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1. 发明授权

US07320745B2 Energy efficient method for exothermic reactions 有权
标题翻译：放热反应的节能方法
公开(公告)号：US07320745B2
公开(公告)日：2008-01-22
申请号：US11038755
申请日：2005-01-19
申请人： Arvids Judzis, Jr. , Abraham P. Gelbein , John R. Adams , Christopher C. Boyer
发明人： Arvids Judzis, Jr. , Abraham P. Gelbein , John R. Adams , Christopher C. Boyer
IPC分类号： B01D3/14 , C10G7/00
CPC分类号： B01D3/009 , B01J19/0033 , B01J2219/00006 , Y10S203/08 , Y10S585/914
摘要： An energy efficient process scheme for a highly exothermic reaction-distillation system in which the reactor is external to the distillation column and the feed to the reactor is a mixture of at least one liquid product stream from the distillation column with or without other liquid/vapor reactants. The reactor is operated under adiabatic and boiling point conditions and at a pressure that results in vaporizing a portion of the liquid flow through the reactor due to the heat of reaction. Under these conditions, reaction temperature is controlled by reactor pressure. The pressure (and hence the temperature) is maintained at a sufficiently high level such that the reactor effluent can be efficiently used to provide reboil heat for the distillation column.
摘要翻译：用于高放热反应 - 蒸馏系统的能量效率方法，其中反应器在蒸馏塔外部和反应器的进料是来自蒸馏塔的至少一种液体产物流与有或没有其它液体/蒸气的混合物反应物。反应器在绝热和沸点条件下运行，并且在由于反应热导致部分液体流过反应器的压力下运行。在这些条件下，反应温度由反应器压力控制。压力（因此温度）保持在足够高的水平，使得反应器流出物可以有效地用于为蒸馏塔提供再沸腾热。

2. 发明授权

US08101810B2 Reformate benzene reduction via alkylation 有权
标题翻译：通过烷基化改性苯还原
公开(公告)号：US08101810B2
公开(公告)日：2012-01-24
申请号：US12195118
申请日：2008-08-20
申请人： Christopher C. Boyer , Lawrence A. Smith, Jr. , Arvids Judzis, Jr. , John R. Adams
发明人： Christopher C. Boyer , Lawrence A. Smith, Jr. , Arvids Judzis, Jr. , John R. Adams
IPC分类号： C07C2/52
CPC分类号： C07C2/66 , Y02P20/127 , C07C15/085 , C07C15/02
摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.
摘要翻译：一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。

3. 发明申请

US20100048970A1 REFORMATE BENZENE REDUCTION VIA ALKYLATION 有权
标题翻译：通过烷基化改性降低苯并噻吩
公开(公告)号：US20100048970A1
公开(公告)日：2010-02-25
申请号：US12195118
申请日：2008-08-20
申请人： Christopher C. Boyer , Lawrence A. Smith, JR. , Arvids Judzis, JR. , John R. Adams
发明人： Christopher C. Boyer , Lawrence A. Smith, JR. , Arvids Judzis, JR. , John R. Adams
IPC分类号： C07C2/64
CPC分类号： C07C2/66 , Y02P20/127 , C07C15/085 , C07C15/02
摘要： A process for reformate benzene reduction, the process including: feeding a light reformate fraction, an olefin feed, and an alkylation catalyst to an alkylation reaction zone; contacting the light reformate fraction and the olefin feed in the presence of the alkylation catalyst in the alkylation reaction zone to convert at least a portion of the benzene and the olefin to a monoalkylate; recovering a catalyst fraction from an alkylation reaction zone effluent; and recovering a light reformate product having a reduced benzene content.
摘要翻译：一种重整苯还原的方法，该方法包括：将轻质重整油馏分，烯烃进料和烷基化催化剂进料至烷基化反应区; 在烷基化反应区中在烷基化催化剂存在下使轻重整油馏分和烯烃进料接触，将至少一部分苯和烯烃转化成单烷基化物; 从烷基化反应区流出物回收催化剂级分; 并回收苯含量降低的轻质重整产物。

