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1. 发明授权

US06805788B1 Electrochemical impedance evaluation and inspection sensor 失效
标题翻译：电化学阻抗评估和检测传感器
公开(公告)号：US06805788B1
公开(公告)日：2004-10-19
申请号：US09113925
申请日：1998-07-10
申请人： Anuncia Gonzalez-Martin , Jinseong Kim , Dalibor Hodko , Carlos Salinas
发明人： Anuncia Gonzalez-Martin , Jinseong Kim , Dalibor Hodko , Carlos Salinas
IPC分类号： G01N2126
CPC分类号： G01N17/02
摘要： An apparatus for electrochemical impedance spectroscopy having a solid electrolyte is disclosed. The apparatus has a chamber made of an electronically insulating material, a solid electrolyte coupled to the chamber and an electrode disposed in the chamber. A biasing member is used to urge the electrode towards the solid electrolyte and urge the solid electrolyte toward the substrate. The solid electrolyte is designed to contact the surface to be tested directly with no corrosive or otherwise harmful effect to the surface. A method for the detection of corrosion in bare or coated metallic substrates is also provided.
摘要翻译：公开了一种具有固体电解质的电化学阻抗谱的装置。该装置具有由电子绝缘材料制成的室，耦合到室的固体电解质和设置在室中的电极。偏置构件用于将电极推向固体电解质并将固体电解质推向衬底。固体电解质被设计成直接接触要测试的表面，对表面没有腐蚀性或其他有害影响。还提供了用于检测裸露或涂覆的金属基底中的腐蚀的方法。

2. 发明授权

US6117337A Enhanced photocatalytic oxidation of organics using a porous titanium dioxide membrane 失效
标题翻译：使用多孔二氧化钛膜增强有机物的光催化氧化
公开(公告)号：US6117337A
公开(公告)日：2000-09-12
申请号：US96277
申请日：1998-06-11
申请人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Dalibor Hodko , Carlos Salinas
发明人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Dalibor Hodko , Carlos Salinas
IPC分类号： B01D53/86 , B01J8/00 , B01J19/12 , B01J19/24 , B01J35/00 , C01B3/38 , C02F1/30 , C02F1/32 , C02F1/467 , C02F1/72 , C02F1/78 , B01J19/08
CPC分类号： B01D53/864 , B01D53/8668 , B01J19/123 , B01J19/127 , B01J19/2415 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J8/009 , C01B3/38 , C02F1/325 , C02F1/725 , B01D2251/104 , B01D2251/106 , B01D2255/20707 , B01J2219/00067 , B01J2219/00144 , B01J2219/00162 , B01J2219/00164 , B01J2219/0883 , C02F1/4672 , C02F1/722 , C02F1/78 , C02F2101/303 , C02F2101/322 , C02F2101/363 , C02F2201/009 , C02F2201/3223 , C02F2201/328 , C02F2305/10 , Y02P20/52 , Y02W10/37
摘要： A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a unique two-phase or three-phase boundary system formed in each pore of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous oxidant, liquid contaminant, and solid semiconductor photocatalyst having a metal catalyst disposed thereon meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures.
摘要翻译：用于矿化水或空气中的有机污染物的方法和装置在光催化反应器中在TiO 2膜的每个孔中形成的独特的两相或三相边界系统中提供光化学氧化。在三相系统中，具有设置在其上的金属催化剂的气态氧化剂，液体污染物和固体半导体光催化剂满足并参与有效的氧化反应。多孔膜具有这样的孔，其中液体的弯月面从水的分子直径变化到毛细管的弯液面，导致比最近的已知反应器小几个数量级的扩散层。光催化反应器在环境温度和低压下有效运行。

