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1. 发明授权

US06444866B1 Sequence of processes for olefin oligomerization 失效
标题翻译：烯烃低聚方法的顺序
公开(公告)号：US06444866B1
公开(公告)日：2002-09-03
申请号：US09110434
申请日：1998-07-06
申请人： Dominique Commereuc , Alain Forestiere , François Hughes , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Alain Forestiere , François Hughes , Hélène Olivier-Bourbigou
IPC分类号： C07C202
CPC分类号： C10G50/00 , C07C2/08 , C07C2/32 , C07C2531/14 , C07C2531/22
摘要： A process for oligomerising olefins in an organic feed containing at least one olefin comprises two steps with different types of catalysis. The cut to be treated containing at least one olefin (Cn) is introduced via line 1 into a reaction zone R1 where in a first step it undergoes catalytic oligomerisation, either of a liquid phase homogeneous type, or heterogeneous with a solid support. The effluent produced is sent via line 2 to a heat exchanger E1 traversed by a cold liquid. The effluent is thus cooled before being sent via line 3 to a second reaction zone R2 where it undergoes catalytic oligomerisation in a liquid-liquid two-phase medium. After reaction, the effluent is fed via line 4 to a zone L1 where it is washed. After washing, the hydrocarbon fraction is sent via line 5 to separator S1. The fraction containing the unreacted olefins (Cn) is separated from the oligomer product fraction produced, this fraction Cn is evacuated from the apparatus via line 6, and the fraction containing the oligomer products is evacuated via line 7.
摘要翻译：在含有至少一种烯烃的有机进料中使烯烃低聚的方法包括具有不同催化类型的两个步骤。待处理的包含至少一种烯烃（Cn）的切割物通过管线1引入到反应区域R1中，其中在第一步骤中，它经历液相均相型的催化低聚反应，或与固体支持物异相。产生的流出物通过管线2输送到由冷液体穿过的热交换器E1。因此，流出物在通过管线3送入第二反应区R2之前被冷却，在第二反应区R2中，其在液 - 液两相介质中经历催化低聚。反应后，流出物通过管线4进料至其中洗涤的区域L1。洗涤后，烃馏分通过管线5送至分离器S1。将含有未反应的烯烃（Cn）的馏分与所生产的低聚物产物馏分分离，将馏分Cn通过管线6从装置排出，含有低聚物产物的馏分通过管线7排出。

2. 发明授权

US06646173B2 Sequence of processes for olefin oligomerisation 有权
公开(公告)号：US06646173B2
公开(公告)日：2003-11-11
申请号：US09984053
申请日：2001-10-26
申请人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Alain Forestiere , François Hugues , Hélène Olivier-Bourbigou
IPC分类号： C07C202
CPC分类号： C07C2/30 , C07C2/32 , C07C2531/14 , C07C2531/16
摘要： A process is described for carrying out olefin oligomerisation in two catalysis steps of different types, using an organic feed containing at least one olefin. The cut to be treated, containing at least one olefin (Cn), is introduced into a first reaction zone where, in a first step, it undergoes catalytic oligomerisation either of the homogeneous liquid phase type, or of the heterogeneous type with a solid support. The effluent produced is generally sent to a heat exchanger traversed by a cold liquid, the effluent thus being cooled before being sent to a second reaction zone where it undergoes catalytic oligomerisation in a liquid—liquid two-phase medium, the invention being characterized in that at least an ethylenic hydrocarbon containing 3 to 5 carbon atoms per molecule is added to the inlet to the second reaction zone.

3. 发明授权

US06706657B2 Catalytic composition for dimerizing, co-dimerizing and oligomerizing olefins 有权
标题翻译：用于二烯化，共二聚和低聚烯烃的催化组合物
公开(公告)号：US06706657B2
公开(公告)日：2004-03-16
申请号：US09775556
申请日：2001-02-05
申请人： Dominique Commereuc , Dominique Le Pennec , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Dominique Le Pennec , Hélène Olivier-Bourbigou
IPC分类号： B01J3100
CPC分类号： C07C2/32 , B01J31/0284 , B01J31/0288 , B01J31/14 , B01J31/143 , B01J31/1845 , B01J31/185 , B01J31/24 , B01J31/2409 , B01J2231/20 , B01J2531/847 , C07C2/26 , C07C2527/128 , C07C2531/22
摘要： A catalytic composition comprising at least one nickel compound mixed or complexed with at least one tertiary phosphine or a phosphite carrying a functional group, at least partly dissolved in a non-aqueous medium with an ionic nature resulting from bringing at least one aluminum halide into contact with at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, is useful for dimerizing, co-dimerizing and oligomerizing olefins. Functional groups include, but are not limited to, an amine, a cyclic amine, a nitrogen-containing heterocycle, an ester, an acid, an alcohol, a quaternary ammonium, a quaternary phosphonium, a sulfonium, a sulfonate or a phosphonate group.
摘要翻译：一种催化组合物，其包含与至少一种叔膦或携带官能团的亚磷酸酯混合或络合的至少一种镍化合物，至少部分地溶解在具有离子性质的非水介质中，所述非水介质使至少一种卤化铝接触与至少一种季铵卤化物和/或至少一种季鏻卤化物可用于烯烃的二聚，共二聚和低聚。官能团包括但不限于胺，环胺，含氮杂环，酯，酸，醇，季铵，季鏻，锍，磺酸盐或膦酸酯基团。

