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1. 发明授权

US06864318B2 Thermoplastic compositions comprising a crosslinked phase 失效
标题翻译：包含交联相的热塑性组合物
公开(公告)号：US06864318B2
公开(公告)日：2005-03-08
申请号：US09384315
申请日：1999-08-27
申请人： Alain Bouilloux , Laurent Teze
发明人： Alain Bouilloux , Laurent Teze
IPC分类号： C08L63/00 , C08G59/20 , C08G59/42 , C08G59/52 , C08K5/00 , C08L33/06 , C08L67/00 , C08L67/02 , C08L69/00 , C08L77/00 , C08L77/06 , C08L23/08 , C08L63/02 , C08L67/03 , C08L77/02
CPC分类号： C08L77/00 , C08L67/02 , C08L77/06 , C08L23/00 , C08L2666/04 , C08L33/00
摘要： A composition comprising a thermoplastic polymer having incorporated therein a crosslinked phase derived from the reaction of: (A) a copolymer made from ethylene and an unsaturated epoxide, a polyolefin grafted with an unsaturated epoxide, or a product having two epoxide groups, (B) a copolymer made from ethylene and an unsaturated carboxylic acid anhydride, and (C) a copolymer made from an unsaturated carboxylic acid or an α,ω-aminocarboxylic acid.
摘要翻译：（A）由乙烯和不饱和环氧化物制得的共聚物，接枝有不饱和环氧化物的聚烯烃或具有两个环氧基的产物的组合物，（B）由乙烯和不饱和羧酸酐制成的共聚物，和（C）由不饱和羧酸或α，ω-氨基羧酸制得的共聚物。

2. 发明授权

US06203920B1 Flexible, polyamide-based compositions suitable for extrusion blow moulding 有权
标题翻译：适用于挤出吹塑的柔性聚酰胺基组合物
公开(公告)号：US06203920B1
公开(公告)日：2001-03-20
申请号：US09385433
申请日：1999-08-30
申请人： Alain Bouilloux , Laurent Teze
发明人： Alain Bouilloux , Laurent Teze
IPC分类号： B32B2302
CPC分类号： C08L77/06 , C08L77/00 , C08L77/12 , Y10T428/24777 , Y10T428/31511 , Y10T428/31725 , Y10T428/31728 , Y10T428/31739 , Y10T428/31855 , C08L23/00 , C08L2666/02 , C08L51/00
摘要： The invention relates to compositions comprising a matrix of an alloy of (a) polyamide and (b) polymer having polyamide blocks and polyether blocks, dispersed in which matrix is a crosslinked phase (c), the said compositions having a melt strength of more than 1.5 and a flexural modulus at 23° C. (in accordance with ISO 178-93) of less than 700 MPa and preferably between 50 and 250 MPa. Such a composition is useful for manufacturing extrusion blow-moulded parts, especially for cars. It also relates to articles additionally comprising a part made of polyamide and polyolefin or of a mixture of polyamide and polyolefin.
摘要翻译：本发明涉及包含（a）聚酰胺和（b）具有聚酰胺嵌段和聚醚嵌段的聚合物的基体的基体的组合物，其中基质是交联相（c），所述组合物的熔体强度大于 1.5和在23℃（根据ISO 178-93）的挠曲模量小于700MPa，优选在50和250MPa之间。这种组合物可用于制造挤出吹塑成型部件，特别是用于汽车。其还涉及另外包括由聚酰胺和聚烯烃或聚酰胺和聚烯烃的混合物制成的部件的制品。

3. 发明授权

US06368723B1 Films comprising metallocene polyethylene and polyamide 失效
标题翻译：包含茂金属聚乙烯和聚酰胺的薄膜
公开(公告)号：US06368723B1
公开(公告)日：2002-04-09
申请号：US09426721
申请日：1999-10-26
申请人： Alain Bouilloux , Laurent Teze , Jean-Marc Andre
发明人： Alain Bouilloux , Laurent Teze , Jean-Marc Andre
IPC分类号： C08L7700
CPC分类号： B32B27/08 , B32B27/32 , B32B27/34 , B32B2323/04 , B32B2377/00 , B32B2439/00 , C08J5/18 , C08J2377/00 , C08L23/0815 , C08L23/0869 , C08L77/00 , C08L77/02 , C08L77/06 , Y10T428/31746 , C08L2666/20 , C08L23/00
摘要： The present invention relates to a film comprising at least one layer (A) of a mixture of polyamide and polyethylene, and optionally a layer (B) of polyethylene, such that if the polyethylene, of the layer (A) is not a metallocene polyethylene then the layer (B) is obligatory and essentially consists of metallocene polyethylene. These films are used for the moulding of polyesters, for fumigation or for the manufacture of packaging.
摘要翻译：本发明涉及包含至少一层聚酰胺和聚乙烯的混合物层（A）和任选的聚乙烯层（B）的薄膜，使得如果层（A）的聚乙烯不是金属茂聚乙烯那么层（B）是必需的，并且基本上由茂金属聚乙烯组成。这些膜用于模制聚酯，用于熏蒸或用于制造包装。

