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1. 发明授权

US4992380A Continuous on-stream monitoring of cooling tower water 失效
标题翻译：连续在线监测冷却塔水
公开(公告)号：US4992380A
公开(公告)日：1991-02-12
申请号：US258131
申请日：1988-10-14
申请人： Barbara E. Moriarty , James J. Hickey , Wayne H. Hoy , John E. Hoots , Donald A. Johnson
发明人： Barbara E. Moriarty , James J. Hickey , Wayne H. Hoy , John E. Hoots , Donald A. Johnson
IPC分类号： F28G13/00 , C23F11/00 , F28F19/01 , F28F27/00 , G01N33/18
CPC分类号： G01N33/1893 , F28F19/00 , F28F25/00 , Y10T436/12
摘要： The performance of a treating agent added to a body of water employed in a cooling tower is continuously monitored by real-time analysis of a spectral or chemical characteristic of an inert tracer proportioned to the treating agent, said characteristic being indicative of tracer concentration, and converted to a voltage analog. The voltage analog is compared to a monitor value representing par performance and if performance is nonstandard (nonpar) a signal is generated which alters the output of a pump which feeds the dosage of treating agent containing proportioned tracer.

2. 发明授权

US06312644B1 Fluorescent monomers and polymers containing same for use in industrial water systems 有权
标题翻译：含有相同用途的荧光单体和聚合物用于工业水系统
公开(公告)号：US06312644B1
公开(公告)日：2001-11-06
申请号：US09465146
申请日：1999-12-16
申请人： Barbara E. Moriarty , Mingli Wei , John E. Hoots , David P. Workman , Jeffrey P. Rasimas
发明人： Barbara E. Moriarty , Mingli Wei , John E. Hoots , David P. Workman , Jeffrey P. Rasimas
IPC分类号： C23F1110
CPC分类号： C09K11/06 , C02F1/50
摘要： Fluorescent monomers of the formula wherein M is selected from the group consisting of hydrogen, sodium, potassium, cesium, rubidium, lithium and ammonium, and n is selected from the group consisting of 1, 2, 3, 4, 6 and 9; are provided which are useful in the production of pyranine-tagged polymers which can be detected using a fluorometer and can be used in industrial water systems as treatment polymers.
摘要翻译：马来酰亚胺M的荧光单体选自氢，钠，钾，铯，铷，锂和铵，n选自1,2,3,4,6和9组;其中可用于生产可以使用荧光计检测并可用于工业水系统中的吡喃标记聚合物作为处理聚合物。