4. 发明授权

US06617474B2 Process for the hydroformylation of olefinically unsaturated compounds in a non-aqueous ionic solvent 有权
标题翻译：烯属不饱和化合物在非水离子溶剂中加氢甲酰化的方法
公开(公告)号：US06617474B2
公开(公告)日：2003-09-09
申请号：US10053706
申请日：2002-01-24
申请人： Frédéric Favre , Dominique Commereuc , Hélène Olivier-Bourbigou
发明人： Frédéric Favre , Dominique Commereuc , Hélène Olivier-Bourbigou
IPC分类号： C07C4550
CPC分类号： C07C45/80 , C07C45/50 , C07C47/02
摘要： A process for the hydroformylation of an olefinically unsaturated compound in the liquid phase by reaction, in a reaction section, with carbon monoxide and hydrogen in the presence of a polar phase comprising: a non-aqueous ionic liquid which is at least partly miscible with the reaction products and comprises a salt of general formula Q+A−, in which Q+ represents a quaternary ammonium and/or phosphonium and A− represents an anion; and a catalyst comprising a compound or a complex of a transition metal of groups 8, 9 and 10, optionally co-ordinated with a ligand containing at least one atom of phosphorus, arsenic, antimony or nitrogen, comprises addition to the medium, after the reaction section, of an organic solvent in a manner such as to improve the separation by demixing of the crude reaction products from the said polar phase, which is recycled to the reaction section.
摘要翻译：在极性相存在下，通过在反应段中与一氧化碳和氢气反应，在液相中加氢甲酰化烯属不饱和化合物的方法，该方法包括：非水离子液体，其至少部分地与反应产物并包含通式Q + A-的盐，其中Q +表示季铵和/或鏻，而A-代表阴离子;和催化剂，其包含化合物或第8,9族过渡金属的络合物和10，任选地与含有至少一个磷，砷，锑或氮原子的配体配位，包括在反应段之后向介质中加入有机溶剂，以便通过分层改进分离的来自所述极性相的粗反应产物，其被再循环到反应段。

5. 发明授权

US06501001B2 Process for selective dimerization of propylene principally into branched dimers 有权
标题翻译：主要将丙烯选择性二聚化为支化二聚体的方法
公开(公告)号：US06501001B2
公开(公告)日：2002-12-31
申请号：US09775555
申请日：2001-02-05
申请人： Dominique Commereuc , Dominique Le Pennec , Hélène Olivier-Bourbigou
发明人： Dominique Commereuc , Dominique Le Pennec , Hélène Olivier-Bourbigou
IPC分类号： C07C226
CPC分类号： C07C2/36 , C07C2527/053 , C07C2527/128 , C07C2531/02 , C07C2531/04 , C07C2531/22 , C07C2531/24 , C07C11/107
摘要： In order to carry out selective dimerization of propylene principally into branched dimers, a catalytic composition resulting from at least partly dissolving a nickel compound mixed or complexed with a tertiary phosphine carrying a functional group is used in a medium resulting from mixing at least one quaternary ammonium halide and/or at least one quaternary phosphonium halide, at least one aluminum halide and optionally at least one organometallic aluminum compound.
摘要翻译：为了将丙烯主要进行支化二聚体的选择性二聚反应，将至少部分溶解与携带有官能团的叔膦混合或络合的镍化合物的催化剂组合物用于混合至少一种季铵卤化物和/或至少一种卤化鏻，至少一种卤化铝和任选的至少一种有机金属铝化合物。

