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    • 1. 发明授权
    • Dye mixtures of fiber-reactive azo dyes and their use for dyeing
hydroxy-and/or carboxamido-containing fiber material
    • 纤维反应性偶氮染料的染料混合物及其用于染色含羟基和/或羧酰氨基的纤维材料的用途
    • US5779739A
    • 1998-07-14
    • US627937
    • 1996-03-28
    • Andreas Von Der EltzWerner Hubert RussBengt-Thomas Grobel
    • Andreas Von Der EltzWerner Hubert RussBengt-Thomas Grobel
    • C09B67/22D06P1/38D06P1/384
    • D06P1/38C09B67/0052
    • Dye mixtures of fiber-reactive azo dyes and their use for dyeing hydroxy- and/or carboxamido-containing fiber material Red-dyeing fiber-reactive phenylazoaminonaphthol dyes, yellow-dyeing fiber-reactive phenylazoaminobenzene dyes, blue-dyeing fiber-reactive copper formazan dyes and navy-dyeing fiber-reactive disazo dyes of the formulae (1) to (5) as claimed and defined in claim 1 are described which are suitable for dyeing hydroxy- and/or carboxamido-containing fiber material, such as cellulose fiber materials, wool and synthetic polyamide fibers individually or together or some of them together or as a mixture in trichromatic dyeing methods. During the dyeing process a definite hue within the color triangle can be obtained and kept constant by adding the individual dye solutions of the individual dyes and/or mixtures of some of the dyes in a controlled manner by means of the ATR measurement technique.
    • 纤维反应性偶氮染料的染料混合物及其用于染色含羟基和/或羧酰氨基的纤维材料的用途红色染色纤维反应性苯偶氮基萘酚染料,黄染色纤维反应性苯偶氮苯胺染料,蓝染色纤维反应性铜甲an染料 并描述了适用于染色含羟基和/或羧酰氨基的纤维材料如纤维素纤维材料的如权利要求1所述的式(1)至(5)的海军染色纤维反应性双偶氮染料, 羊毛和合成聚酰胺纤维单独或一起或其中一些在三色染色方法中一起或作为混合物。 在染色过程中,通过用ATR测量技术以受控的方式加入各种染料和/或一些染料的混合物,可以获得颜色三角形内的确定色调并保持恒定。
    • 4. 发明授权
    • Dye mixture, process for it's preparation and use thereof
    • 染料混合物,其制备方法及其用途
    • US6165231A
    • 2000-12-26
    • US436548
    • 1999-11-09
    • Bengt-Thomas GrobelChristian SchumacherMieke SchaffeldKarl KriegerDierk Rohrig
    • Bengt-Thomas GrobelChristian SchumacherMieke SchaffeldKarl KriegerDierk Rohrig
    • C09B29/36C09B62/51C09B67/22C09B67/24D06P1/382D06P1/384
    • C09B67/0052Y10S8/918
    • Described are dye mixtures comprising dyes containing a coupling component comprising a 1-(chlorotriazinyl)amino-3,6-disulfo-8-naphthol radical, the dye or dyes of the one group of dyes containing an optionally loweralkyl-, loweralkoxy-, halogen, sulfo- and/or carboxy-substituted phenylamino or naphthylamino radical attached to the chlorotriazine radical and possessing a diazo component comprising an optionally loweralkyl-, loweralkoxy-, sulfo- and/or carboxy-substituted phenyl radical which is substituted by a fiber-reactive group of the vinyl sulfone series, and the dye or dyes of the other group of dyes containing attached to the chlorotriazine radical a phenylamino radical whose phenyl is substituted by a fiber-reactive group of the vinyl sulfone series and may be substituted by lower alkyl, lower alkoxy, sulfo and/or carboxy, and possessing a diazo component comprising a radical of benzene or naphthalene which may in each case be optionally substituted by lower alkyl, lower alkoxy, halogen, sulfo and/Qr carboxy. The dye mixtures are useful for preparing a dyeings and prints on hydroxy and/or carboxamido-containing fiber material, for example cotton and viscose fibers, and also wool and synthetic polyamide fiber materials and afford strong fast dyeings having a red hue.
