codeposition processes involving the formation of diffusion coating of chromium and aluminum on high nickel and high cobalt alloys known as superalloys. The compositions are characterized by easy flowability and, particularly, by the use of the intermetallic compound Co.sub.2 Al.sub.9.
摘要翻译：用于共沉积方法的改进的粉末型扩散涂料组合物，其涉及在称为超级合金的高镍和高钴合金上形成铬和铝的扩散涂层。组合物的特征在于容易的流动性，特别是通过使用金属间化合物Co2Al9。

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