3. 发明授权

US06280635B1 Autocycle control of cooling water systems 有权
标题翻译：自动循环控制冷却水系统
公开(公告)号：US06280635B1
公开(公告)日：2001-08-28
申请号：US09562603
申请日：2000-05-01
申请人： Barbara E. Moriarty , Dennis P. Bakalik , Ronald V. Davis , John E. Hoots , Robert W. Shiely
发明人： Barbara E. Moriarty , Dennis P. Bakalik , Ronald V. Davis , John E. Hoots , Robert W. Shiely
IPC分类号： C02F100
CPC分类号： G01N17/008 , C02F1/008 , C02F5/08 , C02F2103/023 , C02F2209/40 , C02F2303/08 , C02F2303/20 , G01N33/18 , G01N33/1853 , G01N33/1866 , Y10T137/0329
摘要： An autocycle method to control a cooling water system comprising the steps of: a) adding a treatment product to said cooling water system, with said treatment product comprising inert tracer and tagged treatment polymer in a set proportion; b) providing a sufficient number of fluorometers, c) using said sufficient number of fluorometers to measure the fluorescent signal of said inert tracer and the fluorescent signal of said tagged treatment polymer in the water from the cooling water system; d) using these measured fluorescent signals from step c) to determine the amount of said tagged treatment polymer present in said cooling water system; e) comparing the amount of said tagged treatment polymer present to the amount of tagged treatment polymer being fed into the system to determine the consumption of said tagged treatment polymer; and f) using said consumption of said tagged treatment polymer to control the concentration cycles of said cooling water system, with the proviso that said control is implemented by linking any or all of the following parameters i) the flowrate of the make-up water to the cooling water system; ii) the flowrate of the treatment product comprising inert tracer and tagged treatment polymer, iii) frequency and amount of blowdown flowrate from the cooling water system; iv) overall water flowrate through the cooling tower; v) overall volume of water in the cooling tower; and vi) composition of makeup water; to the consumption of said tagged treatment polymer, with the provisos that: &agr;) the minimum flowrate of treatment product comprising inert tracer and tagged treatment polymer must be sufficient to supply the cooling water system with the requisite amount of tagged treatment product; and &bgr;) when control is implemented by linking flowrates, the flowrates are balanced.
摘要翻译：一种用于控制冷却水系统的自动循环方法，包括以下步骤：a）向所述冷却水系统中加入处理产物，所述处理产物包含惰性示踪剂和标记处理聚合物，其设定比例; b）提供足够数量的荧光计 c）使用所述足够数量的荧光计测量来自冷却水系统的所述惰性示踪剂的荧光信号和所述标记的处理聚合物的荧光信号; d）使用来自步骤c）的这些测量的荧光信号来确定存在于所述冷却水体系中的所述标记的处理聚合物的量; e）将所述标记的处理聚合物的存在量与进料到系统中的标记处理聚合物的量进行比较，以确定所述标记的处理聚合物的消耗; 以及f）使用所述标记的处理聚合物的所述消耗来控制所述冷却水系统的浓缩循环，条件是通过将补充水的流量与冷却水的任何或全部连接来实现所述控制水系统; ii）包含惰性示踪剂和标记处理聚合物的处理产品的流量，iii）来自冷却水系统的排放流量的频率和量; iv）通过冷却塔的总体水流量; v）总体积的水冷却塔; 和）维生素水的组成;对所述标记的处理聚合物的消耗，条件是：α）包含惰性示踪剂和带标签的处理聚合物的处理产物的最小流速必须足以向冷却水系统提供必需量的标记治疗产品; andbeta）当通过连接流量来实现控制时，流量平衡。

4. 发明授权

US5049310A Zinc stabilization with modified acrylamide based polymers and corrosion inhibition derived therefrom 失效
标题翻译：具有改性丙烯酰胺基聚合物的锌稳定化及其衍生的腐蚀抑制
公开(公告)号：US5049310A
公开(公告)日：1991-09-17
申请号：US419567
申请日：1989-10-10
申请人： Donald A. Johnson , John E. Hoots , Dodd W. Fong , Guy A. Crucil
发明人： Donald A. Johnson , John E. Hoots , Dodd W. Fong , Guy A. Crucil
IPC分类号： C02F5/12 , C23F11/08
CPC分类号： C02F5/125 , C23F11/08 , C23F11/173 , C23F14/02
摘要： New zinc stabilizing polymers containing at least 5 mole percent of a monomer represented by the structure: ##STR1## wherein: R is independently, at each occurrence, chosen from H and lower (C.sub.1 -C.sub.4) alkyl groups;R' is a hydrocarbonaceous bridging group containing from 1-12 carbon atoms;X is chosen from --SO.sub.3 M, --OH, --COOM groups or mixtures thereof,M is hydrogen or some other cation species; andn ranges from 1-10,are described. Also, the use of these polymers in combination with zinc salts, and in further combination with phosphate salts, to inhibit corrosion of iron containing metals, and other metals, when these metals are exposed to industrial waters is demonstrated. Deposit control or scale inhibition on these metals exposed to industrial waters is also observed.
摘要翻译：含有至少5摩尔％的由以下结构表示的单体的新的锌稳定化聚合物：其中：R各自独立地选自H和低级（C 1 -C 4）烷基; R'是含有1-12个碳原子的烃基桥联基团; X选自-SO 3 M，-OH，-COOM基团或其混合物，M是氢或一些其它阳离子物质; 并描述n的范围为1-10。此外，证明了当这些金属暴露于工业水中时，这些聚合物与锌盐的组合以及与磷酸盐的进一步组合用于抑制含铁金属和其它金属的腐蚀。也观察到暴露于工业水域的这些金属的沉积物控制或垢垢抑制。

5. 发明授权

US4966711A Transition metals as treatment chemical tracers 失效
标题翻译：过渡金属作为治疗化学示踪剂
公开(公告)号：US4966711A
公开(公告)日：1990-10-30
申请号：US315713
申请日：1989-02-27
申请人： John E. Hoots , Rodney H. Banks , Donald A. Johnson
发明人： John E. Hoots , Rodney H. Banks , Donald A. Johnson
IPC分类号： C02F1/00 , G01N33/18
CPC分类号： G01N33/1813 , G01N33/182 , Y10T436/13
摘要： Methods for utilizing transition metals as tracers in aqueous liquid systems are provided by this invention. Transition metals with low background levels in system waters are identified as preferred when soluble in said aqueous liquid systems. The transition metals show low levels of deposition on equipment scale and provide reliable information as to the process history of the liquid systems.

