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1. 发明申请

US20080103263A1 Emulsifiable Polyisocyanate 审中-公开
标题翻译：可乳化聚异氰酸酯
公开(公告)号：US20080103263A1
公开(公告)日：2008-05-01
申请号：US11660775
申请日：2005-09-02
申请人： Bedri Erdem , Jorge Jimenez , Debkumar Bhattacharjee , John N. Argyropoulos
发明人： Bedri Erdem , Jorge Jimenez , Debkumar Bhattacharjee , John N. Argyropoulos
IPC分类号： C08L63/00
CPC分类号： C08G18/753 , C08G18/706 , C08G18/757 , C08G18/792 , C09D175/04
摘要： The present invention is to emulsifiable polyisocyanate compositions comprising the reaction product of (i) an aliphatic polyisocyanate and (ii) an emulsifier wherein the polyisocyanate comprises a mixture of two or more isomers of cis-1,3-bis(isocyanatomethyl)cyclohexane, trans-1,3-bis(isocyanatomethyl)cyclohexane, cis-1,4-bis(isocyanatomethyl)cyclohexane or trans-1,4-bis(isocyanatomethyl)cyclohexane, with the proviso said isomeric mixture comprises at least about 5 weight percent of said trans-1,4-bis(isocyanatomethyl)cyclohexane. The emulsifiable polyisocyanates are particularly in formulations for producing paints and varnishes, coatings, adhesives, impregnating materials and sealants.
摘要翻译：本发明涉及可乳化的多异氰酸酯组合物，其包含（i）脂族多异氰酸酯和（ii）乳化剂的反应产物，其中所述多异氰酸酯包含顺式-1,3-双（异氰酸酯基甲基）环己烷的两种或多种异构体的混合物，反式 1,3-双（异氰酸根合甲基）环己烷，顺式-1,4-双（异氰酸甲酯基）环己烷或反式-1,4-双（异氰酸甲酯基）环己烷，条件是所述异构体混合物包含至少约5重量％反式-1,4-双（异氰酸甲酯基）环己烷。可乳化的多异氰酸酯特别是用于制备油漆和清漆，涂料，粘合剂，浸渍材料和密封剂的制剂。

2. 发明申请

US20120035318A1 POLYURETHANE DISPERSION, METHOD OF PRODUCING THE SAME, COATED ARTICLES, AND METHOD FOR COATING ARTICLES 有权
标题翻译：聚氨酯分散体，其制造方法，涂层制品及涂料方法
公开(公告)号：US20120035318A1
公开(公告)日：2012-02-09
申请号：US13262572
申请日：2010-02-08
申请人： Bedri Erdem , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Paul Foley , Debkumar Bhattacharjee
发明人： Bedri Erdem , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Paul Foley , Debkumar Bhattacharjee
IPC分类号： C09D175/04
CPC分类号： C08G18/6662 , B32B27/40 , C08G18/0819 , C08G18/0823 , C08G18/36 , C09D175/04
摘要： The instant invention is a polyurethane dispersion, method of producing the same, coated articles, and method for coating articles. The polyurethane dispersion according to the present inventions includes (a) one or more polyurethane units derived from one or more prepolymers wherein the one or more prepolymers comprise the reaction product of a mixture dissolved in dipropylene glycol dimethyl ether in the presence of one or more first surfactants with one or more isocyanates, wherein the mixture comprises one or more natural oil based polyols, and one or more adipate polyols, and optionally one or more short diols; and (b) water.
摘要翻译：本发明是一种聚氨酯分散体，其制备方法，涂覆制品和用于涂覆制品的方法。根据本发明的聚氨酯分散体包括（a）一种或多种衍生自一种或多种预聚物的聚氨酯单元，其中一种或多种预聚物包含溶解在二丙二醇二甲醚中的混合物的反应产物，在一种或多种第一具有一种或多种异氰酸酯的表面活性剂，其中所述混合物包含一种或多种天然油基多元醇，和一种或多种己二酸酯多元醇，以及任选的一种或多种短二醇; 和（b）水。

