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1. 发明授权

US06759480B1 Thermoplastic resins modified by copolymers based on heavy acrylates 失效
标题翻译：基于重质丙烯酸酯的共聚物改性的热塑性树脂
公开(公告)号：US06759480B1
公开(公告)日：2004-07-06
申请号：US09670121
申请日：2000-09-26
申请人： Alain Bouilloux , Christophe Lacroix , Jean-Marc Le Blevec , Thibaut Montanari
发明人： Alain Bouilloux , Christophe Lacroix , Jean-Marc Le Blevec , Thibaut Montanari
IPC分类号： C08L2904
CPC分类号： C08L101/00 , C08L23/08 , C08L27/12 , C08L29/04 , C08L33/12 , C08L61/00 , C08L67/00 , C08L69/00 , C08L73/00 , C08L75/04 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/20 , C08L2666/04 , C08L23/00 , C08L33/00
摘要： The invention relates to thermoplastic compositions comprising: −40 to 97 parts of a thermoplastic polymer (M) forming a matrix, chosen from polyamides, polyamide block copolymers, fluoro polymers, polycarbonate, styrene resins, PMMA, thermoplastic polyurethanes (TPU), copolymers containing polyester blocks and polyether blocks, polycarbonate-polyester alloys, polyketones, PVC and ethylene-vinyl alcohol copolymers (EVOH), −60 to 3 parts of (B) comprising: either an ethylene-alkyl (meth)acrylate copolymer (B1), the alkyl having at least 5 carbon atoms, which copolymer (B1) carries a functional group or a blend of an ethylene-alkyl (meth)acrylate copolymer (B2), the alkyl having at least 5 carbon atoms, which copolymer (B2) does not carry a functional group, and of an impact modifier which carries a functional group.
摘要翻译：本发明涉及热塑性组合物，其包含：-40至97份形成基质的热塑性聚合物（M），其选自聚酰胺，聚酰胺嵌段共聚物，氟聚合物，聚碳酸酯，苯乙烯树脂，PMMA，热塑性聚氨酯（TPU），含有聚酯嵌段和聚醚嵌段，聚碳酸酯 - 聚酯合金，聚酮，PVC和乙烯 - 乙烯醇共聚物（EVOH）， - 60〜3份（B），包括：乙烯 - （甲基）丙烯酸烷基酯共聚物（B1）具有至少5个碳原子的烷基，该共聚物（B1）携带官能团或乙烯 - （甲基）丙烯酸烷基酯共聚物（B2），该共聚物（B2）不携带的具有至少5个碳原子的烷基的共混物官能团和带有官能团的抗冲改性剂。

2. 发明申请

US20080182945A1 Mixtures Based on Thermoplastic Elastomers 有权
标题翻译：基于热塑性弹性体的混合物
公开(公告)号：US20080182945A1
公开(公告)日：2008-07-31
申请号：US11911219
申请日：2006-04-12
申请人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
发明人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
IPC分类号： C08L77/02
CPC分类号： C08L77/12 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/20
摘要： The invention relates to a mixture comprising by weight, to give a total of 100%, 99-10% a polyamide block and polyether block copolymer (A) predominantly consisting of lauryl lactam radicals, 1-99% at least one type of polymer (B) selected from polyamides other than polyamide 12, copolyamides which do not consist of the lauryl lactam radicals and the polyamide block and polyether block copolymers whose polyamide blocks do not predominantly consist of the lauryl lactam radicals. The articles, for example, films, foils, strings and tubes made from the inventive mixture are also disclosed.
摘要翻译：本发明涉及一种重量比的混合物，以总共100％，99-10％为主要由月桂基内酰胺基团组成的聚酰胺嵌段和聚醚嵌段共聚物（A），1-99％至少一种类型的聚合物 B）选自聚酰胺12以外的聚酰胺，不由月桂基内酰胺基团组成的共聚酰胺和聚酰胺嵌段和聚醚嵌段共聚物，其聚酰胺嵌段不主要由月桂基内酰胺基团组成。还公开了由本发明混合物制成的制品，例如薄膜，箔，线和管。

3. 发明申请

US20050228145A1 Polyamide 1/interlayer/polyamide 2 multilayer structures for decorated articles 审中-公开
标题翻译：聚酰胺1 /夹层/聚酰胺2多层结构用于装饰物品
公开(公告)号：US20050228145A1
公开(公告)日：2005-10-13
申请号：US11043817
申请日：2005-01-26
申请人： Christophe Lacroix , Thibaut Montanari
发明人： Christophe Lacroix , Thibaut Montanari
IPC分类号： A63C5/12 , B32B27/08 , C08G69/48
CPC分类号： B32B27/08 , A63C5/124 , B32B7/12 , B32B27/34 , B32B2307/554 , B32B2307/558 , B32B2307/71 , B32B2307/714 , B32B2377/00
摘要： The present invention relates to a transparent polyamide 1/interlayer/polyamide 2 multilayer structure manufactured by coextrusion. The invention also relates to a decorated article consisting of an object to which the above structure has been bonded, the polyamide 1 layer being on the outside. The bonding may be carried out by hot pressing or by using an adhesive.
摘要翻译：本发明涉及通过共挤出制造的透明聚酰胺1 /中间层/聚酰胺2多层结构体。本发明还涉及一种由上述结构粘合的物体组成的装饰物品，聚酰胺1层位于外侧。接合可以通过热压或使用粘合剂进行。

