专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明授权

US4524187A Isobutylene-triene copolymers cross-linkable under ambient humidity conditions, a process for their preparation, and intermediate suitable for this purpose 失效
标题翻译：异丁烯 - 三烯共聚物在环境湿度条件下可交联，其制备方法和适于此目的的中间体
公开(公告)号：US4524187A
公开(公告)日：1985-06-18
申请号：US448263
申请日：1982-12-09
申请人： Alberto Greco , Guglielmo Bertolini , Omero Zavattini
发明人： Alberto Greco , Guglielmo Bertolini , Omero Zavattini
IPC分类号： C08F8/42 , C08F210/10 , C08F236/22 , C08F8/34
CPC分类号： C08F236/22 , C08F210/10 , C08F8/42
摘要： Isobutylene copolymers, cross-linkable under ambient humidity conditions, characterized by the presence of pendant functions containing a silyl radical, are prepared by a process comprising the preliminary formation of new copolymers of isobutylene with a triene containing a system of two conjugate double bonds in position 1,3 and at least one other double bond of vinyl type, followed by the silylation of the polymers thus produced by means of a silicon derivative chosen from those of formula (I) or (II): ##STR1##
摘要翻译：在环境湿度条件下可交联的异丁烯共聚物，其特征在于含有甲硅烷基的侧链官能团的存在，通过包括初步形成异丁烯与含有两个共轭双键的系统的三烯的位置的新共聚物的方法制备 1,3和至少一种其它乙烯基类型的双键，然后通过选自式（I）或（II）的硅衍生物制备的聚合物甲硅烷化：

2. 发明授权

US4239873A Process for the polymerization of alpha-olefins, catalyst employed in said process and method for the preparation thereof 失效
标题翻译：用于α-烯烃聚合的方法，所述方法中使用的催化剂及其制备方法
公开(公告)号：US4239873A
公开(公告)日：1980-12-16
申请号：US863695
申请日：1977-12-23
申请人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
发明人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F110/00 , C08F4/02 , C08F10/02
CPC分类号： C08F110/00
摘要： An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (2) the combination product of a transition metal chloride and titanium trichloride, supported on a previously chlorinated material such as chlorinated .gamma.-alumina having a high superficial area.
摘要翻译：在由（1）属于周期性系统的前三组之一的金属的烷基卤化物，烷基衍生物或氢化物的催化剂体系的存在下聚合乙烯等α-烯烃，（2）过渡金属氯化物和三氯化钛的组合产物，负载在具有高表面积的预先氯化的材料如氯化γ-氧化铝上。

3. 发明授权

US4304729A Compounds formed by combining transition metal halides or oxyhalides, or aluminum chloride, with alkaline earth metal halides 失效
标题翻译：通过将过渡金属卤化物或卤氧化物或氯化铝与碱土金属卤化物组合形成的化合物
公开(公告)号：US4304729A
公开(公告)日：1981-12-08
申请号：US109532
申请日：1980-01-04
申请人： Alberto Greco , Guglielmo Bertolini , Gianfranco Pazienza
发明人： Alberto Greco , Guglielmo Bertolini , Gianfranco Pazienza
IPC分类号： C08F4/06 , C01G23/00 , C01G39/00 , C01G41/00 , C01G49/00 , C07F7/28 , C08F4/00 , C08F4/22 , C08F10/00
CPC分类号： C08F10/00 , Y10S526/904
摘要： Novel salt-like compounds adapted to be used as component of catalytic systems in the polymerization of ethylenically unsaturated monomers are disclosed: these compounds are obtained by reacting halides of transition metals or of aluminium with halides of alkaline earth metals, in the presence of phosphorous oxide derivatives which have the function of solvating agents. Also oxyhalides of transition metals lie within the scope of the invention.
摘要翻译：公开了适用于烯属不饱和单体聚合中催化体系的组分的新型盐类化合物：这些化合物是通过使过渡金属或铝的卤化物与碱土金属的卤化物在氧化磷存在下反应具有溶剂化作用的衍生物。过渡金属的卤氧化物也在本发明的范围内。

