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1. 发明授权

US06787596B1 Solvent-free polyrethane-polymer-hybrid-dispersion and use thereof 失效
标题翻译：无溶剂聚氨酯 - 聚合物 - 杂化分散体及其用途
公开(公告)号：US06787596B1
公开(公告)日：2004-09-07
申请号：US10110446
申请日：2002-04-11
申请人： Alois Maier , Stefan Ingrisch , Herbert Winkelmann , Franz Wolfertstetter , Alfred Kern , Werner Temme , Ralph Bergs
发明人： Alois Maier , Stefan Ingrisch , Herbert Winkelmann , Franz Wolfertstetter , Alfred Kern , Werner Temme , Ralph Bergs
IPC分类号： C08J300
CPC分类号： C09D175/04 , C08F283/006 , C08G18/0823 , C08G18/12 , C08G18/6692 , C08L51/08 , C09D151/08 , C08G18/3228
摘要： A solvent-free polyurethane-polymer hybrid dispersion having a high solids content of polymer or formulation constituents is described, which is obtainable by a) the multistage preparation of a polyurethane base dispersion and b) by the subsequent preparation of a polyurethane-polymer hybrid dispersion. This polyurethane-polymer hybrid dispersion not only is distinguished by complete freedom from solvents and high solids contents in combination with low viscosity and a technically simple preparation process but also has excellent mechanical properties and, owing to the low hydrophilicity, high water resistance. The polyurethane-polymer hybrid dispersion proposed according to the invention can be used in an outstanding manner in formulations for sport floor coverings, said dispersion being suitable in particular as a binder for resilient coats, as a spray or leveling coating on resilient or rigid substrates, as an adhesion promoter or primer, as filling compounds for sealing pores, as adhesive for the adhesive bonding of prefabricated resilient layers or for the sealing of sport floor coverings.
摘要翻译：描述了具有高固体含量的聚合物或配制成分的无溶剂的聚氨酯 - 聚合物混合分散体，其可通过以下方式获得：a）通过随后制备聚氨酯 - 聚合物混合分散体的聚氨酯基分散体的多阶段制备和b）。聚氨酯 - 聚合物混合分散体不仅通过完全不含溶剂和高固体含量与低粘度和技术上简单的制备方法相结合，而且具有优异的机械性能，并且由于亲水性低，耐水性高。根据本发明提出的聚氨酯 - 聚合物混合分散体可以以优异的方式用于运动地板覆盖物的配方中，所述分散体特别适用于弹性涂层的粘合剂，作为弹性或刚性基材上的喷涂或流平涂层，作为粘合促进剂或底漆，作为用于密封孔的填充化合物，作为用于预制弹性层的粘合剂粘合剂或用于运动地板覆盖物的密封的粘合剂。

2. 发明授权

US06566438B1 Hybrid polyurethane-polymer dispersion with high film hardness, method for the production and the use thereof 失效
标题翻译：具有高膜硬度的混合聚氨酯 - 聚合物分散体，其制备方法和用途
公开(公告)号：US06566438B1
公开(公告)日：2003-05-20
申请号：US09787939
申请日：2001-03-22
申请人： Stefan Ingrisch , Alois Maier , Herbert Winkelmann , Franz Wolfertstetter , Alfred Kern , Josef Weichmann
发明人： Stefan Ingrisch , Alois Maier , Herbert Winkelmann , Franz Wolfertstetter , Alfred Kern , Josef Weichmann
IPC分类号： C08J300
CPC分类号： C08G18/12 , C08G18/0823 , C08G2270/00 , C09D175/06 , C08G18/3228 , C08L33/00
摘要： Described is a polyurethane/polymer hybrid dispersion with high film hardness, which comprises the reaction components (A) from 3 to 25% by weight of a polyol component consisting of (i) from 2 to 20% by weight of a relatively high molecular mass polyol component, (ii) from 0.5 to 5% by weight of a low molecular mass polyol component, (iii) from 0.5 to 3% by weight of a low molecular mass and anionically modifiable polyol component, (B) from 2 to 20% by weight of a polyisocyanate component, (C) if desired, from 0 to 6% by weight of a solvent component consisting of (i) at least one polyisocyanate-inert organic solvent and/or (ii) a polyisocyanate-inert reactive diluent, (D) from 0.15 to 1.5% by weight of a neutralizing component, (E) from 0.1 to 1% by weight of a chain extender component, (F) from 5 to 40% by weight of a monomer component, (G) from 0.01 to 1.5% by weight of an initiator component, and water as the remainder. The advantages of the polyurethane/polymer hybrid dispersion of the invention, such as high hardness coupled with high flexibility of the crack-free films, good chemical resistance, great stability of the dispersion within a wide pH range, good freeze/thaw stability, and the use of inexpensive raw materials, are achieved in a simplified synthesis route, without subsequence chemical crosslinking, with a simultaneously low organic solvent content (≦4% by weight), and with good filming at temperatures ≦+10° C.
摘要翻译：描述了具有高膜硬度的聚氨酯/聚合物混合分散体，其包含3至25重量％的多元醇组分的反应组分（A），其由（i）2至20重量％的较高分子量多元醇组分，（ii）0.5至5重量％的低分子量多元醇组分，（iii）0.5至3重量％的低分子量和阴离子可修饰的多元醇组分，（B）2至20重量％重量的多异氰酸酯组分，（C）如果需要，0至6重量％的由（i）至少一种多异氰酸酯惰性有机溶剂和/或（ii）多异氰酸酯惰性反应性稀释剂组成的溶剂组分，（D）0.15〜1.5重量％的中和成分（E）0.1〜1重量％的增链剂成分（F）5〜40重量％的单体成分（G）来自 0.01〜1.5重量％的引发剂组分，余量为水。本发明的聚氨酯/聚合物混合分散体的优点例如高硬度，无裂纹膜的高柔韧性，良好的耐化学性，在宽的pH范围内的分散体的稳定性，良好的冷冻/融化稳定性和廉价原料的使用，在简化的合成路线，没有亚序列化学交联，同时低有机溶剂含量（<= 4重量％），并且在<= + 10℃的温度下具有良好的成膜性。

