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1. 发明授权

US4413133A Process for manufacturing chlorolactones from unsaturated carboxylic acids 失效
标题翻译：从不饱和羧酸生产氯内酯的方法
公开(公告)号：US4413133A
公开(公告)日：1983-11-01
申请号：US321145
申请日：1981-11-13
申请人： Bernard Damin , Alain Forestiere , Bernard Sillion
发明人： Bernard Damin , Alain Forestiere , Bernard Sillion
IPC分类号： C07D307/00 , C07D307/33 , C07D307/77 , C07D309/30 , C07D311/00 , C07D493/10 , C07D307/32
CPC分类号： C07D307/00 , C07D307/33 , C07D307/77 , C07D309/30 , C07D311/00 , C07D493/10
摘要： Process for manufacturing chlorolactones by reacting, within an ahydrous organic solvent, a metal N-chlorosulfonamidate of the formula ##STR1## wherein R is a hydrogen or halogen atom or an alkyl radical, Ar is a mono- or polycyclic divalent aromatic radical and M is an alkali metal, with a substantially stoichiometrical proportion of an aliphatic or alicyclic carboxylic acid having at least one double bond separated from the COOH group by at least 2 carbon atoms, in the presence of a substantially stoichiometrical amount of a strong acid whose conjugate base is weakly nucleophilic.
摘要翻译：在无水有机溶剂中使下式的化合物的N-氯磺酰氨基化物，其中R是氢或卤原子或烷基，Ar是单环或多环二价芳基，M是碱金属，具有基本上化学计量比例的具有至少一个双键的脂族或脂环族羧酸，其具有至少2个碳原子的COOH基团，在基本上化学计量的强酸的存在下，其共轭碱为弱亲核。

2. 发明授权

US5256740A Amino-substituted polymers and their use as additives for modifying the cold properties of middle hydrocarbon distillates 失效
标题翻译：氨基取代的聚合物及其作为改性中碳氢化合物馏出物的冷性能的添加剂的用途
公开(公告)号：US5256740A
公开(公告)日：1993-10-26
申请号：US876312
申请日：1992-04-30
申请人： Jacques Denis , Alain Forestiere , Beatrice Bonardi , Bernard Damin
发明人： Jacques Denis , Alain Forestiere , Beatrice Bonardi , Bernard Damin
IPC分类号： B01F17/16 , C08G63/685 , C08G63/91 , C10L1/22 , C08G63/66 , C08G63/68 , C09K7/06
CPC分类号： C10L1/221 , C08G63/6858 , C08G63/918 , Y10S516/07
摘要： Polymer with a number average molecular weight of 400 to 20,000 having amino-substituted groups in its molecule and resulting from the reaction of at least one compound having a secondary amine function with 1 to 60 carbon atoms on an unsaturated polyester resulting from the condensation of an unsaturated, aliphatic dicarboxylic compound having at least one alpha ethylene unsaturation of one of the carboxylic groups on at least one epoxidized compound having 2 to 62 carbon atoms chosen from among epoxyalkenes, ethers, epoxyalcohol esters and epoxyacid esters. Middle distillate composition having a distillation range of 150.degree. to 450.degree. C. and incorporating a minor proportion, preferably 0.001 to 2% by weight, of at least one of the aforementioned polymers.
摘要翻译：在分子中具有氨基取代基的数均分子量为400至20,000的聚合物，并且由至少一种具有1至60个碳原子的仲胺官能团的化合物与不饱和聚酯反应得到的聚合物至少一种选自环氧烯烃，醚，环氧醇酯和环氧酸酯的至少一种具有2至62个碳原子的环氧化合物的羧基之一的α-乙烯不饱和度的不饱和脂族二羧酸化合物。中间馏分组合物，蒸馏范围为150-450℃，并加入少量的上述聚合物中的至少一种，较少的比例，优选为0.001-2％（重量）。

3. 发明授权

US07861737B2 Method of optimizing heavy crude transportation by incorporation under pressure of dimethyl ether 失效
标题翻译：通过在二甲醚压力下并入而优化重质原油运输的方法
公开(公告)号：US07861737B2
公开(公告)日：2011-01-04
申请号：US11766120
申请日：2007-06-21
申请人： Isabelle Henaut , Alain Forestiere , Jean-Philippe Heraud , Jean-François Argillier
发明人： Isabelle Henaut , Alain Forestiere , Jean-Philippe Heraud , Jean-François Argillier
IPC分类号： C10G49/00
CPC分类号： C10L1/14 , C10L1/1616 , C10L1/1852 , F17D1/17 , Y10T137/0391 , Y10T137/0396
摘要： Heavy crude transportation optimization method wherein at least one solvent is added to said crude. According to the method, a predetermined amount of dimethyl ether (DME) is added under pressure so as to adjust the viscosity of the crude.
摘要翻译：重质原油运输优化方法，其中向所述原油中加入至少一种溶剂。根据该方法，在压力下加入预定量的二甲醚（DME）以调节粗品的粘度。