4. 发明授权

US4518766A Polyoxyalkylenediol-.alpha.,.omega.-bisallyl polycarbonate useful as a base for sealants and process for its preparation 失效
标题翻译：聚氧亚烷基二醇-α，ω-双烯丙基聚碳酸酯可用作密封剂的基料及其制备方法
公开(公告)号：US4518766A
公开(公告)日：1985-05-21
申请号：US576869
申请日：1984-02-03
申请人： Alberto Greco , Guglielmo Bertolini
发明人： Alberto Greco , Guglielmo Bertolini
IPC分类号： C08G63/00 , C08G64/00 , C08G64/02 , C08G64/18 , C08G64/20 , C08G64/30 , C08K5/54 , C09K3/10 , C08G63/62
CPC分类号： C09K3/10 , C08G64/183 , C08K5/54 , C09K2200/0645
摘要： For preparing polyoxyalkylenediol-.alpha.,.omega.-bisallyl policarbonates, diallyl carbonate is reacted in a first reaction stage with a polyoxyalkylenediol having a mol wt between 400 and 4500 in the presence of a transesterification catalyst at a temperature in the neighborhood of 100.degree. C. and under reduced pressures, whereafter, in a second reaction stage, the product as obtained from the first stage is treated at a temperature between 70.degree. C. and 150.degree. C. under reduced pressures, still in the presence of a transesterification catalyst. By so doing, the chain extension of the bisallyl carbonate of the polyoxyalkylenediol is achieved, whereas the unreacted diallyl carbonate coming from the first stage, and that produced in the second stage, are eliminated, and the final reaction product can thus be collected.
摘要翻译：为了制备聚氧亚烷基二醇-α，ω-双烯丙基聚碳酸酯，碳酸二烯丙酯在酯交换催化剂存在下，在100℃附近的温度下，在第一反应阶段与摩尔重量在400和4500之间的聚氧化烯二醇反应，在减压下，然后在第二反应阶段中，从70℃至150℃的温度下，将第一阶段得到的产物在酯交换催化剂的存在下进行处理。通过这样做，实现了聚氧化烯二醇的双烯丙基碳酸酯的链延长，而从第一阶段得到的未反应的二烯丙基碳酸酯和在第二阶段中产生的二烯丙基碳酸酯被除去，从而可以收集最终的反应产物。

5. 发明授权

US4333881A Process for reducing metal alkoxides, and the use of the compounds so obtained 失效
标题翻译：还原金属醇盐的方法，以及所得化合物的用途
公开(公告)号：US4333881A
公开(公告)日：1982-06-08
申请号：US124148
申请日：1980-02-25
申请人： Alberto Greco , Guglielmo Bertolini
发明人： Alberto Greco , Guglielmo Bertolini
IPC分类号： C08F4/00 , C07C29/68 , C07C31/28 , C07F7/00 , C07F7/28 , C07F9/00 , C07F9/90 , C07F9/92 , C07F11/00 , C08F4/60 , C08F4/619 , C08F4/62
CPC分类号： C08F4/62 , C07C29/685 , C08F10/02
摘要： Alkoxides of transition metals, selected from among tetravalent Ti, tetravalent and pentavalent V, tetravalent Cr and tetravalent Zr, actinides and lanthanides, are reduced to corresponding alkoxides of lower valency by reacting such higher valency metal alkoxides, in liquid phase, with vapors of metals of the alkaline earth group, the III group and the IV group metals and magnesium. Very efficient polymerization catalysts for the polymerization of unsaturated compounds are thus obtained.
摘要翻译：通过使这种较高价态的金属醇盐在液相中与金属的蒸气反应，将选自四价Ti，四价和五价V，四价Cr和四价Zr，锕系元素和镧系元素的过渡金属的碱金属还原成较低价的相应的醇盐的碱土金属，III族和IV族金属和镁。因此获得了用于不饱和化合物聚合的非常有效的聚合催化剂。