3. 发明授权

US06462127B1 Self-crosslinking polyurethane polymer hybrid dispersion 失效
标题翻译：自交联聚氨酯聚合物混合分散体
公开(公告)号：US06462127B1
公开(公告)日：2002-10-08
申请号：US09743116
申请日：2001-01-05
申请人： Stefan Ingrisch , Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Alfred Kern , Josef Weichmann
发明人： Stefan Ingrisch , Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Alfred Kern , Josef Weichmann
IPC分类号： C08J300
CPC分类号： C08G18/12 , C08F283/006 , C08G18/0823 , C08G18/6659 , C09D175/06 , C08G18/3228 , C08L2666/04
摘要： A self-crosslinking polyurethane polymer hybrid dispersion based on oxidatively drying polyols having a high degree of film hardness is described, which is characterized in that it contains the reaction components claimed. The advantages of the polyurethane polymer hybrid dispersion according to the invention, such as a high degree of hardness in combination with high flexibility of the tear-free films, good resistance to chemicals, high stability of the dispersions in a wide pH range, good stability in the freezing and thawing cycle and the use of economical raw materials, are achieved in a simplified synthesis pathway wityout subsequent chemical crosslinking, and simultaneously with a low content of organic solvent (≦4% by weight) and good film formation at temperatures of ≧+10° C.
摘要翻译：描述了一种基于氧化干燥具有高硬度膜的多元醇的自交联聚氨酯聚合物混合分散体，其特征在于其含有所要求的反应组分。根据本发明的聚氨酯聚合物混合分散体的优点，如硬度高，结合无撕裂膜的高柔性，耐化学性好，分散体在宽pH范围内的稳定性高，稳定性好在冷冻和解冻循环中使用经济的原料，在简化的合成途径中实现随后的化学交联，同时具有低含量的有机溶剂（<= 4重量％）和在 > = + 10°C