4. 发明授权

US6025055A Flexible, polyamide-based compositions suitable for extrusion blow moulding 失效
标题翻译：适用于挤出吹塑的柔性聚酰胺基组合物
公开(公告)号：US6025055A
公开(公告)日：2000-02-15
申请号：US27564
申请日：1998-02-23
申请人： Alain Bouilloux , Laurent Teze
发明人： Alain Bouilloux , Laurent Teze
IPC分类号： C08L33/00 , C08L77/00 , C08L77/06 , C08L77/12 , B32B23/02 , B32B27/08
CPC分类号： C08L77/06 , C08L77/00 , C08L77/12 , Y10T428/24777 , Y10T428/31511 , Y10T428/31725 , Y10T428/31728 , Y10T428/31739 , Y10T428/31855
摘要： The invention relates to compositions comprising a matrix of an alloy of (a) polyamide and (b) polymer having polyamide blocks and polyether blocks, dispersed in which matrix is a crosslinked phase (c), the said compositions having a melt strength of more than 1.5 and a flexural modulus at 23.degree. C. (in accordance with ISO 178-93) of less than 700 MPa and preferably between 50 and 250 MPa.Such a composition is useful for manufacturing extrusion blow-moulded parts, especially for cars.It also relates to articles additionally comprising a part made of polyamide and polyolefin or of a mixture of polyamide and polyolefin.
摘要翻译：本发明涉及包含（a）聚酰胺和（b）具有聚酰胺嵌段和聚醚嵌段的聚合物的基体的基体的组合物，其中基质是交联相（c），所述组合物的熔体强度大于 1.5和在23℃（根据ISO 178-93）的挠曲模量小于700MPa，优选在50和250MPa之间。这种组合物可用于制造挤出吹塑成型部件，特别是用于汽车。它还涉及另外包括由聚酰胺和聚烯烃或聚酰胺和聚烯烃的混合物制成的部件的制品。

5. 发明授权

US06462129B1 Thermoplastic resin compositions comprising a rigid dispersed phase 失效
标题翻译：包含刚性分散相的热塑性树脂组合物
公开(公告)号：US06462129B1
公开(公告)日：2002-10-08
申请号：US09551406
申请日：2000-04-17
申请人： Denis Bertin , Alain Bouilloux , Laurent Teze , Thierry Vivier
发明人： Denis Bertin , Alain Bouilloux , Laurent Teze , Thierry Vivier
IPC分类号： C08F29100
CPC分类号： C08L77/00 , C08L77/02 , C08L77/06 , C08L101/00 , C08L33/00 , C08L51/00 , C08L2666/04
摘要： The invention relates to a thermoplastic composition comprising: a matrix-forming thermoplastic polymer (M), rigid nodules obtained by radical polymerization, and optionally an impact modifier (S). It also relates to a process comprising, in a first stage, forming a homogeneous solution of precursor of the nodules in the thermoplastic (M) in the molten state, in a second stage, introducing the initiator while remaining at a temperature below which the initiator becomes active, and, in a third stage, heating to a temperature sufficient to cause crosslinking of the precursor and to form rigid nodules while kneading the composition, the impact modifier being introduced during the first or the second stage.
摘要翻译：本发明涉及一种热塑性组合物，其包含：形成基质的热塑性聚合物（M），通过自由基聚合获得的刚性结节和任选的抗冲改性剂（S）。它还涉及一种方法，其包括在第一阶段中在熔融状态下在热塑性（M）中形成均匀的结核前体的溶液，在第二阶段中，引入引发剂，同时保持在低于该温度的引发剂并且在第三阶段中，加热至足以引起前体交联的温度，并在捏合组合物的同时形成刚性结节，所述抗冲改性剂在第一阶段或第二阶段期间被引入。