4. 发明申请

US20080154068A1 ACETONITRILE REMOVAL FROM THE OLEFINIC FEED OF ETHER PRODUCTION PROCESSES USING IONIC LIQUIDS 失效
标题翻译：从使用离子液体的生产过程的油脂进料中除去乙腈
公开(公告)号：US20080154068A1
公开(公告)日：2008-06-26
申请号：US11954108
申请日：2007-12-11
申请人： Renaud Cadours , Alain Forestiere , Christophe Vallee
发明人： Renaud Cadours , Alain Forestiere , Christophe Vallee
IPC分类号： C07C41/01
CPC分类号： C07B63/00 , B01D11/0426 , B01D11/0488 , B01D11/0492 , B01J2219/00006 , C07C41/06 , Y02P20/542 , C07C43/046
摘要： An enhanced ether production process from an olefinic cut containing at least one iso-olefin and from an alcohol comprises a stage of removal of the acetonitrile present in the hydrocarbon feed by liquid-liquid extraction, the extraction solvent being a non-aqueous ionic liquid of general formula Q+A−, wherein Q+ is an ammonium, phosphonium and/or sulfonium cation, and A− an anion likely to form a liquid salt with said cation. Advantageously, the method according to the invention generally allows the amount of water at the etherification reactor inlet to be divided by at least two and thus the purity of the ether produced to be improved.
摘要翻译：含有至少一种异烯烃和醇的烯烃切割剂的增强的乙醚生产方法包括通过液 - 液萃取除去存在于烃进料中的乙腈的一个阶段，萃取溶剂是一种非水离子液体其中Q +是铵，鏻和/或锍阳离子，并且A + SUP>可能与所述阳离子形成液体盐的阴离子。有利地，根据本发明的方法通常允许将醚化反应器入口处的水量除以至少两个，从而提高生产的醚的纯度。

5. 发明授权

US07160836B2 Materials comprising organic groups containing sulphur and phosphorous bonded to a mineral oxide via oxygen atoms 有权
标题翻译：包含含硫和磷的有机基团的材料通过氧原子键合到矿物氧化物上
公开(公告)号：US07160836B2
公开(公告)日：2007-01-09
申请号：US11200038
申请日：2005-08-10
申请人： Alain Forestiere , P. Hubert Mutin , Andre Vioux , Gilles Guerrero
发明人： Alain Forestiere , P. Hubert Mutin , Andre Vioux , Gilles Guerrero
IPC分类号： B01J31/00
CPC分类号： B01J31/0217 , B01J20/3204 , B01J20/321 , B01J20/3251 , B01J20/3257 , B01J20/3259 , B01J31/0211 , B01J31/0212 , B01J31/0225 , B01J31/0259 , B01J31/10 , B01J37/033 , C07F9/095 , C07F9/3294 , C07F9/409
摘要： The invention describes materials comprising organic groups containing sulphur and phosphorous bonded together by a hydrocarbon chain and bonded via phosphorous and oxygen atoms to a mineral oxide of an element M, said materials being characterized in that they comprise M-O-M′ bonds, M′representing an element of a mineral oxide identical to or different from M, in that the ratio of the element M to the phosphorous is about 0.5: 1 to about 500:1 and in that each phosphorous atom of the phosphorous-containing groups forms at least one P—O-M bond and/or P—O-M′ bond. The invention also describes a process for preparing such materials.
摘要翻译：本发明描述了包含含硫和磷的有机基团的材料，其通过烃链键合在一起并通过磷和氧原子键合到元素M的矿物氧化物，所述材料的特征在于它们包含MOM'键，M'表示元素的与M相同或不同的矿物氧化物，其中元素M与磷的比例为约0.5:1至约500:1，并且所述含磷基团的每个磷原子形成至少一个POM键和/或POM'债券。本发明还描述了制备这种材料的方法。