4. 发明授权

US07097908B2 Polyamide/polyurethane multilayer structures for decorated articles 有权
标题翻译：用于装饰物品的聚酰胺/聚氨酯多层结构
公开(公告)号：US07097908B2
公开(公告)日：2006-08-29
申请号：US10967587
申请日：2004-10-18
申请人： Christophe Lacroix , Thibaut Montanari
发明人： Christophe Lacroix , Thibaut Montanari
IPC分类号： B32B27/34 , B32B27/40 , B29C41/22
CPC分类号： B32B27/08 , A43B1/0027 , A63C5/003 , A63C5/12 , B32B27/18 , B32B27/34 , B32B27/40 , B32B2307/412 , B32B2437/02 , B44C1/105 , B44C1/1716 , Y10T428/31551 , Y10T428/31562 , Y10T428/31725 , Y10T428/31739
摘要： The present invention relates to a multilayer structure comprising a transparent polyamide-based layer and a layer based on a thermoplastic polyurethane (TPU). The invention also relates to a decorated article consisting of an object to which the above structure has been bonded, the polyamide layer being on the outside. According to another embodiment, the polyamide/TPU structures may be bonded to a polyurethane foam or to a polyurethane resin. It is also possible to overmould the polyurethane foam or the polyurethane resin to the polyamide/TPU structure placed in a mould, the polyamide layer being adjacent to the mould wall. The structure obtained is useful, for example for making skis or sports shoes. The invention also relates to these structures. Advantageously, the polyamide layer is semicrystalline. Advantageously, the TPU layer is transparent. Each of the layers may be formed from several layers.
摘要翻译：本发明涉及包含透明聚酰胺基层和基于热塑性聚氨酯（TPU）的层的多层结构。本发明还涉及一种由上述结构粘合的物体组成的装饰物品，聚酰胺层位于外侧。根据另一个实施方案，聚酰胺/ TPU结构可以结合到聚氨酯泡沫或聚氨酯树脂上。也可以将聚氨酯泡沫或聚氨酯树脂过模制到放置在模具中的聚酰胺/ TPU结构，聚酰胺层与模具壁相邻。获得的结构是有用的，例如用于制造滑雪板或运动鞋。本发明还涉及这些结构。有利地，聚酰胺层是半结晶的。有利地，TPU层是透明的。每个层可以由几层形成。

5. 发明申请

US20060014035A1 Polyamide-based multilayer structure for covering substrates 审中-公开
标题翻译：用于覆盖基材的聚酰胺基多层结构
公开(公告)号：US20060014035A1
公开(公告)日：2006-01-19
申请号：US11154420
申请日：2005-06-16
申请人： Thibaut Montanari , Christophe Lacroix , David Silagy , Jocelyn Mauffrey , Roparz Kervennal , Martin Baumert
发明人： Thibaut Montanari , Christophe Lacroix , David Silagy , Jocelyn Mauffrey , Roparz Kervennal , Martin Baumert
IPC分类号： B32B27/08
CPC分类号： B32B27/34 , Y10T428/31725
摘要： The present invention relates to a polyamide-based multilayer structure comprising in succession: an upper layer made of a transparent polyamide coming from the condensation: either of a lactam or of an α,Ω-amino acid having at least 9 carbon atoms or of a diamine and of a diacid, at least one having at least 9 carbon atoms; a lower layer capable of adhering to the substrate and optionally, an intermediate tie layer (also called a central layer) between the upper layer and the lower layer, each of the layers exhibiting thermomechanical behaviour (strength as a function of temperature) sufficiently similar to allow the structure to be easily formed under the effect of the temperature. The invention also relates to the objects consisting of these substrates covered with these structures, the lower layer being placed against the substrate.
摘要翻译：本发明涉及一种基于聚酰胺的多层结构体，它包括：由透明聚酰胺制成的上层，其由缩合物构成：内酰胺或具有至少9个碳原子的α，ω-氨基酸或二胺和二酸，至少一个具有至少9个碳原子; 能够粘附到基底和可选地在上层和下层之间的中间粘结层（也称为中心层）的下层，每个层具有热机械性能（强度作为温度的函数），足够类似于允许结构在温度的作用下容易地形成。本发明还涉及由这些结构覆盖的这些基底组成的物体，下层被放置在基底上。

