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1. 发明授权

US06858127B2 Process for the preparation of middle distillates 有权
标题翻译：中间馏分油的制备工艺
公开(公告)号：US06858127B2
公开(公告)日：2005-02-22
申请号：US10469843
申请日：2002-03-01
申请人： Arend Hoek , Matthijs Maria Gerardus Senden
发明人： Arend Hoek , Matthijs Maria Gerardus Senden
IPC分类号： C10G67/02 , C10G20060101 , C10G2/00 , C10G45/58 , C10G45/64 , C10G47/20 , C10G65/04 , C10G65/10 , C10M101/02 , C10M107/02 , C10M169/04 , C10M171/02 , C10G65/00 , C07C27/00 , C10G35/00 , C10G47/00
CPC分类号： C10M171/02 , C10G2/32 , C10G65/043 , C10G65/10 , C10G2400/04 , C10G2400/06 , C10G2400/08 , C10M101/02 , C10M107/02 , C10M169/04 , C10M2205/173 , C10N2230/02 , C10N2230/04 , C10N2230/12 , C10N2240/10 , C10N2240/102
摘要： A process for the preparation of one or more hydrocarbon fuel products boiling in the kero/diesel range from a stream of hydrocarbons produced in a Fischer-Tropsch process, in which process synthesis gas is converted into liquid hydrocarbons, at least a part of the hydrocarbons boiling above the kero/diesel range, having the following steps: (1) hydrocracking/hydroisomerizing at least a part of the Fischer-Tropsch hydrocarbons stream at a conversion per pass of at most 80 wt % of the material boiling above 370° C. into material boiling below 370° C.; (2) separating the product stream obtained in step (1) into one or more light fractions boiling below the kero/diesel boiling range, one or more fractions boiling in the kero/diesel boiling range and a heavy fraction boiling above the kero/diesel boiling range; (3) hydrocracking/hydroisomerizing the major part of the heavy fraction obtained in step (2) at a conversion per pass of at most 80 wt % of the material boiling above 370° C. into material boiling below 370° C.; (4) separating the product stream obtained in step (3) into one or more light fractions boiling below the kero/diesel boiling range, one or more fractions boiling in the kero/diesel boiling range and a heavy fraction boiling above the kero/diesel boiling range; and, (5) hydrocracking/hydroisomerizing the major part of the heavy fraction obtained in step (4) in the hydrocracking/hydroisomerizing process described in step (1) and/or step (3), in which process the Fischer-Tropsch hydrocarbons stream comprises at least 35 wt % C30+ (based on total amount of hydrocarbons in the Fischer-Tropsch hydrocarbons stream) and in which stream the weight ratio C60+/C30+ is at least 0.2.
摘要翻译：一种用于制备一种或多种在kero /柴油范围内沸腾的烃类燃料产物的方法，该烃类燃料产物是从费 - 托法生产的烃流中制备的，其中工艺合成气被转化为液态烃，至少一部分烃沸点高于kero /柴油范围，具有以下步骤：（1）以至少一半沸点高于370℃的材料的80重量％的转化率将费 - 托烃流的至少一部分加氢裂化/加氢异构化。沸腾到低于370℃的材料;（2）将步骤（1）中获得的产物流分离成一个或多个沸点低于kero /柴油沸程的轻馏分，一个或多个沸点为kero /柴油沸程的馏分和沸点高于kero /柴油沸点范围的重馏分;（3）在步骤（2）中获得的重馏分的主要部分加氢裂化/加氢异构化，转化率最高为沸点高于370℃的材料的80重量％进入m （4）将步骤（3）中获得的产物流分离成沸点低于kero /柴油沸程的一种或多种轻馏分，一种或多种沸点为kero /柴油沸程的馏分和重馏分沸腾超过kero /柴油沸程; 和（5）在步骤（1）和/或步骤（3）中描述的加氢裂化/加氢异构化方法中，将步骤（4）中获得的重馏分的主要部分加氢裂化/加氢异构化，其中费 - 托烃流包含至少35重量％的C30 +（基于费 - 托烃流中的烃的总量），其中重量比C60 + / C30 +为至少0.2。