6. 发明授权

US06469216B2 Process for hydroformylation using a catalyst based on cobalt and/or rhodium employed in a two-phase medium 有权
标题翻译：使用在两相介质中使用的基于钴和/或铑的催化剂进行加氢甲酰化的方法
公开(公告)号：US06469216B2
公开(公告)日：2002-10-22
申请号：US09730795
申请日：2000-12-07
申请人： Gerhard Hillebrand , André Hirschauer , Dominique Commereuc , Hélène Olivier-Bourbigou , Lucien Saussine
发明人： Gerhard Hillebrand , André Hirschauer , Dominique Commereuc , Hélène Olivier-Bourbigou , Lucien Saussine
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C47/02
摘要： In an improved process for hydroformylation of olefinically unsaturated compounds using a catalyst based on cobalt and/or rhodium employed in a two-phase medium, a catalyst based on cobalt and/or rhodium is used dissolved in a non-aqueous ionic solvent which is liquid at a temperature of less than 90° C., in which the aldehydes formed are slightly soluble or insoluble. More particularly, the catalyst comprises at least one complex of cobalt and/or rhodium co-ordinated with at least one nitrogen-containing ligand and the non-aqueous ionic solvent comprises at least one quaternary ammonium and/or phosphonium cation and at least one inorganic anion. At the end of the reaction, the organic phase is generally separated and the ionic non-aqueous solvent phase containing the catalyst can be re-used.
摘要翻译：在使用基于在两相介质中使用的钴和/或铑的催化剂的烯属不饱和化合物的加氢甲酰基化的改进方法中，使用基于钴和/或铑的催化剂溶解在非水离子溶剂中，其为液体在低于90℃的温度下，形成的醛是微溶或不溶的。更具体地，催化剂包含与至少一种含氮配体配位的至少一种钴和/或铑配合物，非水离子溶剂包含至少一种季铵和/或鏻阳离子和至少一种无机阴离子在反应结束时，通常分离有机相，并且可以重新使用含有催化剂的离子非水溶剂相。

7. 发明授权

US06410799B1 Hydroformylation process employing a catalyst based on cobalt and/or rhodium in a non-aqueous ionic solvent 有权
标题翻译：在非水离子溶剂中使用基于钴和/或铑的催化剂的羰基化方法
公开(公告)号：US06410799B1
公开(公告)日：2002-06-25
申请号：US09935330
申请日：2001-08-23
申请人： Frédéric Favre , Dominique Commereuc , Hélène Olivier-Bourbigou , Lucien Saussine
发明人： Frédéric Favre , Dominique Commereuc , Hélène Olivier-Bourbigou , Lucien Saussine
IPC分类号： C07C4550
CPC分类号： C07C45/50 , C07C47/02
摘要： In a process for hydroformylation of olefinically unsaturated compounds using a catalyst based on cobalt and/or rhodium co-ordinated by at least one ligand selected from the group formed by nitrogen-containing or phosphorus-containing ligands used in a non-aqueous ionic solvent, which catalyst is liquid at a temperature of less than 90° C., in which the aldehydes formed are not or are only slightly soluble and which comprises at least one quaternary ammonium and/or phosphonium cation Q+ and at least one anion A−, the improvement of the invention consists in that in the cobalt and/or rhodium complex, the ligand also carries an ionic function (Q′)+(A′)− where Q and Q′ and/or A and A′ are chemically identical.
摘要翻译：在使用由选自由非水性离子溶剂中使用的含氮或含磷配位体形成的基团中的至少一种配体所协调的基于钴和/或铑的催化剂的烯属不饱和化合物的加氢甲酰化的方法中，该催化剂在低于90℃的温度下是液体，其中形成的醛不是或仅仅是微溶的，并且其包含至少一种季铵和/或鏻阳离子Q +和至少一种阴离子A-，本发明的改进在于在钴和/或铑络合物中，配体还带有离子功能（Q'）+（A'） - 其中Q和Q'和/或A和A'在化学上相同。

8. 发明申请

US20100022789A1 Catalytic compositions for the metathesis of unsaturated fatty bodies with olefins and metathesis methods using catalytic compositions 审中-公开
标题翻译：用于烯烃不饱和脂肪体复分解的催化组合物和使用催化组合物的复分解方法
公开(公告)号：US20100022789A1
公开(公告)日：2010-01-28
申请号：US12458856
申请日：2009-07-24
申请人： Gérard Mignani , Virginie Pevere , Hélène Olivier-Bourbigou , Christophe Vallee , Mikael Berthod , Cécilia Citadelle
发明人： Gérard Mignani , Virginie Pevere , Hélène Olivier-Bourbigou , Christophe Vallee , Mikael Berthod , Cécilia Citadelle
IPC分类号： C07C67/00 , C07F15/00 , C07C51/00
CPC分类号： B01J31/2273 , B01J31/2208 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C2531/22 , C07C69/533
摘要： Catalytic compositions useful for carrying out the metathesis of unsaturated fatty bodies, in particular unsaturated fatty bodies comprising oleic acid or oleic acid esters, contain a ruthenium-based catalyst which can be isolated and which has the formula (I) below:
摘要翻译：用于进行不饱和脂肪体，特别是包含油酸或油酸酯的不饱和脂肪酸的复分解的催化组合物含有可以被分离并具有下式（I）的钌基催化剂：

