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1. 发明申请

US20100113677A1 COMPOSITE BASED ON POLYLACTIC ACID AND A POLYAMIDE, HAVING IMPROVED IMPACT RESISTANCE, ITS MANUFACTURING PROCESS AND USE 失效
标题翻译：基于聚酰胺和聚酰胺的复合材料，具有改善的耐冲击性，其制造工艺和用途
公开(公告)号：US20100113677A1
公开(公告)日：2010-05-06
申请号：US12305141
申请日：2007-06-14
申请人： Benoit Brule , Thomas Fine , Jean-Jacques Flat , Maho Yasuda
发明人： Benoit Brule , Thomas Fine , Jean-Jacques Flat , Maho Yasuda
IPC分类号： C08L23/00 , C08L31/02 , C08L71/00 , B29C47/60
CPC分类号： C08L77/00 , C08L23/0846 , C08L23/0869 , C08L23/0884 , C08L67/04 , C08L2205/03 , C08L2666/02 , C08L2666/06 , C08L2666/18
摘要： The present invention relates to a composite having improved impact resistance. According to the invention, this composite is obtained from a composition comprising the following polymers: polylactic acid (PLA) which forms the matrix; at least one polyamide forming a dispersed phase within the PLA matrix; at least one functionalized polyolefin (A) comprising alpha-olefin units and epoxy, carboxylic acid or carboxylic acid anhydride units; and, optionally, at least one unfunctionnalized polyolefin (B).
摘要翻译：本发明涉及具有改善耐冲击性的复合材料。根据本发明，该复合材料由包含以下聚合物的组合物获得：聚乳酸（PLA），其形成基质; 至少一种在PLA基质内形成分散相的聚酰胺; 至少一种包含α-烯烃单元和环氧，羧酸或羧酸酐单元的官能化聚烯烃（A）; 和任选的至少一种未官能化的聚烯烃（B）。

2. 发明授权

US08076406B2 Composite based on polylactic acid and a polyamide, having improved impact strength, and its manufacturing process and use 失效
标题翻译：基于聚乳酸和聚酰胺的复合材料，具有改善的冲击强度，以及其制造方法和用途
公开(公告)号：US08076406B2
公开(公告)日：2011-12-13
申请号：US12305141
申请日：2007-06-14
申请人： Benoit Brule , Thomas Fine , Jean-Jacques Flat , Maho Yasuda
发明人： Benoit Brule , Thomas Fine , Jean-Jacques Flat , Maho Yasuda
IPC分类号： C08L67/04 , C08L77/00
CPC分类号： C08L77/00 , C08L23/0846 , C08L23/0869 , C08L23/0884 , C08L67/04 , C08L2205/03 , C08L2666/02 , C08L2666/06 , C08L2666/18
摘要： The present invention relates to a composite having improved impact resistance. According to the invention, this composite is obtained from a composition comprising the following polymers: polylactic acid (PLA) which forms the matrix; at least one polyamide forming a dispersed phase within the PLA matrix; at least one functionalized polyolefin (A) comprising alpha-olefin units and epoxy, carboxylic acid or carboxylic acid anhydride units; and, optionally, at least one unfunctionnalized polyolefin (B).
摘要翻译：本发明涉及具有改善耐冲击性的复合材料。根据本发明，该复合材料由包含以下聚合物的组合物获得：聚乳酸（PLA），其形成基质; 至少一种在PLA基质内形成分散相的聚酰胺; 至少一种包含α-烯烃单元和环氧，羧酸或羧酸酐单元的官能化聚烯烃（A）; 和任选的至少一种未官能化的聚烯烃（B）。

