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    • 8. 发明授权
    • Method for removing chlorate from caustic solutions with electrolytic
iron
    • 用电解铁从苛性碱溶液中除去氯酸盐的方法
    • US4276134A
    • 1981-06-30
    • US172923
    • 1980-07-28
    • Augusto PortaJacques Mosetti
    • Augusto PortaJacques Mosetti
    • C01D1/28C01D1/40C25B15/08C25C1/06
    • C25B15/08C01D1/28C01D1/40
    • A process for removing chlorate from a caustic solution by the reduction of the chlorate with metallic iron. The process is particularly distinguished by the steps of contacting the caustic solution with iron to reduce the chlorate to chloride, contacting the caustic solution containing dissolved iron therein with a conductive substrate to electrolytically precipitate the iron on the substrate, thus providing a caustic solution which is substantially free from iron and chlorate ions, separating the purified portion of the caustic solution, and periodically using the iron coated substrate for treating an untreated portion of the caustic solution to reduce the chlorate to chloride, and periodically reusing the iron depleted substrate, for recovering dissolved iron from the caustic solution. The process of this invention decreases the chlorate content of caustic solutions to an acceptable level of a few ppm and also recovers dissolved iron on an iron depleted substrate for reuse and further reduction of chlorate of an untreated portion of the caustic solution.
    • 通过用金属铁还原氯酸盐从苛性碱溶液中除去氯酸盐的方法。 该方法特别区分在于将苛性碱溶液与铁接触以将氯酸盐还原成氯化物,使其中含有溶解的铁的苛性碱溶液与导电基底接触以使铁沉积在基底上的步骤,从而提供苛性碱溶液 基本上不含铁和氯酸根离子,分离纯化的苛性碱溶液部分,并周期性地使用铁涂覆的基底处理苛性碱溶液的未处理部分以将氯酸盐还原成氯化物,并周期性地重复使用贫铁底物以回收 从苛性碱溶液中溶解铁。 本发明的方法将苛性碱溶液的氯酸盐含量降低至几ppm的可接受水平,并且还可在铁贫的底物上回收溶解的铁,以重新使用并进一步还原苛性碱溶液的未处理部分的氯酸盐。
    • 9. 发明授权
    • Process for regenerating contaminated activated carbon
    • 再生污染活性炭的方法
    • US4217191A
    • 1980-08-12
    • US882083
    • 1978-03-01
    • Denis DoniatJean-Michel CorajoudJacques MosettiAugusto Porta
    • Denis DoniatJean-Michel CorajoudJacques MosettiAugusto Porta
    • C01B31/08C02F1/28C02F1/467C25F1/00
    • C01B31/087C02F1/283C02F1/4672C02F2303/16
    • Process for regenerating activated carbon particles contaminated by oxidizable impurities. An electrolysis cell is divided by a liquid-permeable membrane to define an anodic chamber and a cathode chamber therein both filled in operation with an electrolyte. Recycling conduits communicate with the anode chamber and a recirculating pump to establish a fluid circuit therewith. A suspension of particles of activated carbon contaminated by oxidizable impurities suspended in an aqueous solution of an electrolyte is loaded into the fluid circuit and circulated therethrough. A voltage applied to the electrodes of the electrolysis cell develops an electrolysis reaction in the aqueous solution of the electrolyte and atomic oxygen is liberated at the surface of the anode electrode. As particles of the activated carbon flow through the anode cell they contact the anode electrode and atomic oxygen is liberated at their surfaces which oxidizes impurities adsorbed by the particles. After the carbon particles have been circulated for a sufficient time to oxidize all of the impurities thereon, the regenerated particles of activated carbon and the aqueous solution of the electrolyte are discharged from the recirculating circuit.
    • 再生被可氧化杂质污染的活性炭颗粒的方法。 电解槽被液体渗透膜分隔,以确定阳极室和阴极室,其中两者均填充有电解液。 回收管道与阳极室和循环泵连通以与其建立流体回路。 被悬浮在电解质水溶液中的可氧化杂质污染的活性炭颗粒的悬浮液被加载到流体回路中并循环通过。 施加到电解池的电极的电压在电解质的水溶液中产生电解反应,并且在阳极电极的表面释放原子氧。 当活性炭的颗粒流过阳极电池时,它们接触阳极电极,原子氧在其表面释放,氧化颗粒吸附的杂质。 在碳粒子已经循环足够的时间以氧化其上的所有杂质之后,再生的活性炭颗粒和电解质水溶液从再循环回路排出。