3. 发明授权

US6136186A Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant 失效
公开(公告)号：US6136186A
公开(公告)日：2000-10-24
申请号：US115358
申请日：1998-07-14
申请人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Carlos Salinas
发明人： Anuncia Gonzalez-Martin , Oliver J. Murphy , Carlos Salinas
IPC分类号： B01D53/86 , B01J8/00 , B01J19/12 , B01J19/24 , B01J35/00 , C01B3/38 , C02F1/30 , C02F1/32 , C02F1/467 , C02F1/72 , C02F1/78 , B01J19/08
CPC分类号： B01J19/2415 , B01D53/864 , B01D53/8668 , B01J19/123 , B01J19/127 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J8/009 , C01B3/38 , C02F1/325 , C02F1/725 , B01D2251/104 , B01D2251/106 , B01D2255/20707 , B01J2219/00067 , B01J2219/00144 , B01J2219/00162 , B01J2219/00164 , B01J2219/0883 , C02F1/4672 , C02F1/722 , C02F1/78 , C02F2101/303 , C02F2101/322 , C02F2101/363 , C02F2201/009 , C02F2201/3223 , C02F2201/328 , C02F2305/10 , Y02P20/52 , Y02W10/37 , Y10S210/908
摘要： A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a two-phase or three-phase boundary system formed in the pores of a TiO.sub.2 membrane in a photocatalytic reactor. In the three-phase system, gaseous (liquid) oxidant, liquid (gaseous) contaminant, and solid semiconductor photocatalyst meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures. A packed-bed photoreactor using photocatalyst coated particles is also provided.

4. 发明授权

US06232010B1 Unitized barrier and flow control device for electrochemical reactors 有权
标题翻译：用于电化学反应器的单元化屏障和流量控制装置
公开(公告)号：US06232010B1
公开(公告)日：2001-05-15
申请号：US09307410
申请日：1999-05-08
申请人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng , Homayoun Moaddel
发明人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson , Dacong Weng , Homayoun Moaddel
IPC分类号： H01M486
CPC分类号： H01M8/0258 , H01M4/8605 , H01M4/9083 , H01M4/96 , H01M8/0202 , H01M8/0204 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0234 , H01M8/0239 , H01M8/0243 , H01M8/0245 , H01M8/0267 , H01M8/0297 , H01M8/241 , H01M2008/1095
摘要： The invention provides for reducing the number of parts and the number of interfaces found in certain types of chemical reactors, particularly in electrochemical reactors, and especially in the type or reactor known as a fuel cell or fuel cell stack. This reduction comes from the use of a unified structure that combines the functions normally carried out by several components in the unit, particularly by combining the functions of the gas distribution structure and the gas diffusion structure, the gas distribution structure and the gas barrier structure, or all three structures into a single, unitary, metallic part. This offers the advantages of simplified design, better performance, and lighter weight.
摘要翻译：本发明提供减少在某些类型的化学反应器中发现的部件数量和接头数量，特别是在电化学反应器中，特别是在称为燃料电池或燃料电池堆的型式或反应器中。这种减少来自使用将通常由单元中的几个部件执行的功能组合的统一结构，特别是通过组合气体分配结构和气体扩散结构，气体分配结构和气体阻隔结构的功能，或所有三种结构成为单一，单一的金属部分。这提供了简化设计，更好的性能和更轻的重量的优点。