6. 发明授权

US08653192B2 Method for manufacturing a polyester composition having improved impact properties 失效
标题翻译：具有改善冲击性能的聚酯组合物的制造方法
公开(公告)号：US08653192B2
公开(公告)日：2014-02-18
申请号：US13383533
申请日：2010-07-13
申请人： Sebastien Quinebeche , Alexander Korzhenko , Alain Bouilloux , Stephane Girois
发明人： Sebastien Quinebeche , Alexander Korzhenko , Alain Bouilloux , Stephane Girois
IPC分类号： C08L67/04 , C08L67/03 , C08L63/00 , C08L33/12 , B29C47/10
CPC分类号： C08L67/04 , B29C47/385 , C08L23/0884 , C08L51/04 , C08L55/02 , C08L2666/02
摘要： A method for manufacturing a thermoplastic composition including: a polyester resin (c); a mixture including a copolymer (a) of an α-olefin and of a monomer having an ethylenic unsaturation and an epoxy function, as well as a core-shell compound (b); characterized in that said method includes a first step of manufacture the mixture of (a) and (b) by extrusion at a temperature at which the copolymer (a) is in the molten state and at a maximum temperature of 60 to 180° C.; a second step of manufacturing the thermoplastic composition by extrusion or by mixing the polyester resin (c) with the mixture of (a) and (b) produced in the first step.
摘要翻译：一种热塑性组合物的制造方法，其特征在于，包括：聚酯树脂（c）包含α-烯烃的共聚物（a）和具有烯属不饱和度和环氧官能团的单体以及核 - 壳化合物（b）的混合物; 其特征在于所述方法包括通过在共聚物（a）处于熔融状态和最高温度为60至180℃的温度下挤出制备（a）和（b）的混合物的第一步骤。 ; 通过挤出或通过将聚酯树脂（c）与在第一步骤中制备的（a）和（b）的混合物混合来制造热塑性组合物的第二步骤。

7. 发明授权

US06809151B1 Thermoplastic polyester compositions having improved impact properties 失效
标题翻译：热塑性聚酯组合物具有改进的冲击性能
公开(公告)号：US06809151B1
公开(公告)日：2004-10-26
申请号：US09718426
申请日：2000-11-24
申请人： Christophe Lacroix , Alain Bouilloux
发明人： Christophe Lacroix , Alain Bouilloux
IPC分类号： C08G6348
CPC分类号： C08L67/02 , C08L2666/02
摘要： The present invention relates to the thermoplastic polyesters, which comprise, by weight (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shelf copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-saturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 90/10 and 25/75 for proportions of impact modifier between 2 and 40% in 98 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 25/75 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively. It is particularly useful for PET and PBT.
摘要翻译：本发明涉及热塑性聚酯，其包含（i）热塑性聚酯;（ii）抗冲改性剂，其包含：（a）核 - 架共聚物（A）;（b）乙烯共聚物（B）选自乙烯 - 不饱和羧酸酐共聚物（B1），乙烯 - 饱和环氧化物共聚物（B2）及其共混物;（iii）（B）/（A）的比例为90/10至25/75，改性剂在98至60％的聚酯中分别为2至40％;（iv）（B）/（A）比为25/75至10/90，冲击改性剂的比例为82至82％ 60％的聚酯。它对PET和PBT特别有用。

8. 发明授权

US06759480B1 Thermoplastic resins modified by copolymers based on heavy acrylates 失效
标题翻译：基于重质丙烯酸酯的共聚物改性的热塑性树脂
公开(公告)号：US06759480B1
公开(公告)日：2004-07-06
申请号：US09670121
申请日：2000-09-26
申请人： Alain Bouilloux , Christophe Lacroix , Jean-Marc Le Blevec , Thibaut Montanari
发明人： Alain Bouilloux , Christophe Lacroix , Jean-Marc Le Blevec , Thibaut Montanari
IPC分类号： C08L2904
CPC分类号： C08L101/00 , C08L23/08 , C08L27/12 , C08L29/04 , C08L33/12 , C08L61/00 , C08L67/00 , C08L69/00 , C08L73/00 , C08L75/04 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/20 , C08L2666/04 , C08L23/00 , C08L33/00
摘要： The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.
摘要翻译：本发明涉及热塑性组合物，其包含：-40至97份形成基质的热塑性聚合物（M），其选自聚酰胺，聚酰胺嵌段共聚物，氟聚合物，聚碳酸酯，苯乙烯树脂，PMMA，热塑性聚氨酯（TPU），含有聚酯嵌段和聚醚嵌段，聚碳酸酯 - 聚酯合金，聚酮，PVC和乙烯 - 乙烯醇共聚物（EVOH）， - 60〜3份（B），包括：乙烯 - （甲基）丙烯酸烷基酯共聚物（B1）具有至少5个碳原子的烷基，该共聚物（B1）携带官能团或乙烯 - （甲基）丙烯酸烷基酯共聚物（B2），该共聚物（B2）不携带的具有至少5个碳原子的烷基的共混物官能团和带有官能团的抗冲改性剂。