4. 发明授权

US07494584B2 Energy efficient method for exothermic reactions 有权
标题翻译：放热反应的节能方法
公开(公告)号：US07494584B2
公开(公告)日：2009-02-24
申请号：US11845642
申请日：2007-08-27
申请人： Arvids Judzis , Abraham P. Gelbein , John R. Adams , Christopher C. Boyer
发明人： Arvids Judzis , Abraham P. Gelbein , John R. Adams , Christopher C. Boyer
IPC分类号： B01D3/14 , B01D3/00 , C07C7/00
CPC分类号： B01D3/009 , B01J19/0033 , B01J2219/00006 , Y10S203/08 , Y10S585/914
摘要： An energy efficient process scheme for a highly exothermic reaction-distillation system in which the reactor is external to the distillation column and the feed to the reactor is a mixture of at least one liquid product stream from the distillation column with or without other liquid/vapor reactants. The reactor is operated under adiabatic and boiling point conditions and at a pressure that results in vaporizing a portion of the liquid flow through the reactor due to the heat of reaction. Under these conditions, reaction temperature is controlled by reactor pressure. The pressure (and hence the temperature) is maintained at a sufficiently high level such that the reactor effluent can be efficiently used to provide reboil heat for the distillation column.
摘要翻译：用于高放热反应 - 蒸馏系统的能量效率方法，其中反应器在蒸馏塔外部和反应器的进料是来自蒸馏塔的至少一种液体产物流与有或没有其它液体/蒸气的混合物反应物。反应器在绝热和沸点条件下运行，并且在由于反应热导致部分液体流过反应器的压力下运行。在这些条件下，反应温度由反应器压力控制。压力（因此温度）保持在足够高的水平，使得反应器流出物可以有效地用于为蒸馏塔提供再沸腾热。

5. 发明授权

US07250542B2 Paraffin alkylation 有权
标题翻译：石蜡烷基化
公开(公告)号：US07250542B2
公开(公告)日：2007-07-31
申请号：US10793028
申请日：2004-03-04
申请人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
发明人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
IPC分类号： C07C6/00 , C07C2/58 , C07C2/62
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
摘要翻译：一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触使所述异链烷烃和所述烯烃反应生成烷基化物产物。优选地，液体系统保持在反应区域的大约沸点。出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。产物异辛烷基本上与常规冷酸法中产生的相同。

6. 发明授权

US06995296B2 Paraffin alkylation 有权
公开(公告)号：US06995296B2
公开(公告)日：2006-02-07
申请号：US10870104
申请日：2004-06-17
申请人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
发明人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
IPC分类号： C07C2/62
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.

7. 发明授权

US07850929B2 Contact structures 有权
标题翻译：接触结构
公开(公告)号：US07850929B2
公开(公告)日：2010-12-14
申请号：US11477003
申请日：2006-06-28
申请人： Lawrence A. Smith, Jr. , Abraham P. Gelbein , John R. Adams
发明人： Lawrence A. Smith, Jr. , Abraham P. Gelbein , John R. Adams
IPC分类号： B01J8/02
CPC分类号： B01J19/2495 , B01D3/009 , B01J19/32 , B01J35/04 , B01J2219/00006 , B01J2219/32213 , B01J2219/32227 , B01J2219/32231 , B01J2219/32286 , B01J2219/32289 , B01J2219/32408 , B01J2219/32416 , B01J2219/32441 , B01J2219/32466 , B01J2219/32483 , B01J2219/32491 , B01J2219/3306 , B01J2219/3322 , C10G29/205 , C10G50/00
摘要： An internal static mixing system such as a disperser of mesh wire or expanded metal co-knit with a multi filament material selected from inert polymers, catalytic polymers, catalytic metals or mixtures in combination with a vertical reactor having a reaction zone and the disperser disposed in said reaction zone, particularly for carrying out paraffin alkylation using acid catalyst is disclosed. The wire mesh provides the structural integrity of the system as well as the open space required in reactors for the movement of vapors and liquids though the system. The disperser may be in sheets, bundles or bales or positioned within a frame.
摘要翻译：内部静态混合系统，例如网状丝网或多孔金属分散机，与选自惰性聚合物，催化聚合物，催化金属或混合物的多丝材料共同编织，与具有反应区和分散器的立式反应器组合所述反应区，特别是用于使用酸催化剂进行烷基烷基化的反应区。丝网提供了系统的结构完整性以及反应器中通过系统运动蒸气和液体所需的开放空间。分散器可以是片材，束或捆包或定位在框架内。