5. 发明授权

US5958616A Membrane and electrode structure for methanol fuel cell 失效
标题翻译：甲醇燃料电池膜和电极结构
公开(公告)号：US5958616A
公开(公告)日：1999-09-28
申请号：US19733
申请日：1998-02-06
申请人： Carlos Salinas , Stanley F. Simpson , Oliver J. Murphy , Kryzysztof Franaszczuk , Homayoun Moaddel , Dacong Weng
发明人： Carlos Salinas , Stanley F. Simpson , Oliver J. Murphy , Kryzysztof Franaszczuk , Homayoun Moaddel , Dacong Weng
IPC分类号： H01M8/02 , H01M8/10 , H01M8/24 , H01M4/86
CPC分类号： H01M8/1093 , H01M8/0289 , H01M8/1023 , H01M8/1039 , H01M8/1065 , H01M2300/0082 , H01M8/1009 , H01M8/2455 , Y02P70/56
摘要： The invention provides devices and techniques for reducing or eliminating fuel crossover from the anode to the cathode in fuel cells using organic fuels. The invention particularly provides proton exchange membranes having passages or channels with or without a catalyst layer active for the electrochemical oxidation of a fuel. The invention reduces fuel crossover by providing void spaces within the membrane where the fuel may be sequestered as it diffuses through the membrane from the anode to the cathode. The sequestered fuel may be removed physically and/or electrochemically. The invention provides for physical removal of the sequestered fuel by means of flowing a gas stream or a liquid stream through the passages thus evacuating the fuel before it diffuses to the cathode. Electrochemical removal of the fuel involves coating the inner walls of the passages with a catalyst, electronically connecting the catalyst with the anode, and electrooxidation of the crossover fuel sequestered in contact with the catalyst which is active for this oxidation process.
摘要翻译：本发明提供了用于减少或消除使用有机燃料的燃料电池中从阳极到阴极的燃料交叉的装置和技术。本发明特别提供了具有或不具有用于燃料的电化学氧化活性的催化剂层的通道或通道的质子交换膜。本发明通过在膜内提供空隙来减少燃料交叉，其中燃料可以通过膜从阳极扩散到阴极而被隔离。隔离燃料可以物理和/或电化学去除。本发明提供了通过使气体流或液体流流过通道从而物理去除隔离燃料，从而在燃料扩散到阴极之前抽空燃料。燃料的电化学去除包括用催化剂涂覆通道的内壁，将催化剂与阳极电连接，并与与该氧化过程有活性的催化剂相接触的交换燃料电氧化。

6. 发明授权

US06562507B1 Unitized barrier and flow control device for electrochemical reactors 失效
标题翻译：用于电化学反应器的单元化屏障和流量控制装置
公开(公告)号：US06562507B1
公开(公告)日：2003-05-13
申请号：US09680377
申请日：2000-10-05
申请人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson
发明人： Alan J. Cisar , Oliver J. Murphy , King-Tsai Jeng , Carlos Salinas , Stan Simpson
IPC分类号： H01M486
CPC分类号： H01M8/0258 , H01M4/8605 , H01M4/9083 , H01M4/96 , H01M8/0202 , H01M8/0204 , H01M8/0206 , H01M8/0228 , H01M8/0232 , H01M8/0234 , H01M8/0239 , H01M8/0243 , H01M8/0245 , H01M8/0267 , H01M8/0297 , H01M8/241 , H01M2008/1095
摘要： The invention provides for reducing the number of parts and the number of interfaces found in certain types of chemical reactors, particularly in electrochemical reactors, and especially in the type or reactor known as a fuel cell or fuel cell stack This reduction comes from the use of a unified structure that combines the functions normally carried out by several components in the unit, particularly by combining the functions of the gas distribution structure and the gas diffusion structure, the gas distribution structure and the gas barrier structure, or all three structures into a single, unitary, metallic part. This offers the advantages of simplified design, better performance, and lighter weight.
摘要翻译：本发明提供减少在某些类型的化学反应器，特别是在电化学反应器中，特别是在称为燃料电池或燃料电池堆的类型或反应器中发现的界面的数量以及接触的数量。这种减少来自使用结合了通常由单元中的几个部件执行的功能的统一结构，特别是通过将气体分配结构和气体扩散结构，气体分布结构和气体阻隔结构的功能，或所有三种结构组合成单个一体，金属部分。这提供了简化设计，更好的性能和更轻的重量的优点。