4. 发明申请

US20060183848A1 Self-crosslinking high-molecular polyurethane dispersion 审中-公开
标题翻译：自交联高分子量聚氨酯分散体
公开(公告)号：US20060183848A1
公开(公告)日：2006-08-17
申请号：US10565328
申请日：2004-07-29
申请人： Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Josef Weichmann , Alfred Kern
发明人： Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Josef Weichmann , Alfred Kern
IPC分类号： C08G18/08
CPC分类号： C09D175/14 , C08G18/0823 , C08G18/12 , C08G18/4288 , C08G18/6659 , C08G18/3228
摘要： The invention relates to a self-crosslinking, high-molecular polyurethane dispersion based on oxidatively drying diols and/or triols, and consisting of the reaction constituents (A) of an unsaturated fatty acid constituent for oxidative drying, (B) a polyol constituent, (C) a polyisocyanate constituent, (D) a solvent constituent, (E) a neutralisation constituent, (F) a siccative constituent, (G) a chain lengthening constituent, and water. The advantages of said polyurethane dispersion are the technically simple production thereof, whereby the properties of the polyurethane dispersion and the polyurethane films can be tailor-made by means of the polyol constituents, in addition to the excellent drying capacity thereof, and the other good application technology properties thereof such as hardness and chemical resistance during the use of the binding agent for high-grade lacquers and coatings.
摘要翻译：本发明涉及一种基于氧化干燥二醇和/或三醇的自交联高分子量聚氨酯分散体，由用于氧化干燥的不饱和脂肪酸组分的反应组分（A）组成，（B）多元醇组分，（C）多异氰酸酯成分，（D）溶剂成分，（E）中和成分，（F）消声成分，（G）链增长成分和水。所述聚氨酯分散体的优点是技术上简单的制备，除了优异的干燥能力以外，聚氨酯分散体和聚氨酯薄膜的性能可以通过多元醇成分定制，另外还有良好的应用在使用高级漆和涂料的粘合剂时，其技术性质如硬度和耐化学性。

5. 发明授权

US06635723B1 Solvent-free polyurethane dispersion 有权
标题翻译：无溶剂的聚氨酯分散体
公开(公告)号：US06635723B1
公开(公告)日：2003-10-21
申请号：US09623649
申请日：2000-10-30
申请人： Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Josef Weichmann , Alfred Kern
发明人： Alois Maier , Franz Wolfertstetter , Herbert Winkelmann , Josef Weichmann , Alfred Kern
IPC分类号： C08J300
CPC分类号： C09K3/1021 , C03C17/322 , C04B41/4884 , C08G18/0823 , C08G18/12 , C08G18/44 , C08G18/4854 , C08G18/6659 , C08G18/6692 , C09D175/08 , C08G18/3228 , C08G18/2865
摘要： A description is given of a solvent-free polyurethane dispersion having a high solids content of polyurethane polymer or fillers, which is obtainable by a) allowing a relatively high molecular weight polyol component (A) (i) and, if desired, a low molecular weight polyol component (A) (ii) to react with a polyisocyanate component (B) in the presence or absence of a catalyst to give a polyurethane preadduct, then b) reacting the polyurethane preadduct from step a) with a low molecular weight and anionically modifiable polyol component (A) (iii) containing two or more hydroxyl groups and one or more carboxyl groups to give the corresponding prepolymer, c) allowing the prepolymer from step b) to react with a neutralization component (C) until the carboxyl groups have been completely or partially neutralized, subsequently or simultaneously d) dispersing the neutralized prepolymer from step c) in water which may further comprise a formulation component (F) comprising fillers, pigments, plasticizers, fibrous materials and other customary additives, subsequently e) reacting the dispersion from step d) with a chain extension component (D), and f) if desired, allowing the dispersion from step e) to react with a chain stopper component (E). The polyurethane dispersion of the invention has an ideal linear segmented structure due to its method of preparation and has extraordinarily high solids contents combined with comparatively low viscosities, complete freedom from solvents, excellent materials properties (e.g. elasticity, elongation and tensile strength) and is prepared by a technically simple process.
摘要翻译：给出了具有高固体含量的聚氨酯聚合物或填料的无溶剂聚氨酯分散体的描述，其可通过以下方式获得：a）允许相对高分子量的多元醇组分（A）（i），并且如果需要，可以获得低分子量多元醇组分（A）（ⅱ）在催化剂存在或不存在下与多异氰酸酯组分（B）反应得到聚氨酯预加成物，然后b）使来自步骤a）的聚氨酯预加合物与低分子量和阴离子可修饰的多元醇含有两个或多个羟基和一个或多个羧基以得到相应的预聚物的组分（A）（iii），c）使来自步骤b）的预聚物与中和组分（C）反应，直到羧基完全或部分中和，随后或同时）将中和的预聚物从步骤c）分散在水中，其可以进一步包含配料组分（F），其包含填料，颜料，塑性使得步骤d）的分散体与链延伸组分（D）反应，和f）如果需要，使步骤e）的分散体与链终止组分（E）反应。由于其制备方法，本发明的聚氨酯分散体具有理想的线性分段结构，并且具有非常高的固体含量，结合相对低的粘度，完全不含溶剂，优异的材料性能（例如弹性，伸长率和拉伸强度），并通过技术上简单的工艺制备。