6. 发明授权

US4284526A Process for the polymerization of alpha-olefins, catalyst employed in said process and method for the preparation thereof 失效
标题翻译：用于α-烯烃聚合的方法，所述方法中使用的催化剂及其制备方法
公开(公告)号：US4284526A
公开(公告)日：1981-08-18
申请号：US148975
申请日：1980-05-12
申请人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
发明人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F110/00 , C08F4/02
CPC分类号： C08F110/00
摘要： An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (2) the combination product of a transition metal chloride and titanium trichloride, supported on a previously chlorinated material such as chlorinated .alpha.-alumina having a high superficial area.
摘要翻译：在由（1）属于周期性系统的前三组之一的金属的烷基卤化物，烷基衍生物或氢化物的催化剂体系的存在下聚合乙烯等α-烯烃，（2）过渡金属氯化物和三氯化钛的组合产物，负载在预先氯化的材料如具有高表面积的氯化α-氧化铝上。

7. 发明授权

US4151110A Alpha olefin polymerization catalyst comprising an alkyl halide and a combination product of TiCl.sub.3 and transition metal chloride of vanadium, manganese, cobalt or iron 失效
标题翻译：包含烷基卤和TiCl（hd 3 {b和钒，锰，钴或铁的过渡金属氯化物）的组合产物的α-烯烃聚合催化剂
公开(公告)号：US4151110A
公开(公告)日：1979-04-24
申请号：US781480
申请日：1977-03-25
申请人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
发明人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
IPC分类号： C08F4/00 , C08F4/60 , C08F4/64 , C08F110/00 , C08F4/02 , C08F4/68
CPC分类号： C08F110/00
摘要： An alpha-olefin such as ethylene is polymerized in the presence of a catalyst system consisting of (1) an alkyl-halide, alkyl-derivative or hydride of a metal belonging to one of the first three groups of the periodic system and (a) the combination product of a transition metal chloride and titanium trichloride said transition metal chloride being derived from the reaction of a transition metal carbonyl and titanium tetrachloride.
摘要翻译：在由（1）属于周期性系统的前三组之一的金属的烷基卤化物，烷基衍生物或氢化物的催化剂体系的存在下聚合α-烯烃，如（a）过渡金属氯化物和三氯化钛的组合产物表示过渡金属氯化物是由羰基过渡金属和四氯化钛的反应产生的。

8. 发明授权

US4037041A Process for the polymerization of alpha-olefins, catalyst employed in such a process and method for the preparation thereof 失效
标题翻译： α-烯烃聚合方法，用于该方法的催化剂及其制备方法
公开(公告)号：US4037041A
公开(公告)日：1977-07-19
申请号：US562800
申请日：1975-03-27
申请人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
发明人： Sebastiano Cesca , Alberto Greco , Guglielmo Bertolini , Mario Bruzzone
IPC分类号： C08F4/00 , C08F4/02 , C08F4/20 , C08F4/26 , C08F4/60 , C08F4/64 , C08F4/652 , C08F110/00 , C08F110/02 , C08F10/02
CPC分类号： C08F110/00
摘要： Ethylene is polymerized through the use of an improved catalyst system consisting of a carrier such as neodymium oxide having a high superficial area, an aluminum compound such as triisobutylaluminum and the combination product of titanium trichloride and an isostructural chloride of another transition metal prepared by impregnating the carrier with a solution of a carbonyl derivative of the other transition metal, refluxing the impregnated carrier with titanium tetrachloride until that carbonyl derivative is converted to the chloride of the other transition metal, and then removing the excess of titanium tetrachloride.
摘要翻译：乙烯通过使用由载体如高表面积的氧化钕，三异丁基铝等铝化合物和三氯化钛的组合产物和另一种过渡金属的结构氯化物组成的改进的催化剂体系进行聚合，所述过渡金属通过浸渍载体与其他过渡金属的羰基衍生物的溶液，使浸渍的载体与四氯化钛回流，直到羰基衍生物转化为其它过渡金属的氯化物，然后除去过量的四氯化钛。

