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1. 发明授权

US07772320B2 High scratch-resistance and high elasticity coating materials based on alkoxysilane functional components 失效
标题翻译：基于烷氧基硅烷功能组分的高抗刮性和高弹性涂料
公开(公告)号：US07772320B2
公开(公告)日：2010-08-10
申请号：US11575979
申请日：2005-09-03
申请人： Andreas Poppe , Guenter Klein , Andre Brosseit , Karin Wermelt , Martina Mollers
发明人： Andreas Poppe , Guenter Klein , Andre Brosseit , Karin Wermelt , Martina Mollers
IPC分类号： C08L83/00
CPC分类号： C08G18/284 , C08G18/631 , C08G18/706 , C08L2666/02 , C09D175/06 , C09J133/04 , Y10T428/31663
摘要： A thermosetting coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material of (A1) from 0% to 50% by weight, based on the entirety of components (A1) and (A2), of a polymethacrylate copolymer containing more than 50% by weight, based on the entirety of comonomers in the copolymer (A1), of free-radically polymerizable, ethylenically unsaturated compounds (a1) containing at least one reactive group of the formula I —X—SiR″x(OR′)3-x (I) and (A2) from 50% to 100% by weight, based on the entirety of components (A1) and (A2), of an adduct of polyisocyanate and alkoxysilane, (A2) containing at least one reactive group of the formula II: —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II) (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要翻译：一种热固性涂料，其包含（A）至少50重量％，基于组合物（A1）和（A1）的总成分（A1）中（A1）的涂料中的非挥发性物质的量为0重量％至50重量％ A2），含有基于共聚物（A1）中共聚单体总共的50重量％以上的含有至少一个式I的反应性基团的可自由基聚合的烯属不饱和化合物（a1）的聚甲基丙烯酸酯共聚物 -X-SiR“x（OR'）3-x（I）和（A2）以组分（A1）和（A2）为基础的50％至100％重量的多异氰酸酯和烷氧基硅烷，（A2）含有至少一个式II的反应性基团：-NR-C（O）-N-（X-SiR“x（OR'）3-x）n（X'-SiR”y ）3-y）m（II）（B）用于交联-Si（OR'）3-x单元的催化剂，和（C）非质子溶剂或非质子溶剂的混合物。

2. 发明申请

US20080220173A1 Coating Agents Containing Adducts Having an Alkoxysilane Functionality 审中-公开
标题翻译：含有具有烷氧基硅烷功能的加合物的涂层剂
公开(公告)号：US20080220173A1
公开(公告)日：2008-09-11
申请号：US11575766
申请日：2005-09-03
申请人： Andreas Poppe , Elke Westhoff , Wilfried Stuebbe , Manuela Niemeier , Dunja Mikolajetz , Simone Hesener , Andre Brosseit , Karin Wermelt , Guenter Klein , Martina Moellers
发明人： Andreas Poppe , Elke Westhoff , Wilfried Stuebbe , Manuela Niemeier , Dunja Mikolajetz , Simone Hesener , Andre Brosseit , Karin Wermelt , Guenter Klein , Martina Moellers
IPC分类号： C09D175/04 , C08G18/80 , B05D1/36
CPC分类号： C08G18/792 , C08G18/222 , C08G18/809 , C09D175/00
摘要： The invention relates to a coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material, of at least one compound (A1) containing at least one reactive group of the formula(I) —NR—C(O)—N—(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (I) where R=hydrogen, alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, with Ra=alkyl, cycloalkyl, aryl or aralkyl, R′=hydrogen, alkyl or cycloalkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, X, X′=linear and/or branched alkylene or cycloalkylene radical of 2 to 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, n=0 to 2, m=0 to 2, m+n=2, and x, y=0 to 2, (B) a catalyst for the crosslinking of the —Si(OR′)3-X(y) units, and (C) an aprotic solvent or a mixture of aprotic solvents.
摘要翻译：本发明涉及一种涂料，其包含（A）至少一种含至少一种式（I）的反应性基团的化合物（A1）至少50重量％，基于涂料中不挥发物质的量， - NR-C（O）-N-（X-SiR“'X'（OR'）（X'-SiR“'Y'（OR'）3-y）m（I）＆lt; 3-x） line-formula description =“In-line Formulas”end =“tail”？>其中R =氢，烷基，环烷基，芳基或芳烷基，碳链不间断或不相邻的氧，硫或NRa基团中断，其中Ra = 烷基，芳基或芳烷基，R'=氢，烷基或环烷基，碳链不间断或不相邻的氧，硫或NR a基团，X，X'=线性和/或支链亚烷基或亚环烷基， 20个碳原子，R“=烷基，环烷基，芳基或芳烷基，碳链不间断或不相邻的氧，硫或NR a基团，n = 0〜2，m = 0〜2，m + n = 2，x，y = 0〜2，（B）-Si（OR' 3-X（y）单元，和（C）非质子溶剂或非质子溶剂的混合物。