3. 发明申请

US20100087585A1 COMPOSITE MATERIAL BASED ON POLYAMIDE AND ON POLY(LACTIC ACID), MANUFACTURING PROCESS AND USE THEREOF 有权
标题翻译：基于聚酰胺和聚（酸）酸的复合材料，制造工艺及其用途
公开(公告)号：US20100087585A1
公开(公告)日：2010-04-08
申请号：US12524691
申请日：2008-01-29
申请人： Maho Yasuda , Nicolas Amouroux , Benoit Brule , Nadine Decraemer , Jean-Jacques Flat
发明人： Maho Yasuda , Nicolas Amouroux , Benoit Brule , Nadine Decraemer , Jean-Jacques Flat
IPC分类号： C08K3/40 , C08L77/00
CPC分类号： C08L77/02 , C08J5/10 , C08J2377/00 , C08J2377/02 , C08J2377/06 , C08K7/14 , C08L23/0869 , C08L23/0884 , C08L67/04 , C08L77/00 , C08L77/06 , C08L2666/02 , C08L2666/20 , C08L2666/18
摘要： The present invention relates to a composite obtained from a composition comprising: 50 (excluded) to 90% by weight of at least one polyamide; 10 to 50% by weight of polylactic acid (PLA); and 0 to 30% by weight of at least one compatibilizing agent. The present invention also relates to a process for manufacturing this composite and its use.
摘要翻译：本发明涉及一种由组合物得到的复合物，该组合物包含：50（不包括）至90重量％的至少一种聚酰胺; 10〜50重量％的聚乳酸（PLA）; 和0〜30重量％的至少一种相容剂。本发明还涉及这种复合材料的制造方法及其用途。

4. 发明授权

US09169392B2 Composite material based on polyamide and on poly(lactic acid), manufacturing process and use thereof 有权
标题翻译：基于聚酰胺和聚（乳酸）的复合材料，其制造方法和用途
公开(公告)号：US09169392B2
公开(公告)日：2015-10-27
申请号：US12524691
申请日：2008-01-29
申请人： Maho Yasuda , Nicolas Amouroux , Benoit Brule , Nadine Decraemer , Jean-Jacques Flat
发明人： Maho Yasuda , Nicolas Amouroux , Benoit Brule , Nadine Decraemer , Jean-Jacques Flat
IPC分类号： C08L77/00 , C08L67/04 , C08L23/08 , B29C43/00 , B29C45/00 , B29C47/00 , B29C51/00 , C08L77/02 , C08J5/10 , C08L77/06 , C08K7/14
CPC分类号： C08L77/02 , C08J5/10 , C08J2377/00 , C08J2377/02 , C08J2377/06 , C08K7/14 , C08L23/0869 , C08L23/0884 , C08L67/04 , C08L77/00 , C08L77/06 , C08L2666/02 , C08L2666/20 , C08L2666/18
摘要： The invention relates to a composite obtained from a composition comprising: 50 (excluded) to 90% by weight of at least one polyamide; 10 to 50% by weight of polylactic acid (PLA); and 0 to 30% by weight of at least one compatibilizing agent. The invention also relates to a process for manufacturing this composite and its use.
摘要翻译：本发明涉及一种由组合物获得的复合材料，所述组合物包含：50（不包括）至90重量％的至少一种聚酰胺; 10〜50重量％的聚乳酸（PLA）; 和0〜30重量％的至少一种相容剂。本发明还涉及这种复合材料的制造方法及其用途。