3. 发明申请

US20120053292A1 POLYURETHANE DISPERSION, METHOD OF PRODUCING THE SAME, COATED ARTICLES, AND METHOD FOR COATING ARTICLES 有权
标题翻译：聚氨酯分散体，其制造方法，涂层制品及涂料方法
公开(公告)号：US20120053292A1
公开(公告)日：2012-03-01
申请号：US13262574
申请日：2010-03-31
申请人： Bedri Erdem , Debkumar Bhattacharjee , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Suresh Subramonian
发明人： Bedri Erdem , Debkumar Bhattacharjee , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Suresh Subramonian
IPC分类号： C09D175/04
CPC分类号： C08G18/36 , C08G18/0823 , C08G18/0866 , C08G18/3212 , C08G18/3228 , C09D175/04 , Y10T428/31551
摘要： The instant invention is a polyurethane dispersion, method of producing the same, coated articles, and method of coating articles. The polyurethane dispersion according to the instant invention comprises (a) one or more polyurethane units derived from one or more prepolymers, wherein the one or more prepolymers comprise the reaction product of one or more natural oil based polyols dissolved in dipropylene glycol dimethyl ether in the presence of one or more first surfactants with one or more isocyanates; and (b) water.
摘要翻译：本发明是聚氨酯分散体，其制造方法，涂布制品，以及涂布物品的方法。根据本发明的聚氨酯分散体包含（a）一种或多种衍生自一种或多种预聚物的聚氨酯单元，其中一种或多种预聚物包含一种或多种溶于二丙二醇二甲醚中的天然油基多元醇的反应产物一种或多种第一表面活性剂与一种或多种异氰酸酯的存在; 和（b）水。

4. 发明授权

US07232859B2 Polyurethane dispersion and articles prepared therefrom 有权
标题翻译：聚氨酯分散体及其制备的制品
公开(公告)号：US07232859B2
公开(公告)日：2007-06-19
申请号：US10531944
申请日：2003-10-28
申请人： John N. Argyropoulos , Paul Foley , Debkumar Bhattacharjee , Bedri Erdem
发明人： John N. Argyropoulos , Paul Foley , Debkumar Bhattacharjee , Bedri Erdem
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , B32B27/00
CPC分类号： C08G18/757 , C08G18/0823 , C08G18/12 , C08G18/283 , C08G18/4018 , C08G18/4277 , C08G18/4854 , C08G18/664 , C08G18/6692 , Y10T428/31551 , C08G18/302 , C08G18/3234 , C08G18/3228
摘要： The present invention is to a polyurethane dispersion and products produced therefrom wherein the dispersion contains a polyurethane prepolymer produced from the a reaction of an excess of a polyisocyanate with an isocyanate reactive molecule wherein the polyisocyanate is a bis(isocyanatomethyl)cyclohexane. Preferably the isocyanate comprises (i) trans-1,4-bis(isocyanatomethyl)cyclohexane or (ii) an isomeric mixture of two or more of cis-1,3-bis(isocyanatomethyl)cyclohexane, trans-1,3-bis(isocyanatomethyl)cyclohexane, cis-1,4-bis(isocyanatomethyl)cyclohexane and trans-1,4-bis(isocyanatomethyl)cyclohexane, with the proviso said isomeric mixture comprises at least about 5 weight percent of said trans-1,4-bis(isocyanatomethyl)cyclohexane.
摘要翻译：本发明涉及聚氨酯分散体及其制备的产品，其中分散体含有由过量的多异氰酸酯与异氰酸酯反应性分子的反应生成的聚氨酯预聚物，其中多异氰酸酯是双（异氰酸酯基甲基）环己烷。优选地，异氰酸酯包含（i）反式-1,4-双（异氰酸甲酯基）环己烷或（ii）顺式-1,3-双（异氰酸甲酯基）环己烷，反式-1,3-双（异氰酸根合甲基）异氰酸酯基甲基）环己烷，顺式-1,4-双（异氰酸甲酯基）环己烷和反式-1,4-双（异氰酸甲酯基）环己烷，条件是所述异构体混合物包含至少约5重量％的所述反式-1,4-双（异氰酸甲酯基）环己烷。

