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1. 发明授权

US4682468A Non-catalytic method for reducing the NO emissions of gas turbines 失效
标题翻译：用于减少燃气轮机NO排放的非催化方法
公开(公告)号：US4682468A
公开(公告)日：1987-07-28
申请号：US715120
申请日：1985-03-22
申请人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Richard K. Lyon
发明人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Richard K. Lyon
IPC分类号： B01D53/56 , F02C7/00
CPC分类号： B01D53/56
摘要： Disclosed is a method for non-catalytically reducing the amount of NO emitted from gas turbines. The method involves contacting condition effluents of the gas turbine with ammonia, replacing at least a portion of the secondary air used to dilute and cool the combustion effluents with an inert gas, such as exhaust gas from the gas turine. The temperature of the combustion effluents, the time between contacting the combustion effluents with ammonia and passage through the turbine blades, and the amount of ammonia employed is determined by the solution of the set of simultaneous equations derived from the kinetic model disclosed herein.
摘要翻译：公开了一种非催化还原从燃气轮机排出的NO的量的方法。该方法包括使燃气轮机的条件流出物与氨接触，用惰性气体（例如来自气体塔内的废气）代替用于稀释和冷却燃烧废水的至少一部分二次空气。燃烧废气的温度，接触燃烧废水与氨和通过涡轮叶片的时间之间的时间以及所使用的氨的量通过由本文公开的动力学模型导出的一组联立方程的解决方案来确定。

2. 发明授权

US4624840A Non-catalytic method for reducing the concentration of NO in combustion effluents by injection of ammonia at temperatures greater than about 1300.degree. K. 失效
标题翻译：通过在大于约1300°K的温度下注入氨来降低燃烧废水中NO的浓度的非催化方法。
公开(公告)号：US4624840A
公开(公告)日：1986-11-25
申请号：US714965
申请日：1985-03-22
申请人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Boyd E. Hurst , Richard K. Lyon
发明人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Boyd E. Hurst , Richard K. Lyon
IPC分类号： B01D53/56 , C01B21/00 , B01J8/00
CPC分类号： B01D53/56
摘要： Disclosed is a process for non-catalytically removing NO from combustion effluent streams at temperatures from about 1300.degree. K. to 1600.degree. K. by injecting ammonia into a combustion effluent stream at a point where the stream is cooling at a rate of at least about 250.degree. K./sec, wherein the amount of ammonia injected and its point of injection are determined by the solution of a set of simultaneous equations derived from the kinetic model of Table I hereof.
摘要翻译：公开了一种在约1300°至1600°K的温度下从燃烧流出物流中非催化除去NO的方法。通过在流以至少大约的速率冷却的时刻将氨注入燃烧流出物流中 250°K / sec，其中注入的氨的量及其注入点由通过表I的动力学模型导出的一组联立方程式的解决方案确定。

3. 发明授权

US4636370A Non-catalytic method for reducing the concentration of NO in combustion effluents by injection of ammonia at temperatures from about 975 degrees K. to 1300 degrees K. 失效
标题翻译：用于通过在约975摄氏度至1300度K的温度下注射氨来降低燃烧废气中的NO浓度的非催化方法。
公开(公告)号：US4636370A
公开(公告)日：1987-01-13
申请号：US715119
申请日：1985-03-22
申请人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Boyd E. Hurst , Richard K. Lyon
发明人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Boyd E. Hurst , Richard K. Lyon
IPC分类号： B01D53/56 , C01B21/00 , B01J8/00
CPC分类号： B01D53/56
摘要： Disclosed is a method for non-catalytically reducing the concentration of NO in combustion effluents by the injection of ammonia into an effluent stream where the stream is at a temperature from about 975.degree. K. to 1300.degree. K. More particularly, the amount of NH.sub.3 and its point of injection are determined by the solution of a set of simultaneous equations derived from the kinetic model disclosed herein. Particular benefits of the present invention occur when ammonia is injected into a cooling zone.
摘要翻译：公开了一种通过将氨注入流出物流中而在约975℃至1300℃的温度下非燃性降低燃烧废气中的NO浓度的方法。更具体地说，NH 3的量并且其注入点由通过本文公开的动力学模型导出的一组联立方程式的解决方案来确定。当将氨注入冷却区时，发生本发明的特别益处。