5. 发明申请

US20090314375A1 POLYAMIDE-BASED ANTISTATIC MULTILAYER TUBE FOR TRANSFERRING FLUIDS 审中-公开
标题翻译：用于转移流体的基于聚酰胺的抗静电多层管
公开(公告)号：US20090314375A1
公开(公告)日：2009-12-24
申请号：US12090756
申请日：2006-10-17
申请人： Jean-Jacques Flat , Gaelle Bellet , Nicolas Amouroux , Benoit Brule
发明人： Jean-Jacques Flat , Gaelle Bellet , Nicolas Amouroux , Benoit Brule
IPC分类号： F16L11/127
CPC分类号： B32B27/32 , B32B1/08 , B32B27/08 , B32B27/306 , B32B27/34 , B32B2270/00 , B32B2597/00 , F16L11/045 , F16L2011/047
摘要： The present invention relates to a multilayer tube comprising, in succession in its radial direction from the outside inwards: a nylon-11 or nylon-12 polyamide outer layer (1); a tie layer (2); an optional EVOH layer (3); an optional layer (4) made of PA-6 or a PA-6/polyolefin blend having a PA-6 matrix and polyolefin dispersed phase; an inner layer (5) based on PA-6 in contact with the transported fluid, comprising by weight, the total being 100%: 40 to 65% (advantageously 45 to 60%) of PA-6, 1 to 20% (advantageously 5 to 15%) of HDPE, 10 to 30% (advantageously 15 to 25%) of at least one polymer P1 chosen from impact modifiers and polyethylenes, either or both of the HDPE and the P1 being completely or partly functionalized and 5 to 30% (advantageously 15 to 30% and preferably 17 to 24%) of an electrically conductive material. The tube of the present invention has a very low permeability to petrol, particularly to hydrocarbons and to their additives, in particular alcohols such as methanol and ethanol or else ethers such as MTBE or ETBE. These tubes also have a very good resistance to fuels and lubricating oils for engines.This tube has very good mechanical properties at low temperature or at high temperature. The invention also relates to the use of these tubes for transporting petrol.
摘要翻译：本发明涉及一种多层管，其从外向内径向连续地包括：尼龙11或尼龙-12聚酰胺外层（1）; 连结层（2）; 可选的EVOH层（3）; 由PA-6制成的任选的层（4）或具有PA-6基体和聚烯烃分散相的PA-6 /聚烯烃共混物; 基于与所输送的流体接触的PA-6的内层（5），其包含重量百分比为100％：PA-6的40至65％（有利地为45至60％），1至20％ 5至15％）的HDPE，10至30％（有利地为15至25％）的选自抗冲改性剂和聚乙烯的至少一种聚合物P1，HDPE和P1中的任一种或两者完全或部分官能化，并且5至30 ％（有利地为15〜30％，优选为17〜24％）的导电性材料。本发明的管具有非常低的汽油渗透性，特别是对烃及其添加剂，特别是醇如甲醇和乙醇，或醚如MTBE或ETBE的渗透性极低。这些管也对发动机的燃料和润滑油具有非常好的抵抗力。该管在低温或高温下具有非常好的机械性能。本发明还涉及这些管用于运输汽油的用途。

6. 发明申请

US20060008604A1 Multilayer structure having a layer based on polyamide and on HDPE 审中-公开
标题翻译：具有基于聚酰胺和HDPE层的多层结构
公开(公告)号：US20060008604A1
公开(公告)日：2006-01-12
申请号：US11154422
申请日：2005-06-16
申请人： Jean-Jacques Flat , Gaelle Bellet , Benoit Brule , Philippe Blondel
发明人： Jean-Jacques Flat , Gaelle Bellet , Benoit Brule , Philippe Blondel
IPC分类号： B65D1/00
CPC分类号： B32B27/32 , Y10T428/1341 , Y10T428/1383
摘要： The present invention relates to a structure successively comprising: a first layer of high density polyethylene (HDPE), a tie layer, a second layer of EVOH or of a blend based on EVOH, optionally a tie layer, a third layer of a blend comprising, by weight, the total being 100%: 50 to 90% of polyamide (A) having a conversion temperature of at most 230° C., 1 to 30% of high density polyethylene (HDPE), 5 to 30% of an impact modifier chosen from elastomers and very low density polyethylenes, at least one of the HDPE and of the impact modifier being functionalized, in all or part, the layers being coextrudable. The present invention also relates to devices for the transfer or storage of fluids and more particularly to pipes, tanks, conduits, bottles and containers composed of the above structure in which the layer of the blend of polyamide (A) and of HDPE is in direct contact with the fluid present or transported
摘要翻译：本发明涉及一种结构，其连续包括：第一层高密度聚乙烯（HDPE），粘结层，第二层EVOH或基于EVOH的共混物，任选的粘结层，第三层共混物，包括，总重量为100％：转化温度为230℃以下的聚酰胺（A）为50〜90％，高密度聚乙烯（HDPE）为1〜30％，冲击强度为5〜30％选自弹性体和非常低密度聚乙烯的改性剂，HDPE和抗冲改性剂中的至少一种在全部或部分中被共同挤出。本发明还涉及用于转移或储存流体的装置，更具体地涉及由上述结构组成的管，罐，导管，瓶和容器，其中聚酰胺（A）和HDPE的共混物层直接与存在或运输的液体接触