7. 发明授权

US06409928B1 Photocatalytic oxidation of organics using a porous titanium dioxide membrane and an efficient oxidant 有权
标题翻译：使用多孔二氧化钛膜和有效的氧化剂对有机物进行光催化氧化
公开(公告)号：US06409928B1
公开(公告)日：2002-06-25
申请号：US09679891
申请日：2000-10-05
申请人： Anuncia Gonzalez , Oliver J. Murphy , Carlos Salinas
发明人： Anuncia Gonzalez , Oliver J. Murphy , Carlos Salinas
IPC分类号： C02F132
CPC分类号： B01J19/2415 , B01D53/864 , B01D53/8668 , B01D2251/104 , B01D2251/106 , B01D2255/20707 , B01J8/009 , B01J19/123 , B01J19/127 , B01J19/2475 , B01J35/002 , B01J35/004 , B01J2219/00067 , B01J2219/00144 , B01J2219/00162 , B01J2219/00164 , B01J2219/0883 , C01B3/38 , C02F1/325 , C02F1/4672 , C02F1/722 , C02F1/725 , C02F1/78 , C02F2101/303 , C02F2101/322 , C02F2101/363 , C02F2201/009 , C02F2201/3223 , C02F2201/328 , C02F2305/10 , Y02A20/212 , Y02P20/52 , Y02W10/37 , Y10S210/908
摘要： A method and apparatus for mineralizing organic contaminants in water or air provides photochemical oxidation in a two-phase or three-phase boundary system formed in the pores of a TiO2 membrane in a photocatalytic reactor. In the three-phase system, gaseous (liquid) oxidant, liquid (gaseous) contaminant, and solid semiconductor photocatalyst meet and engage in an efficient oxidation reaction. The porous membrane has pores which have a region wherein the meniscus of the liquid varies from the molecular diameter of water to that of a capillary tube resulting in a diffusion layer that is several orders of magnitude smaller than the closest known reactors. The photocatalytic reactor operates effectively at ambient temperature and low pressures. A packed-bed photoreactor using photocatalyst coated particles is also provided.
摘要翻译：在水或空气中矿化有机污染物的方法和装置在光催化反应器中在TiO 2膜的孔中形成的两相或三相边界系统中提供光化学氧化。在三相系统中，气体（液体）氧化剂，液体（气体）污染物和固体半导体光催化剂会聚并进行有效的氧化反应。多孔膜具有这样的孔，其中液体的弯月面从水的分子直径变化到毛细管的弯液面，导致比最近的已知反应器小几个数量级的扩散层。光催化反应器在环境温度和低压下有效运行。还提供了使用光催化剂涂覆的颗粒的填充床光反应器。

8. 发明授权

US06804949B2 Water sources for automotive devices 失效
标题翻译：汽车设备用水源
公开(公告)号：US06804949B2
公开(公告)日：2004-10-19
申请号：US10226361
申请日：2002-08-22
申请人： Craig C. Andrews , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy , A. John Appleby
发明人： Craig C. Andrews , Alan J. Cisar , Carlos Salinas , Oliver J. Murphy , A. John Appleby
IPC分类号： F01N300
CPC分类号： C25B15/08 , F01N2240/22 , F02B43/10 , F02B47/02 , F02B2043/106 , Y02T10/121 , Y02T10/32 , Y02T90/42
摘要： The present invention provides a self-replenishing liquid water source onboard an automobile for supplying liquid water to an electrolyzer, such as an on-board hydrogen generator useful for the suppression of unwanted emissions. While automobiles typically have water reservoirs resupplied by a person, the invention provides a passive means of water collection for reliable replenishment due to operations of the automobile itself. The invention provides condensate from the engine exhaust gas by cooling a region of the exhaust system using cooling fluid from the engine coolant system. The cooling fluid is circulated during a period following the engine cold start event when the heat load on the engine coolant system is low.
摘要翻译：本发明提供了一种用于向电解器供应液体水的汽车上的自补充液体水源，例如可用于抑制不期望的排放物的板上氢气发生器。虽然汽车通常具有由人员补充的储水器，但是由于汽车本身的操作，本发明提供了一种被动的水收集装置，用于可靠的补给。本发明通过使用来自发动机冷却剂系统的冷却流体冷却排气系统的区域来提供来自发动机废气的冷凝物。当发动机冷启动事件发动机冷却系统的热负荷低时，冷却液循环。