4. 发明授权

US4507269A Non-catalytic method for reducing the concentration of NO in combustion effluents by injection of ammonia at temperatures greater than about 1300 degree K 失效
标题翻译：通过在大于约1300度K的温度下注入氨来降低燃烧废水中的NO浓度的非催化方法
公开(公告)号：US4507269A
公开(公告)日：1985-03-26
申请号：US550398
申请日：1983-11-10
申请人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Boyd E. Hurst , Richard K. Lyon
发明人： Anthony M. Dean , Anthony J. DeGregoria , James E. Hardy , Boyd E. Hurst , Richard K. Lyon
IPC分类号： B01D53/56 , C01B21/00
CPC分类号： B01D53/56
摘要： Disclosed is a process for non-catalytically removing NO from combustion effluent streams at temperatures from about 1300.degree. K. to 1600.degree. K. by injecting ammonia immediately before or directly into a zone where the combustion effluent is cooling at a rate of at least about 250.degree. K.
摘要翻译：公开了一种在约1300°K至1600°K的温度下从燃烧流出物流中非催化除去NO的方法。通过在燃烧流出物以至少约 250°K

5. 发明授权

US06669917B2 Process for converting coal into fuel cell quality hydrogen and sequestration-ready carbon dioxide 失效
标题翻译：将煤转化为燃料电池质量的氢和封存的二氧化碳的方法
公开(公告)号：US06669917B2
公开(公告)日：2003-12-30
申请号：US09917801
申请日：2001-07-31
申请人： Richard K. Lyon
发明人： Richard K. Lyon
IPC分类号： C01B3120
CPC分类号： C10J3/725 , B01J8/0055 , B01J8/26 , B01J8/388 , B01J2208/00292 , B01J2208/00513 , B01J2208/025 , C01B3/56 , C01B2203/0425 , C01B2203/0475 , C10J3/463 , C10J3/56 , C10J2300/093 , C10J2300/0956 , C10J2300/0983 , C10J2300/0996 , C10J2300/16 , C10J2300/1646 , F23C2900/99008 , Y02C10/08 , Y02E20/346 , Y02P30/30
摘要： A process for burning coal to produce substantially pure hydrogen for use in fuel cells, together with “sequestration ready” carbon dioxide and a stream of oxygen depleted air for powering gas turbines, characterized by using a combination of two fluidized bed reactors and a third transfer line reactor, the first reactor being supplied with coal particles or “char” and fluidized with high temperature steam; the second reactor being fluidized with high temperature steam and the third reactor being fluidized by compressed air. Solids circulated among these three reactors include a mixture of materials containing calcium compounds (present as CaO, CaCO3 and mixtures thereof) and iron compounds (present as FeO, Fe2O3 and mixtures thereof). The coal is gasified by the steam in the presence of CaO to produce CaCO3 and relatively pure hydrogen for use in fuel cells per a CO2 acceptor process. Because only part of the coal char input to the first reactor is gasified to produce hydrogen, the remainder can be burned to supply thermal energy necessary to regenerate the CaCO3 back to CaO. Carbon in the middle bed fluidized bed reactor reacts with Fe2O3 in the third reactor and the temperature in the middle fluidized bed reactor is sufficiently high to decompose CaCO3 back into CaO.
摘要翻译：一种用于燃烧煤以生产用于燃料电池的基本上纯的氢的方法，以及“隔离准备好”的二氧化碳和用于为燃气轮机供电的耗氧空气流，其特征在于使用两个流化床反应器和第三次转移第一反应器供应煤颗粒或“炭”并用高温蒸汽流化; 第二反应器用高温蒸汽流化，第三反应器被压缩空气流化。在这三个反应器中循环的固体包括含有钙化合物（以CaO，CaCO 3及其混合物存在）和铁化合物（以FeO，Fe 2 O 3及其混合物存在）的材料的混合物。煤在CaO的存在下被蒸汽气化以产生CaCO 3和相对纯的氢气，用于每个CO2受体过程的燃料电池。由于仅输入到第一反应器的煤焦炭的一部分被气化以产生氢气，所以其余部分可被燃烧以提供再生CaCO3所需的热能回到CaO。中间床流化床反应器中的碳与第三反应器中的Fe 2 O 3反应，中流化床反应器中的温度足够高以将CaCO3分解成CaO。