7. 发明申请

US20060100375A1 Polyamide and polyolefin blends with a polyamide matrix and containing nanofillers 失效
标题翻译：聚酰胺和聚烯烃共混物与聚酰胺基质并含有纳米填料
公开(公告)号：US20060100375A1
公开(公告)日：2006-05-11
申请号：US11301153
申请日：2005-12-12
申请人： Jean-Jacques Flat , Benoit Barriere , Benoit Brule
发明人： Jean-Jacques Flat , Benoit Barriere , Benoit Brule
IPC分类号： C08L77/00 , C08K9/04 , C08F8/30 , C08K3/34
CPC分类号： C08L77/02 , B29C37/0075 , B32B27/20 , B32B27/34 , C08L23/0815 , C08L23/10 , C08L51/06 , C08L77/00 , C08L77/06 , C08L2205/08 , C08L2666/20 , C08L2666/06 , C08L2666/24
摘要： The present invention relates to polyamide (A) and polyolefin (B) blends containing nanofillers in which the polyamide forms the matrix. These blends can also be referred to as “polyamide (A), polyolefin (B) and nanofiller blends in which the polyamide forms the matrix”. The invention also relates to structures with barrier properties comprising at least one layer of these blends and optionally at least one layer of another material. These structures are a barrier to numerous fluids, and in particular to oxygen, to styrene, to fumigation fluids, to pentane and to air conditioning fluids. These structures can be made into bottles, reservoirs, containers, pipes and vessels of all sorts. They can also be converted to films which are used to make packagings.
摘要翻译：本发明涉及含有纳米填料的聚酰胺（A）和聚烯烃（B）共混物，其中聚酰胺形成基质。这些共混物也可以称为“聚酰胺（A），聚烯烃（B）和纳米填料共混物，其中聚酰胺形成基体”）。本发明还涉及具有阻挡性质的结构，其包含至少一层这些共混物和任选的至少一层其它材料。这些结构是许多流体，特别是氧气，苯乙烯，熏蒸流体，戊烷和空调流体的障碍。这些结构可以制成各种瓶子，水箱，容器，管道和各种容器。它们也可以转换成用于制造包装的胶片。

8. 发明授权

US08883899B2 Flame-retarded thermoplastic compositions of high thermomechanical strength, in particular for electric cables 有权
标题翻译：具有高热机械强度的阻燃热塑性组合物，特别是电缆
公开(公告)号：US08883899B2
公开(公告)日：2014-11-11
申请号：US13881491
申请日：2011-10-18
申请人： Dominique Jousset , Jean-Jacques Flat , Pierre Georlette
发明人： Dominique Jousset , Jean-Jacques Flat , Pierre Georlette
IPC分类号： H01B3/44 , F16L57/04 , C08L53/00 , C08G81/02 , C08L87/00 , C08L33/16
CPC分类号： H01B3/447 , C08G81/028 , C08L33/16 , C08L53/00 , C08L87/005 , F16L57/04
摘要： A flame-retarded thermoplastic composition including a graft copolymer containing polyamide blocks and composed of a polyolefin backbone and on average at least one polyamide graft, in which the grafts are attached to the backbone by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide, the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from its double bond, wherein the composition includes: —between 60% and 70% by weight of the graft copolymer containing polyamide blocks, —between 22% and 28% by weight of poly(pentabromobenzyl acrylate), —between 4% and 8% by weight of a synergistic flame retardant chosen from antimony trioxide, derivatives of tin, of molybdenum and/or bismuth and also boron and zinc oxides, calcium borates, calcium sulphate and/or zinc stannate, between 0.5% and 5% by weight of organophilic treated clay.
摘要翻译：一种阻燃热塑性组合物，其包含含有聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和平均至少一个聚酰胺接枝物组成，其中移植物通过具有功能的不饱和单体（X）的残基连接到主链上能够与聚酰胺反应，不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上，其中组合物包括：含有聚酰胺的接枝共聚物的60重量％至70重量％（聚丙烯酸五溴苄酯）的22重量％至28重量％，4重量％至8重量％的协同阻燃剂，其选自三氧化锑，锡，钼和/或铋的衍生物，以及硼和氧化锌，硼酸钙，硫酸钙和/或锡酸锌，占亲水处理粘土的0.5重量％至5重量％。