3. 发明授权

US08603587B2 Coating agent containing addition compounds with silane functionality, and highly scratch-resistant coatings with improved crack resistance 有权
标题翻译：含有具有硅烷官能度的加成化合物和具有改善的抗裂性的高耐刮擦涂层的涂层剂
公开(公告)号：US08603587B2
公开(公告)日：2013-12-10
申请号：US12531342
申请日：2008-01-22
申请人： Andreas Poppe , Egon Wegner , Guenter Klein
发明人： Andreas Poppe , Egon Wegner , Guenter Klein
IPC分类号： B05D5/06
CPC分类号： C09D5/29 , C08G18/289 , C08G18/61 , C08G18/6254 , C08G18/792 , C08G18/809 , C08L75/12 , C09D143/04 , C09D175/04 , C08L2666/20 , C08L2666/16
摘要： Disclosed are coating compositions comprising film-forming material with at least one reactive functional group G′″, catalyst for the crosslinking of the silane groups, aprotic solvents, and at least one adduct with silane functionality which is prepared by an addition reaction of (a) at least one silane (S1) which has at least one functional group G′ which is reactive with the complementary functional groups G″ of the compound (O), and (b) at least one compound (O) which has at least one complementary functional group G″ and at least one surface-active radical. Also disclosed are multicoat paint systems in which the transparent coating has been produced from these coating compositions, methods of making and use, as well as methods of improving the hardness and/or the scratch resistance of coatings.
摘要翻译：公开了包含具有至少一个反应性官能团G“的成膜材料，用于硅烷基团交联的催化剂，非质子溶剂和至少一种与硅烷官能团的加合物的涂料组合物，其通过（ a）至少一种具有至少一个与化合物（O）的互补官能团G“反应的官能团G'的硅烷（S1），和（b）至少一种化合物（O）至少一个互补官能团G“和至少一个表面活性基团。还公开了多层涂料体系，其中由这些涂料组合物制备透明涂料，制备和使用方法，以及提高涂层硬度和/或耐划伤性的方法。

4. 发明授权

US08569438B2 Coating agents having high scratch resistance and weathering stability 有权
标题翻译：具有高耐刮擦性和耐候稳定性的涂层剂
公开(公告)号：US08569438B2
公开(公告)日：2013-10-29
申请号：US12519458
申请日：2007-12-19
申请人： Matthijs Groenewolt , Andreas Poppe , Guenter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stuebbe , Simone Hesener
发明人： Matthijs Groenewolt , Andreas Poppe , Guenter Klein , Manuela Niemeier , Elke Westhoff , Wilfried Stuebbe , Simone Hesener
IPC分类号： C08G77/08
CPC分类号： C09D175/14 , C08G18/289 , C08G18/6254 , C08G18/778 , C08G18/809 , C09D175/04
摘要： Disclosed are coating compositions comprising (a) at least one hydroxyl-containing compound (A), (b) at least one compound (B) having isocyanate groups, and (c) at least one catalyst (D) for the crosslinking of silane groups, said catalyst (D) comprising phosphorus. It is an aspect of the disclosed coating compositions that (i) one or more constituents of the coating composition contain hydrolyzable silane groups and (ii) the coating composition can be finally cured to a coating which has statistically distributed regions of an Si—O—Si network.
摘要翻译：公开了包含（a）至少一种含羟基化合物（A），（b）至少一种具有异氰酸酯基团的化合物（B）和（c）至少一种用于硅烷基团交联的催化剂（D），所述催化剂（D）包含磷。所公开的涂料组合物的一个方面是（i）涂料组合物中的一种或多种组分含有可水解的硅烷基团，和（ii）涂料组合物可以最终固化成具有统计分布的Si-O- Si网络。