2. 发明授权

US09333492B2 Hydrogenation catalyst and use thereof for hydrogenating fischer-tropsch endproducts 有权
标题翻译：氢化催化剂及其用于氢化费 - 托最终产物的用途
公开(公告)号：US09333492B2
公开(公告)日：2016-05-10
申请号：US12161634
申请日：2006-01-23
申请人： Focco Cornelis Bijlsma , Jan Lodewijk Maria Dierickx , Arend Hoek , Frans Joris Antonius Kellendonk , Anna Elisabeth Maria Oud
发明人： Focco Cornelis Bijlsma , Jan Lodewijk Maria Dierickx , Arend Hoek , Frans Joris Antonius Kellendonk , Anna Elisabeth Maria Oud
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J23/755 , B01J21/04 , B01J35/10 , B01J37/02 , C10G45/00 , C10G3/00 , C10G45/06 , C10G45/12 , C10G2/00
CPC分类号： B01J23/755 , B01J21/04 , B01J35/10 , B01J35/1061 , B01J35/1085 , B01J37/0205 , C10G2/332 , C10G3/45 , C10G3/50 , C10G45/00 , C10G45/06 , C10G45/12 , C10G2300/1022 , C10G2300/4018 , Y02P30/20
摘要： A hydrogenation catalyst particularly suitable for hydrogenating oxygenates in a hydrogenation unit of a Fischer-Tropsch plant is disclosed. A preferred embodiment comprises more than 5% and less than 20% nickel based on a wide pore alumina support. The catalyst successfully hydrogenates oxygenates which otherwise tend to poison a catalyst in a hydroconversion unit downstream. Moreover, the temperature at which the unwanted hydrogenolysis of long chain paraffins to methane occurs is higher for one catalyst disclosed herein than a comparable known catalyst. This allows the hydrogenation plant to operate at a higher temperature.
摘要翻译：公开了一种特别适用于在费 - 托工厂的氢化单元中氢化含氧化合物的氢化催化剂。优选的实施方案包括基于宽孔氧化铝载体的超过5％且小于20％的镍。催化剂成功地氢化含氧化合物，否则其倾向于在下游的加氢转化单元中毒催化剂。此外，与可比较的已知催化剂相比，长链烷烃对甲烷的不期望的氢解发生的温度比本文公开的一种催化剂更高。这允许氢化装置在较高的温度下运行。

3. 发明授权

US08685231B2 Process for conversion of paraffinic feedstock 有权
标题翻译：石蜡原料转化工艺
公开(公告)号：US08685231B2
公开(公告)日：2014-04-01
申请号：US12952986
申请日：2010-11-23
申请人： Jolinde Machteld Van De Graaf , Arend Hoek , Johannes Petrus De Jonge , Wiebe Sjoerd Kijlstra , Antonius Adrianus Maria Roovers , Jelle Rudolf Anne Sietsma , Johannes Anthonius Robert Van Veen
发明人： Jolinde Machteld Van De Graaf , Arend Hoek , Johannes Petrus De Jonge , Wiebe Sjoerd Kijlstra , Antonius Adrianus Maria Roovers , Jelle Rudolf Anne Sietsma , Johannes Anthonius Robert Van Veen
IPC分类号： C10G47/14 , C07C4/06
CPC分类号： C10G47/16 , C10G47/14 , C10G65/12 , C10G67/04 , C10G2300/202 , C10G2300/301 , C10G2300/44
摘要： The invention provides a process for converting a paraffinic feedstock comprising at least 50 wt % of compounds boiling above 370° C., a paraffin content of at least 60 wt %, an aromatics content below 1 wt %, a naphthenic content below 2 wt %, a nitrogen content below 0.1 wt %, and a sulphur content below 0.1 wt %, comprising: (a) reacting the feedstock with hydrogen at a temperature between 175 and 400° C. and a pressure between 20 and 100 bar using a catalyst comprising 0.005 to 5.0 wt % of a Group VIII noble metal on a carrier comprising 0.1-15 wt % zeolite beta and at least 40 wt % amorphous silica-alumina (b) withdrawing the effluent (c) subjecting the effluent to a fractionation step to form a heavy fraction, an intermediate fraction, and a light fraction; and (d) providing at least part of the heavy fraction to the reaction zone.
摘要翻译：本发明提供了一种转化石蜡原料的方法，该方法包括至少50重量％的沸点高于370℃的化合物，至少60重量％的链烷烃含量，低于1重量％的芳烃含量，低于2重量％的环烷烃含量，，低于0.1重量％的氮含量和低于0.1重量％的硫含量，包括：（a）使原料与氢在175-400℃之间的温度下反应，压力在20-100巴之间，使用的催化剂包括 0.005至5.0重量％的载体上的第VIII族贵金属，其包含0.1-15重量％的沸石β和至少40重量％的无定形二氧化硅 - 氧化铝（b）回收流出物（c）使流出物进行分馏步骤以形成重馏分，中间馏分和轻馏分; 和（d）将至少部分重馏分提供到反应区。