9. 发明授权

US07897673B2 Flexible high thermomechanical stress-resistant and fireproof halogen-free thermoplastic compositions 有权
标题翻译：柔软的高机械耐热和耐火无卤素热塑性组合物
公开(公告)号：US07897673B2
公开(公告)日：2011-03-01
申请号：US12303174
申请日：2007-06-01
申请人： Jean-Jacques Flat , Philippe Blondel , David Meslet
发明人： Jean-Jacques Flat , Philippe Blondel , David Meslet
IPC分类号： C08K3/32 , C08K3/34
CPC分类号： C09K21/12 , C08G81/028 , C08L23/02 , C09D5/18 , C09K21/04 , H01B7/295 , H01R13/527 , C08L2666/20
摘要： The invention concerns flexible high thermomechanical stress-resistant and fire retardant halogen-free thermoplastic compositions, comprising a polyamide block-graft copolymer consisting of a trunk and on average at least one polyamide graft, wherein the grafts are bound to the trunk by the residues of an unsaturated monomer (X) having a function capable of reacting with a polyamide at the amine-terminal, the unsaturated monomer residues (X) being bound on the trunk by grafting or copolymerization from the double bond thereof. The invention is characterized in that the compositions comprise a mixture: 50 to 70 wt. % of polyamide block copolymer, 25 to 35 wt. % of a flame-retardant agent selected among ammonium phosphates, phosphinates, pyrophosphates, and polyphosphates, about 2 wt. % of zeolite, or hydrotalcitemolecular sieves. Said compositions are particularly useful for making electric cables, electric components, for molding electrotechnical housings, or for making coating layers or thermal protection sleeves for fluid transfer lines in the automotive industry.
摘要翻译：本发明涉及柔性高的热机械应力阻力和阻燃无卤热塑性组合物，其包含由树干和平均至少一个聚酰胺接枝物组成的聚酰胺嵌段共聚物共聚物，其中移植物通过残留物具有能够在胺末端与聚酰胺反应的功能的不饱和单体（X），不饱和单体残基（X）通过从其双键接枝或共聚而结合在树干上。本发明的特征在于，所述组合物包含混合物：50至70wt。％的聚酰胺嵌段共聚物，25〜35重量％选自磷酸铵，次膦酸盐，焦磷酸盐和多磷酸盐的阻燃剂的百分比为约2重量％％的沸石或水分子分子筛。所述组合物特别可用于制造用于汽车工业中的流体输送线的电缆，用于模制电工技术外壳的电气部件或用于制造涂层或热保护套管。

10. 发明申请

US20100099817A1 FLEXIBLE THERMOPLASTIC COMPOSITION WITH IMPROVED RESISTANCE TO THE EFFECT OF OILS, AND USE OF SUCH A COMPOSITION 有权
标题翻译：具有改善耐油性的柔性热塑性组合物，以及这些组合物的使用
公开(公告)号：US20100099817A1
公开(公告)日：2010-04-22
申请号：US12526097
申请日：2008-02-06
申请人： Stephane Bizet , Jean-Jacques Flat
发明人： Stephane Bizet , Jean-Jacques Flat
IPC分类号： C08L77/00 , C08F287/00
CPC分类号： C08L51/08 , C08F255/00 , C08F255/02 , C08G81/028 , C08L23/0861 , C08L51/06 , C08L2666/24 , C08L2666/20 , C08L2666/02 , C08L2666/04
摘要： The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerisation from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.
摘要翻译：本发明涉及耐油性的老化作用的柔性热塑性组合物，所述组合物包含含聚酰胺嵌段的接枝共聚物，由聚烯烃骨架和至少一种聚酰胺接枝物组成。根据本发明，移植物通过具有可与包含胺末端或羧酸端的聚酰胺反应的功能的不饱和单体（X）的残基连接到芯上; 不饱和单体（X）的残基通过从其双键接枝或共聚而连接到主链上; 并且所述组合物包含40-90重量％的包含不饱和单体（X）的聚烯烃芯; 5〜40重量％的聚酰胺接枝物; 和5至40％的至少一种选自皂化乙烯/乙酸乙烯酯共聚物和聚酰胺的聚合物。

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