5. 发明申请

US20080057207A1 Extremely Scratch-Resistant, Highly Elastic Coating Agents Based On Alkoxysilanes 失效
标题翻译：基于烷氧基硅烷的耐刮擦，高弹性涂层剂
公开(公告)号：US20080057207A1
公开(公告)日：2008-03-06
申请号：US11576347
申请日：2005-10-08
申请人： Andreas Poppe , Guenter Klein , Michael Kutschera
发明人： Andreas Poppe , Guenter Klein , Michael Kutschera
IPC分类号： B05D1/36 , C08G77/08
CPC分类号： C09D143/04
摘要： A coating material comprising (A) at least 50% by weight, based on the amount of nonvolatile substances in the coating material, of at least one compound (A1) and/or (A1′) containing at least two reactive groups of the formula I —X—SiR″x(OR′)3-x (I) where R′=hydrogen, alkyl or cycloalkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, where Ra alkyl, cycloalkyl, aryl or aralkyl, X=linear and/or branched alkylene or cycloalkylene radical having 2 to 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, the carbon chain being uninterrupted or interrupted by nonadjacent oxygen, sulfur or NRa groups, and x=0 to 2, (B) a catalyst for the crosslinking of the —Si(OR′)3-x units, and (C) an organic solvent or a mixture of organic solvents, the reactive groups (I) being crosslinked, in the course of curing of the coating material, such that nanoindentation testing on the cured coat results in the following properties: a. elastic volume recovery >86.5%, b. plastic deformation
摘要翻译：一种涂料，其包含（A）至少一种化合物（A1）和/或（A1'）占至少50重量％，基于涂料中不挥发物质的量，所述化合物（A1）和/或（A1'）含有至少两个式 I <？in-line-formula description =“In-line Formulas”end =“lead”？> - X-SiR“x”（OR'）3-x （I）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R'=氢，烷基或环烷基，碳链不间断或不相邻的氧，硫或NRa 基团，其中R a烷基，环烷基，芳基或芳烷基，X =具有2至20个碳原子的直链和/或支链亚烷基或亚环烷基，R“=烷基，环烷基，芳基或芳烷基，碳链不间断或被不相邻的氧，硫或NR a基团，x = 0至2，（B）用于交联-Si（OR'）3-x 单元的催化剂，和（C）有机溶剂或反应性基团（I）交联的有机溶剂的混合物他固化涂层材料的过程，使得固化涂层上的纳米压痕测试产生以下性能：a。弹性体积恢复> 86.5％，b。塑性变形<3.5％，c。脆性变形<10.0％。