4. 发明授权

US07855234B2 Fischer-tropsch process and reactor assembly 有权
标题翻译：费 - 托法和反应器组装
公开(公告)号：US07855234B2
公开(公告)日：2010-12-21
申请号：US11988970
申请日：2006-07-14
申请人： Arend Hoek , Hans Michiel Huisman
发明人： Arend Hoek , Hans Michiel Huisman
IPC分类号： C07C27/00
CPC分类号： C10G2/32 , B01J8/0278 , B01J8/065 , B01J8/067 , B01J8/22 , B01J2219/00038 , B01J2219/00202 , B01J2219/00211 , B01J2219/00231 , B01J2219/00238 , C10G2/34 , C10G2400/02 , C10G2400/06 , C10G2400/08 , C10G2400/10 , C10G2400/18
摘要： A method of accommodating a reduction in production capacity of one or more reactors in a multi-reactor assembly adapted for the production of hydrocarbon products from syngas, the syngas being provided by a syngas manufacturing facility and provided to an entry stream system providing syngas to each of the reactors, and having an exit stream system taking at least hydrocarbon products from the reactors, wherein the method comprises the steps of: redistributing the syngas from the one or more said reactors to one or more other reactors, and increasing the temperature in the said one or more other reactors to at least partially take over the reduction in production capacity of the one or more reactors.
摘要翻译：一种在适合从合成气生产碳氢化合物产品的多反应器组合中容纳一个或多个反应器的生产能力降低的方法，合成气由合成气制造设施提供并提供给进入流系统，其将合成气提供给每个的反应器，并且具有至少从反应器中取出烃产物的出口流系统，其中所述方法包括以下步骤：将来自所述一个或多个所述反应器的合成气重新分配到一个或多个其它反应器，并且增加所述反应器中的温度所述一个或多个其它反应器至少部分地承担一个或多个反应器的生产能力的降低。