5. 发明授权

US09512262B2 Polyurethane dispersion, method of producing the same, coated articles, and method for coating articles 有权
标题翻译：聚氨酯分散体，其制造方法，涂布制品和涂布物品的方法
公开(公告)号：US09512262B2
公开(公告)日：2016-12-06
申请号：US13262572
申请日：2010-02-08
申请人： Bedri Erdem , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Paul Foley , Debkumar Bhattacharjee
发明人： Bedri Erdem , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Paul Foley , Debkumar Bhattacharjee
IPC分类号： C08G18/08 , C08G18/36 , C08G18/66 , C09D175/04 , B32B27/40
CPC分类号： C08G18/6662 , B32B27/40 , C08G18/0819 , C08G18/0823 , C08G18/36 , C09D175/04
摘要： The instant invention is a polyurethane dispersion, method of producing the same, coated articles, and method for coating articles. The polyurethane dispersion according to the present inventions includes (a) one or more polyurethane units derived from one or more prepolymers wherein the one or more prepolymers comprise the reaction product of a mixture dissolved in dipropylene glycol dimethyl ether in the presence of one or more first surfactants with one or more isocyanates, wherein the mixture comprises one or more natural oil based polyols, and one or more adipate polyols, and optionally one or more short diols; and (b) water.
摘要翻译：本发明是一种聚氨酯分散体，其制备方法，涂覆制品和用于涂覆制品的方法。根据本发明的聚氨酯分散体包括（a）一种或多种衍生自一种或多种预聚物的聚氨酯单元，其中一种或多种预聚物包含溶解在二丙二醇二甲醚中的混合物的反应产物，在一种或多种第一具有一种或多种异氰酸酯的表面活性剂，其中所述混合物包含一种或多种天然油基多元醇，和一种或多种己二酸酯多元醇，以及任选的一种或多种短二醇; 和（b）水。

6. 发明授权

US08927646B2 Polyurethane dispersion, method of producing the same, coated articles, and method for coating articles 有权
标题翻译：聚氨酯分散体，其制造方法，涂布制品和涂布物品的方法
公开(公告)号：US08927646B2
公开(公告)日：2015-01-06
申请号：US13262574
申请日：2010-03-31
申请人： Bedri Erdem , Debkumar Bhattacharjee , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Suresh Subramonian
发明人： Bedri Erdem , Debkumar Bhattacharjee , Kumar Nanjundiah , John N. Argyropoulos , Michael C. Kaufman , Jihui Guo , Suresh Subramonian
IPC分类号： C08G18/36 , C09D175/04 , C08G18/08 , C08G18/32
CPC分类号： C08G18/36 , C08G18/0823 , C08G18/0866 , C08G18/3212 , C08G18/3228 , C09D175/04 , Y10T428/31551
摘要： The instant invention is a polyurethane dispersion, method of producing the same, coated articles, and method of coating articles. The polyurethane dispersion according to the instant invention comprises (a) one or more polyurethane units derived from one or more prepolymers, wherein the one or more prepolymers comprise the reaction product of one or more natural oil based polyols dissolved in dipropylene glycol dimethyl ether in the presence of one or more first surfactants with one or more isocyanates; and (b) water.
摘要翻译：本发明是聚氨酯分散体，其制造方法，涂布制品，以及涂布物品的方法。根据本发明的聚氨酯分散体包含（a）一种或多种衍生自一种或多种预聚物的聚氨酯单元，其中一种或多种预聚物包含一种或多种溶于二丙二醇二甲醚中的天然油基多元醇的反应产物一种或多种第一表面活性剂与一种或多种异氰酸酯的存在; 和（b）水。