9. 发明授权

US4948888A Process for the preparation of stabilizers for organic polymers 失效
标题翻译：制备有机聚合物稳定剂的方法
公开(公告)号：US4948888A
公开(公告)日：1990-08-14
申请号：US080259
申请日：1987-07-27
申请人： Alberto Greco , Luciano Pallini
发明人： Alberto Greco , Luciano Pallini
IPC分类号： C08K5/13 , C07F7/14 , C07F7/16 , C07F7/18 , C08G77/00 , C08G77/02 , C08K5/00 , C08K5/34 , C08K5/3412 , C08K5/35 , C08K5/5419 , C08K5/544 , C08L101/00
CPC分类号： C07F7/182 , C08K5/5419 , C08K5/5442
摘要： Stabilizers for organic polymers are disclosed, of the type of sterically hindered phenols or amines, which are obtained by means of the reaction of a sterically hindered phenol or amine bearing in the molecule at least in alkoxysilanol group with a mono- or poly-hydroxy aliphatic alcohol, by a transesterification reaction.The stabilizers so obtained are compatible with the organic polymers, wherein they remain stably.
摘要翻译：公开了用于有机聚合物的稳定剂，其是通过至少在烷氧基硅烷醇基团中的空间位阻酚或在轴承体中与单羟基或多羟基脂族基团反应得到的空间位阻酚或胺类型醇，通过酯交换反应。如此获得的稳定剂与有机聚合物相容，其中它们保持稳定。

10. 发明授权

US4684726A Reactive stabilizing compounds containing a sterically hindered amino group and a hydrolyzable silyl function 失效
标题翻译：含有空间位阻氨基和可水解甲硅烷基官能团的反应性稳定化合物
公开(公告)号：US4684726A
公开(公告)日：1987-08-04
申请号：US733526
申请日：1985-05-13
申请人： Alberto Greco , Carlo Busetto , Luigi Cassar , Carlo Neri
发明人： Alberto Greco , Carlo Busetto , Luigi Cassar , Carlo Neri
IPC分类号： C07D207/08 , C07D211/46 , C07D211/58 , C07D265/32 , C07F7/08 , C07F7/12 , C07F7/18 , C07F11/00 , C08F8/12 , C08F8/42 , C08K5/00 , C08K5/54 , C08K5/5419 , C08K5/544 , C08K5/548 , C08K9/12 , C08L7/00 , C08L21/00 , C08L23/00 , C08L101/00 , C07F7/10
CPC分类号： C07D207/08 , C07D211/46 , C07D211/58 , C07D265/32 , C07F7/0854 , C07F7/0896 , C07F7/12 , C07F7/182 , C08F8/42 , C08K5/5442 , C08K9/12
摘要： Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.According to a further embodiment, the reactive stabilizing compound is made to interact with the polymer so that the stabilizing compound becomes chemically bonded to the polymer chains.In all cases, stabilized polymers are obtained containing the stabilizing compound in a form which is not removable from the polymer.The processes for preparing the reactive stabilizing compounds and for preparing the stabilized polymer compositions are also described.
摘要翻译：能够稳定有机聚合物的反应性稳定化合物在其分子中含有空间位阻氨基和可水解的甲硅烷基官能团。在稳定有机聚合物中，所述反应性稳定化合物可以在甲硅烷基官能团下水解，形成硅烷醇基团，使其相互作用以形成复杂的树脂稳定结构。这些后者以稳定的量加入要稳定的聚合物中。根据一个具体实施方案，甲硅烷基官能团中的水解和树脂结构的形成在待稳定的聚合物内自发发生。根据另一个实施方案，将反应性稳定化合物通过与具有表面羟基的无机固体反应稳定地负载在固体载体上之后加入到聚合物中。根据另一个实施方案，使反应性稳定化合物与聚合物相互作用，使得稳定化合物变得化学键合到聚合物链上。在所有情况下，获得的稳定化聚合物含有不能从聚合物中除去的形式的稳定化合物。还描述了制备反应性稳定化合物和制备稳定化聚合物组合物的方法。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式