6. 发明授权

US06958307B2 Materials comprising organic phosphorous-containing groups bonded to a mineral oxide via oxygen atoms 有权
标题翻译：包含通过氧原子与无机氧化物键合的含有机磷基团的材料
公开(公告)号：US06958307B2
公开(公告)日：2005-10-25
申请号：US09930153
申请日：2001-08-16
申请人： Alain Forestiere , P-Hubert Mutin , André Vioux , Gilles Guerrero
发明人： Alain Forestiere , P-Hubert Mutin , André Vioux , Gilles Guerrero
IPC分类号： B01J20/281 , B01J20/32 , B01J21/04 , B01J21/06 , B01J31/02 , C01B13/14 , C01F7/02 , C01G1/02 , C01G23/04 , C07F5/06 , C07F7/28 , C07F9/38 , C07F9/40 , G01N30/88 , B01J31/00 , B01J20/22 , B01J27/14
CPC分类号： B01J31/0225 , B01J20/3204 , B01J20/3219 , B01J20/3248 , B01J20/3251 , B01J20/3257 , B01J20/3259 , B01J20/3265 , B01J21/04 , B01J21/063 , B01J21/066 , B01J31/0269 , B82Y30/00 , B82Y40/00
摘要： The present invention relates to a composition including an organic phosphorous-containing group bonded via an oxygen atom to a metal oxide of at least one element M. Generally, the composition is essentially amorphous, and includes an essentially monomolecular layer of an organic group directly bonded to the phosphorous atom. In addition, the composition is generally essentially free of any phosphate, phosphonate or phosphinate phase of the element M. Moreover, the composition has a ratio of the element M to phosphorous of about 15:1-200:1.
摘要翻译：本发明涉及包含通过氧原子与至少一个元素M的金属氧化物键合的含有机磷基团的组合物。通常，该组合物基本上是无定形的，并且包括直接键合的有机基团的基本单分子层到磷原子。此外，组合物通常基本上不含元素M的任何磷酸盐，膦酸盐或次膦酸盐相。此外，组合物的元素M与磷的比例为约15：1-200:1。

7. 发明授权

US06878837B2 Process for producing alkyl esters from a vegetable or animal oil and an aliphatic monoalcohol 失效
标题翻译：从植物油或动物油和脂肪族一元醇生产烷基酯的方法
公开(公告)号：US06878837B2
公开(公告)日：2005-04-12
申请号：US10411384
申请日：2003-04-11
申请人： Laurent Bournay , Gerard Hillion , Pierre Boucot , Jean-Alain Chodorge , Charles Bronner , Alain Forestiere
发明人： Laurent Bournay , Gerard Hillion , Pierre Boucot , Jean-Alain Chodorge , Charles Bronner , Alain Forestiere
IPC分类号： C07C67/03 , C07C51/00
CPC分类号： C11C3/003 , C07C67/03 , C07C69/24 , C07C69/52
摘要： Alkyl esters of fatty acids, and high purity glycerin, are produced using a process comprising a set of transesterification reactions between a vegetable or animal oil and an aliphatic monoalcohol employing a heterogeneous catalyst, for example based on zinc aluminate, the water content in the reaction medium being controlled to a value that is below a given limiting value.
摘要翻译：脂肪酸和高纯度甘油的烷基酯是使用包含一系列植物油或动物油与脂肪族一元醇之间的酯交换反应的方法制备的，该方法使用非均相催化剂，例如以铝酸铝为基准，反应中的水含量介质被控制到低于给定极限值的值。

8. 发明授权

US06630112B2 Process and unit for carrying out a reaction on an organic feed, such as dimerization or metathesis, in the presence of a polar phase containing a catalyst 有权
标题翻译：在含有催化剂的极性相存在下，在有机原料上进行反应的方法和单元，例如二聚或复分解
公开(公告)号：US06630112B2
公开(公告)日：2003-10-07
申请号：US09779649
申请日：2001-02-09
申请人： Helene Olivier , Dominique Commereuc , Alain Forestiere , Francois Hugues
发明人： Helene Olivier , Dominique Commereuc , Alain Forestiere , Francois Hugues
IPC分类号： C08F200
CPC分类号： C07C6/04 , B01J19/245 , B01J2219/00103 , B01J2219/00159 , B01J2219/00186 , C07B61/00 , C07C2527/125 , C07C2531/14
摘要： A process for carrying out a reaction on an organic feed, for example dimerization, co-dimerization, oligomerization or metathesis of olefins, as described in which the catalyst is a catalytic metal compound dissolved in a non-aqueous ionic medium which is not or is only slightly miscible with hydrocarbons. The reaction is carried out in a system comprising at least two treatment loops each comprising at least one reaction zone and at least one zone for separating the organic and polar phases between which the polar medium containing the catalytic metal compound, and the organic phase circulate. Fresh polar phase is injected into the second loop and used polar phase is eliminated from the first loop. The hydrocarbon to be transformed is injected into the first loop and the products are withdrawn from the second loop. The invention also concerns a unit for carrying out the process.
摘要翻译：对有机原料进行反应的方法，例如烯烃的二聚，共二聚，低聚或复分解，其中催化剂是溶解在非水性离子介质中的催化金属化合物，其不是或不是只与碳氢化合物轻微混溶。该反应在包括至少两个处理回路的系统中进行，每个处理回路各自包含至少一个反应区和至少一个用于分离有机相和极性相的区域，在该区域之间含有催化金属化合物的极性介质和有机相循环。新鲜极性相注入到第二回路中，并且使用极性相从第一回路中消除。将待转化的烃注入第一回路中，并从第二回路中取出产物。本发明还涉及用于执行该过程的单元。