7. 发明申请

US20110077345A1 PRESSURE SENSITIVE ADHESIVE COMPOSITIONS AND METHOD OF MAKING THE SAME 审中-公开
标题翻译：压敏粘合剂组合物及其制备方法
公开(公告)号：US20110077345A1
公开(公告)日：2011-03-31
申请号：US12995534
申请日：2009-06-02
申请人： Bedri Erdem , Debkumar Bhattacharjee , Keith Andes
发明人： Bedri Erdem , Debkumar Bhattacharjee , Keith Andes
IPC分类号： C09J175/04
摘要： The instant invention is a pressure sensitive adhesive composition comprising an ultra-high solid polyurethane dispersion. The ultra-high solid polyurethane dispersion comprises (1) a first component comprising a first polyurethane prepolymer comprising the reaction product of a polyol and polyisocyanate, (2) a second component comprising a media phase selected from the group consisting of a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, and combinations thereof; and (3) optionally a chain extender. The ultra-high solid polyurethane dispersion has at least a solid content of at least 60 percent by weight of solid content, based on the total weight of the ultra-high solid polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C. using spindle #4 with Brookfield viscometer.
摘要翻译：本发明是包含超高固含量聚氨酯分散体的压敏粘合剂组合物。超高固体聚氨酯分散体包括（1）包含第一聚氨酯预聚物的第一组分，所述第一聚氨酯预聚物包含多元醇和多异氰酸酯的反应产物，（2）第二组分，其包含介质相，其选自第二聚氨酯预聚物乳液，低固含量聚氨酯分散体，种子胶乳及其组合; 和（3）任选的扩链剂。基于超高固体聚氨酯分散体的总重量，超高固含量聚氨酯分散体至少具有至少60重量％固体含量的固体含量，并且在20rpm时粘度小于5000cps 21°C，使用纺锤＃4与布鲁克菲尔德粘度计。

8. 发明授权

US08349945B2 Composite dispersion, method of producing the same, and articles made therefrom 有权
标题翻译：复合分散体，其制造方法以及由其制成的制品
公开(公告)号：US08349945B2
公开(公告)日：2013-01-08
申请号：US12994999
申请日：2009-05-27
申请人： David L. Malotky , Sarah T. Eckersley , Bedri Erdem , Debkumar Bhattacharjee
发明人： David L. Malotky , Sarah T. Eckersley , Bedri Erdem , Debkumar Bhattacharjee
IPC分类号： C08L83/07 , C08L67/00 , C08L71/02
CPC分类号： C08L83/04 , C08J3/05 , C08L23/16 , C08L33/04 , C08L63/00
摘要： The instant invention is a composite dispersion, method of producing the same, and articles made therefrom. The composite dispersion according to the instant invention comprises (1) a first seed dispersion comprising (a) a first internal phase; and (b) an external phase, and (2) a second internal phase; wherein the composite dispersion comprises more than 60 percent by the combined weight of the first internal phase and the second internal phase, and the composite dispersion has a viscosity of less than 10,000 cP measured by RV4 spindle at 20 rpm at greater than 60 weight percent total internal phase, and wherein the composite dispersion has a bimodal particle size distribution and a particle size ratio (P2/P1) in the range of 2 to 200. The first internal phase comprises a first hydrophobic material selected from the group consisting of alkyd, silicone, polyolefin, polyurethane, epoxy, emulsion polymer, and polyester. The external phase comprises water. The second internal phase comprises a second hydrophobic material selected from the group consisting of alkyd, silicone, polyurethane prepolymer, epoxy, and polyester.
摘要翻译：本发明是一种复合分散体，其制备方法和由其制成的制品。根据本发明的复合分散体包含（1）第一种子分散体，其包含（a）第一内相; 和（b）外部相，和（2）第二内部相; 其中所述复合分散体包含多于60％的第一内相和第二内相的组合重量，并且所述复合分散体具有通过RV4主轴在20rpm下以大于60重量％的总量测量的小于10,000cP的粘度内部相，并且其中所述复合分散体具有2至200范围内的双峰粒度分布和粒径比（P2 / P1）。所述第一内相包含选自醇酸树脂，硅氧烷，聚烯烃，聚氨酯，环氧树脂，乳液聚合物和聚酯。外部相包括水。第二内相包括选自醇酸树脂，硅氧烷，聚氨酯预聚物，环氧树脂和聚酯的第二疏水材料。