6. 发明授权

US06825268B2 Polyurethane (polymer hybrid) dispersion with reduced hydrophilicity, method for producing the same and the use thereof 失效
标题翻译：具有降低的亲水性的聚氨酯（聚合物混合物）分散体，其制备方法及其用途
公开(公告)号：US06825268B2
公开(公告)日：2004-11-30
申请号：US10220089
申请日：2002-11-26
申请人： Alois Maier , Norbert Steidl , Alfred Kern , Franz Wolfertstetter , Gerhard Reusmann , Frank Reichel
发明人： Alois Maier , Norbert Steidl , Alfred Kern , Franz Wolfertstetter , Gerhard Reusmann , Frank Reichel
IPC分类号： C08G1848
CPC分类号： C09D153/00 , C08G18/0823 , C08G18/12 , C08G18/4854 , C08G18/4879 , C08G18/6659 , C08L53/00 , C08L2666/02 , C09D175/04 , C09J153/00 , C08G18/3228 , C08L2666/14 , C08L2666/24
摘要： Polyurethane or polyurethane polymer hybrid dispersions, with reduced hydrophilicity and methods for preparing and using them are disclosed.
摘要翻译：公开了具有降低的亲水性的聚氨酯或聚氨酯聚合物混合分散体及其制备和使用方法。

7. 发明授权

US5789526A Highly viscous condensation products containing sulfonic acid groups based on amino-s-triazines 失效
标题翻译：含有基于氨基-s-三嗪的磺酸基的高粘度缩合产物
公开(公告)号：US5789526A
公开(公告)日：1998-08-04
申请号：US604852
申请日：1996-02-22
申请人： Josef Weichmann , Franz Wolfertstetter , Herbert Winkelmann , Alfred Kern
发明人： Josef Weichmann , Franz Wolfertstetter , Herbert Winkelmann , Alfred Kern
IPC分类号： C08G12/30 , B01F17/52 , C04B24/22 , C08G12/40
CPC分类号： C04B24/223 , C08G12/40
摘要： Disclosed is a highly viscous condensation product containing sulfonic acid groups based on amino-s-triazines with at least 2 amino groups and formaldehyde which has a viscosity of 500 to 100,000 cp at 20.degree. C. and a pH value of 8.0 to 13.0 as an aqueous solution with a solids content of 20% by weight. The product is obtainable by (a) condensation of amino-s-triazine, formaldehyde and sulfite in a molar ratio of 1:1.9 to 2.9:0.7 to 1.3 in aqueous solution at a pH value of 9.0 to 12.0 and a temperature of 50.degree. to 90.degree. C. until the sulfite is no longer detectable, and (b) subsequent further condensation at a pH value of 2.0 to 5.0 and a temperature of 50.degree. to 100.degree. C. until the viscosity exhibits the desired value.
摘要翻译：公开了一种高粘度的缩合产物，其含有基于具有至少2个氨基的氨基-s-三嗪和在20℃下具有500至100,000cp的粘度的甲酸和基于8.0至13.0的pH值为8.0至13.0的磺酸基固体含量为20重量％的水溶液。该产物可通过（a）在9.0至12.0的pH值和50℃的温度下，在水溶液中的摩尔比为1:1.9至2.9:0.7至1.3的氨基-s-三嗪，甲醛和亚硫酸盐的缩合获得。至90℃，直到亚硫酸盐不再可检测为止，（b）随后在2.0至5.0的pH值和50至100℃的温度下进一步冷凝，直至粘度显示所需值。