6. 发明授权

US5339754A Method and apparatus for prevention of puffing by rotary kiln and other incinerators and combustion systems 失效
标题翻译：用于防止旋转窑和其他焚化炉和燃烧系统膨化的方法和装置
公开(公告)号：US5339754A
公开(公告)日：1994-08-23
申请号：US990880
申请日：1992-12-11
申请人： Richard K. Lyon
发明人： Richard K. Lyon
IPC分类号： B01D53/86 , B01J8/02 , C01B3/38 , F23C99/00 , F23G7/06 , F23G7/07 , F23J15/00
CPC分类号： F23G7/07 , B01D53/864 , B01D53/8668 , B01J8/0285 , C01B3/38 , C01B3/384 , F23C99/00 , F23G7/06 , B01J2208/00415 , C01B2203/0233 , C01B2203/0277 , C01B2203/0283 , C01B2203/04 , C01B2203/0495 , C01B2203/066 , C01B2203/0877 , C01B2203/1011 , C01B2203/1041 , C01B2203/1052 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/146 , C01B2203/1604 , C01B2203/1609 , C01B2203/169 , C01B2203/80 , F23C2900/99008 , F23M2900/13003 , Y02E20/346
摘要： A method and apparatus are provided for oxidizing unoxidized fuel in combustion systems in which the air and fuel are not completely and uniformly mixed, the average air fuel ratio being sufficient for complete oxidation, but portions not containing sufficient air for complete oxidation. A bed of a readily reducible metal oxide, the reduced form of this metal oxide being readily oxidized, is placed within the combustion system. The air and fuel are passed through the bed at an elevated temperature, the metal oxide oxidizing those portions not containing sufficient air for complete combustion, and then being reoxidized by those portions which contain more than sufficient air for complete combustion.
摘要翻译：提供了一种用于在燃烧系统中氧化未氧化燃料的方法和装置，其中空气和燃料不完全和均匀地混合，平均空燃比足以完全氧化，但是部分不含足够的空气用于完全氧化。容易还原的金属氧化物的床被放置在燃烧系统内，该金属氧化物的还原形式容易氧化。空气和燃料在升高的温度下通过床，金属氧化物氧化那些不足够的空气以完全燃烧的部分，然后被那些含有足够的空气以完全燃烧的部分再氧化。

7. 发明授权

US4051016A Fluid coking with H.sub.2 S addition 失效
标题翻译：流体焦化与H {HD 2 {B S添加
公开(公告)号：US4051016A
公开(公告)日：1977-09-27
申请号：US652761
申请日：1976-01-27
申请人： William J. Metrailer , Charles Rebick , Richard K. Lyon
发明人： William J. Metrailer , Charles Rebick , Richard K. Lyon
IPC分类号： C10B55/10 , C10G9/00 , C10G9/32
CPC分类号： C10G9/32 , C10B55/10 , C10G9/005 , C10G2400/26
摘要： A fluid coking process is provided in which a relatively large amount of hydrogen sulfide is added to the coker fluidizing gas. A preferred fluidizing gas is a mixture of hydrogen and hydrogen sulfide.
摘要翻译：提供了一种流化焦化方法，其中相对大量的硫化氢被加入到焦化器流化气体中。优选的流化气体是氢和硫化氢的混合物。

8. 发明授权

US06797253B2 Conversion of static sour natural gas to fuels and chemicals 有权
标题翻译：将静态酸性天然气转化为燃料和化学品
公开(公告)号：US06797253B2
公开(公告)日：2004-09-28
申请号：US09992004
申请日：2001-11-26
申请人： Richard K. Lyon
发明人： Richard K. Lyon
IPC分类号： C01B326
CPC分类号： C01B3/38 , C01B2203/0233 , C01B2203/0425 , C01B2203/043 , C01B2203/1241 , C01B2203/127
摘要： A new cost effective and thermally efficient process for converting nearly valueless resources, such as “static,” lower quality sour natural gas containing hydrogen sulfide, to useable fuels and chemicals, such as hydrogen, methanol and high cetane diesel fuel. The preferred method and apparatus can be used to treat conventional sour gas, i.e., gas having a ratio of H2S to CH4 of at least 0.1 moles and preferably of at least 0.33 moles/mole, using a reforming catalyst and a sulfur capture agent. The process nominally can be carried out using two reactors that repeatedly cycle reactants between two basic process steps—reforming, and air regeneration.
摘要翻译：将几乎无价值资源（例如“静态”，含硫化氢的低质量酸性天然气）转化为可用的燃料和化学物质（如氢气，甲醇和高十六烷值的柴油）的新型成本效益和热效率的过程。优选的方法和装置可用于使用重整催化剂和硫捕获剂来处理常规的酸性气体，即H 2 S与CH 4的比例为至少0.1摩尔，优选至少0.33摩尔/摩尔的气体。该方法名义上可以使用在两个基本工艺步骤（重整）和空气再生之间重复循环反应物的两个反应器进行。