    • 描述了包含含有包含1-(氯代三嗪基)氨基-3,6-二磺基-8-萘酚基团的偶联组分的染料的染料混合物,所述一组染料的染料或染料含有任选的低级烷基 - 低级烷氧基 - 卤素 ,连接到氯三嗪基上的磺基和/或羧基取代的苯基氨基或萘基氨基,并且具有包含任选的低级烷基,低级烷氧基,磺基和/或羧基取代的苯基的重氮组分,其被纤维反应性 乙烯基砜系列的染料或染料,以及附着在氯代三嗪基上的另一组染料的染料或染料,苯基氨基被苯基被乙烯基砜系列的纤维反应性基团取代,并且可被低级烷基取代, 低级烷氧基,磺基和/或羧基,并且具有包含苯或萘基团的重氮组分,其可以在任何情况下任选被低级烷基,低级烷氧基 ,卤素,磺基和/或羧基。 染料混合物可用于在含羟基和/或羧酰胺的纤维材料(例如棉和粘胶纤维)以及羊毛和合成聚酰胺纤维材料上制备染色和印花,并提供具有红色色调的强烈快速染色。
    • 6. 发明授权
    • 1-hydroxy-2-pyridones, a process for their preparation, and medicaments
which contain them, and intermediates formed in the preparation of the
1-hydroxy-2-pyridones
    • 1-羟基-2-吡啶酮,其制备方法和含有它们的药物,以及在制备1-羟基-2-吡啶酮时形成的中间体
    • US4797409A
    • 1989-01-10
    • US038903
    • 1987-04-16
    • Gerhard LohausWalter DittmarHeinz HanelWolfgang RaetherDieter ReuschlingBengt-Thomas Grobel
    • Gerhard LohausWalter DittmarHeinz HanelWolfgang RaetherDieter ReuschlingBengt-Thomas Grobel
    • A61K31/44C07D213/89C07D309/38
    • C07D213/89C07D309/38
    • New 1-hydroxy-2-pyridones of the general formula I ##STR1## in which R.sup.1, R.sup.2 and R.sup.3, which are identical or different, denote hydrogen or lower alkyl having 1-4 carbon atoms, R.sup.1 and R.sup.3 preferably being hydrogen, and R.sup.2 preferably being methyl,X denotes S or, preferably, O,Y denotes hydrogen or up to 2 halogen atoms, namely chlorine and/or bromine,Z denotes a single bond or the bivalent radicals O, S, --CR.sub.2 -- (R=H or C.sub.1 -C.sub.4 -alkyl) or other 2-valent radicals with 2-10 carbon and, optionally, oxygen and/or sulfur atoms linked to form a chain, it being obligatory when the radicals contain 2 or more oxygen and/or sulfur atoms for the latter to be separated by at least 2 carbon atoms, and it being possible for 2 adjacent carbon atoms also to be linked together by a double bond, and the free valencies of the carbon atoms being saturated by H and/or C.sub.1 -C.sub.4 -alkyl groups,Ar denotes an aromatic ring system which has up to two rings and can be substituted by up to three radicals from the group comprising fluorine, chlorine, bromine, methoxy, C.sub.1 -C.sub.4 -alkyl, trifluoromethyl and trifluoromethoxy, are prepared by a variety of process variants. The compounds and their physiologically tolerated salts with inorganic or organic bases mainly have antimycotic, anti-bacterial and antiviral activity. The compounds of the formula V ##STR2## in which R.sup.1, R.sup.2, R.sup.3, X, Y, Z and Ar have the same meaning as in formula I, which occur in the preparation of the compounds of the formula I, are also new.
    • 通式I的新的1-羟基-2-吡啶酮其中R1,R2和R3相同或不同,表示氢或具有1-4个碳原子的低级烷基,R1和R3优选为氢, 并且R2优选为甲基,X表示S或优选O,Y表示氢或最多2个卤素原子,即氯和/或溴,Z表示单键或二价基团O,S,-CR 2 - (R = H或C 1 -C 4 - 烷基)或其它具有2-10个碳的任选的2-价基团和任选的连接形成链的氧和/或硫原子,当基团含有2个或更多个氧和/或 后者的硫原子被至少2个碳原子分开,并且可以通过双键将两个相邻的碳原子连接在一起,并且碳原子的自由价被H和/或C1饱和 -C4-烷基,Ar表示芳族环系,其具有多达两个环,并且可以被至少三个基团取代。 通过各种工艺变体制备氟,氯,溴,甲氧基,C 1 -C 4 - 烷基,三氟甲基和三氟甲氧基。 化合物及其与无机或有机碱的生理耐受盐主要具有抗真菌,抗细菌和抗病毒活性。 其中R 1,R 2,R 3,X,Y,Z和Ar具有与式I化合物相同的含义的式Ⅴ的化合物也是新的 。