9. 发明授权

US06491809B1 Synthetic oil with a high viscosity number and a low pour point 有权
标题翻译：具有高粘度数和低倾点的合成油
公开(公告)号：US06491809B1
公开(公告)日：2002-12-10
申请号：US09671294
申请日：2000-09-27
申请人： Patrick Briot , Alain Forestiere , Serge Gautier , Eric Benazzi , Leon Lew
发明人： Patrick Briot , Alain Forestiere , Serge Gautier , Eric Benazzi , Leon Lew
IPC分类号： C10M10506
CPC分类号： C10M105/02 , C10M105/06
摘要： Synthetic oil that contains wholly or partly of dialkylbenzenes and/or partially or totally hydrogenated dialkylbenzenes. The synthetic oil according to the invention can also be used as an oil base or oil base additive and comprises at least one dialkylbenzene and/or at least one partially or totally hydrogenated dialkylbenzene and meets the general chemical formula: R1—A—R2 in which R1 and R2 represent alkyl groups and A is a benzene core and/or a cyclohexane core and/or a cyclohexene core and/or a cyclohexadiene core and is characterized in that it contains between 1 and 20% by weight or ortho isomers and in that at least one of the alkyl groups is attached for the most part to group A by carbon 2 of the aliphatic chain. The two alkyl groups are preferably attached for the most part to group A by carbon 2 of the aliphatic chain.
摘要翻译：含有全部或部分二烷基苯和/或部分或完全氢化的二烷基苯的合成油。根据本发明的合成油还可以用作油基或油基添加剂，并且包含至少一种二烷基苯和/或至少一种部分或全部氢化的二烷基苯，并且满足以下通式：其中R 1和R 2表示烷基基团和A是苯核心和/或环己烷核心和/或环己烯核心和/或环己二烯核心，其特征在于其含有1至20重量％或邻位异构体，并且其中至少一个烷基通过脂族链的碳2大部分连接到基团A上。两个烷基优选通过脂族链的碳2连接到大部分为基团A。

10. 发明授权

US06444866B1 Sequence of processes for olefin oligomerization 失效
标题翻译：烯烃低聚方法的顺序
公开(公告)号：US06444866B1
公开(公告)日：2002-09-03
申请号：US09110434
申请日：1998-07-06
申请人： Dominique Commereuc , Alain Forestiere , François Hughes , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Alain Forestiere , François Hughes , Hélène Olivier-Bourbigou
IPC分类号： C07C202
CPC分类号： C10G50/00 , C07C2/08 , C07C2/32 , C07C2531/14 , C07C2531/22
摘要： A process for oligomerising olefins in an organic feed containing at least one olefin comprises two steps with different types of catalysis. The cut to be treated containing at least one olefin (Cn) is introduced via line 1 into a reaction zone R1 where in a first step it undergoes catalytic oligomerisation, either of a liquid phase homogeneous type, or heterogeneous with a solid support. The effluent produced is sent via line 2 to a heat exchanger E1 traversed by a cold liquid. The effluent is thus cooled before being sent via line 3 to a second reaction zone R2 where it undergoes catalytic oligomerisation in a liquid-liquid two-phase medium. After reaction, the effluent is fed via line 4 to a zone L1 where it is washed. After washing, the hydrocarbon fraction is sent via line 5 to separator S1. The fraction containing the unreacted olefins (Cn) is separated from the oligomer product fraction produced, this fraction Cn is evacuated from the apparatus via line 6, and the fraction containing the oligomer products is evacuated via line 7.
摘要翻译：在含有至少一种烯烃的有机进料中使烯烃低聚的方法包括具有不同催化类型的两个步骤。待处理的包含至少一种烯烃（Cn）的切割物通过管线1引入到反应区域R1中，其中在第一步骤中，它经历液相均相型的催化低聚反应，或与固体支持物异相。产生的流出物通过管线2输送到由冷液体穿过的热交换器E1。因此，流出物在通过管线3送入第二反应区R2之前被冷却，在第二反应区R2中，其在液 - 液两相介质中经历催化低聚。反应后，流出物通过管线4进料至其中洗涤的区域L1。洗涤后，烃馏分通过管线5送至分离器S1。将含有未反应的烯烃（Cn）的馏分与所生产的低聚物产物馏分分离，将馏分Cn通过管线6从装置排出，含有低聚物产物的馏分通过管线7排出。

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