9. 发明授权

US06475454B1 Thermally limited selective oxidation methods and apparatus 失效
标题翻译：热选择氧化方法和设备
公开(公告)号：US06475454B1
公开(公告)日：2002-11-05
申请号：US09231563
申请日：1999-01-14
申请人： Jerald A. Cole , Richard K. Lyon
发明人： Jerald A. Cole , Richard K. Lyon
IPC分类号： B01D1900
CPC分类号： C01B3/583 , B01D53/864 , C01B2203/044 , C01B2203/047
摘要： A method and apparatus are provided for selectively oxidizing carbon monoxide in the presence of hydrogen gas while leaving the hydrogen substantially unoxidized. This method utilizes a catalytic material, such as copper/copper oxide, silver/silver oxide, nickel/nickel oxide, and the higher and lower oxides of cerium, which in a more oxidized state is readily reduced by carbon monoxide and which in a more reduced state is readily oxidized by air. A carbon monoxide/hydrogen gas mixture and air are alternately contacted with the catalytic material, such that the carbon monoxide is selectively oxidized and the catalytic material is regenerated.
摘要翻译：提供了一种方法和装置，用于在氢气存在下选择性地氧化一氧化碳，同时使氢基本上未被氧化。该方法利用了铜/铜氧化物，银/氧化银，镍/镍氧化物等催化材料，以及铈的高级和低级氧化物，它们在氧化态更容易被一氧化碳还原，还原状态容易被空气氧化。一氧化碳/氢气混合物和空气与催化材料交替接触，使得一氧化碳被选择性氧化并且催化材料被再生。

10. 发明授权

US5509362A Method and apparatus for unmixed combustion as an alternative to fire 失效
标题翻译：用于混合燃烧作为火灾的替代品的方法和装置
公开(公告)号：US5509362A
公开(公告)日：1996-04-23
申请号：US270157
申请日：1994-06-30
申请人： Richard K. Lyon
发明人： Richard K. Lyon
IPC分类号： B01D53/86 , B01J8/02 , C01B3/38 , F23C99/00 , F23G7/06 , F23G7/07 , F23J11/00
CPC分类号： B01D53/864 , B01D53/8668 , B01J8/0285 , C01B3/38 , C01B3/384 , F23C99/00 , F23G7/06 , F23G7/07 , B01J2208/00415 , C01B2203/0233 , C01B2203/0277 , C01B2203/0283 , C01B2203/04 , C01B2203/0495 , C01B2203/066 , C01B2203/0877 , C01B2203/1011 , C01B2203/1041 , C01B2203/1052 , C01B2203/1082 , C01B2203/1223 , C01B2203/1241 , C01B2203/1247 , C01B2203/146 , C01B2203/1604 , C01B2203/1609 , C01B2203/169 , C01B2203/80 , F23C2900/99008 , F23M2900/13003 , Y02E20/346
摘要： Methods and apparatus are provided for combustion systems wherein fuel may be burned completely with use of air as the oxidant, without the necessity for completely mixing the fuel with the air before, during, or after the combustion process. A bed of readily reducible metal oxide, the reduced form of this metal oxide being readily oxidized, is placed within a combustion system. The air and fuel are contacted with the bed at an elevated temperature, with the metal oxide oxidizing the fuel and being regenerated by the air. In one embodiment, complete combustion of fuel occurs without complete mixing of fuel and air. In other embodiments fuel can be burned with little or no mixing with a the combustion process, or fuel can be burned with little or no mixing with air, before, during, or after the combustion process, thereby avoiding a number of disadvantages of such mixing.
摘要翻译：提供了用于燃烧系统的燃烧方法和装置，其中燃料可以通过使用空气作为氧化剂而完全燃烧，而不需要在燃烧过程之前，期间或之后完全混合燃料。将容易还原的金属氧化物床（该金属氧化物的还原形式容易氧化）置于燃烧系统内。空气和燃料在升高的温度下与床接触，金属氧化物氧化燃料并被空气再生。在一个实施例中，燃料的完全燃烧而不会完全混合燃料和空气。在其它实施例中，燃料可以与燃烧过程很少或不混合燃烧，或燃料在燃烧过程之前，期间或之后几乎不与空气混合燃烧，从而避免了这种混合的许多缺点。

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