6. 发明授权

US09371469B2 Coating agent compositions, coatings made therefrom and exhibiting high scratch resistance and good polishability, and use thereof 有权
标题翻译：涂层剂组合物，由其制成并具有高抗擦伤性和良好抛光性的涂层及其用途
公开(公告)号：US09371469B2
公开(公告)日：2016-06-21
申请号：US14124972
申请日：2012-05-23
申请人： Matthijs Groenewolt , Guenter Klein , Oliver Hilge , Berthold Austrup , Katharina Huebner
发明人： Matthijs Groenewolt , Guenter Klein , Oliver Hilge , Berthold Austrup , Katharina Huebner
IPC分类号： C09D183/08 , B05D1/38 , B05D1/36 , C09D175/04 , B05D7/00 , C08G18/62 , C08G18/79 , C08G18/28 , C08K5/521
CPC分类号： C09D175/04 , B05D7/53 , B05D7/56 , C08G18/289 , C08G18/6229 , C08G18/791 , C08K5/521 , Y10T428/31551
摘要： Compositions comprising (B1) at least one polyisocyanate-group-containing compound (B1) having free or blocked isocyanate groups and a cycloaliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, and (B2) at least one polyisocyanate-group-containing compound (B2) having free or blocked isocyanate groups and an acyclic, aliphatic polyisocyanate parent structure, and/or a polyisocyanate derived therefrom, where at least one of component (B1) and component (B2) comprise at least one structural unit selected from the group of structural unit (I) —NR—(X—SiR″x(OR′)3-x) (I), structural unit (II) —N(X—SiR″x(OR′)3-x)n(X′—SiR″y(OR′)3-y)m (II), and mixtures of two or more of the foregoing, wherein the compound (B1) is in an amount such that the binder fraction of the compound (B1) is between 5% and 45% by weight, based on the sum of the binder fraction of the compound (B1) and of the compound (B2), and the mixture of components (B1) and (B2) includes structural units (I) and structural units (II).
摘要翻译：包含（B1）至少一种具有游离或封闭的异氰酸酯基团的含异氰酸酯基的化合物（B1）和脂环族多异氰酸酯母体结构的组合物和/或由其衍生的多异氰酸酯和（B2）至少一种含有多异氰酸酯基团具有游离或封闭的异氰酸酯基团的化合物（B2）和非环状脂族多异氰酸酯母体结构和/或由其衍生的多异氰酸酯，其中组分（B1）和组分（B2）中的至少一种包含至少一种选自结构单元（I）-NR-（X-SiR“x（OR'）3-x）（I），结构单元（II）-N（X-SiR”x（OR'）3-x）n （X'-SiR“y（OR'）3-y）m（II）以及上述两种或更多种的混合物，其中化合物（B1）的量使得化合物（B1 ）为5〜45重量％，基于化合物（B1）和化合物（B2）的粘合剂组分和组分（B1 ）和（B2）包括结构单元（I）和结构单元（II）。

7. 发明申请

US20100253072A1 DETACHABLE PNEUMATIC CONNECTION 审中-公开
标题翻译：可拆卸气动连接
公开(公告)号：US20100253072A1
公开(公告)日：2010-10-07
申请号：US12664364
申请日：2008-06-13
申请人： Guenter Klein
发明人： Guenter Klein
IPC分类号： F16L33/00
CPC分类号： F16L33/227 , B60T17/043 , F16L37/0925 , F16L2201/30
摘要： A detachable pneumatic pipe or hose connection includes: a) a compressed-air-carrying body with an accommodating bore for a compressed air hose or pipe, the accommodating bore having a radially inner wedge section, b) an at least partially radially elastic clamping collet which surrounds the hose or pipe and which has a radially outer wedge section, c) the radially outer wedge section of the clamping collet interacting with the radially inner wedge section of the accommodating bore so that, by an axial movement of the clamping collet in one direction, the wedge sections can be braced against one another, and the clamping collet is elastically deformed, at least partially, radially inward to clamp the pipe or the hose frictionally and/or positively and so that, by an axial movement of the clamping collet in the opposite direction, the wedge sections can be moved away from one another, and the clamping collet is elastically deformed radially outward to cancel the clamping of the pipe or hose in the accommodating bore, in which d) the radially inner wedge section is molded directly to a wall of the accommodating bore and is constructed in one piece therewith.
摘要翻译：可拆卸气动管或软管连接件包括：a）具有用于压缩空气软管或管道的容纳孔的压缩空气携带体，所述容纳孔具有径向内部楔形部分，b）至少部分径向弹性的夹紧夹头其围绕软管或管道并且具有径向外部楔形部分，c）夹紧夹头的径向外部楔形部分与容纳孔的径向内部楔形部分相互作用，使得通过夹紧夹头在一个中的一个轴向运动楔形部分可以彼此支撑，并且夹紧夹头至少部分地径向向内弹性变形，以摩擦和/或正向地夹紧管或软管，使得通过夹紧夹头的轴向运动在相反方向上，楔形部分可以彼此远离地移动，并且夹紧夹头径向向外弹性变形以消除管子的夹紧或在容纳孔中的软管，其中d）径向内部楔形部分直接模制到容纳孔的壁上并且与其一体构成。