9. 发明授权

US5965668A Polyamide injection mouldings which include an impact strength modifier that has a particular distribution in the polyamide 失效
标题翻译：聚酰胺注射成型品，其包括在聚酰胺中具有特定分布的冲击强度改性剂
公开(公告)号：US5965668A
公开(公告)日：1999-10-12
申请号：US843591
申请日：1997-04-16
申请人： Patrice Perret , Alain Bouilloux
发明人： Patrice Perret , Alain Bouilloux
IPC分类号： C08L33/06 , C08L63/00 , C08L77/00 , C08L77/02 , C08L77/06 , C08F37/16
CPC分类号： C08L77/00 , C08L77/02 , C08L77/06
摘要： The invention relates to impact-resistant injection mouldings based on polyamide resin (A) and on a disperse phase whose particles have a number-average diameter greater than 0.4 .mu.m, a volume-average diameter greater than 1 .mu.m and such that more than 50% by volume of the particles are larger than 1 .mu.mThe disperse phase may consist of a mixture including at least one copolymer (B) of ethylene and of an unsaturated epoxide and of at least one polyolefin (C).
摘要翻译：本发明涉及基于聚酰胺树脂（A）的抗冲击注塑成型体和分散相，其粒径的平均直径大于0.4μm，体积平均直径大于1μm， 50体积％的颗粒大于1μm分散相可以由包含至少一种乙烯和不饱和环氧化物的共聚物（B）和至少一种聚烯烃（C）的混合物组成。

10. 发明授权

US06576705B1 Thermoplastic resin composition and molded articles 失效
标题翻译：热塑性树脂组合物和模塑制品
公开(公告)号：US06576705B1
公开(公告)日：2003-06-10
申请号：US09117872
申请日：1999-02-09
申请人： Jerome Maillet , Takatoshi Kuratsuji , Alain Bouilloux , Yves Germain
发明人： Jerome Maillet , Takatoshi Kuratsuji , Alain Bouilloux , Yves Germain
IPC分类号： C08L6702
CPC分类号： C08L23/08 , C08L67/025 , C08L71/02 , C08L75/08 , C08L77/00 , C08L2205/08 , Y10T428/1331 , C08L2666/24 , C08L2666/18 , C08L2666/20 , C08L23/00 , C08L2666/04
摘要： The objective of the present invention lies in providing a resin composition which enables water vapor permeability to be controlled over a broad range while maintaining a high gas permeability, together with molded articles or packaging materials comprising said composition, in particular a packaging material for foodstuffs like fruit and vegetables. A thermoplastic resin composition which is characterized in that a polymer (A) containing polyether chains as structural units, polyethylene (B) of density as specified in JIS K6760 of less than 0.91 g/cm3 and a compatibilizing agent (C) are blended together in proportions by weight of A/B/C=99.5 to 0.5/0.5 to 99.5/0 to 30 (where A+B+C=100); and molded articles comprising said composition, in particular a packaging material for vegetables and fruit cultivation or foodstuffs storage.
摘要翻译：本发明的目的在于提供一种能够在保持高透气性的情况下在宽范围内控制水蒸气透过性的树脂组合物，以及包含所述组合物的成型制品或包装材料，特别是用于食品的包装材料水果和蔬菜。一种热塑性树脂组合物，其特征在于，含有作为结构单元的聚醚链的聚合物（A），JIS K6760规定的密度的聚乙烯（B）小于0.91g / cm 3，相容剂（C） A / B / C = 99.5〜0.5 / 0.5〜99.5 / 0〜30（A + B + C = 100）的重量比。以及包含所述组合物的模塑制品，特别是用于蔬菜和水果栽培或食品储存的包装材料。

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