5. 发明授权

US07642294B2 Process to prepare lower olefins from a carbon containing feedstock 有权
标题翻译：从含碳原料制备低级烯烃的方法
公开(公告)号：US07642294B2
公开(公告)日：2010-01-05
申请号：US11664657
申请日：2005-10-06
申请人： Emil Eduard Antonius Cruijsberg , Jan Lodewijk Maria Dierickx , Arend Hoek , Johannes Marie Gemma Van Schijndel , Jeroen Van Westrenen
发明人： Emil Eduard Antonius Cruijsberg , Jan Lodewijk Maria Dierickx , Arend Hoek , Johannes Marie Gemma Van Schijndel , Jeroen Van Westrenen
IPC分类号： C07C27/00 , C10G47/02 , C10G35/00
CPC分类号： C10G9/00 , C10G2/30
摘要： A process is provided to make ethylene and propylene from a carbonaceous feedstock. The process comprises preparing a gaseous mixture of carbon monoxide and hydrogen from a feedstock. A Fischer Tropsch synthesis is then performed on the gaseous mixture to obtain a Fischer Tropsch product along with unconverted carbon monoxide and hydrogen. The Fischer Tropsch product in admixture with the unconverted carbon monoxide and hydrogen from the previous step is then subjected to terminal cracking to form ethylene and propylene.
摘要翻译：提供了从碳质原料制备乙烯和丙烯的方法。该方法包括从原料制备一氧化碳和氢气的气体混合物。然后在气体混合物上进行费 - 托合成，以获得费 - 托产物以及未转化的一氧化碳和氢气。然后将与前一步骤中未转化的一氧化碳和氢气混合的费托产品进行末端裂化以形成乙烯和丙烯。

6. 发明申请

US20090011134A1 Zirconium Stabilised Fischer Tropsch Catalyst and Catalyst Support 审中-公开
标题翻译：锆稳定费托催化剂和催化剂载体
公开(公告)号：US20090011134A1
公开(公告)日：2009-01-08
申请号：US12158204
申请日：2006-12-20
申请人： Arend Hoek , Gerardus Petrus Niesen
发明人： Arend Hoek , Gerardus Petrus Niesen
IPC分类号： B05D3/02 , B01J32/00 , B01J23/34
CPC分类号： B01J37/0225 , B01J21/063 , B01J21/066 , B01J23/745 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J23/8896 , B01J23/89 , B01J35/1014 , B01J37/0045 , C10G2/332
摘要： The present invention relates to a method of preparing a catalyst support or a supported metal catalyst, the method comprising: (a) admixing a porous refractory oxide with a water soluble zirconium precursor in an alkaline solution, and if a supported metal catalyst is prepared, with a precursor of the metal, yielding a slurry, (b) drying the slurry, and (c) calcining; thus yielding a catalyst support or supported metal catalyst having an increased hydrothermal strength. The invention further relates to a method of preparing a catalyst body, the method comprising: (a) admixing a porous refractory oxide with a water soluble zirconium precursor in an alkaline solution, and if a supported metal catalyst is prepared, with a precursor of the metal or the metal itself, yielding a slurry, (b) coating metal with the slurry, (c) drying the coating, and (d) calcining; thus yielding a catalyst body comprising a catalyst support or supported metal catalyst having an increased hydrothermal strength In a preferred embodiment, the zirconium containing compound comprises zirconium carbonate in an ammonium solution. The improved hydrothermal strength is particularly suitable for slurry-type Fischer-Tropsch reactors.
摘要翻译：本发明涉及一种制备催化剂载体或负载型金属催化剂的方法，所述方法包括：（a）在碱性溶液中将多孔难熔氧化物与水溶性锆前体混合，如果制备负载型金属催化剂，与金属的前体一起产生浆料，（b）干燥浆料，和（c）煅烧; 从而产生具有增加的热液强度的催化剂载体或负载型金属催化剂。本发明还涉及一种制备催化剂体的方法，所述方法包括：（a）在碱性溶液中将多孔难熔氧化物与水溶性锆前体混合，如果制备负载型金属催化剂，则其前体为金属或金属本身，产生浆料，（b）用浆料涂覆金属，（c）干燥涂层，和（d）煅烧; 从而产生包含具有增加的热液强度的催化剂载体或负载型金属催化剂的催化剂体。在优选的实施方案中，含锆化合物包括在铵溶液中的碳酸锆。改进的水热强度特别适用于淤浆型费 - 托反应器。