8. 发明授权

US4404416A Isomerization 失效
标题翻译：异构化
公开(公告)号：US4404416A
公开(公告)日：1983-09-13
申请号：US286639
申请日：1981-07-24
申请人： John R. Adams , Abraham P. Gelbein , Robert Hansen , Jimmy Y. Peress , Martin B. Sherwin
发明人： John R. Adams , Abraham P. Gelbein , Robert Hansen , Jimmy Y. Peress , Martin B. Sherwin
IPC分类号： B01J21/04 , B01J23/00 , B01J27/00 , B01J31/00 , B01J35/10 , B01J37/24 , C07B61/00 , C07C1/00 , C07C5/27 , C07C11/02 , C07C67/00
CPC分类号： B01J37/24 , B01J21/04 , B01J35/10 , C07C5/277 , B01J35/1019 , B01J35/1042 , B01J35/1061
摘要： A process is provided for the skeletal isomerization of straight chain olefins to branched chain olefins wherein the olefin is contacted with an activated alumina catalyst which has a particle size of from about 0.5.times.10.sup.-3 cm to about 160.times.10.sup.-3 cm and at least 10% of the pore volume is attributable to pores having radii between about 100 and 10,000 Angstroms.
摘要翻译：提供了一种将直链烯烃骨架异构化成支链烯烃的方法，其中烯烃与活性氧化铝催化剂接触，活性氧化铝催化剂的粒径为约0.5×10 -3 cm至约160×10 -3 cm，至少10％的孔体积可归因于具有在约100和10,000埃之间的半径的孔。

9. 发明授权

US07319180B2 Paraffin alkylation 有权
标题翻译：石蜡烷基化
公开(公告)号：US07319180B2
公开(公告)日：2008-01-15
申请号：US10973746
申请日：2004-10-26
申请人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
发明人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
IPC分类号： C07C2/54
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
摘要翻译：一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触使所述异链烷烃和所述烯烃反应生成烷基化物产物。优选地，液体系统保持在反应区域的大约沸点。出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。产物异辛烷基本上与常规冷酸法中产生的相同。

10. 发明授权

US06858770B2 Paraffin alkylation 有权
标题翻译：石蜡烷基化
公开(公告)号：US06858770B2
公开(公告)日：2005-02-22
申请号：US10219877
申请日：2002-08-15
申请人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
发明人： Lawrence A. Smith, Jr. , Mitchell E. Loescher , John R. Adams , Abraham P. Gelbein
IPC分类号： B01J27/053 , B01J35/12 , C07C2/06 , C07C2/54 , C07C2/56 , C07C2/58 , C07C2/62 , C10G35/04 , C10G50/00 , C10G63/02
CPC分类号： C07C2/62 , C07C11/02 , C07C2527/054 , C10G29/205 , C10G2300/1081 , C10G2300/1088
摘要： A process for the alkylation of alkane with olefin or olefin precursor such as an oligomer of tertiary olefin comprising contacting a liquid system comprising acid catalyst, isoparaffin and olefin in concurrent downflow into contact in a reaction zone with a disperser mesh under conditions of temperature and pressure to react said isoparaffin and said olefin to produce an alkylate product is disclosed. Preferably, the liquid system is maintained at about its boiling point in the reaction zone. Unexpectedly, the olefin oligomers have been found to function as olefin precursors and not as olefins in the reaction. Thus, for example, a cold acid alkylation using an oligomer of isobutene (principally dimer and trimer) with isobutane produces isooctane with the isobutane reacting with the constituent isobutene units of the oligomers on a molar basis. The product isooctane is essentially the same as that produced in the conventional cold acid process.
摘要翻译：一种烷烃与烯烃或烯烃前体烷基化的方法，例如叔烯烃的低聚物，包括使含有酸催化剂，异链烷烃和烯烃的液体体系同时向下流动，在温度和压力条件下在分散网中与反应区接触使所述异链烷烃和所述烯烃反应生成烷基化物产物。优选地，液体系统保持在反应区域的大约沸点。出乎意料地，已经发现烯烃低聚物作为烯烃前体而不是反应中的烯烃。因此，例如，使用异丁烯（主要是二聚体和三聚体）的低聚物与异丁烷的冷酸烷基化产生异辛烷，异丁烷与摩尔的低聚物的组分异丁烯单元反应。产物异辛烷基本上与常规冷酸法中产生的相同。

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