9. 发明申请

US20110077348A1 SEALANT COMPOSITION 审中-公开
标题翻译：密封组合物
公开(公告)号：US20110077348A1
公开(公告)日：2011-03-31
申请号：US12995532
申请日：2009-06-02
申请人： Bedri Erdem , Li Zhang , Debkumar Bhattacharjee , YI Jin
发明人： Bedri Erdem , Li Zhang , Debkumar Bhattacharjee , YI Jin
IPC分类号： C08L75/04
CPC分类号： C08G18/283 , C08G18/4808 , C08G18/4833 , C08G18/4891 , C08G18/758 , C08G2170/40 , C08G2270/00 , C08L2666/04 , C08L2666/20 , C09J175/08
摘要： The instant invention is a sealant composition comprising an ultra-high solid polyurethane dispersion. The ultra-high solid polyurethane dispersion comprises (1) a first component comprising a first polyurethane prepolymer comprising the re-action product of a natural oil based polyol and polyisocyanate, (2) a second component comprising a media phase selected from the group consisting of a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, and combinations thereof; and (3) optionally a chain extender. The ultra-high solid polyurethane dispersion has at least a solid content of at least 60 percent by weight of solid content, based on the total weight of the ultra-high solid polyurethane dispersion, and a viscosity of less than 5000 cps at 20 rpm at 21° C. using spindle #4 with Brookfield viscometer.
摘要翻译：本发明是一种包含超高固含量聚氨酯分散体的密封剂组合物。超高固体聚氨酯分散体包含（1）第一组分，其包含第一聚氨酯预聚物，其包含天然油基多元醇和多异氰酸酯的反作用产物，（2）第二组分，其包含介质相，其选自第二聚氨酯预聚物乳液，低固含量聚氨酯分散体，种子胶乳及其组合; 和（3）任选的扩链剂。基于超高固体聚氨酯分散体的总重量，超高固含量聚氨酯分散体至少具有至少60重量％固体含量的固体含量，并且在20rpm时粘度小于5000cps 21°C，使用纺锤＃4与布鲁克菲尔德粘度计。

10. 发明授权

US08821983B2 Ultra-high solid content polyurethane dispersion and a continuous process for producing ultra-high solid content polyurethane dispersions 有权
公开(公告)号：US08821983B2
公开(公告)日：2014-09-02
申请号：US12519831
申请日：2007-12-19
申请人： Bedri Erdem , Debkumar Bhattacharjee
发明人： Bedri Erdem , Debkumar Bhattacharjee
IPC分类号： B05D3/02 , C08G18/12 , C08G18/32 , C08G18/30 , C08G18/28 , C08G18/40 , C08G18/42 , C08G18/48 , C08G18/62
CPC分类号： C08G18/12 , B05D3/02 , C08G18/283 , C08G18/302 , C08G18/3225 , C08G18/4018 , C08G18/4277 , C08G18/4808 , C08G18/4833 , C08G18/4841 , C08G18/6216 , C08G2190/00 , C08G2270/00
摘要： The instant invention is an ultra-high solid content polyurethane dispersion, and a continuous process for producing ultra-high solid content polyurethane dispersions. The ultra-high solid content polyurethane dispersion includes the reaction product of: (1) a first component, wherein the first component is a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; (2) a second component, wherein the second component is a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a low solid content polyurethane dispersion, a seed latex, or combinations thereof; (3) and a chain extender. The ultra-high solid content polyurethane dispersion has a solid content of at least 60 percent by weight of the solid, based on the total weight of the ultra-high solid content polyurethane dispersion, and a viscosity in the range of less than 5000 cps at 20 rpm at 21° C. using spindle #4 with Brookfield viscometer. The method for producing a high-solid content polyurethane dispersion includes the following steps: (1) providing a first stream, wherein said first stream comprising a first polyurethane prepolymer or a first polyurethane prepolymer emulsion; (2) providing a second stream, wherein said second stream being a media phase selected from the group consisting of a second polyurethane prepolymer, a second polyurethane prepolymer emulsion, a polyurethane prepolymer dispersion, a seed latex emulsion, or combinations thereof; (3) continuously merging said first stream with said second stream in the presence of a chain extender; and (4) thereby forming a polyurethane dispersion having a solid content of at least 60 percent by weight of the solid, based on the total weight of the ultra-high solid content polyurethane dispersion, and a viscosity in the range of less than 5000 cps at 20 rpm at 21° C. using spindle #4 with Brookfield viscometer.

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