7. 发明授权

US07300565B2 Process to prepare a microcrystalline wax and a middle distillate fuel 失效
标题翻译：制备微晶蜡和中间馏分燃料的方法
公开(公告)号：US07300565B2
公开(公告)日：2007-11-27
申请号：US10521668
申请日：2003-07-17
申请人： Arend Hoek
发明人： Arend Hoek
IPC分类号： C10G45/58
CPC分类号： C10G45/58 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2400/04 , Y10S208/95
摘要： The invention relates to a process to prepare a microcrystalline wax and a middle distillate fuel by (a) hydrocracking/hydroisomerizing a Fischer-Tropsch product, wherein the weight ratio of compounds having at least 60 or more carbon atoms and compounds having at least 30 carbon atoms in the Fischer-Tropsch product is at least 0.2 and wherein at least 30 wt % of compounds in the Fischer-Tropsch product have at least 30 carbon atoms, (b) performing one or more distillate separations on the effluent of step (a) to obtain a middle distillate fuel fraction and a microcrystalline wax having an initial boiling point of between 500 and 600° C.
摘要翻译：本发明涉及通过（a）费 - 托产物的加氢裂化/加氢异构化制备微晶蜡和中间馏分燃料的方法，其中具有至少60个或更多碳原子的化合物的重量比和具有至少30个碳原子的化合物费 - 托产物中的原子为至少0.2，并且其中费 - 托产物中至少30wt％的化合物具有至少30个碳原子，（b）在步骤（a）的流出物上进行一种或多种馏出物分离，以获得中间馏分燃料馏分和初始沸点为500-600℃的微晶蜡。

8. 发明申请

US20060149117A1 Process for the preparation of detergent compounds 有权
标题翻译：洗涤剂化合物的制备方法
公开(公告)号：US20060149117A1
公开(公告)日：2006-07-06
申请号：US10546281
申请日：2004-02-19
申请人： Henk Dirkzwager , Robert Van Hardeveld , Arend Hoek , Peter Lednor , Joannes Geijsel
发明人： Henk Dirkzwager , Robert Van Hardeveld , Arend Hoek , Peter Lednor , Joannes Geijsel
IPC分类号： C07C7/12
CPC分类号： C10G67/02 , C07C1/0485 , C10G2/00 , C10G65/04 , C10G69/123 , C10G2300/1022 , C10G2300/301
摘要： A process for the preparation of detergents containing a relatively low amount of isoparaffins, involving separating a hydrocarbonaceous product stream from a Fischer-Tropsch process using a cobalt based catalyst and producing normally liquid and normally solid hydrocarbons into a light fraction boiling below an intermediate fraction having detergent hydrocarbons, an intermediate boiling fraction having detergent hydrocarbons and a heavy fraction boiling above the intermediate boiling fraction having detergent hydrocarbons, followed by conversion of the detergent hydrocarbons present in the intermediate boiling fraction into detergents, the Fischer-Tropsch process being carried out at a relatively high pressure.
摘要翻译：一种用于制备含有相对低量的异链烷烃的洗涤剂的方法，包括使用钴基催化剂从费 - 托法中分离烃产物流，并将通常为液态的和通常为固体的烃生产成沸点低于具有洗涤剂烃，具有洗涤剂烃的中间沸点馏分和在具有洗涤剂烃的中间沸点馏分以上沸腾的重馏分，随后将存在于中间沸点馏分中的洗涤剂烃转化为洗涤剂，费 - 托方法在比较高的压力。