8. 发明授权

US06855764B2 Method for producing self- emulsifiable aqueous polyurethane resins having improved characteristics 失效
标题翻译：具有改进特性的自乳化水性聚氨酯树脂的制造方法
公开(公告)号：US06855764B2
公开(公告)日：2005-02-15
申请号：US10129291
申请日：2000-12-07
申请人： Alois Maier , Stefan Ingrisch , Alfred Kern
发明人： Alois Maier , Stefan Ingrisch , Alfred Kern
IPC分类号： C08G18/08 , C08G18/12 , C08G18/66 , C08J3/00 , C08K3/20 , C08L75/00
CPC分类号： C08G18/6674 , C08G18/0823 , C08G18/12 , C08G18/348
摘要： A method for producing self-emulsifiable, aqueous polyurethane resins by a) preparing a premix of polyol component including a least one diol having a molar mass of 500 to 5,000 Dalton, at least one polyhydroxyalkane at least one anionically modifiable dihydroxyalkane-carboxylic acid and 0 to 9 parts by weight of a solvent component in desired ratios; b) reacting a polyisocyanate component the premix from stage a) to give a polyurethane preadduct, c) reacting the polyurethane preadduct from stage b) with either the premix from stage a) or with an anionically modifiable dihydroxyalkanecarboxylic acid to give a polyurethane prepolymer; d) mixing the polyurethane prepolymer from stage c) with a prepared mixture of water, a neutralizing component and an antifoam component; and thereafter or simultaneously reacting the aqueous polyurethane prepolymer from stage d) with a chain-extending component which is diluted with water.
摘要翻译：一种制备自乳化的水性聚氨酯树脂的方法，该方法是：a）制备包含摩尔质量为500-5,000道尔顿的至少一种二醇的多元醇组分的预混物，至少一种聚羟基烷烃至少一种阴离子可修饰的二羟基烷烃羧酸和0 至9重量份的所需比例的溶剂组分; b）将多异氰酸酯组分与步骤a）的预混物反应得到聚氨酯预加成物，c）使来自阶段b）的聚氨酯预加合物与来自阶段a）的预混物或与阴离子可修饰的二羟基烷烃羧酸反应得到聚氨酯预聚物; d）将来自阶段c）的聚氨酯预聚物与制备的水，中和组分和消泡剂组分的混合物混合; 然后或同时使来自阶段d）的水性聚氨酯预聚物与用水稀释的链延伸组分反应。

9. 发明授权

US06893497B2 Use of water-soluble polysaccharide derivatives as dispersing agents for mineral binder suspensions 失效
标题翻译：使用水溶性多糖衍生物作为矿物粘合剂悬浮液的分散剂
公开(公告)号：US06893497B2
公开(公告)日：2005-05-17
申请号：US10472558
申请日：2002-03-21
申请人： Lars Einfeldt , Gerhard Albrecht , Alfred Kern , Matilde Calado Vieira , Dieter Klemm
发明人： Lars Einfeldt , Gerhard Albrecht , Alfred Kern , Matilde Calado Vieira , Dieter Klemm
IPC分类号： C04B24/16 , C04B24/38
CPC分类号： C04B24/383 , C04B24/168 , C04B2103/408
摘要： The invention concerns the use of water-soluble polysaccharide derivatives as dispersing agents for mineral binder suspensions. A partially hydrolyzed cellulose containing carboxyl groups and optionally hydroxyalkyl and/or sulfate groups and/or a partially hydrolyzed amylose-rich starch which also has sulfoalkyl groups with 1 to 4 carbon atoms is used as the polysaccharide derivative. These polysaccharide derivatives have a low viscosity and an excellent plasticizing effect in mineral binder suspensions, especially in those based on cement, lime and/or gypsum.
摘要翻译：本发明涉及使用水溶性多糖衍生物作为矿物粘合剂悬浮液的分散剂。作为多糖衍生物，使用含有羧基和任选的羟基烷基和/或硫酸基的部分水解纤维素和/或具有1-4个碳原子的具有磺基烷基的部分水解的直链淀粉。这些多糖衍生物在矿物粘合剂悬浮液中具有低粘度和优异的增塑效果，特别是在基于水泥，石灰和/或石膏的那些中。

10. 发明授权

US5595239A Heating, venting, and/or air conditioning unit 失效
标题翻译：加热，排气和/或空调机组
公开(公告)号：US5595239A
公开(公告)日：1997-01-21
申请号：US284355
申请日：1994-08-01
申请人： Hannes Wolf , Alfred Kern
发明人： Hannes Wolf , Alfred Kern
IPC分类号： B60H1/00 , F28F13/00
CPC分类号： B60H1/00378 , B60H2001/00235
摘要： A heating-venting-air conditioning unit for a cabin vehicle is positioned at the roof of the cabin vehicle. The unit has at least one blower having air channels connected to a suction side and a pressure side of the blower. At least one of the air channels is connected to the suction side to form a suction channel and at least one of the air channels is connected to the blower side to form an air distributing channel. At least one of the suction channel and the air distributing channel is comprised of two half-shells manufactured by a double deep-drawing process.
摘要翻译：用于客舱车辆的加热排气空调单元位于客舱车辆的顶部。该单元具有至少一个鼓风机，其具有连接到鼓风机的吸入侧和压力侧的空气通道。至少一个空气通道连接到吸入侧以形成吸入通道，并且至少一个空气通道连接到鼓风机侧以形成空气分配通道。抽吸通道和空气分配通道中的至少一个由双重深拉工艺制造的两个半壳组成。

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