9. 发明授权

US07060860B2 Hydroformylation process employing a cobalt-based catalyst in a non-aqueous liquid with improved catalyst recycling 有权
标题翻译：在具有改进的催化剂再循环的非水液体中使用钴基催化剂的羰基化方法
公开(公告)号：US07060860B2
公开(公告)日：2006-06-13
申请号：US10411389
申请日：2003-04-11
申请人： Lionel Magna , Hélène Olivier-Bourbigou , Lucien Saussine , Virginie Kruger-Tissot
发明人： Lionel Magna , Hélène Olivier-Bourbigou , Lucien Saussine , Virginie Kruger-Tissot
IPC分类号： C07C45/50
CPC分类号： C07B41/06 , C07C45/50 , Y02P20/584 , C07C47/02
摘要： A process for hydroformylating olefinically unsaturated compounds by means of a cobalt-based catalyst is carried out in a non-aqueous ionic liquid which is a liquid at a temperature below 90° C. and comprises at least one ammonium and/or phosphonium and/or sulfonium cation Q+ and at least one anion A−; catalyst recycling is improved by using a ligand selected from the group consisting of Lewis bases and employing a depressurization step between the pressurized reaction step and the step for separating the phases by decanting. At the end of said depressurization step, the organic phase is separated in the decanting step and the non-aqueous ionic liquid containing the catalyst can be re-used.
摘要翻译：通过钴基催化剂加氢甲酰化烯属不饱和化合物的方法是在低于90℃的温度下为液体的非水性离子液体中进行的，并且包含至少一种铵和/或鏻和/或锍阳离子Q + +和至少一种阴离子A - 通过使用选自路易斯碱的配体和在加压反应步骤和通过倾析分离相的步骤之间的减压步骤来改善催化剂再循环。在所述减压步骤结束时，在倾析步骤中分离有机相，并且可以重新使用含有催化剂的非水性离子液体。

10. 发明授权

US06951831B2 Catalyst composition for dimerizing, co-dimerizing, oligomerizing and polymerizing olefins 有权
标题翻译：用于二聚，共二聚，低聚和聚合烯烃的催化剂组合物
公开(公告)号：US06951831B2
公开(公告)日：2005-10-04
申请号：US10356745
申请日：2003-02-03
申请人： Vincent Lecocq , Hélène Olivier-Bourbigou
发明人： Vincent Lecocq , Hélène Olivier-Bourbigou
IPC分类号： B01J31/22 , B01J31/02 , B01J31/18 , B01J31/28 , C07B61/00 , C07C2/26 , C07C2/34 , C07C11/02 , C07C11/08 , C07C11/107 , C08F4/70 , C08F4/80 , B01J71/00 , C07C2/02 , C07C2/24 , C08F4/44
CPC分类号： B01J31/2282 , B01J31/0284 , B01J31/0288 , B01J31/0289 , B01J31/1805 , B01J31/183 , B01J31/185 , B01J31/28 , B01J2231/12 , B01J2231/20 , B01J2531/847 , C07C2/26 , C07C2531/22 , C07C11/02
摘要： A catalyst composition for use in dimerizing, co-dimerizing or oligomerizing olefins comprises: at least one zero-valent nickel complex; at least one acid with formula H+X− in which X− represents an anion; and at least one ionic liquid with general formula Q+ A− in which A− is an anion identical to or different from X−. The composition can also comprise a nitrogen-containing ligand. It can be used in dimerizing, co-dimerizing, oligomerizing and in polymerizing olefins.
摘要翻译：用于使烯烃二聚，共二聚或低聚的催化剂组合物包括：至少一种零价镍络合物; 至少一种其中X为 - 表示阴离子的式Ⅳ+ X - - ;;;;;;;;;;;;;;;;;;; 和至少一种具有通式Q +，其中A是与X 1或X 2相同或不同的阴离子的至少一种离子液体， - 。组合物还可以包含含氮配体。它可用于二聚，共二聚，低聚和烯烃聚合。

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