6. 发明授权

US07718740B2 Mixtures based on thermoplastic elastomers 有权
标题翻译：基于热塑性弹性体的混合物
公开(公告)号：US07718740B2
公开(公告)日：2010-05-18
申请号：US11911219
申请日：2006-04-12
申请人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
发明人： Frederic Malet , Thibaut Montanari , Christophe Lacroix
IPC分类号： C08L77/00
CPC分类号： C08L77/12 , C08L77/00 , C08L77/02 , C08L77/06 , C08L2666/20
摘要： The invention relates to a mixture comprising by weight, to give a total of 100%, 99-10% a polyamide block and polyether block copolymer (A) predominately consisting of lauryl lactam radicals, 1-99% at least on type of polymer (B) selected from polyamides other than polyamide 12, copolyamides which do not consist of the lauryl lactam radicals and the polyamide block and polyether block copolymers whose polyamide blocks do not predominantly consist of the lauryl lactam radicals. The articles, for example, films, foils, strings and tubes made from the inventive mixture are also disclosed.
摘要翻译：本发明涉及一种包含重量比的混合物，以总共100％，99-10％为主要由月桂基内酰胺基团组成的聚酰胺嵌段和聚醚嵌段共聚物（A），1-99％的至少一种类型的聚合物 B）选自聚酰胺12以外的聚酰胺，不由月桂基内酰胺基团组成的共聚酰胺和聚酰胺嵌段和聚醚嵌段共聚物，其聚酰胺嵌段不主要由月桂基内酰胺基团组成。还公开了由本发明混合物制成的制品，例如薄膜，箔，线和管。

7. 发明申请

US20050084685A1 Polyamide/polyurethane multilayer structures for decorated articles 有权
标题翻译：用于装饰物品的聚酰胺/聚氨酯多层结构
公开(公告)号：US20050084685A1
公开(公告)日：2005-04-21
申请号：US10967587
申请日：2004-10-18
申请人： Christophe Lacroix , Thibaut Montanari
发明人： Christophe Lacroix , Thibaut Montanari
IPC分类号： A63C5/00 , A63C5/12 , B29C41/22 , B32B27/08 , B32B27/34 , B32B27/40 , B44C1/10 , B44C1/17 , B32B31/00
CPC分类号： B32B27/08 , A43B1/0027 , A63C5/003 , A63C5/12 , B32B27/18 , B32B27/34 , B32B27/40 , B32B2307/412 , B32B2437/02 , B44C1/105 , B44C1/1716 , Y10T428/31551 , Y10T428/31562 , Y10T428/31725 , Y10T428/31739
摘要： The present invention relates to a multilayer structure comprising a transparent polyamide-based layer and a layer based on a thermoplastic polyurethane (TPU). The invention also relates to a decorated article consisting of an object to which the above structure has been bonded, the polyamide layer being on the outside. According to another embodiment, the polyamide/TPU structures may be bonded to a polyurethane foam or to a polyurethane resin. It is also possible to overmould the polyurethane foam or the polyurethane resin to the polyamide/TPU structure placed in a mould, the polyamide layer being adjacent to the mould wall. The structure obtained is useful, for example for making skis or sports shoes. The invention also relates to these structures. Advantageously, the polyamide layer is semicrystalline. Advantageously, the TPU layer is transparent. Each of the layers may be formed from several layers.
摘要翻译：本发明涉及包含透明聚酰胺基层和基于热塑性聚氨酯（TPU）的层的多层结构。本发明还涉及一种由上述结构粘合的物体组成的装饰物品，聚酰胺层位于外侧。根据另一个实施方案，聚酰胺/ TPU结构可以结合到聚氨酯泡沫或聚氨酯树脂上。也可以将聚氨酯泡沫或聚氨酯树脂过模制到放置在模具中的聚酰胺/ TPU结构，聚酰胺层与模具壁相邻。获得的结构是有用的，例如用于制造滑雪板或运动鞋。本发明还涉及这些结构。有利地，聚酰胺层是半结晶的。有利地，TPU层是透明的。每个层可以由几层形成。