8. 发明授权

US07879407B2 Extremely scratch-resistant, highly elastic coating agents based on alkoxysilanes 失效
标题翻译：基于烷氧基硅烷的非常耐刮擦，高弹性的涂层剂
公开(公告)号：US07879407B2
公开(公告)日：2011-02-01
申请号：US11576347
申请日：2005-10-08
申请人： Andreas Poppeq , Guenter Klein , Michael Kutschera
发明人： Andreas Poppeq , Guenter Klein , Michael Kutschera
IPC分类号： B05D1/36 , C08G77/08
CPC分类号： C09D143/04
摘要： The invention relates to coating agents, containing (A) at least 50 wt. %, (in relation to the content of non-volatile substances in said coating agent), of at least one compound (A1) and/or (A1′) comprising at least two reactive groups of formula (I): —X—SiR″x(OR′)3-x, in which R′=hydrogen, alkyl or cycloalkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, Ra=alkyl, cycloalkyl, aryl or aralkyl, X=a linear and/or branched alkene or cycloalkene group comprising between 2 and 20 carbon atoms, R″=alkyl, cycloalkyl, aryl or aralkyl, whereby the carbon chain can be interrupted by non-adjacent oxygen, sulphur or NRa groups, and x=0 to 2, (B) a catalyst for cross-linking the —Si(OR′)3-x units, and (C) an organic solvent or a mixture of organic solvents. According to the invention, during the curing of the coating agents, the reactive groups (I) are cross-linked in such a way, that the following characteristics are noted during the nanoindentation test on the cured coating: elastic recovery of volume >86.5%; plastic deformation
摘要翻译：本发明涉及包含（A）至少50wt。至少一种包含至少两个式（I）的反应性基团的化合物（A1）和/或（A1'）：-X-SiR（相对于所述涂层剂中的非挥发性物质的含量） “x（OR'）3-x，其中R'=氢，烷基或环烷基，由此碳链可被非相邻的氧，硫或NR a基团中断，R a =烷基，环烷基，芳基或芳烷基，X =包含2至20个碳原子的直链和/或支链烯烃或环烯烃，R“=烷基，环烷基，芳基或芳烷基，由此碳链可以被不相邻的氧，硫或NRa基团中断，x = 0〜2，（B）交联-Si（OR'）3-x单元的催化剂，（C）有机溶剂或有机溶剂的混合物。根据本发明，在涂层剂固化期间，反应性基团（I）以这种方式交联，在固化涂层的纳米压痕测试中注意到以下特征：弹性恢复体积> 86.5％ ; 塑性变形<3.5％; 脆性变形<10.0％。

9. 发明授权

US4636225A Drying of gases with multi-layer adsorption beds 失效
标题翻译：用多层吸附床干燥气体
公开(公告)号：US4636225A
公开(公告)日：1987-01-13
申请号：US714736
申请日：1985-03-22
申请人： Guenter Klein , Hans-Juergen Wernicke
发明人： Guenter Klein , Hans-Juergen Wernicke
IPC分类号： B01D53/04 , B01D53/26
CPC分类号： B01D53/261 , B01D53/04 , B01D2253/108 , B01D2259/40086 , B01D2259/402
摘要： For drying a gaseous stream in thermally regenerable cyclically connected adsorbers wherein the gaseous stream contains components polymerizable under regeneration conditions, the bed is subdivided into several layers having different adsorbents. The first layer consists essentially of an adsorbent, e.g., zeolite type 4A, having a higher adsorption capacity for polymerizable compounds than the second layer, e.g., zeolite type 3A but with the second layer adsorbent being mechanically more stable than the first layer adsorbent.
摘要翻译：为了在可再热的循环连接的吸附器中干燥气流，其中气流含有在再生条件下可聚合的组分，床被细分为具有不同吸附剂的几层。第一层基本上由诸如沸石4A型的吸附剂组成，其具有比第二层更高的可聚合化合物的吸附能力，例如3A型沸石，但第二层吸附剂在机械上比第一层吸附剂更稳定。

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