6. 发明授权

US4801388A Modified acrylamide polymers used as scale inhibitors 失效
标题翻译：用作阻垢剂的改性丙烯酰胺聚合物
公开(公告)号：US4801388A
公开(公告)日：1989-01-31
申请号：US934598
申请日：1986-11-25
申请人： Dodd W. Fong , John E. Hoots , Donald A. Johnson
发明人： Dodd W. Fong , John E. Hoots , Donald A. Johnson
IPC分类号： C02F5/12 , C02F5/14 , C02F5/10
CPC分类号： C02F5/12 , C02F5/14
摘要： Water supplies are treated to inhibit the formation of scale deposits of alkaline earth phosphates, phosphonates, sulphates and carbonates using various hydrocarbon polymers which contain an amido functionality and which have been prepared by post-polymerization derivatization.
摘要翻译：处理水源以抑制碱土磷酸盐，膦酸盐，硫酸盐和碳酸盐的水垢沉积物的形成，其使用含有酰氨基官能团并且通过后聚合衍生化制备的各种烃聚合物。

7. 发明授权

US4923634A Cooling water corrosion inhibition method 失效
标题翻译：冷却水腐蚀抑制方法
公开(公告)号：US4923634A
公开(公告)日：1990-05-08
申请号：US155393
申请日：1988-02-12
申请人： John E. Hoots , Donald A. Johnson , Dodd W. Fong , James F. Kneller
发明人： John E. Hoots , Donald A. Johnson , Dodd W. Fong , James F. Kneller
IPC分类号： C23F11/08
CPC分类号： C23F11/08
摘要： A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, where R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms,and substituted alkyl of from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide, (poly)carboxy and (poly)hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.
摘要翻译：一种通过用含有能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐的组合物给予水，并且含有至少为6.5的烃聚合物的含有硬度和pH至少为6.5的工业冷却水中的腐蚀的方法具有酰胺结构的N-取代丙烯酰胺聚合物如下：其中R 2是氢或甲基，其中R 1是氢或烷基，R是亚烷基或亚苯基，X是磺酸根，（多）羟基，（聚）羧基或羰基，及其组合; 或含有具有N-取代的马来酰胺酸单元，N-取代的马来酰亚胺单元和具有如下结构的马来酸（和盐）单元的衍生化马来酸酐均聚物，共聚物和三元共聚物：其中R 1，R 2和R 3各自为独立地选自氢，羟基，羧基烷基，羧基酰胺，苯基，取代的苯基，1至10个碳原子的直链或支链烷基和1至10个碳原子的取代烷基，其中取代基是膦酸; 次膦酸磷酸酯; 磺酸硫酸酯，羧酰胺，（多）羧基和（多）羟基，烷氧基和羧酸酯基团; 及其组合。

8. 发明授权

US4929425A Cooling water corrosion inhibition method 失效
标题翻译：冷却水腐蚀抑制方法
公开(公告)号：US4929425A
公开(公告)日：1990-05-29
申请号：US155397
申请日：1988-02-12
申请人： John E. Hoots , Donald A. Johnson , Dodd W. Fong , James F. Kneller
发明人： John E. Hoots , Donald A. Johnson , Dodd W. Fong , James F. Kneller
IPC分类号： C23F11/08
CPC分类号： C23F11/08
摘要： A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, where R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms, and substituted alkyl or from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide, (poly)carboxy and (poly)hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.
摘要翻译：一种通过用含有能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐的组合物给予水，并且含有至少为6.5的烃聚合物的含有硬度和pH至少为6.5的工业冷却水中的腐蚀的方法具有酰胺结构的N-取代丙烯酰胺聚合物如下：其中R 2是氢或甲基，其中R 1是氢或烷基，R是亚烷基或亚苯基，X是磺酸根，（多）羟基，（聚）羧基或羰基，及其组合; 或含有具有N-取代的马来酰胺酸单元，N-取代的马来酰亚胺单元和具有以下结构的马来酸（和盐）单元的衍生化马来酸酐均聚物，共聚物和三元共聚物：其中R 1，R 2和R 3各自为独立地选自氢，羟基，羧基烷基，羧基酰胺，苯基，取代的苯基，1至10个碳原子的直链或支链烷基和取代的烷基或1至10个碳原子，其中取代基是膦酸; 次膦酸磷酸酯; 磺酸硫酸酯，羧酰胺，（多）羧基和（多）羟基，烷氧基和羧酸酯基团; 及其组合。