8. 发明授权

US06809151B1 Thermoplastic polyester compositions having improved impact properties 失效
标题翻译：热塑性聚酯组合物具有改进的冲击性能
公开(公告)号：US06809151B1
公开(公告)日：2004-10-26
申请号：US09718426
申请日：2000-11-24
申请人： Christophe Lacroix , Alain Bouilloux
发明人： Christophe Lacroix , Alain Bouilloux
IPC分类号： C08G6348
CPC分类号： C08L67/02 , C08L2666/02
摘要： The present invention relates to the thermoplastic polyesters, which comprise, by weight (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shelf copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-saturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 90/10 and 25/75 for proportions of impact modifier between 2 and 40% in 98 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 25/75 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively. It is particularly useful for PET and PBT.
摘要翻译：本发明涉及热塑性聚酯，其包含（i）热塑性聚酯;（ii）抗冲改性剂，其包含：（a）核 - 架共聚物（A）;（b）乙烯共聚物（B）选自乙烯 - 不饱和羧酸酐共聚物（B1），乙烯 - 饱和环氧化物共聚物（B2）及其共混物;（iii）（B）/（A）的比例为90/10至25/75，改性剂在98至60％的聚酯中分别为2至40％;（iv）（B）/（A）比为25/75至10/90，冲击改性剂的比例为82至82％ 60％的聚酯。它对PET和PBT特别有用。

9. 发明授权

US07119152B1 Thermoplastic polyester compositions having improved impact properties 失效
标题翻译：热塑性聚酯组合物具有改进的冲击性能
公开(公告)号：US07119152B1
公开(公告)日：2006-10-10
申请号：US09718427
申请日：2000-11-24
申请人： Christophe Lacroix , Alain Bouilloux
发明人： Christophe Lacroix , Alain Bouilloux
IPC分类号： C08L65/00
CPC分类号： C08L67/02 , Y10S525/902 , C08L2666/02
摘要： The present invention relates to thermoplastic polyesters, which comprise, by weight: (i) a thermoplastic polyester; (ii) an impact modifier comprising: (a) a core-shell copolymer (A); (b) an ethylene copolymer (B) chosen from ethylene-unsaturated carboxylic acid anhydride copolymers (B1), ethylene-unsaturated epoxide copolymers (B2) and blends thereof; (iii) the (B)/(A) ratio being between 40/60 and 10/90 for proportions of impact modifier between 18 and 40% in 82 to 60% of polyester, respectively; (iv) the (B)/(A) ratio being between 40/60 and 25/75 for proportions of impact modifier between 2 and 18% in 98 to 82% of polyester, respectively. It is particularly useful for PET and PBT.
摘要翻译：本发明涉及热塑性聚酯，其包含：（i）热塑性聚酯; （ii）抗冲改性剂，其包含：（a）核 - 壳共聚物（A）; （b）选自乙烯 - 不饱和羧酸酐共聚物（B1），乙烯 - 不饱和环氧化物共聚物（B2）及其共混物的乙烯共聚物（B）（iii）分别在82至60％的聚酯中，抗冲改性剂的比例为18至40％时，（B）/（A）的比率为40/60至10/90; （iv）分别在98至82％的聚酯中，抗冲改性剂的比例为2至18％时，（B）/（A）比为40/60至25/75。它对PET和PBT特别有用。

10. 发明授权

US07022768B1 Thermoplastic polyesters with improved shock-proof properties and impact modifying composition 失效
标题翻译：具有改善防震性能和改性组合物的热塑性聚酯
公开(公告)号：US07022768B1
公开(公告)日：2006-04-04
申请号：US10130993
申请日：2000-11-23
申请人： Christophe Lacroix , Alain Bouilloux , Claude Granel , Michael Tran
发明人： Christophe Lacroix , Alain Bouilloux , Claude Granel , Michael Tran
IPC分类号： C08L67/02
CPC分类号： C08L67/02 , C08L2666/02
摘要： The invention concerns thermoplastic polyesters (such as PET or PBT) comprising, by weight, the total being 100%: 60 to 99% of thermoplastic polyester; 1 to 40% of impact modifier comprising: (a) a core-shell copolymer (A), (b) an ethylene copolymer (B) selected among ethylene copolymers (B1) and an unsaturated carboxylic acid anhydride, ethylene copolymers (B2) and an unsaturated epoxy compound and mixtures thereof, (c) a copolymer (C) selected among ethylene copolymers (C1) and an alkyl (meth)acrylate, ethylene copolymers (C2) and (meth)acrylic acid optionally neutralised and mixtures thereof. The invention also concerns an impact modifying composition which can be added in thermoplastic polyesters to improve their shock-proof properties and comprising constituents (A), (B) and (C).
摘要翻译：本发明涉及热塑性聚酯（例如PET或PBT），其包含总重量为100％:60-99％的热塑性聚酯; 1〜40％的抗冲击改性剂，其包含：（a）核 - 壳共聚物（A），（b）选自乙烯共聚物（B1）和不饱和羧酸酐的乙烯共聚物（B），乙烯共聚物（B2）和不饱和环氧化合物及其混合物，（c）选自乙烯共聚物（C1）和（甲基）丙烯酸烷基酯，乙烯共聚物（C2）和（甲基）丙烯酸任选中和的共聚物（C）及其混合物。本发明还涉及可加入到热塑性聚酯中以改善其抗冲击性能并且包含组分（A），（B）和（C））的抗冲击改性组合物。

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