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    • 3. 发明授权
    • Triazole-organodithiophosphate reaction product additives for functional
fluids
    • 功能液三唑 - 有机二硫代磷酸酯反应产物添加剂
    • US4791206A
    • 1988-12-13
    • US861186
    • 1986-05-09
    • Robert M. O'NeilUlrich KristenUlrich Haring
    • Robert M. O'NeilUlrich KristenUlrich Haring
    • C10M159/12C07F9/6518C07F9/6561C10M137/10C10N10/02C10N10/04C10N10/10C10N10/12C10N10/14C10N10/16C10N30/00C10N30/14C10N40/08C10N40/12C07F9/65
    • C07F9/6518C10M137/10
    • New reaction products, useful as additives for functional fluids, are obtained by reacting, at elevated temperature,(A) a triazole having the formula IA or IB: ##STR1## wherein R.sub.7 is hydrogen or a C.sub.1 -C.sub.20 alkyl residue;R.sub.8 and R.sub.9 are the same or different and each is C.sub.1 -C.sub.20 alkyl, C.sub.3 -C.sub.20 alkenyl, C.sub.5 -C.sub.12 cycloalkyl, C.sub.7 -C.sub.13 aralkyl, C.sub.6 -C.sub.10 aryl or R.sub.8 and R.sub.9, together with the nitrogen atom to which they are attached, form a 5-, 6- or 7-membered heterocyclic residue or R.sub.8 and R.sub.9 is each a residue of formula:R.sub.12 X[(alkylene)O].sub.n (alkylene)-- II wherein X is O, S or N(R.sub.12), R.sub.12 is hydrogen or C.sub.1 -C.sub.20 alkyl, "alkylene" is a C.sub.1 -C.sub.12 alkylene residue and n is 0 or an integer from 1 to 6;R.sub.10 is hydrogen, C.sub.1 -C.sub.20 alkyl or C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.18 alkyl phenyl; and R.sub.11 is hydrogen, C.sub.1 -C.sub.20 alkyl or a residue --CH.sub.2 NR.sub.8 R.sub.9 wherein R.sub.8 and R.sub.9 have their previous significance; with(B) an organodithiophosphate having the formula: ##STR2## in which R.sub.13 is a C.sub.1 -C.sub.20 alkyl or C.sub.7 -C.sub.18 alkyl phenyl or C.sub.7 -C.sub.13 aralkyl group, M is a metal ion of Group IA, IB, IIA, IIB, VB, VIB, VIIB or VIII of the Periodic System of Elements, and y is the valency of M.
    • 通过在升高的温度下使(A)具有式IA或IB的三唑:其中R 7是氢或C 1 -C 20烷基,可以获得用作功能流体的添加剂的新反应产物 残留物 R 8和R 9相同或不同,各自为C 1 -C 20烷基,C 3 -C 20烯基,C 5 -C 12环烷基,C 7 -C 13芳烷基,C 6 -C 10芳基或R 8和R 9,以及它们所连接的氮原子 形成5-,6-或7-元杂环残基,或R 8和R 9各自为下式的残基:R 12 X [(亚烷基)O] n(亚烷基)-II其中X为O,S或N(R 12) R 12是氢或C 1 -C 20烷基,“亚烷基”是C 1 -C 12亚烷基,n是0或1-6的整数; R 10是氢,C 1 -C 20烷基或C 6 -C 10芳基或C 7 -C 18烷基苯基; 并且R 11是氢,C 1 -C 20烷基或残基-CH 2 NR 8 R 9,其中R 8和R 9具有其先前的含义; (B)具有下式的有机二硫代磷酸酯:其中R 13是C 1 -C 20烷基或C 7 -C 18烷基苯基或C 7 -C 13芳烷基,M是IA,IB,IIA,IIB族的金属离子 ,VB,VIB,VIIB或VIII元素,y是M的化合价。