9. 发明授权

US6040072A Apparatus and method for compressing a stack of electrochemical cells 失效
标题翻译：用于压缩电化学电池堆的装置和方法
公开(公告)号：US6040072A
公开(公告)日：2000-03-21
申请号：US974384
申请日：1997-11-19
申请人： Oliver J. Murphy , Carlos Salinas , Alan J. Cisar
发明人： Oliver J. Murphy , Carlos Salinas , Alan J. Cisar
IPC分类号： C25B9/18 , H01M8/24
CPC分类号： C25B9/18 , H01M8/247
摘要： The present invention provides an apparatus and method for assembling an electrochemical cell stack, or an assemblage of components which need to be clamped together, especially where minimizing the size and weight of the clamping mechanism is advantageous. The invention encompasses combining a band or strap to transmit load to a plurality of components. A metal link is provided to apply greater tension to the band than could normally be achieved with the band alone. The invention may provide a band having a spiral screw clamp wherein the screw portion is used to apply and control tension in the band and the band is used to transmit the tension to a plurality of components. The invention also provides systems that improve the distribution of the force over a portion of the assembly, preferably the entire area of at least one face of the assembly. The invention encompasses a system with straps surrounding a fuel cell stack placed between two end plates, with raised ridges placed under the strapping system to concentrate the compressive force at selected points on the endplates. The invention also encompasses a device comprising an array of adjustable elements that control the distribution of the compressive load.
摘要翻译：本发明提供一种用于组装电化学电池堆的装置和方法，或需要夹紧在一起的组件的组合，特别是在最小化夹紧机构的尺寸和重量的情况下是有利的。本发明包括组合带或带以将负载传输到多个组件。提供金属连接件以对带宽施加比通常可以单独实现的带宽更大的张力。本发明可以提供具有螺旋螺旋夹具的带，其中螺钉部分用于施加和控制带中的张力，并且带用于将张力传递到多个部件。本发明还提供了改善组件部分上的力的分布的系统，优选组件的至少一个面的整个区域。本发明包括具有围绕放置在两个端板之间的燃料电池堆的带的系统，其具有放置在捆扎系统下方的凸脊，以将压缩力集中在端板上的选定点处。本发明还包括一种包括控制压缩载荷分布的可调元件阵列的装置。

10. 发明申请

US20090324452A1 HYDROGEN GENERATOR 失效
标题翻译：氢发电机
公开(公告)号：US20090324452A1
公开(公告)日：2009-12-31
申请号：US10845971
申请日：2004-05-14
申请人： Carlos Salinas , Alan Cisar , Eric Clarke , Oliver J. Murphy , Brad Fiebig
发明人： Carlos Salinas , Alan Cisar , Eric Clarke , Oliver J. Murphy , Brad Fiebig
IPC分类号： B01J8/00 , C01B6/00
CPC分类号： C01B3/065 , B01J4/001 , B01J4/02 , Y02E60/362
摘要： An apparatus and method apply water to a hydrogen-containing composition, such as a hydride, in the presence of a catalyst that promotes hydrolysis to generate hydrogen in a controlled manner. The amount of catalyst used can be carefully tailored so that the reaction rate is limited by the amount of catalyst present (passive control) or it can be sufficiently large so that the reaction is controlled by the rate of water addition (active control).
摘要翻译：一种装置和方法，在催化剂存在下，将水用于含氢组合物如氢化物，催化剂以受控的方式促进水解产生氢。可以仔细地调整所用催化剂的量，使得反应速度受到存在的催化剂量（被动控制）的限制，或者可以足够大以使反应受添加速率（主动控制）的控制。

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