9. 发明授权

US08497310B2 Integrated process and reactor arrangement for hydrocarbon synthesis 有权
标题翻译：烃合成的综合工艺和反应堆装置
公开(公告)号：US08497310B2
公开(公告)日：2013-07-30
申请号：US12643706
申请日：2009-12-21
申请人： Arend Hoek , Hans Michiel Huisman
发明人： Arend Hoek , Hans Michiel Huisman
IPC分类号： C07C27/00
CPC分类号： B01J8/0278 , B01J8/065 , B01J8/22 , B01J23/75 , B01J23/8472 , B01J23/8892 , B01J2208/00548 , B01J2219/00038 , C10G2/332 , C10G2/341 , C10G2/342
摘要： The present invention relates to a process for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle (i.e. between regenerations or between start-up with freshly loaded catalyst and the first regeneration) by catalytic conversion of synthesis gas in a multiple reactor arrangement comprising at least two parallel operating reactors containing a catalyst capable of converting synthesis gas to hydrocarbons, and each reactor having a different relative reaction rate, wherein synthesis gas is distributed to each reactor at a feed rate proportional to the relative reaction rate in the respective reactor. It further relates to a reactor arrangement suitable for operating the process according to the invention for producing normally gaseous, normally liquid and optionally normally solid hydrocarbons during a production cycle by catalytic conversion of synthesis gas comprising at least two parallel operating reactors, each containing a catalyst, wherein the reactors are connected to a common header for the distribution of synthesis gas to the reactors, and wherein the common header comprises a distribution means for selectively controlling the amount of synthesis gas fed to each reactor.
摘要翻译：本发明涉及在生产周期（即，在再生之间或在新鲜负载的催化剂的启动与第一次再生之间）中生产通常为气态的，通常为液体的和任选的常规固体烃的方法，其通过多次合成气的催化转化反应器装置包括至少两个并联的操作反应器，其包含能够将合成气转化为烃的催化剂，每个反应器具有不同的相对反应速率，其中合成气以与该反应器中的相对反应速率成正比的进料速率分配给每个反应器相应的反应器。本发明还涉及一种适用于操作根据本发明的方法的反应器装置，用于在生产循环期间通过催化转化包含至少两个平行操作反应器的催化转化来生产通常为气态的，通常为固体的烃，每个反应器含有催化剂，其中所述反应器连接到用于将合成气分配到所述反应器的公共集管，并且其中所述公共集管包括用于选择性地控制供给到每个反应器的合成气量的分配装置。

10. 发明申请

US20090018374A1 HYDROGENATION CATALYST AND USE THEREOF FOR HYDROGENATING FISCHER-TROPSCH ENDPRODUCTS 有权
标题翻译：氢化催化剂及其加氢脱硫催化剂产品的应用
公开(公告)号：US20090018374A1
公开(公告)日：2009-01-15
申请号：US12161634
申请日：2006-01-23
申请人： Focco Cornelis Bijlsma , Jan Lodewijk Maria Dierickx , Arend Hoek , Frans Joris Antonius Kellendonk , Anna Elisabeth Maria Oud
发明人： Focco Cornelis Bijlsma , Jan Lodewijk Maria Dierickx , Arend Hoek , Frans Joris Antonius Kellendonk , Anna Elisabeth Maria Oud
IPC分类号： B01J21/04 , C07C5/02 , C07B35/00
CPC分类号： B01J23/755 , B01J21/04 , B01J35/10 , B01J35/1061 , B01J35/1085 , B01J37/0205 , C10G2/332 , C10G3/45 , C10G3/50 , C10G45/00 , C10G45/06 , C10G45/12 , C10G2300/1022 , C10G2300/4018 , Y02P30/20
摘要： A hydrogenation catalyst particularly suitable for hydrogenating oxygenates in a hydrogenation unit of a Fischer-Tropsch plant is disclosed. A preferred embodiment comprises more than 5% and less than 20% nickel based on a wide pore alumina support. The catalyst successfully hydrogenates oxygenates which otherwise tend to poison a catalyst in a hydroconversion unit downstream. Moreover, the temperature at which the unwanted hydrogenolysis of long chain paraffins to methane occurs is higher for one catalyst disclosed herein than a comparable known catalyst. This allows the hydrogenation plant to operate at a higher temperature.
摘要翻译：公开了一种特别适用于在费 - 托工厂的氢化单元中氢化含氧化合物的氢化催化剂。优选的实施方案包括基于宽孔氧化铝载体的超过5％且小于20％的镍。催化剂成功地氢化含氧化合物，否则其倾向于在下游的加氢转化单元中毒催化剂。此外，与可比较的已知催化剂相比，长链烷烃对甲烷的不期望的氢解发生的温度比本文公开的一种催化剂更高。这允许氢化装置在较高的温度下运行。

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