9. 发明授权

US4919821A Modified maleic anhydride polymers and the like for use as scale inhibitors 失效
标题翻译：改性马来酸酐聚合物等用作阻垢剂
公开(公告)号：US4919821A
公开(公告)日：1990-04-24
申请号：US239137
申请日：1988-08-31
申请人： Dodd W. Fong , John E. Hoots , Donald A. Johnson , James Kneller
发明人： Dodd W. Fong , John E. Hoots , Donald A. Johnson , James Kneller
IPC分类号： C02F5/12 , C02F5/14
CPC分类号： C02F5/14 , C02F5/12
摘要： Water supplies are treated to inhibit the formation of scale deposits of alkaline earth phosphates, phosphonates, sulphates and carbonates using various hydrocarbon polymers which contain an amido functionality and which have been prepared by post-polymerization derivatization.
摘要翻译：处理水源以抑制碱土磷酸盐，膦酸盐，硫酸盐和碳酸盐的水垢沉积物的形成，其使用含有酰氨基官能团并且通过后聚合衍生化制备的各种烃聚合物。

10. 发明授权

US4752443A Cooling water corrosion inhibition method 失效
标题翻译：冷却水腐蚀抑制方法
公开(公告)号：US4752443A
公开(公告)日：1988-06-21
申请号：US861763
申请日：1986-05-09
申请人： John E. Hoots , Donald A. Johnson , Dodd W. Fong , James F. Kneller
发明人： John E. Hoots , Donald A. Johnson , Dodd W. Fong , James F. Kneller
IPC分类号： C23F11/167 , C09D5/08 , C09D133/24 , C09D135/00 , C23F11/08 , C23F11/173 , C23F11/18 , C02F5/14
CPC分类号： C09D133/24 , C09D135/00 , C09D5/08 , C23F11/08
摘要： A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.3 are each independently chosen from the group consisting of hydrogen, hydroxyl, carboxyalkyl, carboxyamide, phenyl, substituted phenyl, linear or branched alkyl of from one to ten carbon atoms, and substituted alkyl of from one to ten carbon atoms, where the substituent is phosphonic acid; phosphinic acid; phosphate ester; sulfonic acid; sulfate ester, carboxyamide, (poly)carboxy and (poly)hydroxy, alkoxy and carboxylate ester groups; and combinations thereof.
摘要翻译：一种通过用含有能够在碱性水溶液中抑制腐蚀的水溶性无机磷酸盐的组合物给予水，并且含有至少为6.5的烃聚合物的含有硬度和pH至少为6.5的工业冷却水中的腐蚀的方法具有酰胺结构的N-取代丙烯酰胺聚合物如下：其中R 2是氢或甲基，R 1是氢或烷基，R是亚烷基或亚苯基，X是磺酸根，（多）羟基，（多）羧基或羰基，及其组合; 或含有具有N-取代的马来酰胺酸单元，N-取代的马来酰亚胺单元和具有如下结构的马来酸（和盐）单元的衍生化马来酸酐均聚物，共聚物和三元共聚物：其中R 1，R 2和R 3各自为独立地选自氢，羟基，羧基烷基，羧基酰胺，苯基，取代的苯基，1至10个碳原子的直链或支链烷基和1至10个碳原子的取代烷基，其中取代基是膦酸; 次膦酸磷酸酯; 磺酸硫酸酯，羧酰胺，（多）羧基和（多）羟基，烷氧基和羧酸酯基团; 及其组合。

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